Development of ternary Ni_3Al-alloy catalysts for hydrogen production

• Project/Area Number: 19360321
• Research Category: Grant-in-Aid for Scientific Research (B)
• Allocation Type: Single-year Grants
• Section: 一般
• Research Field: Structural/Functional materials
• Research Institution: National Institute for Materials Science
• Principal Investigator: HIRANO Toshiyuki National Institute for Materials Science, 燃料電池材料センター, NIMS特別研究員 (90354183)
• Co-Investigator(Kenkyū-buntansha): XU Ya 独立行政法人物質・材料研究機構, 燃料電池材料センター, 主幹研究員 (00370304) ; DEMURA Masahiko 独立行政法人物質・材料研究機構, 燃料電池材料センター, 主任研究員 (10354177)
• Project Period (FY): 2007 – 2009
• Project Status: Completed (Fiscal Year 2009)
• Budget Amount: ¥20,150,000 (Direct Cost: ¥15,500,000、Indirect Cost: ¥4,650,000); Fiscal Year 2009: ¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000); Fiscal Year 2008: ¥5,590,000 (Direct Cost: ¥4,300,000、Indirect Cost: ¥1,290,000); Fiscal Year 2007: ¥9,750,000 (Direct Cost: ¥7,500,000、Indirect Cost: ¥2,250,000)
• Keywords: 水素 / 触媒・化学プロセス / 構造・機能材料 / 金属間化合物 / 触媒 / 表面ナノ粒子 / 合金化 / コンビナトリアル

Research Abstract

The proponents of this study have discovered a catalytic activity for hydrogen production via methanol decomposition. In this study we examined the effect of alloying elements on the catalytic activity. It was found that Fe enhances the activity and lowers the active temperature. Silicon and titanium were also found to show a similar effect, but have a disadvantage of accelerating carbon deposition. Chromium and vanadium were found to significantly decrease the activity.

Research Products

• [Journal Article] Characterization of surface structure evolution in Ni3Al foil catalysts by hard X-ray photoelectron spectroscopy (2010)
  • Author(s): Ya Xu, H. Yoshikawa, J.H. Jang, M. Demura, K. Kobayashi, S. Ueda, Y. Yamashita, D.M. Wee, T. Hirano
  • Journal Title: Journal of Physical Chemistry C Vol.114 Pages: 6047-6053
  • Peer Reviewed
• [Journal Article] Catalytic properties of cold-rolled Ni3(Si, Ti) intermetallic foils for methanol decomposition (2010)
  • Author(s): Y. Kaneno, T. Kondo, Y. Fujimoto, H. Tsuda, Ya Xu, M. Demura, H. Iwai, T. Hirano, T. Takasugi
  • Journal Title: Materials Transactions Vol.51 Pages: 1002-1010
  • Peer Reviewed
• [Journal Article] Catalytic activity of pre-activated Ni3Al foil catalysts for hydrogen production from methanol under steam addition (2010)
  • Author(s): J.H. Jang, Ya Xu, D.H. Chun, M. Demura, D.M. Wee, T. Hirano
  • Journal Title: Catalysis Letters Vol.134 Pages: 258-263
  • Peer Reviewed
• [Journal Article] Evolution of surface morphology in Ni(gamma)/Ni3Al(gamma') two-phase foils during electrochemical etching (2010)
  • Author(s): H.Y. Lee, M. Demura, Ya Xu, D.M. Wee, T. Hirano
  • Journal Title: ADVANCED MATERIALS RESEARCH Vol.89-91 Pages: 331-336
  • Peer Reviewed
• [Journal Article] Ni3Al Intermetallic catalysts for hydrogen production from methane steam reforming (2010)
  • Author(s): Ya Xu, D.H. Chun, J.H. Jang, M. Demura, D.M. Wee, T. Hirano
