DNA-templated assembly of organic molecule-based magnets
| Project/Area Number |
19350072
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| Research Category |
Grant-in-Aid for Scientific Research (B)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Functional materials chemistry
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| Research Institution | Osaka City University |
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Principal Investigator |
SHIOMI Daisuke Osaka City University, 大学院・理学研究科, 准教授 (40260799)
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| Project Period (FY) |
2007 – 2009
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| Project Status |
Completed (Fiscal Year 2009)
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| Budget Amount *help |
¥13,780,000 (Direct Cost: ¥10,600,000、Indirect Cost: ¥3,180,000)
Fiscal Year 2009: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
Fiscal Year 2008: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
Fiscal Year 2007: ¥8,320,000 (Direct Cost: ¥6,400,000、Indirect Cost: ¥1,920,000)
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| Keywords | 電気 / 磁気的性質 / 磁性 / 超分子化学 / 分子性固体 / ラジカル / フェリ磁性 / 核酸塩基 / シトシン / グアニン |
|---|
| Research Abstract |
As a novel supramolecular approach to rationalized construction of organic molecule-based magnets, we have proposed "bio-inspired molecule-based approach", in which the complementary hydrogen bonding between nucleobases are introduced to stable radical molecules with various spin quantum numbers for the control of the molecular arrangement. We have succeeded in synthesizing the first example of a Watson-Crick type cytosine-guanine hydrogen-bonded complex composed of cytosine- and guanine-substituted nitroxide radical molecules, which have been characterized by single-crystal X-ray crystallography. As another approach to construct a molecular spin assembly, we have proposed and designed molecular spin assembly templated by single-stranded oligonucleotides. A minimal model system for the assembly containing a covalent base vacancy has been designed, in which nucleobase-substituted radicals should be confined in the base-specific manner.
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Report
(4 results)
Research Products
(48 results)
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[Journal Article] Molecular electron-spin quantum computers and quantum information processing: pulse-based electron magnetic resonance spin technology applied to matter spin-qubits2009
Author(s)
K. Sato, S. Nakazawa, R. Rahimi, T. Ise, S. Nishida, T. Yoshino, N. Mori, K. Toyota, D. Shiomi, Y. Yakiyama, Y. Morita, M. Kitagawa, K. Nakasuji, M. Nakahara, H. Hara, P. Carl, P. Hoefer, T. Takui
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Journal Title
J. Mater. Chem 19
Pages: 3739-3754
Related Report
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[Journal Article] A New Ferrimagnet Based on a Radical-Substituted Radical Cation Salt2009
Author(s)
Y. Masuda, M. Kuratsu, S. Suzuki, M. Kozaki, D. Shiomi, K. Sato, T. Takui, Y. Hosokoshi, X.-Z. Lan, Y. Miyazaki, A. Inaba, K. Okada
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Journal Title
J. Am. Chem. Soc 131
Pages: 4670-4673
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[Journal Article] Thermochromism in an Organic Crystal Based on the Co-existence of Sigma-and π-dimers2008
Author(s)
Y. Morita, S. Suzuki, K. Fukui, S. Nakazawa, H. Kitagawa, H. Kishida, H. Okamoto, A. Naito, A. Sekine, Y. Ohashi, M. Shiro, K. Sasaki, D. Shiomi, K. Sato, T. Takui, K. Nakasuji
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Journal Title
Nature Materials 7
Pages: 48-51
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[Journal Article] Preparation, Structure, and Magnetic Interaction of a Mn(hfac)2-Bridged [2-(3-Pyridyl)(Nitronyl Nitroxide)-Mn(hfac)2]2 Chain Complex2007
Author(s)
K. Okada, S. Beppu, K. Tanaka, M. Kuratsu, K. Furuichi, M. Kozaki, S. Suzuki, D. Shiomi, K. Sato, T. Takui, Y. Kitagawa, K. Yamaguchi
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Journal Title
Chem. Commun
Pages: 2485-2487
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[Journal Article] Implementation of Molecular Spin Quantum Computing by Pulsed ENDOR Technique: Direct Observation of Quantum Enatnglement and Spinor2007
Author(s)
K. Sato, R. Rahimi, N. Mori, S. Nishida, K. Toyota, D. Shiomi, Y. Morita, A. Ueda, S. Suzuki, K. Furukawa, T. Nakamura, M. Kitagawa, K. Nakasuji, M. Nakahara, H. Hara, P. Carl, P. Hoefer, T. Takui
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Journal Title
Physica E 40
Pages: 363-366
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