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Research on Upper Limits of Critical Temperature of Practical Superconductors by Solid-State Chemistry

Research Project

Project/Area Number 19360293
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Inorganic materials/Physical properties
Research InstitutionThe University of Tokyo

Principal Investigator

SHIMOYAMA Jun-ichi  The University of Tokyo, 大学院・工学系研究科, 准教授 (20251366)

Co-Investigator(Kenkyū-buntansha) KISHIO Kohji  東京大学, 大学院・工学系研究科, 教授 (50143392)
OGINO Hiraku  東京大学, 大学院・工学系研究科, 助教 (70359545)
HORII Shigeru  東京大学, 大学院・工学系研究科, 助教 (80323533)
Project Period (FY) 2007 – 2009
Project Status Completed (Fiscal Year 2009)
Budget Amount *help
¥20,540,000 (Direct Cost: ¥15,800,000、Indirect Cost: ¥4,740,000)
Fiscal Year 2009: ¥3,120,000 (Direct Cost: ¥2,400,000、Indirect Cost: ¥720,000)
Fiscal Year 2008: ¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
Fiscal Year 2007: ¥13,650,000 (Direct Cost: ¥10,500,000、Indirect Cost: ¥3,150,000)
Keywords超伝導 / 化学組成 / 臨界温度 / 超伝導体 / 精密化学組成 / 臨界電流特性 / ドーピング
Research Abstract

Enhancement of critical temperatures (T_c) of practical superconductors with high T_c has been attempted by precise control of their chemical compositions. For Bi-based oxide superconductors, T_c of Bi(Pb)2223 tapes was successfully enhanced up to 116K with maintaining strong grain coupling. On the other hand, nonstoichiometry in cation compositions of Y123 and heavy-RE123 oxide was discovered. The cation nonstoichiometry was found to seriously degrade superconducting properties, such as T_c and critical current properties. This new knowledge gave a new guideline to develop high performance materials.

Report

(4 results)
  • 2009 Annual Research Report   Final Research Report ( PDF )
  • 2008 Annual Research Report
  • 2007 Annual Research Report
  • Research Products

    (35 results)

All 2010 2009 2008 2007 Other

All Journal Article (13 results) (of which Peer Reviewed: 13 results) Presentation (22 results)

  • [Journal Article] Excellent Critical Current Properties of Cation and Oxygen Composition Controlled Bi2212 Sinele Crystals2010

    • Author(s)
      Y.Kageshima, J.Shimoyama, H.Ogino, S.Horii, K.Kishio
    • Journal Title

      J.Phys.Conf.Ser. (印刷中(掲載確定))

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of c-axis oriented MgB_2 bulks by magneto-scientific method2010

    • Author(s)
      T.Mochizuki, J.Shimoyama, H.Ogino, S.Horii, Y.Yamada, K.Kishio
    • Journal Title

      J.Phys.Conf.Ser. (印刷中(掲載確定))

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Improved Flux Pinning Properties of Bi-Based Superconductors by Dilute RE-Doping2009

    • Author(s)
      K. Takimoto, J. Shimoyama, Y. Kageshima, H. Ogino, S. Horii, K. Kishio
    • Journal Title

      IEEE Trans.Appl.Supercond Vol. 19

      Pages: 3080-3083

    • NAID

      10019981342

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Excellent Critical Current Properties of Dilute Sr-Doped Dy123 Melt-Solidified Bulks at Low Temperatures2009

    • Author(s)
      Y. Ishii, Y. Yamazaki, T. Akasaka, H. Ogino, S. Horii, J. Shimoyama, K. Kishio
    • Journal Title

      IEEE Trans.Appl.Supercond Vol. 19

      Pages: 3487-3490

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Improved flux piming properties of Bi-based superconductors by dilute RE-dopin=2009

    • Author(s)
      K. Takimoto, J. Shimoyama, Y. Kageshima, H. Ogino, S. Horii and K. Kishio
    • Journal Title

