Preparation of Single Molecular Electronics Device based on DNA-Conductive Polymer Conjugate

• Project/Area Number: 19350106
• Research Category: Grant-in-Aid for Scientific Research (B)
• Allocation Type: Single-year Grants
• Section: 一般
• Research Field: Polymer/Textile materials
• Research Institution: Hokkaido University
• Principal Investigator: IJIRO Kuniharu Hokkaido University, 電子科学研究所, 教授 (90221762)
• Co-Investigator(Kenkyū-buntansha): NIIKURA Kkenichi 北海道大学, 電子科学研究所, 准教授 (40360896) ; MATSUO Yasutaka 北海道大学, 電子科学研究所, 助教 (90374652)
• Project Period (FY): 2007 – 2008
• Project Status: Completed (Fiscal Year 2008)
• Budget Amount: ¥18,070,000 (Direct Cost: ¥13,900,000、Indirect Cost: ¥4,170,000); Fiscal Year 2008: ¥6,500,000 (Direct Cost: ¥5,000,000、Indirect Cost: ¥1,500,000); Fiscal Year 2007: ¥11,570,000 (Direct Cost: ¥8,900,000、Indirect Cost: ¥2,670,000)
• Keywords: 天然 / 生体高分子材料 / ナノテクノロジー / 単一分子デバイス / 無電解メッキ / ナノワイヤー / ナノギャップ電極 / DNA / LB膜

Research Abstract

高度情報通信社会を将来にわたって持続的に発展させるためには、電子デバイスの微細化と高性能化を低コストでさらに進めなければならないが、これは従来の半導体デバイスの延長線上では実現が困難であり、それに代わる新しいナノデバイスの開発が不可欠である。そこで本研究では単一分子で動作する極微細ナノデバイスの作製を目標として、DNAの自己組織化と無電解メッキを応用することで単一分子デバイスを作製する手法の開発を行った。

Research Products

• [Journal Article] Double-layered Metal Mesh Film Having a Limited Viewing Angle Property Prepared by Electroless Plating of Self-rganization Honeycomb Film (2008)
  • Author(s): H. Yabu, Y. Hirai, Y. Matsuo, K. Ijiro, and M. Shimomura
  • Journal Title: Macromolecular Symposia 267 Pages: 100-104
  • Peer Reviewed
• [Journal Article] Sequence-specifically platinum metaldeposition on enzymatically synthesized DNA block copolymer Sequence-specifically platinum metaldeposition on enzymatically synthesized DNA block copolymer (2008)
  • Author(s): A. Tanaka, Y. Matsuo, Y. Hashimoto, and K.Ijiro
  • Journal Title: Chem. Commun Pages: 4270-4272
  • Peer Reviewed
• [Journal Article] Stabilization of Multiassembly byAddition of a Phosphate Group at the 5'-Sticky End (2008)
  • Author(s): A. Tanaka, Y. Matsuo, K. Niikura, and K. Ijiro
  • Journal Title: Chemistry Letters 37(7) Pages: 758-759
  • Peer Reviewed
• [Journal Article] Sequence-Specific Control of Azobenzene Assemblies byMolecular Recognition of DNA (2008)
  • Author(s): O. Haruta, Y. Matsuo, Y. Hashimoto, K.Niikura, and K. Ijiro
  • Journal Title: Langmuir 24(6) Pages: 2618-2624
  • Peer Reviewed
• [Journal Article] Enhanced Cellular Uptake of Virus-Like Particlesthrough Immobilization on a Sialic Acid-Displaying Solid Surface (2008)
  • Author(s): N. Ohtake, K. Niikura, T. Suzuki, K.Nagakawa, H. Sawa, and K. Ijiro
  • Journal Title: Bioconjugate Chemistry 19 Pages: 507-515
  • Peer Reviewed
• [Journal Article] Development of lipid particles targeted viasugar-lipid conjugates as novel nuclear genedelivery system (2008)
  • Author(s): T. Masuda, H. Akita, T. Nishio, K. Niikura, K.Kogure, K. Ijiro, and H. Harashima
  • Journal Title: Biomaterials 29 Pages: 709-723
