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Bioabsorption and environmental degradation of high strength fibers and nanofibers of bio-based polymers

Research Project

Project/Area Number 19350075
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Environmental chemistry
Research InstitutionThe University of Tokyo

Principal Investigator

IWATA Tadahisa  The University of Tokyo, 大学院・農学生命科学研究科, 准教授 (30281661)

Co-Investigator(Kenkyū-buntansha) YAMAOKA Tetsuji  国立循環器病センター, 生体工学部, 部長 (50243126)
Project Period (FY) 2007 – 2010
Project Status Completed (Fiscal Year 2010)
Budget Amount *help
¥19,240,000 (Direct Cost: ¥14,800,000、Indirect Cost: ¥4,440,000)
Fiscal Year 2009: ¥3,510,000 (Direct Cost: ¥2,700,000、Indirect Cost: ¥810,000)
Fiscal Year 2008: ¥5,590,000 (Direct Cost: ¥4,300,000、Indirect Cost: ¥1,290,000)
Fiscal Year 2007: ¥10,140,000 (Direct Cost: ¥7,800,000、Indirect Cost: ¥2,340,000)
Keywordsバイオベース高分子 / 生分解性高分子 / 高強度繊維 / ナノファイバー / 分子鎖構造 / 酵素分解 / 生体内分解 / 環境分解 / 酸素分解 / 生本内分解
Research Abstract

High tensile strength fibers and nanofibers were processed from microbial polyesters and poly(lactic acid) produced from renewable resources as sugar and plant oil. Mechanical properties were investigated and molecular, crystal and inner structures were analyzed by using micro-beam X-ray diffraction and X-ray micro-tomography techniques in SPring-8. Furthermore, bio-absorbability of nanofibers in rat and environmental degradability of monofilament in soil and were demonstrated.

Report

(4 results)
  • 2010 Final Research Report ( PDF )
  • 2009 Annual Research Report
  • 2008 Annual Research Report
  • 2007 Annual Research Report
  • Research Products

    (58 results)

All 2009 2008 2007 Other

All Journal Article (27 results) (of which Peer Reviewed: 9 results) Presentation (16 results) Book (12 results) Remarks (3 results)

  • [Journal Article] Left or right-handed lamellar twists depend on twist axis in poly[(R)-3-hydroxyvalerate] banded spherulite2009

    • Author(s)
      Hai-Mu Ye, Jun Xu, Bao-Hua Guo, Tadahisa Iwata
    • Journal Title

      Macromolecules 42

      Pages: 694-701

    • Related Report
      2010 Final Research Report
  • [Journal Article] In vivo tissue response and degradation behavior of PLLA and stereocomplexed PLA nanofibers2009

    • Author(s)
      Daisuke Ishii, Tang Hui Ying, Atsushi Mahara, Sunao Murakami, Tetsuji Yamaoka, Won-ki Lee, Tadahisa Iwata
    • Journal Title

      Biomacromolecules 10

      Pages: 237-242

    • Related Report
      2010 Final Research Report
  • [Journal Article] 生分解性プラスチックとしてのセルロースのこれから2009

    • Author(s)
      岩田忠久
    • Journal Title

      木材工業 64

      Pages: 160-165

    • NAID

      10024950360

    • Related Report
      2010 Final Research Report
  • [Journal Article] 生分解性バイオマスプラスチックの高性能化に向けた材料設計2009

    • Author(s)
      岩田忠久
    • Journal Title

      未来材料 4

      Pages: 18-23

    • NAID

      40016635650

    • Related Report
      2010 Final Research Report
  • [Journal Article] Biodegradability of poly(hydroxyalkanoate) materials2009

    • Author(s)
      Keiji Numata, Hideki Abe, Tadahisa Iwata
    • Journal Title

      Materials 2

      Pages: 1104-1126

    • Related Report
      2010 Final Research Report
  • [Journal Article] Characterization and biocompatibility of biopolyester nanofibers2009

    • Author(s)
      Daisuke Ishii, Tank Hui Ying, Tetsuji Yamaoka, Tadahisa Iwata
    • Journal Title

      Materials 2

      Pages: 1520-1546

    • Related Report
      2010 Final Research Report
  • [Journal Article] ナノ構造制御による生分解性バイオマスプラスチックの高機能化2009

