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Construction of New Chiral Skeletons Using by Catalytic Cycloaddition

Research Project

Project/Area Number 19350052
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Synthetic chemistry
Research InstitutionWaseda University

Principal Investigator

SHIBATA Takanori  Waseda University, 理工学術院, 教授 (80265735)

Project Period (FY) 2007 – 2009
Project Status Completed (Fiscal Year 2009)
Budget Amount *help
¥16,640,000 (Direct Cost: ¥12,800,000、Indirect Cost: ¥3,840,000)
Fiscal Year 2009: ¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2008: ¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2007: ¥7,670,000 (Direct Cost: ¥5,900,000、Indirect Cost: ¥1,770,000)
Keywords有機合成 / 遷移金属 / 錯体触媒 / 選択的合成・反応 / 有機金属触媒 / ファインケミカルズ / 不斉合成
Research Abstract

Transition metal catalyzed-reactions realize efficient and useful synthetic transformations. In particular, transition metals with chiral ligands can induce high enantioselectivity, and various types of chiral skeletons can be synthesized. I have focused on the development of chiral transition metal-catalyzed cycloadditions in this project. For example, consecutive inter- and intramolecular [2+2+2] cycloadditions of two o-phenylene-tethered triynes provided highly enantioselective synthesis of chiral substituted tetraphenylenes. The present protocol is a new and facile approach to the construction of chiral tetraphenylene skeleton. We also reported the enantioselective synthesis of the tripodal cage-type compounds with planar chirality. Intramolecular [2+2+2] cycloaddition of branched triynes, where diyne and alkyne moieties were connected by 2-aminophenol linkage, gave tripodal cyclophanes with almost perfect enantioselectivity.

Report

(5 results)
  • 2009 Annual Research Report   Self-evaluation Report ( PDF )   Final Research Report ( PDF )
  • 2008 Annual Research Report
  • 2007 Annual Research Report
  • Research Products

    (70 results)

All 2010 2009 2008 2007 Other

All Journal Article (24 results) (of which Peer Reviewed: 21 results) Presentation (42 results) Book (1 results) Remarks (3 results)

  • [Journal Article] Catalytic Enantioselective Synthesis of Chiral Tetraphenylenes : Consecutive Inter-and Intramolecular Cycloadditions of Two Triynes2009

    • Author(s)
      T.Shibata, T.Chiba, H.Hirashima, Y.Ueno, K.Endo
    • Journal Title

      Angew.Chem., Int.Ed. 48

      Pages: 8066-8069

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Enantioselective Synthesis of Chiral Tripodal Cage Compounds by [2+2+2] Cycloaddition of Branched Triynes2009

    • Author(s)
      T.Shibata, T.Uchiyama K.Endo
    • Journal Title

      Org.Lett. 11

      Pages: 3906-3908

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Catalytic Enantioselective Synthesis of Chiral Tetraphenylenes : Consecutive Inter- and Intramolecular Cycloadditions of Two Triynes2009

    • Author(s)
      Shibata, T.; Chiba, T.; Hirashima, H.; Ueno, Y.; Endo, K.
    • Journal Title

      Angew.Chem.Int.Ed. 48

      Pages: 8066-8069

    • Related Report
      2009 Self-evaluation Report
  • [Journal Article] Enantioselective Synthesis of Chiral Tripodal Cage Compounds by [2+2+2] Cycloaddition of Branched Triynes2009

    • Author(s)
      Shibata, T.; Uchiyama, T.; Endo, K.
    • Journal Title

      Org.Lett. 11

      Pages: 3906-3908

    • Related Report
      2009 Self-evaluation Report
  • [Journal Article] Enantioselective Synthesis of Chiral Tripodal Cage Compounds by[2+2+2]Cycloaddition of Branched Triynes2009

    • Author(s)
      T.Shibata, T.Uchiyama, K.Endo
    • Journal Title

      Org.Lett. 11

      Pages: 3906-3908

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Catalytic Enantioselective Synthesis of Chiral Tetraphenylenes : Consecutive Inter-and Intramolecular Cycloadditions of Two Triynes2009

    • Author(s)
      T.Shibata, T.Chiba, H.Hirashima, Y.Ueno, K.Endo
    • Journal Title

      Angew.Chem.Int.Ed. 48

      Pages: 8066-8069

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Recent Advances in Enantioselective [2+2+2] Cycloaddition2008

