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Effect of straight chain polymer additives on the purification of metal by electrolysis

Research Project

Project/Area Number 19360345
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Metal making engineering
Research InstitutionKyushu University

Principal Investigator

FUKUSHIMA Hisaaki  Kyushu University, 大学院・工学研究院, 教授 (50038113)

Co-Investigator(Kenkyū-buntansha) NAKANO Hiroaki  九州大学, 大学院・工学研究院, 教授 (70325504)
OUE Satoshi  九州大学, 工学研究院, 助教 (90264085)
上村 治男  九州大学, 大学院・工学研究院, 助教 (40294897)
Project Period (FY) 2007 – 2009
Project Status Completed (Fiscal Year 2009)
Budget Amount *help
¥20,150,000 (Direct Cost: ¥15,500,000、Indirect Cost: ¥4,650,000)
Fiscal Year 2009: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
Fiscal Year 2008: ¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2007: ¥12,870,000 (Direct Cost: ¥9,900,000、Indirect Cost: ¥2,970,000)
Keywords電解精製 / 電解採取 / 銅 / 亜鉛 / 分極曲線 / 高分子添加剤 / 電位 / 電解 / PEG / 分極 / 塩化物イオン / 交流インピーダンス / 吸着中間体 / 再溶解 / 不純物 / 分子量 / 陰極電位 / ゼラチン / 表面形態
Research Abstract

Gelatin and polyethylene glycol were used as additives to make clear the effect of polymer additives on Cu electrorefining and Zn electrowinning. The effect of polymer additives on the deposition behavior, surface morphology and micro structure of Cu and Zn, and suppression effect of harmful impurity by additives were investigated. The effect and degradation behavior of polymer additives were clarified by synergistic effect of Cl^- ions and polymer additives and quantification of molecular weight of additives in electrolytic solution.

Report

(4 results)
  • 2009 Annual Research Report   Final Research Report ( PDF )
  • 2008 Annual Research Report
  • 2007 Annual Research Report
  • Research Products

    (17 results)

All 2009 2008 2007 Other

All Journal Article (10 results) (of which Peer Reviewed: 10 results) Presentation (6 results) Remarks (1 results)

  • [Journal Article] 銅の電解精製におけるチオ尿素添加の影響2009

    • Author(s)
      久保山宏, 中野博昭, 大上悟, 福島久哲, 小林繁夫
    • Journal Title

      Journal of MMIJ vol.125, No.2

      Pages: 62-67

    • NAID

      10024761627

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] 銅の電解精製におけるチオ尿素添加の影響2009

    • Author(s)
      久保山宏, et al.
    • Journal Title

      Journal of MMIJ 125

      Pages: 62-67

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 銅電解精製における高分子添加剤の経時劣化の評価2008

    • Author(s)
      中野博昭, 大上悟, 藤本敦, 久保山宏, 福島久哲, 林部豊
    • Journal Title

      Journal of MMIJ vol.124, No.10,11

      Pages: 626-631

    • NAID

      10024484622

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] 亜鉛電解採取における高分子添加剤の経時劣化2008

    • Author(s)
      中野博昭, 大上悟, 清水誠一郎, 久保山宏, 福島久哲, 林部豊
    • Journal Title

      Journal of MMIJ vol.124, No.9

      Pages: 583-588

    • NAID

      10021999127

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] 亜鉛電解採取における高分子添加剤の経時劣化2008

    • Author(s)
      中野博昭, et al.
    • Journal Title

      Journal of MMIJ 124

      Pages: 583-588

    • NAID

      10021999127

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 銅電解精製における高分子添加剤の経時劣化の評価2008

    • Author(s)
      中野博昭, et al.
    • Journal Title

      Journal of MMIJ 124

      Pages: 626-631

    • NAID

      10024484622

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 不純物を含有した亜鉛電解採取浴における電析亜鉛の再溶解挙動に及ぼすポリエチレングリコール添加の影響2007

    • Author(s)
      中野博昭, 大上悟, 萩本雅久, 福島久哲, 小林繁夫
    • Journal Title

      Journal of MMIJ vol.123, No.6,7

      Pages: 351-356

    • NAID

      10019555819

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] 銅の電解精製における高分子添加剤と塩化物イオンの相乗効果2007

    • Author(s)
      中野博昭, 大上悟, 青屋健吾, 久保山宏, 福島久哲, 小林繁夫
    • Journal Title

      Journal of MMIJ vol.123, No.4,5

      Pages: 165-170

    • NAID

      130000253518

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] 銅の電解精製における高分子添加剤と塩化物イオンの相乗効果2007

    • Author(s)
      中野 博昭, et. al.
    • Journal Title

      Journal of MMIJ 123

      Pages: 165-170

    • NAID

      130000253518

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 不純物を含有した亜鉛電解採取浴における電析亜鉛の再溶解挙動に及ぼすポリエチレングリコール添加の影響2007

    • Author(s)
      中野 博昭, et. al.
    • Journal Title

      Journal of MMIJ 123

      Pages: 351-356

    • NAID

      10019555819

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Presentation] Synergistic effect of Polymer additives and Chloride Ions and the degradation of Polymer Additives in Copper Electrorefining2009

    • Author(s)
      中野博昭
    • Organizer
      Third International Conference on Processing Materials for Properties
    • Place of Presentation
      北海道大学(北海道)
    • Year and Date
      2009-09-07
    • Related Report
      2009 Final Research Report
  • [Presentation] Synergistic effect of Polymer additives and Chloride Ions and the degradation of Polymer Additives in. Copper Electrorefining2009

    • Author(s)
      中野博昭
    • Organizer
      Third International Conference on Processing Materials for Properties
    • Place of Presentation
      北海道大学(北海道)
    • Year and Date
      2009-09-07
    • Related Report
      2009 Annual Research Report
  • [Presentation] Degradation of Polymer Additives during Long-Term Zn Electrowinning2009

    • Author(s)
      中野博昭
    • Organizer
      European Metallurgical Conference 2009
    • Place of Presentation
      インスブルック国際センター(オーストリア)
    • Year and Date
      2009-07-01
    • Related Report
      2009 Annual Research Report 2009 Final Research Report
  • [Presentation] 亜鉛電解採取における直鎖状高分子添加剤の経時劣化挙動2008

    • Author(s)
      成清久純
    • Organizer
      資源・素材学会
    • Place of Presentation
      仙台・国際センター
    • Year and Date
      2008-10-07
    • Related Report
      2009 Final Research Report 2008 Annual Research Report
  • [Presentation] Effect of polymer additives on zinc electrowinning2007

    • Author(s)
      中野博昭
    • Organizer
      European Metallurgical Conference 2007
    • Place of Presentation
      ドイツ, デュッセルドルフ
    • Year and Date
      2007-06-13
    • Related Report
      2009 Final Research Report
  • [Presentation] Effect of polymer additives on zinc electrowinning2007

    • Author(s)
      中野 博昭
    • Organizer
      European metallurgical Conference 2007
    • Place of Presentation
      ドイツ,デュッセルドルフ
    • Year and Date
      2007-06-13
    • Related Report
      2007 Annual Research Report
  • [Remarks]

    • URL

      http://hyoka.ofc.kyushu-u.ac.jp/search/details/K001417/index.html

    • Related Report
      2009 Final Research Report

URL: 

Published: 2007-04-01   Modified: 2016-04-21  

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