  • Journal Title: ADVANCED MATERIALS RESEARCH Vol.89-91 Pages: 645-650
  • Peer Reviewed
• [Journal Article] Catalytic activity of pre-activated Ni_3Al foil catalysts for hydrogen production from methanol under steam addition (2010)
  • Author(s): J.H.Jang, Ya Xu, D.H.Chun, M.Demura, D.M.Wee, T.Hirano
  • Journal Title: Catalysis Letters 134 Pages: 258-263
  • Peer Reviewed
• [Journal Article] Recrystallization textures in heavily cold-rolled Ni3Al based single crystals (2010)
  • Author(s): M.Demura, Ya Xu, T.Hirano
  • Journal Title: Mater.Sci. Forum 638-642 Pages: 1288-1293
  • Peer Reviewed
• [Journal Article] Evolution of surface morphology in Ni (gamma)/Ni_3Al (gamma') two- phase foils during electrochemical etching (2010)
  • Author(s): H.Y.Lee, M.Demura, Ya Xu, D.M.Wee, T.Hirano
  • Journal Title: ADVANCED MATERIALS RESEARCH 89-91 Pages: 331-336
  • Peer Reviewed
• [Journal Article] Ni_3Al Intermetallic catalysts for hydrogen production from methane steam reforming (2010)
  • Author(s): Ya Xu, D.H.Chun, J.H.Jang, M.Demura, D.M.Wee, T.Hirano
  • Journal Title: ADVANCED MATERIALS RESEARCH 89-91 Pages: 645-650
  • Peer Reviewed
• [Journal Article] Catalytic Properties of Cold-Rolled Ni3(Si, Ti) Intermetallic Foils for Methanol Decomposition (2010)
  • Author(s): Y.Kaneno, T.Kondo, Y.Fujimoto, H.Tsuda, Y.Xu, M.Demura, H.Iwai, T.Hirano, T.Takasugi
  • Journal Title: Mater.Trans. 51 Pages: 1002-1010
  • Peer Reviewed
• [Journal Article] Characterization of Surface Structure Evolution in Ni3Al Foil Catalysts by Hard X-ray Photoelectron Spectroscopy (2010)
  • Author(s): Y.Xu, H.Yoshikawa, J.H.Jang, M.Demura, K.Kobayashi, S.Ueda, Y.Yamashita, D.M.Wee, T.Hirano
  • Journal Title: J.Phys.Chem 114 Pages: 6047-6053
  • Peer Reviewed
• [Journal Article] Effects of steam addition on the spontaneous activation in Ni3Al foil catalysts during methanol decomposition (2009)
  • Author(s): J.H. Jang, Ya Xu, D.H. Chun, M. Demura, D.M. Wee, T. Hirano
  • Journal Title: Journal of Molecular Catalysis A: Chemical Vol.307 Pages: 21-28
  • Peer Reviewed
• [Journal Article] Catalytic properties of chemically pretreated Ni3Al/Ni two-phase alloy foils for methane steam reforming (2009)
  • Author(s): D. Kamikihara, Y. Xu, M. Demura, T. Hirano
  • Journal Title: Mat. Res. Soc., Proc. Vol.1128 Pages: 263-268
  • Peer Reviewed
• [Journal Article] Surface modification of Ni/Ni3Al two-phase foils by electrochemically selective etching (2009)
  • Author(s): H.Y. Lee, M. Demura, Y. Xu, D.M. Wee, T. Hirano
  • Journal Title: Mat. Res. Soc., Proc. Vol.1128 Pages: 269-274
  • Peer Reviewed
• [Journal Article] Surface structure modification of Ni3Al foil catalysts by oxidation-reduction treatment (2009)
  • Author(s): J.H. Jang, Y. Xu, D.H. Chun, M. Demura, D.M. Wee, T. Hirano
  • Journal Title: Mat. Res. Soc., Proc. Vol.1128 Pages: 275-280
  • Peer Reviewed
• [Journal Article] Catalytic properties of Atomized Ni3Al Powder for Methane Steam Reforming (2009)
  • Author(s): Y. Ma, Y. Xu, M. Demura, T. Hirano
