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Synthesis of Mordenite Nanocrystals and its Application to Structured Catalytic Reactor for Complicated Reactions

Research Project

Project/Area Number 19360356
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Reaction engineering/Process system
Research InstitutionHokkaido University

Principal Investigator

MASUDA Takao  Hokkaido University, 大学院工学研究科, 教授 (20165715)

Co-Investigator(Kenkyū-buntansha) TAGO Teruoki  北海道大学, 大学院・工学研究科, 准教授 (20304743)
Project Period (FY) 2007 – 2008
Project Status Completed (Fiscal Year 2008)
Budget Amount *help
¥18,590,000 (Direct Cost: ¥14,300,000、Indirect Cost: ¥4,290,000)
Fiscal Year 2008: ¥7,540,000 (Direct Cost: ¥5,800,000、Indirect Cost: ¥1,740,000)
Fiscal Year 2007: ¥11,050,000 (Direct Cost: ¥8,500,000、Indirect Cost: ¥2,550,000)
Keywords反応装置 / 構造体触媒反応器 / 触媒膜 / ゼオライトナノクリスタル / モルデナイト / 界面活性剤 / アルキル化反応 / ナフタレン / ナノサイズゼオライト / 構造体触媒 / 構造性活性点 / ジメチルナフタレン / 分子篩
Research Abstract

水/界面活性剤/有機溶媒を利用するゼオライト合成法により, モルデナイト結晶のナノサイズ化に成功した. ナノサイズモルデナイト結晶の外表面酸点を, 有機シラン化合物由来シリカにより選択的に不活性化させた構造性活性点を有する触媒の開発, およびモルデナイトナノクリスタルを積層させた膜型構造体触媒反応器の開発に成功した. 同モルデナイト触媒はナフタレンからの2,6-ジメチルナフタレン選択合成に高活性を示した.

Report

(3 results)
  • 2008 Annual Research Report   Final Research Report ( PDF )
  • 2007 Annual Research Report
  • Research Products

    (29 results)

All 2009 2008 2007 Other

All Journal Article (13 results) (of which Peer Reviewed: 12 results) Presentation (15 results) Patent(Industrial Property Rights) (1 results) (of which Overseas: 1 results)

  • [Journal Article] Synthesis of Mono-Dispersed Silicalite-1Nanocrystals in Water-Surfactant-Organic Solvent2009

    • Author(s)
      Tago T., Iwakai K., Nishi M., and Masuda T.
    • Journal Title

      J. Nanosc. Nanotechnol 9(1)

      Pages: 612-617

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of Mono-Dispersed Silicalite-1 Nanocrystals in Water-Surfact ant-Organic Solvent2009

    • Author(s)
      Tago T., Iwakai K., Nishi M., and Masuda T.
    • Journal Title

      Journal of Nanoscience and Nanotechnology 9(1)

      Pages: 612-617

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Preparation for Size-Controlled MOR Zeolite Nanocrystal using Water / Surfactant / Organic Solvent2009

    • Author(s)
      Tago T., Aoki D., Iwakai K., and Masuda T.
    • Journal Title

      Topics in Catalysis (印刷中)

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Measurement of Intracrystalline Diffusivityof Benzene within MFI-type Zeolite from Bulk Benzene/ Cyclohexane Liquid Phase2008

    • Author(s)
      Nakasaka Y., Tago T., Odate K., and Masuda T.
    • Journal Title

      Micropor. Mesopor. Mater 112

      Pages: 162-169

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] ゼオライトナノクリスタル新規合成法の開発2008

    • Author(s)
      多湖輝興・岩貝和幸・増田隆夫
    • Journal Title

      ケミカルエンジニヤリング 53(6)

      Pages: 432-439

    • Related Report
      2008 Final Research Report
  • [Journal Article] Preparation of hydrophilicsilicalite-1 nanocrystal-layered membranesand their application to separating waterfrom water-acetone solution2008

    • Author(s)
      Tago T., Nakasaka Y., Kayoda A., and Masuda T.
    • Journal Title

      Micropor. Mesopor. Mater. 115

      Pages: 176-183

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Measurement of Intracrystalline Diffusivity of Benzene within MFI-type Zeolite from Bulk Benzene / Cyclohexane Liquid Phase2008