  • Peer Reviewed
• [Journal Article] Sequence-Specific Control of Azobenzene Assemblies by Molecular Recognition of DNA (2008)
  • Author(s): Osamu Haruta
  • Journal Title: Langmuir 24(6) Pages: 2618-2624
  • Peer Reviewed
• [Journal Article] Stabilization of Multiassembly by Addition of a Phosphate Group at the 5'-Sticky End (2008)
  • Author(s): Aya Tanaka
  • Journal Title: Chemistry Letters 37(7) Pages: 758-759
  • Peer Reviewed
• [Journal Article] Sequence-specifically platinum metal deposition on enzymatically synthesized DNA block copolymer (2008)
  • Author(s): Aya Tanaka
  • Journal Title: Chem. Commun. 2008 Pages: 4270-4272
  • Peer Reviewed
• [Journal Article] Double-layered Metal Mesh Film Having a Limited Viewing Angle Property Prepared by Electroless Plating of Self-rganization Honeycomb Film (2008)
  • Author(s): Hiroshi Yabu
  • Journal Title: Macromolecular Symposia 267 Pages: 100-104
  • Peer Reviewed
• [Journal Article] Development of lipid particles targeted via sugar-lipid conjugates as novel nuclear gene delivery system (2008)
  • Author(s): Tomoya Masuda
  • Journal Title: Biomaterials 29 Pages: 709-723
  • Peer Reviewed
• [Journal Article] Enhanced Cellular Uptake of Virus-Like Particles through Immobilization on a Sialic Acid-Displaying Solid Surface (2008)
  • Author(s): Noriko Ohtake
  • Journal Title: Bioconjugate Chemistry 19 Pages: 507-515
  • Peer Reviewed
• [Journal Article] Sequence-Specific Control of Azobenzene Assemblies by Molecular Recognition of DNA (2008)
  • Author(s): O. Haruta
  • Journal Title: Langmuir 24(6) Pages: 2618-2624
  • Peer Reviewed
• [Journal Article] Phase Separation of Aqueous Poly (vinyl methyl ether) SolutionsInduced by the Photon Pressure of a Focused Near-Infrared Laser Beam (2007)
  • Author(s): Y. Tsuboi, M. Nishino, Y. Matsuo, K. Ijiroand and N. Kitamura
  • Journal Title: Bull. Chem. Soc.Jpn. 80(10) Pages: 1926-1931
  • Peer Reviewed
• [Journal Article] Patterned Immobilization of Unprotected Carbohydrates on an Aminooxy Polymer-Grafted Solid Surface (2007)
  • Author(s): R. Kamitani, K. Niikura, T. Onodera, N.Iwasaki, H. Shimaoka, and K. Ijiro
  • Journal Title: Bulletin of the Chemical Society of Japan 80(9) Pages: 1808-1813
  • NAID: 10019847528
  • Peer Reviewed
• [Journal Article] 血管内皮細胞の初期伸展に及ぼすハニカムフィルム細孔径の影響 (2007)
  • Author(s): 山本貞明, 田中賢, 伊藤絵美子, 森田有香, 角南寛, 居城邦治, 下村政嗣
  • Journal Title: 表面科学 28(8) Pages: 433-439
  • NAID: 10019860359
• [Journal Article] Application of Oligonucleotide as a Template for the Assembly of Nucleoamphiphile Bearing Azobenzene at the Air-Water Interface (2007)
  • Author(s): O. Haruta, and K. Ijiro
  • Journal Title: Journal of Nanoscience and Nanotechnology 7 Pages: 734-737
  • Peer Reviewed
• [Journal Article] Application of Oligonucleotide as a Template for the Assembly of Nucleoamphiphie Bearing Azobenzene at the Air一Water Interface (2007)
  • Author(s): Osamu Haruta
