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Elucidation of Physical Properties of Novel Barium Titanate and Development of Process Technology for Application

Research Project

Project/Area Number 19360299
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Inorganic materials/Physical properties
Research InstitutionShimane University

Principal Investigator

AKISHIGE Yukikuni (2008-2009)  Shimane University, 教育学部, 教授 (30150981)

秋重 幸邦 (2007)  Shimane University, 教育学部, 教授 (50159331)

Co-Investigator(Kenkyū-buntansha) MATSUMOTO Ichiro  島根大学, 教育学部, 准教授 (30335541)
SHIGEMATSU Hirotake  島根大学, 教育学部, 准教授 (40281068)
XU Jun  島根大学, プロジェクト研究推進機構, 研究員 (30448203)
Project Period (FY) 2007 – 2009
Project Status Completed (Fiscal Year 2009)
Budget Amount *help
¥13,780,000 (Direct Cost: ¥10,600,000、Indirect Cost: ¥3,180,000)
Fiscal Year 2009: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
Fiscal Year 2008: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Fiscal Year 2007: ¥9,230,000 (Direct Cost: ¥7,100,000、Indirect Cost: ¥2,130,000)
Keywords誘電体物性 / セラミックス / 単結晶育成 / ナノ材料 / 配向制御 / 鉛フリー / 強誘電体 / 圧電体 / チタン酸バリウム / 単結晶 / 誘電率 / リラクサー
Research Abstract

On novel barium titanate (BaTi_2O_5), which is difficult to synthesize because it decomposes at high temperatures, we tried to develop process technology for application. By using sol-gel powders as a starting material and a Spark Plasma Sintering technique, dense and orientated ceramics were synthesized. Furthermore, by using MnO_2 as sintering-additives, dense ceramics were successfully synthesized without using any special sintering techniques. In KF-doped BaTi_2O_5, the Curie-temperature T_C steeply decreases with increasing content of KF, and a relaxor state appears. Single crystals with 3-5 mm in length were obtained.

Report

(4 results)
  • 2009 Annual Research Report   Final Research Report ( PDF )
  • 2008 Annual Research Report
  • 2007 Annual Research Report
  • Research Products

    (40 results)

All 2009 2008 2007 Other

All Journal Article (17 results) (of which Peer Reviewed: 16 results) Presentation (11 results) Remarks (4 results) Patent(Industrial Property Rights) (8 results)

  • [Journal Article] Piezoelectric Properties near the Tricritical Point in KF-doped BaTiO32009

    • Author(s)
      Y. Akishige, Y. Hiraki
    • Journal Title

      Jpn. J. Appl. Phys 48

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Enhanced Polarization Fluctuation in KF-Substituted BaTiO3 Single Crystals2009

    • Author(s)
      S. Tsukada, Y. Hiraki, Y. Akishige, S. Kojima
    • Journal Title

      Phys. Rev. B 80

    • NAID

      120007131525

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of BaTi2O5 Nanopowders by Sol-Gel Method and the Dielectric Properties of the Ceramics2009

    • Author(s)
      Y. Akishige, J. Xu, H. Shigematsu, S. Morito, T. Ohba
    • Journal Title

      Jpn. J. Appl. Phys. 48

    • NAID

      40016585493

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of BaTi_2O_5 Nanopowders by Sol-Gel Method and the Dielectric Properties of the Ceramics2009

    • Author(s)
      Y.Akishige, J.Xu、H.Shigematsu, S.Morito, T.Ohba
    • Journal Title

      Japan Journal of Applied Physics 48

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Enhanced Polarization Fluctuation in KF-Substituted BaTiO_3 Single Crystals2009

    • Author(s)
      S.Tsukada, Y.Hiraki, Y.Akishige, S.Kojima
    • Journal Title

      Physical Review B 80

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Piezoelectric Properties near the Tricritical Point in KF-doped BaTiO_32009

    • Author(s)
      Y.Akishige, Y.Hiraki
    • Journal Title

      Japan Journal of Applied Physics 48

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of BaTi_2O_5 Nanopowders by Sol-Gel Method and the Dielectric Properties of the Ceramics2009

    • Author(s)
      Y. Akishige, J. Xu, H. Shigematsu, S. Morito, T. Ohba
    • Journal Title

      Japan J. Applied Physics 48(in press)

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Phase Diagram of KF-doped BaTiO3 Single Crystal2008

    • Author(s)
      Y. Akishige
    • Journal Title

      Ferroelectrics 369

      Pages: 91-97

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Relaxor in KF-doped BaTi2O5 Ceramics by Spark Plasma Sintering2008

