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Electrochemical Thin Layer Processing by Reduction-Diffusion Method Using Ionic Liquid Baths at Medium-Low Temperatures

Research Project

Project/Area Number 19360343
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Metal making engineering
Research InstitutionKyoto University

Principal Investigator

MURASE Kuniaki  Kyoto University, 大学院・工学研究科, 准教授 (30283633)

Co-Investigator(Kenkyū-buntansha) SUGIMURA Hiroyuki  京都大学, 大学院・工学研究科, 教授 (10293656)
AWAKURA Yasuhiro  京都大学, 大学院・工学研究科, 教授 (70109015)
Co-Investigator(Renkei-kenkyūsha) ICHII Takashi  京都大学, 大学院・工学研究科, 助教 (30447908)
ITO Akira  京都大学, 大学院・工学研究科, 修士課程学生(現 株式会社キーエンス)
NISHIZAKI Yui  京都大学, 大学院・工学研究科, 修士課程学生(現 川崎重工業株式会社)
Project Period (FY) 2007 – 2008
Project Status Completed (Fiscal Year 2008)
Budget Amount *help
¥20,800,000 (Direct Cost: ¥16,000,000、Indirect Cost: ¥4,800,000)
Fiscal Year 2008: ¥5,330,000 (Direct Cost: ¥4,100,000、Indirect Cost: ¥1,230,000)
Fiscal Year 2007: ¥15,470,000 (Direct Cost: ¥11,900,000、Indirect Cost: ¥3,570,000)
Keywordsイオン液体 / 室温溶融塩 / 常温溶融塩 / 還元拡散 / 電析 / 電気めっき / 合金形成 / 薄膜 / めっき
Research Abstract

スズイオンを含む溶液に浸した金属銅素地を陰極とし、ある条件で電解を行う。するとスズイオンは銅素地表面でスズ原子に還元されると同時に素地内部へと拡散し、銅素地はCu-Sn 合金(スペキュラム合金)となる。還元拡散と呼ばれるこのような現象は、水溶液が使えない100~200 °C の中低温を必要とし、本研究では作業環境のよい疎水性イオン液体を溶媒に用いる技術を開発した。ここではCu-Sn 合金薄膜形成に加え、Cu-Zn 合金(黄銅)の形成にも成功した。これらは自然順応型の新しい装飾めっきプロセスとして期待される。

Report

(3 results)
  • 2008 Annual Research Report   Final Research Report ( PDF )
  • 2007 Annual Research Report
  • Research Products

    (36 results)

All 2009 2008 2007 Other

All Journal Article (12 results) (of which Peer Reviewed: 6 results) Presentation (23 results) Remarks (1 results)

  • [Journal Article] Cu-Sn Alloy Metallization of Polymer Substrate through Reduction-Diffusion Method Using Ionic Liquid Bath at Medium-Low Temperatures2009

    • Author(s)
      A. Ito, K. Murase, T. Ichii, and H. Sugimura
    • Journal Title

      Electrochemistry(in press) Vol.77, No.8

    • NAID

      10025015852

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] 中低温イオン液体を用いた還元拡散法による銅合金形成2009

    • Author(s)
      邑瀬邦明
    • Journal Title

      溶融塩および高温化学 52巻, 1号

      Pages: 14-21

    • NAID

      40016711846

    • Related Report
      2008 Final Research Report
  • [Journal Article] Cu-Sn Alloy Metallization of Polymer through Reduction-Diffusion Method Using Ionic Liquid Bath at Medium-Low Temperature2009

    • Author(s)
      A. Ito, K. Murase, T. Ichii, and H. Sugimura
    • Journal Title

      ECS Transactions(in press) Vol.16(Molten Salts and Ionic Liquids 16)

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Cu-Sn Alloy Metallization of Polymer Substrate through Reduction-Diffusion Method Using Ionic Liquid Bath at Medium-Low Temperatures, Proceedings of 2008 Joint Symposium on Molten Salts2009

    • Author(s)
      A. Ito, K. Murase, T. Ichii, and H. Sugimura
    • Pages
      542-546
    • Related Report
      2008 Final Research Report
  • [Journal Article] Cu-Sn Alloy Metallization of Polymer through Reduction-Diffusion Method Using Ionic Liquid Bath at Medium-Low Temperature2009