  • Journal Title: Journal of Nanoscience and Nanotechnology 7 Pages: 734-737
  • Peer Reviewed
• [Journal Article] 血管内皮細胞の初期伸展に及ぼすハニカムフィルム細孔径の影響(The Influence of Pore Size of a Honeycomb Film on Early Spreading Process of Endothelial Cells) (2007)
  • Author(s): 山本貞明
  • Journal Title: 表面科学 8(8) Pages: 433-439
• [Journal Article] Patterned Immobilization of Unprotectected Carbohydrates on an Aminooxy Polymer-Grafted Solid Surface (2007)
  • Author(s): Ryosuke Kamitani
  • Journal Title: Bulletin of the Chemical Society of Japan 80(9) Pages: 1808-1813
  • Peer Reviewed
• [Journal Article] Phase Separation of Aqueous Poly(vinyl methyl ether)Solutions Induced by the Photon Pressure of a Focused Near-Infrared Laser Beam (2007)
  • Author(s): Yasuyuki Tsuboi
  • Journal Title: Bull. Chem. Soc. Jpn 80(10) Pages: 1926-1931
  • Peer Reviewed
• [Presentation] Fabrication of Nanowires by Base-Selective Metallization of DNA (2008)
  • Author(s): K. Ijiro
  • Organizer: Japan-Korea-China Mini-symposium on Nanotechnology, Biotechnology and Catalysis -Satellite Session-
  • Place of Presentation: Hokkaido University, Sapporo
  • Year and Date: 2008-11-07
• [Presentation] Fabrication of Nanowires by Base-Selective Metallization of DNA", Japan-Korea-China Mini-symposium on Nanotechnology (2008)
  • Author(s): Kuniharu Ijiro
  • Organizer: Japan-Korea-China Mini-symposium on Nanotechnology, Biotechnology and Catalysis
  • Place of Presentation: Hokkaido Univ. (Sapporo)
  • Year and Date: 2008-11-07
• [Presentation] DNASequence-Selective Fabrication of Platinum Nanowires (2008)
  • Author(s): K. Ijiro, Y. Matsuo, A. Tanaka
  • Organizer: Asian Conference on Nanoscience and Nanotechnology
  • Place of Presentation: Singapore
• [Presentation] DNA Sequence Specific Fabrication of Metal Nanostructures (2008)
  • Author(s): K. Ijiro
  • Organizer: Korea-Japan Joint Forum (KJF)
  • Place of Presentation: Chitose Institute of Scienceand Technology (CIST), Chitose
• [Presentation] DNA-assisted Fabrication of Photoluminescent Silver Nanoparticles (2008)
  • Author(s): K. Ijiro
  • Organizer: SPIE Optics + Photonics
  • Place of Presentation: San Diego, USA
• [Presentation] 2-D organic and inorganic nanofabrication through molecular recognition of DNA at the air-water interface (2008)
  • Author(s): Kuniharu Ijiro
  • Organizer: SPIE Optics+Photonics 2008
  • Place of Presentation: San Diego (USA)
• [Presentation] DNA Sequence Specific Fabrication of Metal Nanostructures (2008)
  • Author(s): Kuniharu Ijiro
  • Organizer: Korea-Japan Joint Forum (KJF) 2008
  • Place of Presentation: Chitose Institute of Science and Technology (CIST)(Chitose)
• [Presentation] DNA Sequence-Selective Fabrication of Platinum Nanowires (2008)
  • Author(s): Kuniharu Ijiro
  • Organizer: AsiaNANO2008
  • Place of Presentation: Biopolis (Singapore)
• [Presentation] DNA-templated fabrication ofmetal nanowires and nanoparticles (2007)
  • Author(s): K. Ijiro