    • Author(s)
      T.Shibata, K.Tsuchikama
    • Journal Title

      Org.Biomol.Chem. 6

      Pages: 1317-1323

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] 触媒的不斉付加環化反応によるキラル環状化合物の合成2008

    • Author(s)
      柴田高範、土釜恭直
    • Journal Title

      ファインケミカル 5

      Pages: 55-67

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Iridium-Catalyzed Consecutive and Enantioselective [2+2+2] Cycloaddition of Tetraynes and Hexaynes for the Construction of Axially Chiral Biaryl System2008

    • Author(s)
      T.Shibata, S.Yoshida, Y.Arai, M.Otsuka, K.Endo
    • Journal Title

      Tetrahedron 64

      Pages: 821-830

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Rh-Catalyzed Intermolecular and Enantioselective [4+2] Cycloaddition of 1,3-Dienes with Dimethyl Acetylenedicarboxylate2008

    • Author(s)
      T.Shibata, D.Fujiwara, K.Endo
    • Journal Title

      Org.Biomol.Chem. 6

      Pages: 464-467

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Carbonylative and Hydrosilylative Carbocyclization of 1,5-Diynes for the Synthesis of Cyclic Dienones2008

    • Author(s)
      T.Shibata, N.Nakagawa, Y.Ueno, K.Endo
    • Journal Title

      Organometallics 27

      Pages: 1342-1344

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Enantioselective Syntheses of Various Chiral Multicyclic Compounds with Quaternary Carbon Stereocenters by Catalytic Intramolecular Cycloaddition2008

    • Author(s)
      T.Shibata, Y.Tahara, K.Tamura, K.Endo
    • Journal Title

      J.Am.Chem.Soc. 130

      Pages: 3451-3457

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Iridium-Catalyzed Enantioselective Formal [4+2] Cycloaddition of Biphenylene and Alkynes for the Construction of Axial Chirality2008

    • Author(s)
      T.Shibata, G.Nishizawa, K.Endo, K.Synlett
    • Journal Title

      Speciall issue

      Pages: 765-768

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Rhodium-Catalyzed Intramolecular Cycloaddition of Cyclopropene-Ynes Triggered by Carbon-Carbon bond Cleavage2008

    • Author(s)
      T.Shibata, S.Maekawa, K.Tamura
    • Journal Title

      Heterocycles 76

      Pages: 1261-1270

    • NAID

      40016323230

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Highly Diastereo- and Enantioselective Construction of Both Central and Axial Chiralities by Rh-Catalyzed [2+2+2] Cycloaddition2008

    • Author(s)
      T.Shibata, M.Otomo, Y.Tahara, K.Endo
    • Journal Title

      Org.Biomol.Chem. 6

      Pages: 4296-4298

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Enantioselective Syntheses of Various Chiral Multicyclic Compounds with Quaternary Carbon Stereocenters by Catalytic Intramolecular Cycloaddition2008

    • Author(s)
      Shibata, T.; Tahara, Y.; Tamura, K.; Endo, K.
    • Journal Title

      J.Am.Chem.Soc. 130

      Pages: 3451-3457

    • Related Report
      2009 Self-evaluation Report 2007 Annual Research Report
  • [Journal Article] Iridium-catalyzed enantioselective formal [4+2] cycloaddition of biphenylene and alkynes for the construction of axial ohirality2008

    • Author(s)
      Shibata, T., Nishizawa, G., Endo, K.
    • Journal Title

      Synlett 2008

      Pages: 765-768

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] lridium-catalyzed consecutive and enantioselective [2+2+2] cycloaddition of tetraynes and hexaynes for the construction of axially chiral biaryl system2008

    • Author(s)
      Shibata. T., Yoshida, S., Arai, Y., Otsuka, M., Endo, K.
    • Journal Title

      Tetrahedron 64

      Pages: 821-830

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Rhodium-catalyzed intramolecular cycloaddition of cyclopropene-ynes triggered by carbon-carbon bond cleavage2008

    • Author(s)
      Shibata, T., Maekawa, S, Tamura, K.
    • Journal Title

      Heterocycles 76

      Pages: 1261-1270

    • NAID

      40016323230

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Highly diastereo- and enantioselective construction of both central and axial chiralities by Rh-catalyzed [2+2+2] cycloaddition2008

    • Author(s)
      Shibata, T., Otomo, M., Tahara, Y., Endo, K.
    • Journal Title

      Org. Biomol. Chem. 6

      Pages: 4296-4298

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Rh-catalyzed intermolecular and Enantioselective [4+2] Cycloaddition of 1,3-Dienes with Dimethyl Acetylenedicarboxylate2008