    • Author(s)
      岩田忠久
    • Journal Title

      日本接着学会 45

      Pages: 357-364

    • NAID

      10026425590

    • Related Report
      2010 Final Research Report
  • [Journal Article] Left or right-handed lamellar twists depend on twist axis in poly[(R)-3-hydroxybutyrate] banded sperulite2009

    • Author(s)
      Hai-Mu, T.Iwata, et al.
    • Journal Title

      Macromolecules

      Volume: 42 Pages: 694701-694701

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] In vivo tissue response and degradation behavior of PLLA and stereocomplexd PLA nanofibers2009

    • Author(s)
      D.Ishii, T.Iwata, et al.
    • Journal Title

      Biomacromolecules

      Volume: 10 Pages: 237-242

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Biodegradability of poly(hydroxyalkanoate) materials2009

    • Author(s)
      K.Numata, H.Abe, T.Iwata
    • Journal Title

      Materials

      Volume: 2 Pages: 1104-1126

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Characterization and biocompatibility of biopolyester nanofibers2009

    • Author(s)
      D.Ishii, T.Iwata, et al.
    • Journal Title

      Materials

      Volume: 2 Pages: 1520-1546

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 生分解性プラスチックとしてのセルロースのこれから2009

    • Author(s)
      岩田忠久
    • Journal Title

      木材工業

      Volume: 64 Pages: 160-165

    • NAID

      10024950360

    • Related Report
      2009 Annual Research Report
  • [Journal Article] 生分解性バイオマスプラスチックの高性能化に向けた材料設計2009

    • Author(s)
      岩田忠久
    • Journal Title

      未来材料

      Volume: 4 Pages: 18-23

    • NAID

      40016635650

    • Related Report
      2009 Annual Research Report
  • [Journal Article] ナノ構造制御により生分解性バイオマスプラスチックの高機能化2009

    • Author(s)
      岩田忠久
    • Journal Title

      日本接着学会

      Volume: 45 Pages: 357-364

    • Related Report
      2009 Annual Research Report
  • [Journal Article] Scaffolds from electrospun polyhydroxyalknoate copolymers : Fabrication, characterization, bioabsorption and tissue response2008

    • Author(s)
      Tang Hui Ying, Daisuke Ishii, Atsushi Mahara, Sunao Murakami, Tetsuji Yamaoka, Kumar Sudesh, Razip Samian, Masahiro Fujita, Mizuo Maeda, Tadahisa Iwata
    • Journal Title

      Biomaterials 29

      Pages: 1307-1317

    • Related Report
      2010 Final Research Report
  • [Journal Article] Stereocomplex formation through reorganization of poly(L-lactic acid) and poly(D-lactic acid) crystals2008

    • Author(s)
      Masahiro Fujita, Tomoharu Sawayanagi, Hideki Abe, Toshihisa Tanaka, Tadahisa Iwata, Kazuki Ito, Tetsuro Fujisawa, Mizuo Maeda
    • Journal Title

      Macromolecules 41

      Pages: 2852-2858

    • Related Report
      2010 Final Research Report 2008 Annual Research Report
  • [Journal Article] Sustainability of biobased and biodegradable plastics2008

    • Author(s)
      Kumar Sudesh, Tadahisa Iwata
    • Journal Title

      Clean 36

      Pages: 433-442

    • Related Report
      2010 Final Research Report 2008 Annual Research Report
  • [Journal Article] Morphological study, thermal treatment and degradation behaviors of solution-grown poly(l-lactide) single crystals2008

    • Author(s)
      Won-ki Lee, Tadahisa Iwata
    • Journal Title

      Ultramicroscopy 108

      Pages: 1054-1057

    • Related Report
      2010 Final Research Report
  • [Journal Article] Scaffolds from electrospun polyhydroxyalknoate copolymers : Fabrication characterization, bioabsorption and tissue response2008

    • Author(s)
      Tang Hui Ying, Daisuke Ishii, Atsushi Mahara, Sunao Murakami, Tetsuji Yamaoka, Kumar Sudesh, Razip Samian, Masahiro Fujita, Mizuo Maeda, Tadahisa Iwata
    • Journal Title

      Biomaterials 29

      Pages: 1307-1317

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Morphological study thermal treatment and degradation behaviors of solution-grown poly(l-lactide)single crystals2008

