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Spatial-temporal control of polarization reversal characteristicsin ferroelectric polymer and development of non-volatile polymer memory devices

Research Project

Project/Area Number 19350114
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Polymer/Textile materials
Research InstitutionTokyo University of Science

Principal Investigator

FURUKAWA Takeo  Tokyo University of Science, 理学部・第一部化学科, 教授 (90087411)

Co-Investigator(Kenkyū-buntansha) TAKAHASHI Yoshiyuki  東京理科大学, 理学部・第一部, 助教 (80266923)
YAMAMOTO Ryoichi  群馬産業技術センター, 材料食品グループ, 独立研究員 (40469888)
NAKAJIMA Takashi  東京理科大学, 理学部・第一部, 助教 (60516483)
Research Collaborator OKADA Akifumi  東京理科大学, 大学院・理学研究科修士課程
TOMODA Naoko  東京理科大学, 大学院・理学研究科修士課程
Project Period (FY) 2007 – 2009
Project Status Completed (Fiscal Year 2009)
Budget Amount *help
¥19,760,000 (Direct Cost: ¥15,200,000、Indirect Cost: ¥4,560,000)
Fiscal Year 2009: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Fiscal Year 2008: ¥7,150,000 (Direct Cost: ¥5,500,000、Indirect Cost: ¥1,650,000)
Fiscal Year 2007: ¥10,660,000 (Direct Cost: ¥8,200,000、Indirect Cost: ¥2,460,000)
Keywords高分子材料物性 / 高分子機能材料 / 強誘電体 / 構造制御 / 分極反転 / PFM / 時分割PFM / メモリー / 強誘電性 / フッ化ビニリデン / 薄膜 / 走査プローブ顕微鏡 / 圧電応答 / ドメイン / 運動論 / 強誘電性高分子 / 走査プローブ顕微法 / 強誘電体メモリー / 分極制御 / 分域構造 / 反転ダイナミクス
Research Abstract

Copolymers of vinylidene fluoride are high-performance ferroelectrics, although their microscopic understanding is missing due to their complex structure. In this study, we clarified the polarization reversal process microscopically by use of a piezoresponse force microscope that scans the distribution of polarization with a cantilever. We also measured the polarization reversal process at very short time and found that these polymers show very quick polarization reversal. In addition, we manufactured memory devices with a ferroelectric polymer and clarified the electronic behavior in these devices.

Report

(4 results)
  • 2009 Annual Research Report   Final Research Report ( PDF )
  • 2008 Annual Research Report
  • 2007 Annual Research Report
  • Research Products

    (39 results)

All 2010 2009 2008 2007

All Journal Article (14 results) (of which Peer Reviewed: 8 results) Presentation (25 results)

  • [Journal Article] Recent advances in ferroelectric poly-mer thin films for memory applications2010

    • Author(s)
      T. Furukawa, Y. Takahashi, T. Nakajima
    • Journal Title

      Current Applied Physics Vol.10

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Recent advances in ferroelectric polymer thin films for memory applications2010

    • Author(s)
      T.Furukawa, Y.Takahashi, T.Nakajima
    • Journal Title

      Current Applied Physics 10

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Ferro-electric switching dynamics in VDF-TrFE copolymer thin films spin coated on Si substrate.2009

    • Author(s)
      T. Furukawa, S. Kana Takahashi, R. Yamamoto
    • Journal Title

      J. Appl. Phys. Vol.105

      Pages: 61636-61636

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Ferroelectric switching dynamics in VDF-TrFE copolymer thin films spin coated on Si substrate2009

    • Author(s)
      T.Furukawa, S.Kanai, A.Okada, Y.Takahashi, R.Yamamoto
    • Journal Title

      J.Appl.Phys. 105

      Pages: 61636-61636

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Recent developments in electrets, ferroelectrets and related devices2009

    • Author(s)
      R.Gerhard, T.Furukawa, Y.Takahashi, X.Qiu
    • Journal Title

      IEEE Trans.Dielectr.Electr.Insul 16

      Pages: 290-290

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Ultralow-dielectric-constant films prepared from hollow polyimide nanop articles possessing controllable core sizes2009

    • Author(s)
      G.F.Zhao, T.Ishizawa, H.Kasai, M.Hasegawa, T.Furukawa, H.Nakanishi, H.Oikawa
    • Journal Title

      Chem.Mater. 21

      Pages: 419-424

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] SPM Study of Ferroelectric Properties of Vinylidene Fluoride and Trifluoroethylene Co-polymer2008