    • Author(s)
      Akira Ito
    • Journal Title

      ECS Transactions 16(印刷中)

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Faster Growth of Cu-Sn Layers through Reduction-Diffusion Method using Ionic Liquid Bath at Medium-Low Temperatures, ECS Transactions, Vol.11, No.28(Electrodeposition of Nanoengineered Materials and Alloys 2)2008

    • Author(s)
      K. Murase, A. Ito, and H. Sugimura
    • Pages
      103-109
    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] 中低温イオン液体を用いた還元拡散による銅合金形成2008

    • Author(s)
      邑瀬邦明
    • Journal Title

      化学工業 Vol.59, No.3

      Pages: 207-213

    • Related Report
      2008 Final Research Report
  • [Journal Article] Cu-Sn Alloy Metallization of Polymer Substrate through Reduction-Diffusion Method Using Ionic Liquid Bath at Medium-Low Temperatures2008

    • Author(s)
      Akira Ito
    • Journal Title

      Proceedings of 2008 Joint Symposium on Molten Salts

      Pages: 542-546

    • NAID

      130002150632

    • Related Report
      2008 Annual Research Report
  • [Journal Article] Electrochemical Alloying of Copper Substrate with Tin Using Ionic Liquid as an Electrolyte at Medium-Low Temperatures2007

    • Author(s)
      K. Murase, R. Kurosaki, T. Katase, H. Sugimura, T. Hirato, and Y. Awakura
    • Journal Title

      J. Electrochem. Soc. Vol.154, No.11

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Electrochemical Alloying of Copper Substrate with Tin Using Ionic Liquid as an Electrolyte at Medium-Low Temperatures2007

    • Author(s)
      Kuniaki Murase
    • Journal Title

      Journal of the Electrochemical Society 154

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Electrochemical Alloying of Copper Substrate with Tin Using Ionic Liquid as an Electrolyte at Medium-Low Temperatures2007

    • Author(s)
      Kuniaki Murase
    • Journal Title

      ECS Transactions 3(35)

      Pages: 313-322

    • Related Report
      2007 Annual Research Report
  • [Journal Article] 中低温イオン液体浴を用いた還元拡散による銅合金形成2007

    • Author(s)
      邑瀬邦明
    • Journal Title

      化学工業 59

      Pages: 207-213

    • Related Report
      2007 Annual Research Report
  • [Presentation] イオン液体中での定電位法によるCu 素地表面の黄銅化2009

    • Author(s)
      簗瀬功造, 伊藤 輝,邑瀬邦明,一井 崇, 杉村博之
    • Organizer
      電気化学会第76 回大会
    • Place of Presentation
      電気化学会第76 回大会
    • Year and Date
      2009-03-29
    • Related Report
      2008 Final Research Report
  • [Presentation] イオン液体中での還元拡散法によるCu-Zn 合金形成2009

    • Author(s)
      簗瀬功造, 伊藤輝,邑瀬邦明,一井崇, 杉村博之
    • Organizer
      表面技術協会第119回講演大会
    • Place of Presentation
      山梨大学
    • Year and Date
      2009-03-17
    • Related Report
      2008 Final Research Report
  • [Presentation] 中低温イオン液体を用いた還元拡散法による銅合金形成2009

    • Author(s)
      邑瀬邦明
    • Organizer
      第168 回溶融塩委員会
    • Place of Presentation
      神戸大学
    • Year and Date
      2009-01-27
    • Related Report
      2008 Final Research Report
  • [Presentation] 中低温イオン液体を用いた定電位法によるCu-Zn 合金形成2008

    • Author(s)
      簗瀬功造, 西崎ゆい,邑瀬邦明,一井 崇, 杉村博之
    • Organizer
      平成20年度材料化学研究会・鉄鋼プロセス研究会合同研究会
    • Place of Presentation
      大阪大学
    • Year and Date
      2008-12-19
    • Related Report
      2008 Final Research Report
  • [Presentation] イオン液体中での定電位法によるCu-Zn合金形成2008