    • Author(s)
      Won-ki Lee, Tadahisa Iwata
    • Journal Title

      Ultramicroscopy 108

      Pages: 1054-1057

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Mechanical properties and enzyme degradation for poly[(R)-3-hydroxybutyrate] fibers stretched after isothermal crystallization near Tg2007

    • Author(s)
      Toshihisa Tanaka, Tomomi Yabe, Shinya Teramachi, Tadahisa Iwata
    • Journal Title

      Polymer Degradation and Stability 92

      Pages: 1016-1024

    • Related Report
      2010 Final Research Report
  • [Journal Article] Analysis of inner structure in high-strength biodegradable fibers by X-ray microtomography using synchrotron radiation2007

    • Author(s)
      Toshihisa Tanaka, Kentaro Uesugi, Akihisa Takeuchi, Yoshio Suzuki, Tadahisa Iwata
    • Journal Title

      Polymer 48

      Pages: 6145-6151

    • Related Report
      2010 Final Research Report
  • [Journal Article] Fine structure and enzymatic degradation of poly[(R)-3-hydroxybutyrate] and poly(lactide) stereocomplex nanofibers2007

    • Author(s)
      Daisuke Ishii, Won-ki Lee, Ken-ichi Kasuya, Tadahisa Iwata
    • Journal Title

      Journal of Biotechnology 132

      Pages: 318-324

    • Related Report
      2010 Final Research Report
  • [Journal Article] Mechanical properties and enzymatic degradation for poly[(R)-3-hydroxybutyrate] fibers stretched after isothermal crystallization near Tg2007

    • Author(s)
      T. Tanaka, T. Yabe, S. Teramachi, T. Iwata
    • Journal Title

      Polymer Degradation and Stability 92

      Pages: 1016-1024

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Analysis of inner structure in high-strength biodegradable fibers by X-ray microtomography using synchrotron radiation2007

    • Author(s)
      T. Tanaka, K. Uesugi, A. Takeuchi, Y. Suzuki, T. Iwata
    • Journal Title

      Polymer 48

      Pages: 6145-6151

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Fine structure and enzymatic degradation of poly[(R)-3-hydroxybutyrate] and poly(lactide) stereocomplex nanofibers2007

    • Author(s)
      D. Ishii, W. K. Lee, K. Kasuya, T. Iwata
    • Journal Title

      Journal of Biotechnology 132

      Pages: 318-324

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 微生物産生ポリエステルの生分解性制御技術の開発2007

    • Author(s)
      岩田忠久
    • Journal Title

      生物工学会誌 85

      Pages: 255-257

    • NAID

      110006317600

    • Related Report
      2007 Annual Research Report
  • [Presentation] Preparation and Mechanical Properties of Single Nanofiber and Nanoporous Fiber of Bio-based Polymers2009

    • Author(s)
      Tadahisa Iwata
    • Organizer
      International Conference on Bio-based Polymers 2009
    • Place of Presentation
      マレーシア、ペナン
    • Year and Date
      2009-11-13
    • Related Report
      2009 Annual Research Report
  • [Presentation] Structure and biodegradation of biopolyester fibers2009

    • Author(s)
      Tadahisa Iwata
    • Organizer
      EP2009
    • Place of Presentation
      中国、大連
    • Year and Date
      2009-08-24
    • Related Report
      2009 Annual Research Report
  • [Presentation] 生分解性ポリエステル高強度繊維のX線トモグラフィーおよびマイクロビームX線回折による構造解析と酵素分解性評価2009

    • Author(s)
      岩田忠久
    • Organizer
      文部科学省ナノテクノロジー・ネットワーク/重点ナノテクノロジー支援放射光利用研究成果報告会
    • Place of Presentation
      つくば
    • Year and Date
      2009-05-08
    • Related Report
      2009 Annual Research Report
  • [Presentation] Structure, Mechanical Properties and Enzymatic Degradation of Biodegradable Biomass Plastics2008

    • Author(s)
      岩田忠久
    • Organizer
      台湾国立成功大学 特別セミナー
    • Place of Presentation
      台湾
    • Year and Date
      2008-12-12
    • Related Report
      2008 Annual Research Report
  • [Presentation] BETA STRUCTURE AND UNIQUE CRYSTALLINE ORIENTATION ANALYSIS OF PHB FIBERS AND FILMS2008