    • Author(s)
      Shibata, T.; Fujiwara, D.; Endo, K.
    • Journal Title

      Org.Biomol.Chem. 6

      Pages: 464-467

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Carbonylative and Hydrosilylative Carbocyclization of 1,5-Diynes for the Synthesis of Cyclic Dienones2008

    • Author(s)
      Shibata, T.; Nakagawa, N.; Ueno, Y.; Endo, K.
    • Journal Title

      Organometallics 27

      Pages: 1342-1344

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Rhodium-Catalyzed Enantioselective [2+2+2] Cycloaddition of Diynes with Unfunctionalized Alkenes2007

    • Author(s)
      T.Shibata, A.Kawachi, M.Ogawa, Y.Kuwata, K.Tsuchikama, K.Endo
    • Journal Title

      Tetrahedron 63

      Pages: 12853-12859

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Rhodium-catalyzed enantioselective [2+2+2] cycloaddition of diynes with unfunctionalized alkene2007

    • Author(s)
      T.Shibata, A.Kawachi, M.Ogawa, Y.Kuwata, K.Tsuchikama, K.Endo.
    • Journal Title

      Tetrahedron 63

      Pages: 12853-12859

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Presentation] ジエンインの分子内[2+2+2]付加環化反応による連続する三不斉中心の創製2010

    • Author(s)
      大友麻由美, 遠藤恆平, 柴田高範
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      近畿大学、大阪、日本
    • Year and Date
      2010-03-28
    • Related Report
      2009 Annual Research Report
  • [Presentation] 触媒的不斉[2+2+2]付加環化反応によるキラルテトラフェニレン骨格の構築2010

    • Author(s)
      千羽達也, 平島裕之, 遠藤恆平, 柴田高範
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      近畿大学、大阪、日本
    • Year and Date
      2010-03-28
    • Related Report
      2009 Annual Research Report
  • [Presentation] 分子内[2+2+2]付加環化反応による三脚型かご型化合物のエナンチオ選択的合成2010

    • Author(s)
      内山理文, 遠藤恆平, 柴田高範
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      近畿大学、大阪、日本
    • Year and Date
      2010-03-28
    • Related Report
      2009 Annual Research Report
  • [Presentation] ジエンインの分子内[2+2+2]付加環化反応による連続する三不斉中心の創製2010

    • Author(s)
      大友麻由美・遠藤恆平・柴田高範
    • Organizer
      日本化学会第90春季年会(3F1-20)
    • Place of Presentation
      近畿大学
    • Related Report
      2009 Final Research Report
  • [Presentation] 触媒的不斉[2+2+2]付加環化反応によるキラルテトラフェニレン骨格の構築2010

    • Author(s)
      千羽達也・平島裕之・遠藤恆平・柴田高範
    • Organizer
      3F1-2
    • Place of Presentation
      近畿大学
    • Related Report
      2009 Final Research Report
  • [Presentation] 分子内[2+2+2]付加環化反応による三脚型かご型化合物のエナンチオ選択的合成2010

    • Author(s)
      内山理文・遠藤恆平・柴田高範
    • Place of Presentation
      近畿大学
    • Related Report
      2009 Final Research Report
  • [Presentation] Enantioselective Construction of New Cyclic Chiral Skeletons Using [2+2+2] Cycloaddition2009

    • Author(s)
      Shibata, T.
    • Organizer
      Catalysis and Fine Chemicals 2009
    • Place of Presentation
      高麗大学 (ソウル・韓国)
    • Year and Date
      2009-12-14
    • Related Report
      2009 Self-evaluation Report
  • [Presentation] Enantioselective Construction of New Cyclic Chiral Skeletons Using[2+2+2]Cycloaddition2009

    • Author(s)
      柴田高範
    • Organizer
      Catalysis and Fine Chemicals 2009
    • Place of Presentation
      高麗大学、ソウル、韓国
    • Year and Date
      2009-12-14
    • Related Report
      2009 Annual Research Report
  • [Presentation] Enantioselective[2+2+2]Cycloaddition of Branched Triynes for the Synthesis of Chiral Tripodal Cage Compounds2009

    • Author(s)
      内山理文, 遠藤恆平, 柴田高範
    • Organizer
      6th Symposium on Chemical Approaches to Chirality
    • Place of Presentation
      東京理科大学、東京、日本
    • Year and Date
      2009-11-25
    • Related Report
      2009 Annual Research Report
  • [Presentation] Enantioselective Synthesis of Chiral Multicyclic Compound by[2+2+2]Cycloaddition2009

