| Project/Area Number |
19350077
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| Research Category |
Grant-in-Aid for Scientific Research (B)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Environmental chemistry
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| Research Institution | Kanagawa University |
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Principal Investigator |
MORI Wasuke Kanagawa University, 理学部, 教授 (60029709)
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| Co-Investigator(Kenkyū-buntansha) |
KIHARA Nobuhiro 神奈川大学, 理学部, 教授 (30214852)
SAITO Taro 神奈川大学, 理学部, 非常勤講師 (90011006)
NISHIMOTO Yuko 神奈川大学, 理学部, 准教授 (70241114)
MATSUNAGA Satoshi 神奈川大学, 理学部, 助手 (80451516)
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| Project Period (FY) |
2007 – 2009
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| Project Status |
Completed (Fiscal Year 2009)
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| Budget Amount *help |
¥18,070,000 (Direct Cost: ¥13,900,000、Indirect Cost: ¥4,170,000)
Fiscal Year 2009: ¥3,120,000 (Direct Cost: ¥2,400,000、Indirect Cost: ¥720,000)
Fiscal Year 2008: ¥9,750,000 (Direct Cost: ¥7,500,000、Indirect Cost: ¥2,250,000)
Fiscal Year 2007: ¥5,200,000 (Direct Cost: ¥4,000,000、Indirect Cost: ¥1,200,000)
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| Keywords | グリーンケミストリー / 機能性細孔物質 / 水素吸蔵 / 水素発生触媒 / ナノ細孔物質 / カルボン酸金属錯体 / 気体吸蔵 / 水素貯蔵 / 光触媒 / 水素製造 |
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| Research Abstract |
Porous complexes which we found have been extensively studied in recent years because of their intriguing structures and, more importantly, for their potential applications in gas storage, separation, and catalysis. In this project, we have synthesized the novel porous complexes and evaluated hydrogen adsorption properties and the hydrogen production-catalytic activities of the porous complexes in order to construct a clean energy system. The hydrogen adsorption properties depended upon the node-metals, and the porous complexes having small pore size showed a highly hydrogen-adsorption capability. In the Ru- and Rh-based porous complexes showed a hydrogen production-catalytic activity under the existing co-catalysts.
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