      IEEE Trans. Appl. Supercond. (印刷中(掲載確定))

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Systematic Studies on T_c of La123 at Carrier Optimally-Doped State2008

    • Author(s)
      T. Asanuma, J. Shimoyama, T. Nakashima, H. Ogino, S. Horii, K. Kishio
    • Journal Title

      J.Phys.Conf.Ser. Vol. 97

      Pages: 12151-12151

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Enhanced T_c of Bi (Pb) 2223 Sintered Bulks up to 115 K2008

    • Author(s)
      A. Tanimoto, J. Shimoyama, S. Horii, K. Kishio
    • Journal Title

      J.Phys.Conf.Ser. Vol. 97

      Pages: 12146-12146

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Systematic Studies on T_c of La123 at Carrier Optimally-Doped State2008

    • Author(s)
      T.Asanuma, J.Shimoyama, T.Nakashima, H.Ogino, S.Horiiand K.Kishio
    • Journal Title

      J.Phys.Conf.Series (印刷中)(掲載確定)

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Enhanced T_c of Bi(Pb)2223 Sintered Bulks up to 115K2008

    • Author(s)
      A.Tanimoto, J.Shimoyama, S.Horii and K.Kishio
    • Journal Title

      J.Phys.Conf.Series (印刷中)(掲載確定)

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] How to Improve Critical Current Properties of Bi2223 and MgB_2 Tapes2007

    • Author(s)
      J.Shimoyama, A.Tanimoto, T.Makise, A.Yamamoto, Y.Katsura, I.Iwaama S.Horii K.Kishio T.Kato
    • Journal Title

      Physica C 463-465

      Pages: 802-806

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Possibilities of Tc enhancement for already known HTSC compounds2007

    • Author(s)
      J.Shimoyama, A.Tanimoto, T.Nakashima, T.Asanuma, S.Horii, K.Kishio, T.Kato, S.Kobayashi.
    • Journal Title

      Physica C 460-462

      Pages: 1405-1406

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Excellent Critical Current Properties of Cation and Oxygen Composition Controlled Bi2212 Single Crystals

    • Author(s)
      Y. Kageshima, J. Shimoyama, H. Ogino, S. Horii, K. Kishio
    • Journal Title

      J.Phys.Conf.Ser. (印刷中)

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of c-axis oriented MgB_2 bulks by magneto-scientific method

    • Author(s)
      T. Mochizuki, J. Shimoyama, H. Ogino, S. Horii, Y. Yamada, K. Kishio
    • Journal Title

      J.Phys.Conf.Ser. (印刷中)

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Presentation] Derivable potential of cuprates, pnictide oxides and MgB2 for advanced superconducting materials (招待講演)2009

    • Author(s)
      J. Shimoyama
    • Organizer
      14th US-Japan Conference on Advanced Superconductivity
    • Place of Presentation
      米国、タラハシー
    • Year and Date
      2009-12-14
    • Related Report
      2009 Final Research Report
  • [Presentation] Derivable potential of cuprates, pnictide oxides and MgB_2 for advanced superconducting materials(招待講演)2009

    • Author(s)
      J.Shimoyama
    • Organizer
      14th US-Japan Conference on Advanced Superconductivity
    • Place of Presentation
      米国、フロリダ州、国立強磁場研究所
    • Year and Date
      2009-12-14
    • Related Report
      2009 Annual Research Report
  • [Presentation] Serious Effects of Cation Nonstoichiometry on Superconducting Properties of Y1232009

    • Author(s)
      J. Shimoyama. H. Kaku, Y. Ishii, H. Ogino, S. Horii, K. Kishio
    • Organizer
      European Conference on Applied Superconductivity 2009
    • Place of Presentation
      ドイツ、ドレスデン
    • Year and Date
      2009-09-16
    • Related Report
      2009 Final Research Report
  • [Presentation] Serious Effects of Cation Nonstoichiometry on Superconducting Properties of Y1232009