    • Author(s)
      簗瀬功造, 西崎ゆい, 邑瀬邦明,一井崇, 杉村博之
    • Organizer
      第10回関西表面技術フォーラム
    • Place of Presentation
      甲南大学
    • Year and Date
      2008-12-02
    • Related Report
      2008 Final Research Report
  • [Presentation] Cu-Sn Alloy Metallization of Polymer Substrate through Reduction-Diffusion Method Using Ionic Liquid Bath at Medium-Low Temperatures, 2008 Joint Symposium on Molten Salts2008

    • Author(s)
      A. Ito. K. Murase, T. Ichii, and H. Sugimura
    • Place of Presentation
      Kobe, Japan
    • Year and Date
      2008-10-20
    • Related Report
      2008 Final Research Report
  • [Presentation] Copper Alloy Metallization through Reduction-Diffusion Method Using Medium-Low Temperature Ionic Liquid Baths, Pacific Rim Meeting on Electrochemical and Solid-State Science(PRIME 2008)2008

    • Author(s)
      K. Murase, A. Ito, Y. Nishizaki, T. Ichii, and H. Sugimura
    • Place of Presentation
      Honolulu, Hawaii
    • Year and Date
      2008-10-16
    • Related Report
      2008 Final Research Report
  • [Presentation] Copper Alloy Metallization through Reduction-Diffusion Method Using Medium-Low Temperature Ionic Liquid Baths2008

    • Author(s)
      Kuniaki Murase
    • Organizer
      Pacific Rim Meeting on Electrochemical and Solid-State Science(PRiME 2008)
    • Place of Presentation
      Honolulu, Hawaii
    • Year and Date
      2008-10-16
    • Related Report
      2008 Annual Research Report
  • [Presentation] Cu-Sn Metallization of Polymer through Reduction-Diffusion Method Using Ionic Liquid Bath at Medium-Low Temperature, Pacific Rim Meeting on Electrochemical and Solid-State Science(PRIME 2008)2008

    • Author(s)
      A. Ito. K. Murase, T. Ichii, and H. Sugimura
    • Place of Presentation
      Honolulu, Hawaii
    • Year and Date
      2008-10-15
    • Related Report
      2008 Final Research Report
  • [Presentation] イミダゾリウム型イオン液体を用いる電気化学的Cu-Sn合金形成2008

    • Author(s)
      伊藤 輝, 邑瀬邦明, 一井崇, 粟倉泰弘, 杉村博之
    • Organizer
      表面技術協会第116回講演大会
    • Place of Presentation
      長崎大学
    • Year and Date
      2008-09-18
    • Related Report
      2008 Final Research Report
  • [Presentation] K. Murase, A. Ito, T. Ichii, and H. Sugimura, Cu-Sn Metallization of Polymer through Reduction-Diffusion Method Using Ionic Liquid Baths at Medium-Low Temperatures, 59th Annual Meeting of the International Society of Electrochemistry2008

    • Author(s)
      K. Murase, A. Ito, T. Ichii, and H. Sugimura
    • Place of Presentation
      Sevilla, Spain
    • Year and Date
      2008-09-07
    • Related Report
      2008 Final Research Report
  • [Presentation] イオン液体浴を用いた還元拡散によるCu-Sn合金形成挙動2008

    • Author(s)
      伊藤輝, 邑瀬邦明, 一井崇, 杉村博之
    • Organizer
      表面技術協会第118回講演大会
    • Place of Presentation
      近畿大学
    • Year and Date
      2008-09-02
    • Related Report
      2008 Final Research Report
  • [Presentation] 中低温イオン液体浴を用いたCu 素地表面の一段階黄銅化2008

    • Author(s)
      簗瀬功造, 西崎ゆい, 邑瀬邦明, 一井崇, 杉村博之
    • Organizer
      表面技術協会第118回講演大会
    • Place of Presentation
      近畿大学
    • Year and Date
      2008-09-01
    • Related Report
      2008 Final Research Report
  • [Presentation] 中低温イオン液体浴を用いた還元拡散法による高分子表面のCu-Snメタライジング2008