    • Author(s)
      Yoshiyuki Takahashi, Naoko Tomoda, Takeo Furukawa
    • Journal Title

      Proceedings of 13th inter-national symposium on electrets

      Pages: 58-58

    • Related Report
      2009 Final Research Report
  • [Journal Article] Yoshiyuki Takahashi and Ta State in VDF/TrFE Copolymer Thin Films Studied by Scanning Probe Micro-scopy"2008

    • Author(s)
      Naoko Tomoda
    • Journal Title

      Proceedings of 13th international symposium on electrets

      Pages: 82-82

    • Related Report
      2009 Final Research Report
  • [Journal Article] Simul-taneous Measurements of (Q-V, C-V) and (Q-t, C-t) Characteristics in an MFS Capacitor with Ferroelectric VDF-TrFE Copolymer as a Gate Dielectric2008

    • Author(s)
      Yamamoto, A. Okada, D. Ito, Y. Takahashi, T. Furukawa
    • Journal Title

      Proceedings of 13th international sym-posium on electrets

      Pages: 97-97

    • Related Report
      2009 Final Research Report
  • [Journal Article] Pulse train measurement of ferroelectric switching vinylidene fluoride/trifluoroethylene co-polymer.2008

    • Author(s)
      T. Nakajima, Y. Takahashi, T. Furukawa
    • Journal Title

      Appl. Phys. A Vol.91

      Pages: 33-39

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Simultaneous Measurements of (Q-V, C-V) and (Q-t, C-t) Characteristics in an MFS Capacitor with Ferroelectric VDF-TrFE Copolymer as a Gate Dielectric2008

    • Author(s)
      R. Yamamoto, A. Okada, D. Ito, Y. Takahashi, T. Furukawa
    • Journal Title

      Proceedings of 13th international symposium on electrets

      Pages: 97-97

    • Related Report
      2008 Annual Research Report
  • [Journal Article] SPM Study of Ferroelectric Properties of Vinylidene Fluoride and Trifluoroethylene Copolymer2008

    • Author(s)
      Yoshiyuki Takahashi, Naoko Tomoda, Takeo Furukawa
    • Journal Title

      Proceedings of 13th international symposium on electrets

      Pages: 58-58

    • Related Report
      2008 Annual Research Report
  • [Journal Article] The Polarization State in VDF/TrFE Copolymer Thin Films Studied by Scanning Probe Microscopy2008

    • Author(s)
      Naoko Tomoda, Yoshiyuki Takahashi, Takeo Furukawa
    • Journal Title

      Proceedings of 13th international symposium on electrets

      Pages: 82-82

    • Related Report
      2008 Annual Research Report
  • [Journal Article] Pulse train measurement of ferroelectric switching in thin films of vinylidene fluoride/trifluoroethylene copolymer.2008

    • Author(s)
      T. Nakajima, Y. Takahashi and T. Furukawa
    • Journal Title

      Appl. Phys. A 91

      Pages: 33-39

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Presentation] Recent advances in ferroelectric poly-mer thin films2009

    • Author(s)
      T. Furukawa, T. Nakajima, Y. Takahashi
    • Organizer
      International sym-posium on integrated ferroelectrics and functionalities
    • Place of Presentation
      Colorado Spring, USA
    • Year and Date
      2009-09-28
    • Related Report
      2009 Final Research Report
  • [Presentation] Recent advances in ferroelectric polymer thin films(invited)2009

    • Author(s)
      古川猛夫, 中嶋宇史, 高橋芳行
    • Organizer
      International symposium on integrated ferroelectrics and functionalities
    • Place of Presentation
      Colorado Spring, USA
    • Year and Date
      2009-09-28
    • Related Report
      2009 Annual Research Report
  • [Presentation] 圧電応答顕微法を用いたVDF/TrFE共重合体における反転ドメインの生成・成長の定量的解析2009

    • Author(s)
      友田菜穂子, 高橋芳行, 古川猛夫
    • Organizer
      第58回高分子討論会
    • Place of Presentation
      熊本大学
    • Year and Date
      2009-09-17
    • Related Report
      2009 Annual Research Report 2009 Final Research Report
  • [Presentation] VDF/TrFE共重合体薄膜の超高電場における高速強誘電スイッチング特性2009