    • Author(s)
      J. Xu, Y. Akishige
    • Journal Title

      Appl. Phys. Lett. 92

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] KF-doped BaTi2O5 Ferroelectric Ceramics by Solid State Reaction of KF and Sol-Gel-Derived BaTi2O5 Powders2008

    • Author(s)
      J. Xu, Y. Akishige
    • Journal Title

      Appl. Phys. A 90

      Pages: 153-157

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Phase Diagram of KF-doped BaTiO_3 Single Crystal2008

    • Author(s)
      Y. Akishige
    • Journal Title

      Ferroelectrics 369

      Pages: 91-97

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] KF-doped BaTi_2O_5 Ferroelectric Ceramics by Solid State Reaction of KF and Sol-Gel-Derived BaTi_2O_5 Powders2008

    • Author(s)
      J. Xu and Y. Akishige
    • Journal Title

      Applied Physics A 90

      Pages: 153-157

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Relaxor in KF-doped BaTi_2O_5 Ceramics by Spark Plasma Sintering2008

    • Author(s)
      J. Xu and Y. Akishige
    • Journal Title

      Applies Physics Letters 92

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Utilization of Traveling Solvent Floating Zone Method in the Growth of BaTi2O5 Crystal2007

    • Author(s)
      E. Walker, A. Neogi, Y. Akishige
    • Journal Title

      Memoirs of the Faculty of Education, Shimane University 41

      Pages: 141-148

    • Related Report
      2009 Final Research Report
  • [Journal Article] Synthesis and Dielectric Properties of KF-Doped BaTi2O5 Ceramics2007

    • Author(s)
      J. Xu, Y. Akishige
    • Journal Title

      Ferroelectrics 356

      Pages: 24-30

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Neutron Power Diffraction Study of the Phase Transition in BaTi2O52007

    • Author(s)
      H. Shigematsu, Y. Akishige, S. Gvasaliya, V. Pomjakushin, S. Lushnikov, S. Kojima
    • Journal Title

      Ferroelectrics 346

      Pages: 43-48

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Neutron Power Diffraction Study of the Phase Transition in BaTi_2O_52007

    • Author(s)
      H. Shigematsu, et. al.
    • Journal Title

      Ferroelectrics 346

      Pages: 43-48

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Presentation] BaTi2O5セラミックスの作製と誘電特性2009

    • Author(s)
      本多一雄, 塚田真也, 秋重幸邦
    • Organizer
      中国四国北九州地区誘電体シンポジューム
    • Place of Presentation
      岡山大学
    • Year and Date
      2009-12-12
    • Related Report
      2009 Final Research Report
  • [Presentation] BaTi_2O_5セラミックスの作製と誘電特性2009

    • Author(s)
      本多一雄、塚田真也、秋重幸邦
    • Organizer
      中国四国北九州地区誘電体シンポジューム
    • Place of Presentation
      岡山大学
    • Year and Date
      2009-12-12
    • Related Report
      2009 Annual Research Report
  • [Presentation] 精密組成制御によるBaTiO3の巨大応答2009

    • Author(s)
      秋重幸邦
    • Organizer
      日本物理学会2009年秋季大会
    • Place of Presentation
      熊本大学
    • Year and Date
      2009-09-25
    • Related Report
      2009 Final Research Report
  • [Presentation] 精密組成制御によるBaTiO_3の巨大応答2009

    • Author(s)
      秋重幸邦
    • Organizer
      日本物理学会2009年秋季大会
    • Place of Presentation
      熊本大学
    • Year and Date
      2009-09-25
    • Related Report
      2009 Annual Research Report
  • [Presentation] Optically Anomorous Ferroelectric Phase Transition of BaTi_2O_5 Single Crystal2009

    • Author(s)
      Jun Xu, Yukikuni Akishige
    • Organizer
      12^<th> International Meeting on Ferroelectricity
    • Place of Presentation
      Xian、China
    • Year and Date
      2009-08-24
    • Related Report
      2009 Annual Research Report
  • [Presentation] Thermal Properties of Ferrroelectric BaTi2O5: A comparison with Ferroelectric BaTiO32008

    • Author(s)
      Y. Akishige
    • Organizer
      The 4th International Symposium on the New Frontiers of Thermal Studies of Materials
    • Place of Presentation
      Yokohama Media(Invited talk)
    • Related Report
      2009 Final Research Report
  • [Presentation] Ferroelectric Properties of KF-doped BaTiO3 and BaTi2O52008

    • Author(s)
      Y. Akishige
    • Organizer
      The 8th Russia/CIS/Baltic/Japan Symposium on Ferroelectricity
    • Place of Presentation
      Vilnius University, Lithuania(Invited talk)
    • Related Report
      2009 Final Research Report
  • [Presentation] Ferroelectric Properties of KF-doped BaTiO_3 and BaTi_2O_52008