  • Organizer: Joint Symposium for the Promotion of Academicexchange on Nanotechnology and Nanobiology
  • Place of Presentation: Sapporo
  • Year and Date: 2007-11-02
• [Presentation] DNA-templated fabrication of metal nanowires and nanoparticles (2007)
  • Author(s): K. Ijiro
  • Organizer: Joint Symposium for the Promotion of Academic exchange on Nanotechnology and Nanobiology
  • Place of Presentation: Hokkaido Univ. (Sapporo)
  • Year and Date: 2007-11-02
• [Presentation] DNA-assisted Fabrication of Photoluminescent Silver Nanoparticles (2007)
  • Author(s): K. Ijiro
  • Organizer: 2007Korea-Japan Symposium on Frontier Photoscience(KJFP 2007)
  • Place of Presentation: Gyeongju, Korea
• [Presentation] DNAを用いた発光性銀ナノ粒子の作製とバイオイメージングへの応用 (2007)
  • Author(s): 松尾保孝, 佐藤壮人, 石川綾子, 居城邦治
  • Organizer: 第22回生体機能関連化学シンポジウム
  • Place of Presentation: 東北大学多元物質科学研究所
• [Presentation] DNAでコートした銀ナノ粒子の作製と光励起発光現象 (2007)
  • Author(s): 松尾保孝, 佐藤壮人, 石川綾子, 居城邦治
  • Organizer: 第60回コロイドおよび界面化学討論会
  • Place of Presentation: 信州大学
• [Presentation] オリゴヌクレオチド/銀ハイブリットナノ粒子の作製と発光特性解析 (2007)
  • Author(s): 居城邦治, 佐藤壮人, 石川綾子, 松尾保孝
  • Organizer: 第56回高分子討論会
  • Place of Presentation: 名古屋工業大学
• [Presentation] 分子集合体システムの金属化による機能性ナノ構造形成 (2007)
  • Author(s): 居城邦治, 田中あや, 佐藤壮人, 橋本裕一, 松尾保孝
  • Organizer: 2007年秋季第68回応用物理学会学術講演会
  • Place of Presentation: 北海道工業大学
• [Presentation] 核酸塩基を用いて作製した銀ナノ粒子の発光特性 (2007)
  • Author(s): 松尾保孝, 石川綾子, 佐藤壮人, 居城邦治
  • Organizer: 2007 年秋季第68回応用物理学会学術講演会
  • Place of Presentation: 北海道工業大学
• [Presentation] DNA-metal hybrid nanomaterials (2007)
  • Author(s): K. Ijiro, M. Sato, K. Niikura, Y. Matsuo
  • Organizer: SPIEOptics+Photonics 2007
  • Place of Presentation: San Diego, USA
• [Presentation] DNAを鋳型とした機能性ナノ構造の構築 (2007)
  • Author(s): 居城邦治
  • Organizer: 第40回若手ペプチド夏の勉強会
  • Place of Presentation: 小樽
• [Presentation] 水面単分子膜上での核酸分子の認識 (2007)
  • Author(s): 居城邦治
  • Organizer: 超分子組織体の構造と機能化に関するシンポジウム
  • Place of Presentation: ジウム, 東京工業大学
• [Presentation] 水面単分子膜上での核酸分子の認識 (2007)
  • Author(s): 居城邦治
  • Organizer: 超分子組織体の構造と機能化に関するシンポジウム
  • Place of Presentation: 東京工業大学
• [Presentation] DNAを鋳型とした機能性ナノ構造の構築 (2007)
  • Author(s): 居城邦治
  • Organizer: 第40回若手ペプチド夏の勉強会
  • Place of Presentation: おたる自然の村 おこばち山荘
• [Presentation] DNA-metal hybrid nanomaterials (2007)
  • Author(s): Y. Matsuo
  • Organizer: SPIE Optics+Photonics 2007
  • Place of Presentation: San Diego Convention Center, San Diego, California USA
• [Presentation] 核酸塩基を用いて作製した銀ナノ粒子の発光特性 (2007)
  • Author(s): 松尾保孝
  • Organizer: 2007年秋季第68回応用物理学会学術講演会
  • Place of Presentation: 北海道工業大学
• [Book] 超分子サイエンス&テクノロジー-基礎からイノベーションまで-(第4章) (2009)
  • Author(s): 居城邦治
  • Publisher: エヌ・ティー・エス
• [Book] 金属・マイクロ粒子の形状構造制御技術 (2009)
  • Author(s): 居城邦治, 新倉謙一, 松尾保孝
  • Publisher: シーエムシー出版
• [Book] 量子ドットの生命科学領域への応用 (2007)
  • Author(s): 新倉謙一, 居城邦治
  • Publisher: シーエムシー
• [Book] 細胞ストレスのイメージングを目指した糖鎖修飾量子ドットの作製 (2007)
  • Author(s): 新倉謙一
  • Total Pages: 9
  • Publisher: シーエムシー出版