| Project/Area Number |
19350095
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| Research Category |
Grant-in-Aid for Scientific Research (B)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Functional materials/Devices
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| Research Institution | Osaka Prefecture University |
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Principal Investigator |
OGAWA Akiya Osaka Prefecture University, 大学院・工学研究科, 教授 (30183031)
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| Co-Investigator(Kenkyū-buntansha) |
野元 昭宏 大阪府立大学, 工学研究科, 助教 (60405347)
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| Co-Investigator(Renkei-kenkyūsha) |
NOMOTO Akihiro 大阪府立大学, 大学院・工学研究科, 助教 (60405347)
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| Project Period (FY) |
2007 – 2010
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| Project Status |
Completed (Fiscal Year 2010)
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| Budget Amount *help |
¥20,020,000 (Direct Cost: ¥15,400,000、Indirect Cost: ¥4,620,000)
Fiscal Year 2010: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2009: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Fiscal Year 2008: ¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000)
Fiscal Year 2007: ¥13,130,000 (Direct Cost: ¥10,100,000、Indirect Cost: ¥3,030,000)
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| Keywords | パイ共役系分子 / ヘテロ元素 / 複合同時導入法 / 有機発光素子 / ラジカル反応 / 遷移金属触媒反応 / ヘテロ原子複合材料 / ヘテロ環化合物 / 複合同時導入伝 |
|---|
| Research Abstract |
Methods for the introduction of sulfur, selenium, nitrogen or tellurium atoms to π-conjugated molecules were established, and photoluminescence properties of the π-conjugated molecules were investigated. Highly selective photoinduced or transition-metal-catalyzed introduction of sulfur, selenium, tellurium, nitrogen, or phosphorus atoms into unsaturated bonds was carried out, successfully. Crystal structures, redox potentials, and photoluminescence properties of a series of π-conjugated molecules were measured. The sulfur containing polymers indicated strong photoluminescence and complexation with metal species was observed.
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