    • Author(s)
      IWATA, Tadahisa, SATO, Sho, PARK, Jun-Wuk, TANAKA, Toshihisa
    • Organizer
      INTERNATIONAL SYMPOSIUM ON BIOLOGICAL POLYESTERS ISBP 2008
    • Place of Presentation
      ニュージーランド
    • Year and Date
      2008-11-23
    • Related Report
      2008 Annual Research Report
  • [Presentation] 大型放射光の生分解性プラスチックへの応用2008

    • Author(s)
      岩田忠久
    • Organizer
      SPring-8利用者懇談会高分子科学研究会、高分子薄膜・表面研究会、小角散乱研究会合同講演会
    • Place of Presentation
      東京
    • Year and Date
      2008-11-01
    • Related Report
      2008 Annual Research Report
  • [Presentation] ポリ[(R)-3-ヒドロキシブチレート]のβ構造の解析と酵素分解性2008

    • Author(s)
      岩田忠久, 佐藤渉, 吉田泰彦, 田中稔久
    • Organizer
      第57回高分子討論会
    • Place of Presentation
      大阪
    • Year and Date
      2008-09-24
    • Related Report
      2008 Annual Research Report
  • [Presentation] セルロースアセテートナノファイバーとポリヒドロキシブレートから成る複合材料の構造と物性2008

    • Author(s)
      浅野真文、岩田忠久
    • Organizer
      平成20年度繊維学会年次大会
    • Place of Presentation
      東京
    • Year and Date
      2008-06-20
    • Related Report
      2008 Annual Research Report
  • [Presentation] セルロースエステル/ポリ乳酸ブレンドの一軸延伸フィルムにおける構造および物性解析2008

    • Author(s)
      岩田忠久、大口郁夫、伊藤和輝
    • Organizer
      第57回高分子学会年次大会
    • Place of Presentation
      横浜
    • Year and Date
      2008-05-29
    • Related Report
      2008 Annual Research Report
  • [Presentation] X線トモグラフィー測定を用いたポリ(L-乳酸)繊維の内部構造2007

    • Author(s)
      田中稔久, 岩田忠久, 上杉健太朗, 鈴木芳夫, 竹内晃久
    • Organizer
      第56回高分子学会年次大会
    • Place of Presentation
      京都国際会議場
    • Related Report
      2007 Annual Research Report
  • [Presentation] ポリ[(R)-3-ヒドロキシブチレート]の平面ジグザグ構造の結晶構造解析2007

    • Author(s)
      佐藤渉, 田中稔久, 吉田泰彦, 岩田忠久
    • Organizer
      第56回高分子学会年次大会
    • Place of Presentation
      京都国際会議場
    • Related Report
      2007 Annual Research Report
  • [Presentation] 依頼講演:微生物産生ポリエステルの高性能化に向けた材料設計2007

    • Author(s)
      岩田忠久
    • Organizer
      平成19年度繊維学会年次大会
    • Place of Presentation
      タワーホール船堀
    • Related Report
      2007 Annual Research Report
  • [Presentation] 微結晶核延伸法によるP(3HB-co-3HH)高強度繊維の作製と結晶核形成過程の解析2007

    • Author(s)
      田中稔久, 長崎康平, 寺町信哉, 岩田忠久
    • Organizer
      平成19年度繊維学会年次大会
    • Place of Presentation
      タワーホール船堀
    • Related Report
      2007 Annual Research Report
  • [Presentation] Structure and Biodegradability of Bio-based Polyester Fibers2007

    • Author(s)
      Tadahisa Iwata
    • Organizer
      International Conference on Materials for Advanced Technologies 2007
    • Place of Presentation
      Singapore
    • Related Report
      2007 Annual Research Report
  • [Presentation] 大型放射光を用いた生分解性ポリエステルの高次構造解析2007

    • Author(s)
      岩田忠久
    • Organizer
      第56回高分子討論会
    • Place of Presentation
      名古屋工業大学
    • Related Report
      2007 Annual Research Report
  • [Presentation] 生分解性ポリエステルナノファイバーの作製と生体適合性の検討2007

    • Author(s)
      石井大輔, 山岡哲二, 岩田忠久
    • Organizer
      第56回高分子討論会
    • Place of Presentation
      名古屋工業大学
    • Related Report
      2007 Annual Research Report
  • [Book] Bottom-up Nanotechnology : Supramolecules, Self-Assemblies, and Organized Films, Supermoleculae II(edited by K.Ariga and H.S. Nalwa)(Nanotechnology on biodegradable polymers Chapter 8)2009