  • Journal Title: Mat. Res. Soc., Proc. Vol.1128 Pages: 381-386
  • Peer Reviewed
• [Journal Article] Effects of steam addition on the spontaneous activation in Ni_3Al foil catalysts during methanol decomposition (2009)
  • Author(s): J.H.Jang, Ya Xu, D.H.Chun, M.Demura, D.M.Wee, T.Hirano
  • Journal Title: Journal of Molecular Catalysis A : Chemical 307 Pages: 21-28
  • Peer Reviewed
• [Journal Article] Catalytic properties of chemically pretreated Ni_3Al/Ni two-phase alloy foils for methane steam reforming (2009)
  • Author(s): D.Kamikihara, Y.Xu, M.Demura, T.Hirano
  • Journal Title: Mat.Res.Soc.,Proc. 1128 Pages: 263-268
  • Peer Reviewed
• [Journal Article] Surface modification of Ni/Ni_3Al two-phase foils by electrochemically selective etching (2009)
  • Author(s): H.Y.Lee, M.Demura, Y.Xu, D.M.Wee, T.Hirano
  • Journal Title: Mat.Res.Soc.,Proc. 1128 Pages: 269-274
  • Peer Reviewed
• [Journal Article] Surface structure modification of Ni_3Al foil catalysts by oxidation-reduction treatment (2009)
  • Author(s): J.H.Jang, Y.Xu, D.H.Chun, M.Demura, D.M.Wee, T.Hirano
  • Journal Title: Mat.Res.Soc.,Proc. 1128 Pages: 275-280
  • Peer Reviewed
• [Journal Article] Catalytic properties of Atomized Ni_3Al Powder for Methane Steam Reforming (2009)
  • Author(s): Y.Ma, Y.Xu, M.Demura, T.Hirano
  • Journal Title: Mat.Res.Soc.,Proc. 1128 Pages: 381-386
  • Peer Reviewed
• [Journal Article] Spontaneous Catalytic Activation of Ni_3(Si, Ti) Intermetallic Foils in Methanol Decomposition (2009)
  • Author(s): Y.Kaneno, T.Takasugi, H.Tsuda, Y.Xu, M.Demura, T.Hirano, H.Iwai
  • Journal Title: Mat.Res.Soc.,Proc. 1128 Pages: 257-262
  • Peer Reviewed
• [Journal Article] 強冷間圧延と再結晶・粒成長による金属間化合物の集合組織制御～結晶方位はどのように「記憶」されるか? (2009)
  • Author(s): 出村雅彦、許亜、岸田恭輔、平野後幸
  • Journal Title: まてりあ 48 Pages: 452-457
  • NAID: 10025156465
• [Journal Article] Ni超微粒子を担持する金属間化合物ナノ表面構造によるメタノール改質 (2009)
  • Author(s): 高杉隆幸、金野泰幸、津田大、今藤敏和、藤本泰載、平野敏幸、許亜、出村雅彦、岩井秀夫
  • Journal Title: 燃料電池 8 Pages: 66-73
• [Journal Article] Effect of alkali leaching on the surface structure of Ni3Al catalyst (2008)
  • Author(s): Y. Xu, M. Demura, T. Hirano
  • Journal Title: Applied Surface Science 254 Pages: 5413-5420
  • Peer Reviewed
• [Journal Article] Tensile Properties and Cold Rolling of Binary Ni-Al γ/γ' Two-phase Single Crystals (2008)
  • Author(s): D. Q. Li, K. Kishida, M. Demura、T. Hirano
  • Journal Title: Intermetallics 16 Pages: 1317-1324
  • Peer Reviewed
• [Journal Article] Catalytic properties of Ni/Ni_3Al two-phase alloy foils for methane steam reforming (2008)
  • Author(s): D. Kamikihara, Y. Xu, M. Demura, T. Hirano
  • Journal Title: Trans. Mater. Res. Soc. Japan 33 Pages: 1105-1108
  • Peer Reviewed
• [Journal Article] Catalytic stability of Ni_3Al powder for methane steam reforming (2008)
  • Author(s): Y. Ma
  • Journal Title: Apphed Catalysis B:Environmental 80 Pages: 15-23
  • Peer Reviewed
• [Journal Article] Effbct of alkah leaching on tlle suace structure of Ni_3Al catalyst (2008)
