| Budget Amount *help |
¥17,940,000 (Direct Cost: ¥13,800,000、Indirect Cost: ¥4,140,000)
Fiscal Year 2009: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
Fiscal Year 2008: ¥3,640,000 (Direct Cost: ¥2,800,000、Indirect Cost: ¥840,000)
Fiscal Year 2007: ¥11,700,000 (Direct Cost: ¥9,000,000、Indirect Cost: ¥2,700,000)
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| Research Abstract |
Novel porous coordination polymers (PCPs) showing gate phenomena in gas sorption were prepared by combining different building blocks consisting of transitional metal ions, organic ligand molecules, and counter anions based on the properties of [Cu(bpy)_2(BF_4)_2] (LPC), which is known to have a flexible structure having a 2 dimensional grid and its stacking structures. The novel PCPs showed unique gate phenomena according to the properties of the metal, ligand, or anion. The systematic studies enabled us to understand gas sorption properties of the PCPs.
Also the fundamental properties such as the effect of moisture or organic solvents and thermal stability on the structure and gas sorptivity of LPC were examined from the viewpoint of practical use. Fundamental data could be obtained for the application to separation of CO_2.
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