    • Author(s)
      J.Shimoyama. H.Kaku, Y.Ishii, H.Ogino, S.Horii, K.Kishio
    • Organizer
      European Conference on Applied Superconductivity
    • Place of Presentation
      ドイツ、ドレスデン、ドレスデン工科大学
    • Year and Date
      2009-09-16
    • Related Report
      2009 Annual Research Report
  • [Presentation] Cation Nonstoichiometry of Y1232009

    • Author(s)
      J. Shimoyama. H. Kaku, H. Ogino, S. Horii, K. Kishio
    • Organizer
      9th International Conference on Materials and Mechanisms of Superconductivity
    • Place of Presentation
      東京
    • Year and Date
      2009-09-08
    • Related Report
      2009 Final Research Report
  • [Presentation] Cation Nonstoichiometry of Y1232009

    • Author(s)
      J.Shimoyama. H.Kaku, H.Ogino, S.Horii, K.Kishio
    • Organizer
      9th International Conference on Materials and Mechanisms of Superconductivity
    • Place of Presentation
      東京、新宿 京王プラザホテル
    • Year and Date
      2009-09-08
    • Related Report
      2009 Annual Research Report
  • [Presentation] RE系超伝導体における金属不定比性と超伝導特性2009

    • Author(s)
      下山淳一, 加來宏一, 佐藤伸也, 荻野拓, 岸尾光二, 堀井滋
    • Organizer
      2009年春季低温工学・超電導学会
    • Place of Presentation
      東京
    • Year and Date
      2009-05-14
    • Related Report
      2009 Final Research Report
  • [Presentation] Y123における金属不定比性2009

    • Author(s)
      下山淳一, 加來宏一, 佐藤伸也, 石井悠衣, 山崎裕也, 荻野拓, 堀井滋, 岸尾光二
    • Organizer
      2009年春季応用物理学会
    • Place of Presentation
      つくば
    • Year and Date
      2009-03-31
    • Related Report
      2009 Final Research Report
  • [Presentation] Important issues from uncontrolled cation nonstoichiometry in well-known cuprates2009

    • Author(s)
      J. Shimoyama, H, Ogino, S, Horii, Y. Yamazaki, H. Kaku, Y. Ishii, Y. Katsura, K. Kishio
    • Organizer
      American Physica Society 2009 March Meeting
    • Place of Presentation
      米国、ピッツバーグ
    • Year and Date
      2009-03-16
    • Related Report
      2009 Final Research Report
  • [Presentation] Important issues from uncontrolled cation nonstoichiometry in well-known cupra=2009

    • Author(s)
      J. Shimoyama
    • Organizer
      Americal Physical Society 2009 March Meeting
    • Place of Presentation
      ピッツバーグ、合衆国
    • Year and Date
      2009-03-16
    • Related Report
      2008 Annual Research Report
  • [Presentation] International Symposium on Superconductivity (ISS 2008)2008

    • Author(s)
      J. Shimoyama, K. Takimoto, Y. Kageshima, M. Watanabe, H. Ogino, S. Horii, K. Kishio
    • Place of Presentation
      つくば
    • Year and Date
      2008-10-28
    • Related Report
      2009 Final Research Report
  • [Presentation] Effective ways to enhance Jc-B characteristics of Bi-based superconductors2008

    • Author(s)
      J. Shimoyama
    • Organizer
      International Symposium on Superconductivity (ISS2008)
    • Place of Presentation
      つくば
    • Year and Date
      2008-10-28
    • Related Report
      2008 Annual Research Report
  • [Presentation] Effective chemical doping for excellent J_c-B characteristics of HTSCs and MgB2 (招待講演)2008