  • Author(s): Y. Xu
  • Journal Title: Applied Surface Science (印刷中)
  • Peer Reviewed
• [Journal Article] Laser welding of cold-rolled boron-free NisAl foils (2007)
  • Author(s): T. Hirano
  • Journal Title: Met.Mat.Trans.A 38A Pages: 1041-1047
  • Peer Reviewed
• [Journal Article] An athemal deformation model of the yield stress anomaly in Ni_3Al (2007)
  • Author(s): M. Demura
  • Journal Title: Intermetallics 15 Pages: 1322-1331
  • Peer Reviewed
• [Journal Article] Texture memory effect in heavily cold-rolled Ni_3Al single crystals (2007)
  • Author(s): M. Demura
  • Journal Title: Acta Materialia 55 Pages: 1779-1789
  • Peer Reviewed
• [Journal Article] Effect of surface pretreatment on the catalytic activity of atomized Ni_3Al powder fbr methane steam refbrming (2007)
  • Author(s): Y. Ma
  • Journal Title: Tfansactions of the MRS-Japan 32 Pages: 971-974
  • Peer Reviewed
• [Journal Article] Effects of steam addition on the spontaneous activation in Ni_3Al foil catalysts during methanol decomposition
  • Author(s): J. H. Jang, Y. Xu, D. H. Chun, M. Demura, D. M. Wee, T. Hirano
  • Journal Title: J. Mol. Catal. A : Chemical
  • Peer Reviewed
• [Journal Article] Catalytic properties of chemically pretreated Ni_3Al/Ni two-phase alloy foils for methane steam reforming
  • Author(s): D. Kamikihara, Y. Xu, M. Demura, T. Hirano
  • Journal Title: Mat. Res. Soc., Proc
  • Peer Reviewed
• [Journal Article] Surface modification of Ni/Ni_3Al two-phase foils by electrochemically selective etching
  • Author(s): H. Y. Lee, M. Demura, Y. Xu, D. M. Wee, T. Hirano
  • Journal Title: Mat. Res. Soc., Proc
  • Peer Reviewed
• [Journal Article] Surface structure modification of Ni_3Al foil catalysts by oxidation-reduction treatment
  • Author(s): J. H. Jang, Y. Xu, D. H. Chun, M. Demura, D. M. Wee, T. Hirano
  • Journal Title: Mat. Res. Soc., Proc
  • Peer Reviewed
• [Journal Article] Y. Ma, Y. Xu, M. Demura, T. Hirano
  • Author(s): Y. Ma, Y. Xu, M. Demura, T. Hirano
  • Journal Title: Mat. Res. Soc., Proc
  • Peer Reviewed
• [Journal Article] Spontaneous Catalytic Activation of Ni_3(Si,Ti) Intermetallic Foils in Methanol Decomposition
  • Author(s): Y. Kaneno, T. Takasugi, H. Tsuda, Y. Xu, M. Demura, T. Hirano, H. Iwai
  • Journal Title: Mat. Res. Soc., Proc
  • Peer Reviewed
• [Presentation] Surface Modification of Ni (γ) / Ni3Al (γ´) Two-Phase Foils by Selective Etching and alkali leaching for catalitic activity enhancement (2010)
  • Author(s): H.Y. Lee, 許亜, 出村雅彦, D.M. Wee, 平野敏幸
  • Organizer: 日本金属学会2010年春期大会
  • Place of Presentation: 筑波大学
• [Presentation] Behavior of Ni particle formation on Ni3Al foil surface by oxidation-reduction treatment (2010)
  • Author(s): J.H. Jang, 許亜, 出村雅彦, D.M. Wee, 平野敏幸
  • Organizer: 日本金属学会2010年春期大会
  • Place of Presentation: 筑波大学
• [Presentation] Effects of steam addition on spontaneous activation of Ni3Al foils (2009)
  • Author(s): J.H. Jang, 許亜, 出村雅彦, D.M. Wee, 平野敏幸
  • Organizer: 第19回日本MRS学術シンポジウム
  • Place of Presentation: 横浜市開港記念会館