    • Author(s)
      柴田高範
    • Organizer
      The Symposium on Chiral Science & Technology : Mesochemistry & Chemical Wisdom
    • Place of Presentation
      早稲田大学、東京、日本
    • Year and Date
      2009-09-24
    • Related Report
      2009 Annual Research Report
  • [Presentation] Enantioselective Construction of New Chiral Skeleton by[2+2+2]Cycloaddition2009

    • Author(s)
      柴田高範
    • Organizer
      The 238th ACS National Meeting
    • Place of Presentation
      ワシントン、米国
    • Year and Date
      2009-08-18
    • Related Report
      2009 Annual Research Report
  • [Presentation] Chiral Ir and Rh Complex-Catalyzed Cycloaddition for the Synthesis of Chiral Multicyclic Compounds2009

    • Author(s)
      T.Shibata, K.Tsuchikama
    • Organizer
      15th IUPAC International Symposium on Organometallic Chemistry Directed To wards Organic Synthesis(OMCOS 15)
    • Place of Presentation
      グラスゴー、英国
    • Year and Date
      2009-07-28
    • Related Report
      2009 Annual Research Report
  • [Presentation] Enantioselective Construction of New Cyclic Chiral Skeletons Using [2+2+2] Cycloaddition2009

    • Author(s)
      柴田高範
    • Organizer
      Catalysis and Fine Chemicals 2009
    • Place of Presentation
      Soul, Korea(招待講演)
    • Related Report
      2009 Final Research Report
  • [Presentation] Enantioselective construction of new chiral skeleton by [2+2+2] cycloaddition2009

    • Author(s)
      柴田高範
    • Organizer
      The 238th ACS National Meeting
    • Place of Presentation
      Washington, United States
    • Related Report
      2009 Final Research Report
  • [Presentation] Chiral Ir and Rh Complex-Catalyzed Cycloaddition for the Synthesis of Chiral Multicyclic Compounds2009

    • Author(s)
      T.Shibata, K.Tsuchikama
    • Organizer
      15th IUPAC International Symposium on Organometallic Chemistry Directed Towards Organic Synthesis (OMCOS 15)
    • Place of Presentation
      Glasgow, Scotland
    • Related Report
      2009 Final Research Report
  • [Presentation] Enantioselective Synthesis of Axially Chiral Polyaryls using Ir-catalyzed [2+2+2] Cycloaddition2009

    • Author(s)
      柴田高範
    • Organizer
      The Second Waseda-NTU Joint Symposium in Chemistry, Singapore
    • Place of Presentation
      Singapore(招待講演)
    • Related Report
      2009 Final Research Report
  • [Presentation] [2+2+2]付加環化反応によるキラル多環状化合物のエナンチオ選択的合成2009

    • Author(s)
      柴田高範
    • Organizer
      The Symposium on Chiral Science & Technology : Mesochemistry & Chemical Wisdom
    • Place of Presentation
      早稲田大学
    • Related Report
      2009 Final Research Report
  • [Presentation] 触媒的[2+2+2]付加環化反応を利用した中心不斉と軸不斉の同時創製2009

    • Author(s)
      大友麻由美・田原優樹・遠藤恆平・柴田高範
    • Organizer
      日本化学会第89春季年会日本大学(2F2-02)
    • Related Report
      2009 Final Research Report
  • [Presentation] Ir- and Rh-catalyzed Enantioselective Cycloadditions2008

    • Author(s)
      柴田 高範
    • Organizer
      Shanghai Institute of Organic Chemistry Chinese Academy of SciencesSeminar2008
    • Place of Presentation
      上海有機化学研究所
    • Year and Date
      2008-09-03
    • Related Report
      2008 Annual Research Report
  • [Presentation] Rh-Catalyzed Enantioselective Cycloaddition for the Synthesis of Chiral Multicyclic Compounds2008

    • Author(s)
      柴田 高範
    • Organizer
      International Conference on Organometallic Chemistry
    • Place of Presentation
      レンヌ大学(仏)
    • Year and Date
      2008-07-18
    • Related Report
      2008 Annual Research Report
  • [Presentation] Enantioselective Cycloaddition for the Synthesis of Chiral Multicyclic Compounds2008