    • Author(s)
      石井肇, 中嶋宇史, 高橋芳行, 古川猛夫
    • Organizer
      第58回高分子討論会
    • Place of Presentation
      熊本大学
    • Year and Date
      2009-09-17
    • Related Report
      2009 Annual Research Report 2009 Final Research Report
  • [Presentation] ポリフッ化ビニリデン/四フッ化エチレン共重合体薄膜の強誘電特性2009

    • Author(s)
      平原裕基, 高橋芳行, 古川猛夫
    • Organizer
      第58回高分子討論会
    • Place of Presentation
      熊本大学
    • Year and Date
      2009-09-17
    • Related Report
      2009 Annual Research Report
  • [Presentation] Electrical properties of polymer composites with ferroelectric ceramics, carbon fiber and metal salt2009

    • Author(s)
      T.Furukawa, K.Yoshida, D.Kimura
    • Organizer
      The 17th Annual International Conference on composites/nano engineering
    • Place of Presentation
      Honolulu, USA
    • Year and Date
      2009-07-28
    • Related Report
      2009 Annual Research Report
  • [Presentation] Recent advances in ferroelectric polymer thin films for memory applications2009

    • Author(s)
      T. Furukawa
    • Organizer
      The 4th inter-national symposium on next generation non-volatile memory technology for tera-bit memory
    • Place of Presentation
      Hanyang University, Korea
    • Year and Date
      2009-06-24
    • Related Report
      2009 Final Research Report
  • [Presentation] Recent advances in ferroelectric polymer thin films for memory applicati ons(invited)2009

    • Author(s)
      古川猛夫
    • Organizer
      The 4th international symposium on next generation non-volatile memory technology for tera-bit memory
    • Place of Presentation
      Hanyang University, Korea
    • Year and Date
      2009-06-24
    • Related Report
      2009 Annual Research Report
  • [Presentation] VDF/TrFE共重合体薄膜の分極反転過程の局所的観察2009

    • Author(s)
      友田菜穂子, 高橋芳行, 古川猛夫
    • Organizer
      第58回高分子学会年次大会
    • Place of Presentation
      神戸国際会議場
    • Year and Date
      2009-05-29
    • Related Report
      2009 Annual Research Report
  • [Presentation] VDF/TrFE共重合体薄膜の超高電場におけるスイッチング特性2009

    • Author(s)
      石井肇, 中嶋宇史, 高橋芳行, 古川猛夫
    • Organizer
      第58回高分子学会年次大会
    • Place of Presentation
      神戸国際会議場
    • Year and Date
      2009-05-29
    • Related Report
      2009 Annual Research Report
  • [Presentation] VDF/TrFE共重合体薄膜における局所的強誘電物性2008

    • Author(s)
      友田菜穂子・高橋芳行・古川猛夫
    • Organizer
      第57回高分子討論会
    • Place of Presentation
      大阪市立大学
    • Year and Date
      2008-09-24
    • Related Report
      2009 Final Research Report
  • [Presentation] VDF/TrFE共重合体薄膜における局所的強誘電物性2008

    • Author(s)
      友田菜穂子, 高橋芳行, 古川猛夫
    • Organizer
      第57回高分子討論会
    • Place of Presentation
      大阪、大阪市立大学
    • Year and Date
      2008-09-24
    • Related Report
      2008 Annual Research Report
  • [Presentation] SPM Study of Ferroelectric Properties of Vinylidene Fluoride and Trifluoroethylene Copoly-mer2008

    • Author(s)
      Yoshiyuki Takahashi, Naoko Tomoda, Takeo Furukawa
    • Organizer
      13th international symposium on electrets
    • Place of Presentation
      日本科学未来館
    • Year and Date
      2008-09-17
    • Related Report
      2009 Final Research Report
  • [Presentation] SPM Study of Ferroelectric Properties of Vinylidene Fluoride and Trifluoroethylene Copolymer2008

    • Author(s)
      Yoshiyuki Takahashi, Naoko Tomoda, Takeo Furukawa
    • Organizer
      13th international symposium on electrets
    • Place of Presentation
      東京、日本科学未来館
    • Year and Date
      2008-09-17
    • Related Report
      2008 Annual Research Report
  • [Presentation] The Polarization State in VDF/TrFE Copolymer Thin Films Studied by Scanning Probe Micro-scopy2008

    • Author(s)
      Naoko Tomoda, Yoshiyuki Takahashi, Takeo Furukawa
    • Organizer
      13th international symposium on electrets
    • Place of Presentation
      日本科学未来館
    • Year and Date
      2008-09-15
    • Related Report
      2009 Final Research Report
  • [Presentation] Simul-taneous Measurements of (Q (Q-t, C-t) Characteristics in an MFS Capacitor with Ferroelectric VDF-TrFE Copolymer as a Gate Dielectric2008