• [Presentation] Ni3Al金属間化合物箔の水素製造触媒特性 (2009)
  • Author(s): 許亜, D.H. Chun, J.H. Jang, 出村雅彦, D.M. Wee, 平野敏幸
  • Organizer: 第104回日本触媒討論会
  • Place of Presentation: 宮崎大学
• [Presentation] Surface modification of Ni (γ) / Ni3Al (γ´) two-phase foil by electrochemical selective etching (2009)
  • Author(s): H.Y. Lee, 許亜, 出村雅彦, D.M. Wee, 平野敏幸
  • Organizer: 日本金属学会2009秋期大会
  • Place of Presentation: 京都大学
• [Presentation] プラズマ法によるNi-Al系金属間化合物のナノ粒子触媒の作製とその触媒特性 (2009)
  • Author(s): 許亜, 楊君友, 出村雅彦, 平野敏幸, 原徹
  • Organizer: 日本金属学会2009秋期大会
  • Place of Presentation: 京都大学
• [Presentation] Catalytic Properties of Ni3Al Foils for Methane Steam Reforming (2009)
  • Author(s): 馬雁, 許亜, 出村雅彦, 平野敏幸
  • Organizer: ISHHC XIV
  • Place of Presentation: Stockholm University, Stockholm, Sweden
• [Presentation] Catalytic properties of Ni3Al foil catalysts modified by oxidation-reduction for methanol decomposition (2009)
  • Author(s): J.H. Jang, 許亜, 出村雅彦, D.M. Wee, 平野敏幸
  • Organizer: ISHHC XIV
  • Place of Presentation: Stockholm University, Stockholm, Sweden
• [Presentation] Ni3Al INTERMETALLIC CATALYSTS FOR HYDROGEN PRODUCTION FROM METHANE STEAM REFORMING (2009)
  • Author(s): 許亜, D.H. Chun, 出村雅彦, D.M. Wee, 平野敏幸
  • Organizer: THERMEC'2009
  • Place of Presentation: Techincal University-Berlin, Berlin, Germany
• [Presentation] Evolution of surface morphology in Ni (γ) / Ni3Al (γ') two-phase foils during electrochemical etching. (2009)
  • Author(s): H.Y. Lee, 許亜, 出村雅彦, D.M. Wee, 平野敏幸
  • Organizer: THERMEC'2009
  • Place of Presentation: Techincal University-Berlin, Berlin, Germany
• [Presentation] Effects of steam addition on spontaneous activation of Ni3Al foils (2009)
  • Author(s): J.H.Jang, 許亜、出村雅彦、D.M.Wee, 平野敏幸
  • Organizer: 第19回 日本MRS学術シンポジウム
  • Place of Presentation: 横浜市開港記念会館(横浜市)
• [Presentation] 水素製造用Ni金属間化合物触媒の開発 (2009)
  • Author(s): 許亜、出村雅彦、平野敏幸
  • Organizer: 第2回触媒材料研究会
  • Place of Presentation: ラフォーレ蔵王リゾート&スパ(宮城県蔵王町)
• [Presentation] Catalytic properties of Ni_3Al foil catalysts modified by oxidation-reduction for methanol decomposition (2009)
  • Author(s): J.H.Jang, 許亜、出村雅彦、D.M.Wee, 平野敏幸
  • Organizer: 第2回触媒材料研究会
  • Place of Presentation: ラフォーレ蔵王リゾート&スパ(宮城県蔵王町)
• [Presentation] Catalytic Properties of Ni_3Al foils for Methane Steam Reforming (2009)
  • Author(s): 馬雁、許亜、出村雅彦、平野敏幸
  • Organizer: ISHHC XIV
  • Place of Presentation: Stockholm University(スウェーデン)
• [Presentation] Catalytic properties of Ni_3Al foil catalysts modified by oxidation-reduction for methanol decomposition (2009)
  • Author(s): J.H.Jang, 許亜、出村雅彦、D.M.Wee, 平野敏幸
  • Organizer: ISHHC XIV
  • Place of Presentation: Stockholm University(スウェーデン)
• [Presentation] Diffusion Bonding of Boron-free Ni3Al Foils (2009)
  • Author(s): 計紅軍、出村雅彦、許亜、平野敏幸、杉本喜正、中島清美
  • Organizer: 日本金属学会2009秋期講演大会
  • Place of Presentation: 京都大学(京都市)
• [Presentation] Surface modification of Ni (γ)/Ni3Al (γ´) two-phase foil by electrochemical selevtive etching (2009)
  • Author(s): H.Y.Lee, 許亜、出村雅彦、D.M.Wee, 平野敏幸
  • Organizer: 日本金属学会2009秋期講演大会