    • Author(s)
      柴田 高範
    • Organizer
      Taiwan-Japan International Symposium on Organic Chemistry and Molecular Science
    • Place of Presentation
      台湾科技大学(台湾)
    • Year and Date
      2008-04-18
    • Related Report
      2008 Annual Research Report
  • [Presentation] Ir-and Rh-catalyzed Enantioselective Cycloadditions2008

    • Author(s)
      柴田高範
    • Organizer
      008 Science Seminar
    • Place of Presentation
      WuXi PharmaTech Shanghai, China(招待講演)
    • Related Report
      2009 Final Research Report
  • [Presentation] Ir-and Rh-catalyzed Enantioselective Cycloadditions2008

    • Author(s)
      柴田高範
    • Organizer
      SIOC seminar 2008, Shanghai Institute of Organic Chemistry Chinese Academy of Sciences
    • Place of Presentation
      Shanghai, China(招待講演)
    • Related Report
      2009 Final Research Report
  • [Presentation] Rh-Catalyzed Enantioselective Cycloaddition for the Synthesis of Chiral Multicyclic Compounds2008

    • Author(s)
      T.Shibata, Y.Tahara, K.Tamura, K.Endo
    • Organizer
      23th International Conference on Organometallic Chemistry (ICOMC23)
    • Place of Presentation
      Rennes, France
    • Related Report
      2009 Final Research Report
  • [Presentation] Enantioselective Cycloaddition for the Synthesis of Chiral Multicyclic Compounds2008

    • Author(s)
      柴田高範
    • Organizer
      Taiwan-Japan International Symposium on Organic Chemistry and Molecular Science
    • Place of Presentation
      Taipei, Taiwan(招待講演)
    • Related Report
      2009 Final Research Report
  • [Presentation] Enantioselective Cycloaddition for the Synthesis of Chiral Multicyclic Compounds2008

    • Author(s)
      柴田高範
    • Organizer
      1st International Workshop in Organic and Organometallic Chemistry
    • Place of Presentation
      Nagoya, Japan.(招待講演)
    • Related Report
      2009 Final Research Report
  • [Presentation] Rh触媒を用いたジインとカルボニル化合物類とのヘテロ[2+2+2]付加環化反応2008

    • Author(s)
      吉浪雄亮・土釜恭直・芳田志穂・遠藤恆平・柴田高範
    • Organizer
      日本化学会第88春季年会(5H1-01)
    • Place of Presentation
      立教大学
    • Related Report
      2009 Final Research Report
  • [Presentation] ジエンインを用いる分子内付加環化反応を利用した不斉四級炭素を有する光学活性環状化合物の合成2008

    • Author(s)
      田原優樹・田村耕平・遠藤恆平・柴田高範
    • Organizer
      日本化学会第88春季年会(5H1-16)
    • Place of Presentation
      立教大学
    • Related Report
      2009 Final Research Report
  • [Presentation] エンジインを用いる分子内付加環化反応を利用した不斉四級炭素を有する光学活性環状化合物の合成2008

    • Author(s)
      田村耕平・田原優樹・遠藤恆平・柴田高範
    • Organizer
      日本化学会第88春季年会(5H1-17)
    • Place of Presentation
      立教大学
    • Related Report
      2009 Final Research Report
  • [Presentation] ヘキサインの触媒的不斉[2+2+2]付加環化反応を利用した軸不斉大環状化合物の合成2008

    • Author(s)
      千羽達也・西澤豪・遠藤恆平・柴田高範
    • Organizer
      日本化学会第88春季年会(4H3-32)
    • Place of Presentation
      立教大学
    • Related Report
      2009 Final Research Report
  • [Presentation] イリジウム触媒によるビフェニレンの炭素-炭素結合活性化を用いた軸不斉ビアリール化合物の合成2008

    • Author(s)
      西澤豪・遠藤恆平・柴田高範
    • Organizer
      日本化学会第88春季年会(4H3-33)
    • Place of Presentation
      立教大学
    • Related Report
      2009 Final Research Report
  • [Presentation] Enantioselective Syntheses of Chinal Multicyclic Compounds with Quaternary Carbon Stereocenters by Intramolecuiar Cycloaddition2007

    • Author(s)
      T.Shibata
    • Organizer
      International Symposium on Catalysis and Fine Chemicals 2007
    • Place of Presentation
      シンガポール
    • Year and Date
      2007-12-19
    • Related Report
      2007 Annual Research Report
  • [Presentation] Asymmetric Cycloaddition for the Synthesis of Chiral Cyclic Compounds2007