    • Author(s)
      Yoshihiro Kikkawa, Masahiro Fujita, Tadahisa Iwata
    • Publisher
      American Scientific Publishers
    • Related Report
      2010 Final Research Report
  • [Book] Plastics from Bacteria : Natural Functions and Applications, Microbiology Monographs(Ed. Guo-Qiang Chen)(Manufacturing of PHA as fibers Chapter 11)2009

    • Author(s)
      Tadahisa Iwata, Toshihisa Tanaka
    • Publisher
      Springer
    • Related Report
      2010 Final Research Report
  • [Book] Chapter 8 : Nanotechnology on biodegradable polymers, Bottom-up Nanotechnology2009

    • Author(s)
      Y.Kikkawa, M.Fujita, T.Iwata
    • Total Pages
      358
    • Publisher
      American Scientific Publishers
    • Related Report
      2009 Annual Research Report
  • [Book] Chapter 11 : Manufacturing of PHA as fibers, Natural Functions and Applica tions2009

    • Author(s)
      T.Iwata, T.Tanaka
    • Total Pages
      428
    • Publisher
      Springer
    • Related Report
      2009 Annual Research Report
  • [Book] ホワイトバイオテクノロジー:エネルギー、材料の最前線(木村良晴、小原仁実監修)(化学材料・プロセス編 微生物産生ポリエステル 第2編 第14章)2008

    • Author(s)
      岩田忠久、柘植丈治
    • Publisher
      シーエムシー出版
    • Related Report
      2010 Final Research Report
  • [Book] バイオプラスチックの高機能化・再資源化技術(バイオプラスチックの基礎物性 第1編)2008

    • Author(s)
      岩田忠久
    • Publisher
      エヌ・ティー・エス
    • Related Report
      2010 Final Research Report
  • [Book] 人と環境にやさしい材料化学(尾崎幸洋編)(未来を拓く生分解性バイオマスプラスチック-微生物による生合成から生分解まで-)2008

    • Author(s)
      岩田忠久
    • Publisher
      丸善
    • Related Report
      2010 Final Research Report
  • [Book] 第1編バイオプラスチックの基礎物性バイオプラスチックの高機能化・再資源化技術2008

    • Author(s)
      岩田忠久
    • Total Pages
      368
    • Publisher
      エヌ・テイー・エス
    • Related Report
      2008 Annual Research Report
  • [Book] 人と環境にやさしい材料化学未来を拓く生分解性バイオマスプラスチック-微生物による生合成から生分解まで-2008

    • Author(s)
      岩田忠久
    • Total Pages
      182
    • Publisher
      丸善
    • Related Report
      2008 Annual Research Report
  • [Book] バイオプラスチック材料のすべて第6章 生分解性プラスチック(グリーンプラ)2008

    • Author(s)
      岩田忠久
    • Total Pages
      258
    • Publisher
      日刊工業新聞社
    • Related Report
      2008 Annual Research Report
  • [Book] 第25章:バイオポリエステルの構造、物性および生分解性の制御「植物由来プラスチックの高機能化とリサイクル技術」2007

    • Author(s)
      岩田忠久
    • Total Pages
      494
    • Publisher
      サイエンス&テクノロジー
    • Related Report
      2007 Annual Research Report
  • [Book] 植物由来プラスチックの高機能化とリサイクル技術(バイオポリエステルの構造、物性および生分解性の制御 第25章)

    • Author(s)
      岩田忠久
    • Publisher
      サイエンス&テクノロジー
    • Related Report
      2010 Final Research Report
  • [Remarks]

    • URL

      http://web2.fp.a.u-tokyo.ac.jp/cbm/02_02.html

    • Related Report
      2007 Annual Research Report
  • [Remarks]

    • URL

      http://www-db.ccr.u-tokyo.ac.jp/ccr_usr/data/4479.html

    • Related Report
      2007 Annual Research Report
  • [Remarks]

    • URL

      http://www-db.ccr.u-tokyo.ac.jp/ccr_usr/data/4480.html

    • Related Report
      2007 Annual Research Report

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Published: 2007-04-01   Modified: 2016-04-21  

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