  • Place of Presentation: 京都大学(京都市)
• [Presentation] プラズマ法によるNi-Al系金属間化合物のナノ粒子触媒の作製とその触媒特性 (2009)
  • Author(s): 許亜、楊君友、出村雅彦、平野敏幸、原徹
  • Organizer: 日本金属学会2009秋期講演大会
  • Place of Presentation: 京都大学(京都市)
• [Presentation] Ni_3Al金属間化合物箔の水素製造触媒特性 (2009)
  • Author(s): 許亜、D.H.Chun, H.H.Jang, 出村雅彦、D.M.Wee, 平野敏幸
  • Organizer: 第104回日本触媒討論会
  • Place of Presentation: 宮崎大学(宮崎市)
• [Presentation] Ni3Al INTERMETALLIC CATALYSIS FOR HYDROGEN PRODUCTION FROM METHANE STEAM REFORMING (2009)
  • Author(s): 許亜、D.H.Chun, 出村雅彦、D.M.Wee, 平野敏幸
  • Organizer: THERMEC' 2009
  • Place of Presentation: Technical University-Berlin(ドイツ)
• [Presentation] Recrystallization textures in heavily cold-rolled Ni3Al based single crystals (2009)
  • Author(s): 出村雅彦、許亜、平野敏幸
  • Organizer: THERMEC' 2009
  • Place of Presentation: Technical University-Berlin(ドイツ)
• [Presentation] Evolution of surface morphology in Ni (gamma)/Ni3Al (gamma') two-phase foils during electrochemical etching (2009)
  • Author(s): H.Y.Lee, 許亜、出村雅彦、D.M.Wee, 平野敏幸
  • Organizer: THERMEC' 2009
  • Place of Presentation: Technical University-Berlin(ドイツ)
• [Presentation] Ni_3Al/Ni2相箔表面に及ぼすアルカリ処理の影響とその触媒特性 (2009)
  • Author(s): 上木原大介, 許亜, 出村雅彦, 平野敏幸
  • Organizer: 日本金属学会2009年春期大会
  • Place of Presentation: 東工大
• [Presentation] 強圧延・再結晶による金属間化合物の集合組織制御 (2009)
  • Author(s): 出村雅彦
  • Organizer: 日本金属学会2009年春期大会
  • Place of Presentation: 東工大
• [Presentation] In-plane anisotropy in tensile properties of heavily cold-rolled binary Ni_3Al foils (2008)
  • Author(s): M. Demura, Y. Xu, T. Hirano
  • Organizer: The 7^<th> International Workshop on Advanced Intermetallics and Metallic Materials
  • Place of Presentation: Harbin, P. R. China
• [Presentation] Surface Characterization of Ni_3Al foil Catalyst by Hard X-ray Photoelectron Spectroscopy (2008)
  • Author(s): Y. Xu, H. Yoshikawa, J. H. Jang, M. Demura, K. Kobayashi S. Ueda, D. Nomoto, Y. Yamashita, D. M. Wee, T. Hirano
  • Organizer: 14^<th> International Congress on Catalysis
  • Place of Presentation: Seoul, Korea
• [Presentation] Effects of H_2O Addition on the Catalytic Properties of Ni_3Al Foils for Hydrogen Production from Methanol (2008)
  • Author(s): J. H. Jang, Y. Xu, D. H. Chun, M. Demura, D. M. Wee, T. Hirano
  • Organizer: 14^<th> International Congress on Catalysis
  • Place of Presentation: Seoul, Korea
• [Presentation] Properties of Ni/Ni_3Al Two-phase Foil catalysts for Methane Steam Reforming (2008)
  • Author(s): D. Kamikihara, Y. Xu, M. Demura, T. Hirano
  • Organizer: 14^<th> International Congress on Catalysis
  • Place of Presentation: Seoul, Korea
• [Presentation] Ni_3Al/Ni 2相箔の再結晶集合組織 (2008)
  • Author(s): 出村雅彦, 許亜, 平野敏幸
  • Organizer: 日本金属学会2008年度秋期大会
  • Place of Presentation: 熊本大
• [Presentation] Ni基金属間化合物箔の水素製造触媒活性発現機構の考察 (2008)
  • Author(s): 許亜, 出村雅彦, 平野敏幸, 金野泰幸, 高杉隆幸
  • Organizer: 日本金属学会2008年度秋期大会
  • Place of Presentation: 熊本大
• [Presentation] メタノール分解反応におけるNi_3(Si,Ti)冷間圧延箔の触媒活性 (2008)
  • Author(s): 金野泰幸, 今藤敏和, 津田大, 高杉隆幸, 許亜, 出村雅彦, 平野敏幸
  • Organizer: 日本金属学会2008年度秋期大会