    • Author(s)
      Y. Akishige
    • Organizer
      The 8^<9h> Russia/CIS/Baltic/Japan Symposiumon Ferroelectricity
    • Place of Presentation
      ビルニュス、リトアニア
    • Related Report
      2008 Annual Research Report
  • [Presentation] Thermal Properties of Ferrroelectric BaTi_2O_5 : A comparison with Ferroelectric BaTiO_32008

    • Author(s)
      Y. Akishige
    • Organizer
      The 4th International Symposium on the New Frontiers of Thermal Studies of Materials
    • Place of Presentation
      横浜、日本
    • Related Report
      2008 Annual Research Report
  • [Presentation] BaTi2O5ナノ粒子を用いたセラミックスの合成と物性2007

    • Author(s)
      秋重幸邦, 徐軍
    • Organizer
      第24回強誘電体応用会議
    • Place of Presentation
      京都
    • Related Report
      2009 Final Research Report
  • [Presentation] Phase Diagram of KF-doped BaTiO_32007

    • Author(s)
      Y. Akishige
    • Organizer
      第11回 ヨーロッパ強誘電体会議
    • Place of Presentation
      スロベニア
    • Related Report
      2007 Annual Research Report
  • [Remarks]

    • URL

      http://physics.edu.shimane-u.ac.jp

    • Related Report
      2009 Final Research Report
  • [Remarks]

    • URL

      http://physics.edu.shimane-u.ac.jp

    • Related Report
      2009 Annual Research Report
  • [Remarks]

    • URL

      http://physics.edu.shimane-u.ac.jp

    • Related Report
      2008 Annual Research Report
  • [Remarks]

    • URL

      http://physics.edu.shimane-u.ac.jp

    • Related Report
      2007 Annual Research Report
  • [Patent(Industrial Property Rights)] チタン酸バリウム系蛍光物質2009

    • Inventor(s)
      秋重幸邦
    • Industrial Property Rights Holder
      島根大学
    • Industrial Property Number
      2009-286076
    • Filing Date
      2009-12-17
    • Related Report
      2009 Final Research Report
  • [Patent(Industrial Property Rights)] BaTi2O5系強誘電性セラミックス製造方法2009

    • Inventor(s)
      秋重幸邦
    • Industrial Property Rights Holder
      島根大学
    • Industrial Property Number
      2009-148621
    • Filing Date
      2009-06-23
    • Related Report
      2009 Final Research Report
  • [Patent(Industrial Property Rights)] チタン酸バリウム系結晶の製造方法2009

    • Inventor(s)
      秋重幸邦
    • Industrial Property Rights Holder
      島根大学
    • Industrial Property Number
      2009-063809
    • Filing Date
      2009-03-17
    • Related Report
      2009 Final Research Report 2008 Annual Research Report
  • [Patent(Industrial Property Rights)] BaTi_2O_5系強誘電性セラミックス製造方法2009

    • Inventor(s)
      秋重幸邦
    • Industrial Property Rights Holder
      島根大学
    • Industrial Property Number
      2009-148621
    • Filing Date
      2009-06-23
    • Related Report
      2009 Annual Research Report
  • [Patent(Industrial Property Rights)] チタン酸バリウム系蛍物質2009

    • Inventor(s)
      秋重幸邦
    • Industrial Property Rights Holder
      島根大学
    • Filing Date
      2009-12-17
    • Related Report
      2009 Annual Research Report
  • [Patent(Industrial Property Rights)] kfを含有するチタン酸バリウム系圧電体またはその製造方法2007

    • Inventor(s)
      秋重幸邦
    • Industrial Property Rights Holder
      島根大学
    • Industrial Property Number
      2007-122088
    • Filing Date
      2007-05-07
    • Related Report
      2009 Final Research Report
  • [Patent(Industrial Property Rights)] チタン酸バリウム結晶、コンデンサ、光スイッチおよびfram2007

    • Inventor(s)
      秋重幸邦, 深野勝洋
    • Industrial Property Rights Holder
      島根大学
    • Acquisition Date
      2007-12-14
    • Related Report
      2009 Final Research Report
  • [Patent(Industrial Property Rights)] KFを含有するチタン酸バリウム系圧電体またはその製造方法2007

    • Inventor(s)
      秋重幸邦
    • Industrial Property Rights Holder
      島根大学
    • Industrial Property Number
      2007-122088
    • Filing Date
      2007-05-07
    • Related Report
      2007 Annual Research Report

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Published: 2007-04-01   Modified: 2016-04-21  

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