    • Author(s)
      T.Shibata
    • Organizer
      The 17th Symposium on Optically Active Compounds, Yamada & Koga Prize
    • Place of Presentation
      東京
    • Year and Date
      2007-11-16
    • Related Report
      2007 Annual Research Report
  • [Presentation] Iridium-Catalyzed Enantioselective [2+2+2] Cycloaddition for the Synthesis of Axially Chiral Compounds2007

    • Author(s)
      T.Shibata
    • Organizer
      4th Japanese-Sino Symposium on Organic Chemistry for Young Scientists, Narita
    • Place of Presentation
      千葉
    • Year and Date
      2007-09-23
    • Related Report
      2007 Annual Research Report
  • [Presentation] Highly Enantioselective Intramolecular [2+2+2] Cycloaddition of Enediynes and Dienynes2007

    • Author(s)
      T.Shibata, Y.Tahara, K.Tamura
    • Organizer
      American Chemical Society 234nd National Meeting
    • Place of Presentation
      ボストン
    • Year and Date
      2007-08-20
    • Related Report
      2007 Annual Research Report
  • [Presentation] Enantioselective [2+2+2] Cycloaddition for the Synthesis of Various Chiral Cyclic Compounds2007

    • Author(s)
      T.Shibata, Y.Tahara, K.Tamura
    • Organizer
      The 15th European Symposium on Organic Chemistry
    • Place of Presentation
      ダブリン
    • Year and Date
      2007-07-12
    • Related Report
      2007 Annual Research Report
  • [Presentation] Asymmetric Cycloaddition for the Synthesis of Chiral Cyclic Compounds2007

    • Author(s)
      柴田高範
    • Organizer
      The 17th Symposium on Optically Active Compounds, Yamada & Koga Prize
    • Place of Presentation
      Tokyo, Japan.(招待講演)
    • Related Report
      2009 Final Research Report
  • [Presentation] Enantioselective [2+2+2] Cycloaddition as a Synthetic Tool2007

    • Author(s)
      柴田高範
    • Organizer
      IUPAC 3rd International Symposium on Novel Materials and Synthesis & 17th International Symposium on Fine Chemistry and Functional Polymers
    • Place of Presentation
      Shanghai, China(招待講演)
    • Related Report
      2009 Final Research Report
  • [Presentation] Iridium-Catalyzed Enantioselective [2+2+2] Cycloaddition for the Synthesis of Axially Chiral Compounds2007

    • Author(s)
      柴田高範
    • Organizer
      4^<th> Japanese-Sino Symposium on Organic Chemistry for Young Scientists
    • Place of Presentation
      Narita, Japan(招待講演)
    • Related Report
      2009 Final Research Report
  • [Presentation] Highly Enantioselective Intramolecular [2+2+2] Cycloaddition of Enediynes and Dienynes2007

    • Author(s)
      T.Shibata, Y.Tahara, K.Tamura
    • Organizer
      The 234th ACS National Meeting
    • Place of Presentation
      Boston, United States
    • Related Report
      2009 Final Research Report
  • [Presentation] エナンチオ選択的[2+2+2]付加環化反応による軸不斉の創製2007

    • Author(s)
      柴田高範
    • Organizer
      モレキュラー・キラリティー2007
    • Place of Presentation
      東京理科大学
    • Related Report
      2009 Final Research Report
  • [Presentation] 分子内付加環化反応を利用した不斉四級炭素を有する光学活性多環状化合物の合成2007

    • Author(s)
      田原優樹、田村耕平、柴田高範
    • Organizer
      第92回有機合成シンポジウム(O-2)
    • Place of Presentation
      早稲田大学
    • Related Report
      2009 Final Research Report
  • [Book] Iridiium-Catalyzed Cycloadditions in Iridium Complexesin Organic Synthesis2009

    • Author(s)
      Shibata, T.
    • Publisher
      Wiley-VCH
    • Related Report
      2009 Self-evaluation Report
  • [Remarks]

    • URL

      http://www.chem.waseda.ac.jp/shibata/

    • Related Report
      2009 Final Research Report
  • [Remarks]

    • URL

      http://www.chem.waseda.ac.jp/shibata/

    • Related Report
      2009 Annual Research Report
  • [Remarks]

    • URL

      http://www.chem.waseda.ac.jp/shibata/

    • Related Report
      2008 Annual Research Report

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Published: 2007-04-01   Modified: 2016-04-21  

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