  • Place of Presentation: 熊本大
• [Presentation] Electrochemical selective etching in Ni(γ)/Ni_3Al(γ') two-phase alloys (2008)
  • Author(s): 李慧娟, 出村雅彦, 許亜, 韋當文, 平野敏幸
  • Organizer: 日本金属学会2008年度秋期大会
  • Place of Presentation: 熊本大
• [Presentation] Effects of H_2O addition on the spontaneous activation of Ni_3Al foils in methanol decomposition (2008)
  • Author(s): 張〓赫, 許亜, 出村雅彦, 韋當文, 平野敏幸
  • Organizer: 日本金属学会2008年度秋期大会
  • Place of Presentation: 熊本大
• [Presentation] 表面化学処理したNi_3Al/Ni2相箔の水素製造反応に対する触媒特性 (2008)
  • Author(s): 上木原大介, 許亜, 出村雅彦, 平野敏幸
  • Organizer: 日本金属学会2008年度秋期大会
  • Place of Presentation: 熊本大
• [Presentation] Ni_3Alの触媒特性 (2008)
  • Author(s): 平野敏幸
  • Organizer: 第1回触媒材料研究会、日本金属学会・金属触媒材料研究会
  • Place of Presentation: 岩手県一関市
• [Presentation] 表面化学処理したNi_3Al/Ni2相箔の水素製造反応に対する触媒特性 (2008)
  • Author(s): 上木原大介
  • Organizer: 第1回触媒材料研究会、日本金属学会・金属触媒材料研究会
  • Place of Presentation: 岩手県一関市
• [Presentation] Effects of H_2O addition on the spontaneous activation of Ni_3Al foils in methanol decomposition (2008)
  • Author(s): 張〓赫
  • Organizer: 第1回触媒材料研究会、日本金属学会・金属触媒材料研究会
  • Place of Presentation: 岩手県一関市
• [Presentation] Electrochemical selective etching in Ni(γ)/Ni_3Al(γ') two-phase alloys (2008)
  • Author(s): 李慧娟
  • Organizer: 第1回触媒材料研究会、日本金属学会・金属触媒材料研究会
  • Place of Presentation: 岩手県一関市
• [Presentation] Catalytic properties of chemically pretreated Ni_3Al/Ni two-phase alloy foils for methane steam reforming (2008)
  • Author(s): D. Kamikihara, Y. Xu, M. Demura, T. Hirano
  • Organizer: MRS 2008 FALL MEETING
  • Place of Presentation: Boston, USA
• [Presentation] Surface modification of Ni/Ni_3Al two-phase foils by electrochemically selective etching (2008)
  • Author(s): H. Y. Lee, M. Demura, Y. Xu, D. M. Wee, T. Hirano
  • Organizer: MRS 2008 FALL MEETING
  • Place of Presentation: Boston, USA
• [Presentation] Surface Structure Modification of Ni_3Al Foil Catalysts by Oxidation-reduction Treatment (2008)
  • Author(s): J. H. Jang, Y. Xu, M. Demura, W. D. Moon, T. Hirano
  • Organizer: MRS 2008 FALL MEETING
  • Place of Presentation: Boston, USA
• [Presentation] Catalytic properties of Atomized Ni_3Al Powder for Methane Steam Reforming (2008)
  • Author(s): Y. Ma, Y. Xu, M. Demura, T. Hirano
  • Organizer: MRS 2008 FALL MEETING
  • Place of Presentation: Boston, USA
• [Presentation] Spontaneous Catalytic Activation of Ni_3(Si,Ti) Intermetallic Foils in Methanol Decomposition (2008)
  • Author(s): Y. Kaneno, T. Takasugi, H. Tsuda, Y. Xu, M. Demura, T. Hirano, H. Iwai
  • Organizer: MRS 2008 FALL MEETING
  • Place of Presentation: Boston, USA
• [Presentation] Ni_3Al foil catalysts for hydrogen production from methanol (2008)
  • Author(s): Y. Xu, D. H. Chun, J. H. Jang, M. Demura, D. M. Wee, T. Hirano
  • Organizer: IUMRS International Conference in Asia 2008
  • Place of Presentation: Nagoya, Japan
• [Presentation] 強冷間圧延と熱処理によるNi_3Al/Ni複相組織変化 (2008)
  • Author(s): 出村 雅彦
  • Organizer: 日本金属学会2008年度春期大会
  • Place of Presentation: 武蔵工大