    • Author(s)
      J. Shimoyama
    • Organizer
      IUMRS-ICEM 2008
    • Place of Presentation
      豪州、シドニー
    • Year and Date
      2008-07-28
    • Related Report
      2009 Final Research Report
  • [Presentation] Effective chemical doping for excellent Jc-B characteristics of HTSCs and MgB22008

    • Author(s)
      J, Shimoyama
    • Organizer
      IUMRS・ICEM 2008
    • Place of Presentation
      シドニー
    • Year and Date
      2008-07-28
    • Related Report
      2008 Annual Research Report
  • [Presentation] Chemical Techniques for Improving T_c and J_c of HTSC Materials, 4th CREST Nano-Virtual-Labs Joint Workshop on Superconductivity : Critical Current(招待講演)2007

    • Author(s)
      J. Shimoyama
    • Place of Presentation
      北九州
    • Year and Date
      2007-12-17
    • Related Report
      2009 Final Research Report
  • [Presentation] Chemical Techniques for Improving T and Jc of HTSC Materials2007

    • Author(s)
      J. Shimoyama
    • Organizer
      4th CREST Nano-Virtual-Labs Joint Workshop on Superconductivity:Critical Currents
    • Place of Presentation
      北九州国際会議場(北九州)
    • Year and Date
      2007-12-17
    • Related Report
      2007 Annual Research Report
  • [Presentation] 不定比金属組成制御によるBi2223の高T_c化2007

    • Author(s)
      谷本亮, 下山淳一, 滝本孝太, 影島慶明, 荻野拓, 堀井滋, 岸尾光二, 小林慎一, 綾井直樹
    • Organizer
      2007年度秋季低温工学・超電導学会
    • Place of Presentation
      仙台
    • Year and Date
      2007-11-20
    • Related Report
      2009 Final Research Report
  • [Presentation] RE123、Bi系超伝導体における最適キャリアドープ状態2007

    • Author(s)
      下山淳一, 浅沼匠, 谷本亮, 荻野拓, 堀井滋, 岸尾光二
    • Organizer
      2007年度秋季低温工学・超電導学会
    • Place of Presentation
      仙台
    • Year and Date
      2007-11-20
    • Related Report
      2009 Final Research Report
  • [Presentation] 不定比金属組成制御によるBi2223の高T_c化2007

    • Author(s)
      谷本 亮, 下山 淳一, 滝本 孝太, 島慶 明, 荻野 拓, 岸尾 光二, 小林 慎一, 綾井 直樹
    • Organizer
      2007年度秋季低温工学・超電導学会
    • Place of Presentation
      宮城県民会館(仙台)
    • Year and Date
      2007-11-20
    • Related Report
      2007 Annual Research Report
  • [Presentation] "RE123、Bi系超伝導体における最適キャリアドープ状態"2007

    • Author(s)
      下山 淳一, 浅沼 匠, 谷本 亮, 荻野 拓, 堀井 滋, 岸尾 光二
    • Organizer
      2007年度秋季低温工学・超電導学会
    • Place of Presentation
      宮城県民会館(仙台)
    • Year and Date
      2007-11-20
    • Related Report
      2007 Annual Research Report
  • [Presentation] Optimization of Superconducting Properties of Bi-Based Cuprates by Control of Chemical Composition2007

    • Author(s)
      J. Shimoyama
    • Organizer
      The 13th Japan-US Workshop on Advanced Superconductors (招待講演)
    • Place of Presentation
      岐阜
    • Year and Date
      2007-11-10
    • Related Report
      2009 Final Research Report
  • [Presentation] "Optimization of Superconducting Properties of Bi-Based Cuprates by Control of Chemical C2007

    • Author(s)
      J. Shimoyama
    • Organizer
      The 13th Japan-US Workshop on Advanced Superconductors
    • Place of Presentation
      長良川国際会議場(岐阜)
    • Year and Date
      2007-11-10
    • Related Report
      2007 Annual Research Report

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Published: 2007-04-01   Modified: 2016-04-21  

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