    • Author(s)
      伊藤輝, 邑瀬邦明, 一井崇, 杉村博之
    • Organizer
      電気化学会第75回大会
    • Place of Presentation
      山梨大学
    • Year and Date
      2008-03-31
    • Related Report
      2008 Final Research Report
  • [Presentation] 中低温イオン液体浴を用いた還元拡散法によるCu 素地表面の一段階黄銅化2008

    • Author(s)
      西崎ゆい, 邑瀬邦明, 一井崇, 杉村博之
    • Organizer
      電気化学会第75回大会
    • Place of Presentation
      山梨大学
    • Year and Date
      2008-03-29
    • Related Report
      2008 Final Research Report
  • [Presentation] 中低温イオン液体を用いた還元拡散法による銅合金皮膜形成2008

    • Author(s)
      邑瀬邦明
    • Organizer
      京都大学界面科学高等研究院第3回全体セミナー
    • Place of Presentation
      京都大学
    • Year and Date
      2008-03-17
    • Related Report
      2008 Final Research Report
  • [Presentation] 中低温イオン液体を用いた還元拡散法による樹脂上へのCu-Sn合金形成2008

    • Author(s)
      伊藤輝, 邑瀬邦明, 一井崇, 杉村博之
    • Organizer
      表面技術協会第117回講演大会
    • Place of Presentation
      日本大学(津田沼)
    • Year and Date
      2008-03-13
    • Related Report
      2008 Final Research Report
  • [Presentation] 還元拡散によるCu薄膜のCu-Sn合金化2007

    • Author(s)
      伊藤輝, 邑瀬邦明, 一井崇, 杉村博之
    • Organizer
      第9回関西表面技術フォーラム
    • Place of Presentation
      近畿大学
    • Year and Date
      2007-12-12
    • Related Report
      2008 Final Research Report
  • [Presentation] イオン液体を用いた中低温還元拡散法による銅合金の形成法2007

    • Author(s)
      邑瀬邦明
    • Organizer
      溶融塩委員会創立50 周年記念第38 回溶融塩化学講習会
    • Place of Presentation
      神戸大学
    • Year and Date
      2007-10-30
    • Related Report
      2008 Final Research Report
  • [Presentation] Fast Growth of Cu-Sn Layers through Reduction-Diffusion Method using Ionic Liquid Bath at Medium-Low Temperatureas2007

    • Author(s)
      K. Murase, A. Ito, and H. Sugimura
    • Organizer
      212th The Electrochemical Society(ECS)Meeting
    • Place of Presentation
      Washington, DC
    • Year and Date
      2007-10-09
    • Related Report
      2008 Final Research Report
  • [Presentation] Fast Growth of Cu-Sn Layers through Reduction-Diffusion Method using Ionic Liquid Bath at Medium-Low Temperatures2007

    • Author(s)
      Kuniaki Murase
    • Organizer
      212th Meeting of The Electrochemical Society
    • Place of Presentation
      Washington, DC, USA
    • Year and Date
      2007-10-09
    • Related Report
      2007 Annual Research Report
  • [Presentation] イオン液体中でのCu素地の電気化学的Cu-Zn 合金化2007

    • Author(s)
      西崎ゆい, 邑瀬邦明, 一井崇, 粟倉泰弘, 杉村博之
    • Organizer
      表面技術協会第116回講演大会
    • Place of Presentation
      長崎大学
    • Year and Date
      2007-09-18
    • Related Report
      2008 Final Research Report
  • [Presentation] Fast Growth of Cu-Sn Layers through Reduction-Diffusion Method using Ionic Liquid Bath at Medium-Low Temperatures2007

    • Author(s)
      A. Ito, K. Murase, and H. Sugimura
    • Organizer
      2nd International Congress on Ionic Liquids(COIL-2)
    • Place of Presentation
      Yokohama, Japan
    • Year and Date
      2007-08-06
    • Related Report
      2008 Final Research Report
  • [Remarks] 学会発表6を行った伊藤 輝がDistinguishedPresentation Award(溶融塩奨励賞)を受賞

    • URL

      http://www.mtl.kyoto-u.ac.jp/groups/sugimura-g/

    • Related Report
      2008 Final Research Report

URL: 

Published: 2007-04-01   Modified: 2016-04-21  

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