• [Presentation] メタンの水蒸気改質反応におけるNi/Ni_3Al2相箔の触媒特性 (2008)
  • Author(s): 上木 原大介
  • Organizer: 日本金属学会2008年度春期大会
  • Place of Presentation: 武蔵工大
• [Presentation] アルカリ処理にょるNi_3Al粉末表面の微細組織形成 (2008)
  • Author(s): 許 亜
  • Organizer: 日本金属学会2008年度春期大会
  • Place of Presentation: 武蔵工大
• [Presentation] Recrystallization in the binary NisAUNi two-phase heavily cold-rolled foils (2007)
  • Author(s): Xing Wang
  • Organizer: 日本金属学会2007年度秋期大会
  • Place of Presentation: 岐阜大
• [Presentation] 高エネルギー光電子分光によるNi3A1金属間化合物箔触媒の表面解析 (2007)
  • Author(s): 許 亜
  • Organizer: 日本金属学会2007年度秋期大会
  • Place of Presentation: 岐阜大
• [Presentation] 水素製造反応に対するNi3Al金属間化合物の触媒特性 (2007)
  • Author(s): 許 亜
  • Organizer: 日本金属学会2007年度秋期大会
  • Place of Presentation: 岐阜大
• [Presentation] Ni_3Al/Ni2相箔の再結晶集合組織 (2007)
  • Author(s): 出村 雅彦
  • Organizer: 日本金属学会2007年度秋期大会
  • Place of Presentation: 岐阜大
• [Presentation] メタノール分解反応に対するNi_3(Si,Ti)冷間圧延箔の触媒特性 (2007)
  • Author(s): 今藤 敏和
  • Organizer: 日本金属学会2007年度秋期大会
  • Place of Presentation: 岐阜大
• [Presentation] メタンの水蒸気改質反応におけるNi/Ni_3Al2相箔の触媒特性 (2007)
  • Author(s): 上木 原大介
  • Organizer: 日本金属学会2007年度秋期大会
  • Place of Presentation: 岐阜大
• [Presentation] Ni_3(Si,Ti)冷間圧延箔の触媒活性 (2007)
  • Author(s): 今藤 敏和
  • Organizer: 日本鉄鋼協会2007年度秋季大会
  • Place of Presentation: 岐阜大
• [Presentation] メタンの水蒸気改質反応におけるNi/Ni_3Al2相箔の触媒特性 (2007)
  • Author(s): 上木 原大介
  • Organizer: 第18回日本MRS学術シンポジウム
  • Place of Presentation: 日本大学理工学部
• [Patent(Industrial Property Rights)] メタンの水蒸気改質触媒 (2009)
  • Inventor(s): 許亜, 揚君友, 出村雅彦, 平野敏幸, 原徹
  • Industrial Property Rights Holder: 独立行政法人物質・材料研究機構
  • Industrial Property Number: 2009-047471
  • Filing Date: 2009-03-02
• [Patent(Industrial Property Rights)] メタンの水蒸気改質触媒 (2009)
  • Inventor(s): 許亜, 揚君友, 出村雅彦, 平野敏幸, 原徹
  • Industrial Property Rights Holder: 許亜, 出村雅彦, 平野敏幸, 原徹
  • Industrial Property Number: 2008-313902
  • Filing Date: 2009-03-02
• [Patent(Industrial Property Rights)] CO酸化触媒 (2008)
  • Inventor(s): 許亜, 揚君友, 出村雅彦, 平野敏幸, 原徹
  • Industrial Property Rights Holder: 独立行政法人物質・材料研究機構
  • Industrial Property Number: 2008-313902
  • Filing Date: 2008-12-10
• [Patent(Industrial Property Rights)] メタノール分解触媒 (2008)
  • Inventor(s): 許亜、揚君友、出村雅彦、平野敏幸、原徹
  • Industrial Property Rights Holder: 独立行政法人物質・材料研究機構
  • Industrial Property Number: 2008-313931
  • Filing Date: 2008-12-10
• [Patent(Industrial Property Rights)] メタノール分解触媒 (2008)
  • Inventor(s): 許亜, 揚君友, 出村雅彦, 平野敏幸, 原徹
  • Industrial Property Rights Holder: 許亜, 出村雅彦, 平野敏幸, 原徹
  • Industrial Property Number: 2008-313931
  • Filing Date: 2008-12-10
• [Patent(Industrial Property Rights)] Ni3(Si,Ti)系金属間化合物からなるメタノールからの水素製造用触媒,水素製造方法、水素製造装置 (2007)
  • Inventor(s): 高杉隆幸、金野康幸、許亜、出村雅彦、平野敏幸
  • Industrial Property Rights Holder: 独立行政法人物質・材料研究機構
  • Industrial Property Number: 2007-192525
  • Acquisition Date: 2007-07-24
• [Patent(Industrial Property Rights)] Ni_3(Si, Ti)系金属間化合物からなるメタノールからの水素製造用触媒 (2007)
  • Inventor(s): 高杉 隆幸
  • Industrial Property Rights Holder: 高杉 隆幸
  • Industrial Property Number: 2007-192525
  • Filing Date: 2007-07-24