    • Author(s)
      R. Yamamoto, A. Okada, D. Ito, Y. Takahashi, T. Furukawa
    • Organizer
      13th international symposium on electrets
    • Place of Presentation
      日本科学未来館
    • Year and Date
      2008-09-15
    • Related Report
      2009 Final Research Report
  • [Presentation] The Polarization State in VDF/TrFE Copolymer Thin Films Studied by Scanning Probe Microscopy2008

    • Author(s)
      Naoko Tomoda, Yoshiyuki Takahashi, Takeo Furukawa
    • Organizer
      13th international symposium on electrets
    • Place of Presentation
      東京、日本科学未来館
    • Year and Date
      2008-09-15
    • Related Report
      2008 Annual Research Report
  • [Presentation] Simultaneous Measurements of (Q-V, C-V) and (Q-t, C-t) Characteristics in an MFS Capacitor with Ferroelectric VDF-TrFE Copolymer as a Gate Dielectric2008

    • Author(s)
      R. Yamamoto, A. Okada, D. Ito, Y. Takahashi, T. Furukawa
    • Organizer
      13th international symposium on electrets
    • Place of Presentation
      東京、日本科学未来館
    • Year and Date
      2008-09-15
    • Related Report
      2008 Annual Research Report
  • [Presentation] SPMによるVDF/TrFE共重合体薄膜の分極状態の測定2008

    • Author(s)
      友田菜穂子, 高橋芳行, 古川猛夫
    • Organizer
      第57回高分子学会年次大会
    • Place of Presentation
      横浜、パシフイコ横浜
    • Year and Date
      2008-05-29
    • Related Report
      2008 Annual Research Report
  • [Presentation] Kinetics of Crystallization in Thin Films of a Vinylidene Fluoride/Trifluoroethylene Copolymer2007

    • Author(s)
      Yoshiyuki Takahashi, Takeo Furukawa
    • Organizer
      Inter- national Symposium on Polymer Crystallization
    • Place of Presentation
      Toray Conference Hall, Mishima, Japan
    • Year and Date
      2007-09-22
    • Related Report
      2009 Final Research Report
  • [Presentation] Kinetics of Crystallization in Thin Films of a Vinylidene Fluoride/Trifluoroethylene Copolymer2007

    • Author(s)
      Yoshiyuki Takahashi and Takeo Furukawa
    • Organizer
      International Symposium on Polymer Crystallization
    • Place of Presentation
      Toray Conference Hall, Mishima, Shizuoka, Japan
    • Year and Date
      2007-09-22
    • Related Report
      2007 Annual Research Report
  • [Presentation] VDF/TrFE共重合体薄膜の構造形成における基板の効果2007

    • Author(s)
      大澤孝成・工藤渉・高橋芳行・古川猛夫
    • Organizer
      第56回高分子討論会
    • Place of Presentation
      名古屋工業大学
    • Year and Date
      2007-09-21
    • Related Report
      2009 Final Research Report
  • [Presentation] VDF/TrFE共重合体薄膜の構造形成における基板の効果2007

    • Author(s)
      大澤孝成・工藤 渉・高橋芳行・古川猛夫
    • Organizer
      高分子学会 第56回高分子討論会
    • Place of Presentation
      名古屋工業大学
    • Year and Date
      2007-09-21
    • Related Report
      2007 Annual Research Report
  • [Presentation] VDF/TrFE共重合体を用いたMFS素子の分極反転ク゜イナミクス2007

    • Author(s)
      古川猛夫・岡田成史・金井庄太・高橋芳行・山本亮一
    • Organizer
      応用物理学会秋季第69回学術講演会
    • Place of Presentation
      北海道工業大学
    • Year and Date
      2007-09-05
    • Related Report
      2009 Final Research Report
  • [Presentation] VDF/TrFE共重合体を用いたMFS素子の分極反転ダイナミクス2007

    • Author(s)
      古川猛夫・岡田成史・金井庄太・高橋芳行・山本亮一
    • Organizer
      応用物理学会 秋季第69回学術講演会
    • Place of Presentation
      北海道工業大学
    • Year and Date
      2007-09-05
    • Related Report
      2007 Annual Research Report

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Published: 2007-04-01   Modified: 2016-04-21  

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