    • Author(s)
      Nakasaka Y., Tago T., Odate K., Masuda T.
    • Journal Title

      Microporous and Mesoporous Materials 112

      Pages: 162-169

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Preparation of hydrophilic silicalite-1 nanocrystal-layered membranes and their application to separating water from water-acetone solution2008

    • Author(s)
      Tago T., Nakasaka Y., Kayoda A., and Masuda T.
    • Journal Title

      Microporous and Mesoporous Materials 115

      Pages: 176-183

    • NAID

      120000947381

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Measurement of Intracrystalline Diffusivity of Benzene within MFI-type Zeolite from Bulk Benzene/Cyclohexane Liquid Phase2008

    • Author(s)
      Nakasaka Y., Tago T., Odate K., Masuda T.
    • Journal Title

      Microporous and Mesoporous Materials (印刷中)

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of Mono-Dispersed Silicalite-1 Nanocrystals in Water-Surfactant-Organic Solvent2008

    • Author(s)
      Teruoki Tago, Kazuyuki Iwakai, Mieko Nishi, and Takao Masuda
    • Journal Title

      Journal of Nanoscience and Nanotechnology (印刷中)

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Preparation of hydrophilic silicalite-1 nanocrystal-layered membrane for separation of water from water-acetone solution by pervaporation2007

    • Author(s)
      Tago T., Nakasaka Y., Kayouda A and Masuda T
    • Journal Title

      Separation & Purification Tecnology 58

      Pages: 7-11

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Control of Acid-Site Location of MFIZeolite by Catalytic Cracking of Silane andits Application to Olefin Synthesis from Acetone

    • Author(s)
      Tago T., Sakamoto M., Iwakai K., Nishihara H., Mukai S. R., Tanaka T. and Masuda T
    • Journal Title

      J. Chem. Eng. Jpn. (印刷中)

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Preparation for Size-Controlled MOR Zeolite Nanocrystal using Water/Surfactant/Organic Solvent

    • Author(s)
      Tago T., Aoki D., Iwakai K., and Masuda T
    • Journal Title

      J. Nanosc. Nanotechnol Top. Cat. (印刷中)

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Presentation] Measurement of liquid phasebenzene diffusivity within porous materialsusing Raman spectroscopy2008

    • Author(s)
      Y. Nakasaka, T. Tago, K. Yano and T. Masuda
    • Organizer
      21thInternational Symposium on Chemical Engineering
    • Place of Presentation
      Saga, Saga University, Japan
    • Related Report
      2008 Final Research Report
  • [Presentation] Preparation of ZSM-5 nanocrystal-layeredmembrane and its application to MTOreaction2008

    • Author(s)
      K. Iwakai, T. Tago and T. Masuda
    • Organizer
      21th International Symposium on Chemical Engineering
    • Place of Presentation
      Saga, Saga University, Japan
    • Related Report
      2008 Final Research Report
  • [Presentation] Preparation ofnano-crystalline BEA type zeolite byhydrothermal synthesis inwater/surfactant/organic solvent2008

    • Author(s)
      A. Hyojo, D. Aoki, K. Iwakai, T. Tagoand and T. Masuda
    • Organizer
      21thInternational Symposium on Chemical Engineering
    • Place of Presentation
      Saga, Saga University, Japan
    • Related Report
      2008 Final Research Report
  • [Presentation] Olefin synthesis fromacetone over BEA zeolite2008

    • Author(s)
      S. Ikeda, M. Sakamoto, H. Konno, T. Tagoand and T. Masuda
    • Organizer
      21thInternational Symposium on Chemical Engineering
    • Place of Presentation
      Saga, Saga University, Japan
    • Related Report
      2008 Final Research Report
  • [Presentation] Control of Acid-Site Location of MFI zeolite by Catalytic Cracking of Silaneand its Application of olefin Synthesis from Acetone2008

    • Author(s)
      T. Tago, M. Sakamoto, K. Iwakai1, H.Nishihara, S. R. Mukai, T. Tanaka and T.Masuda
    • Organizer
      20th International Symposium on Chemical Reaction Engineering
    • Place of Presentation
      Kyoto, Kyoto International Conference Center, Japan
    • Related Report
      2008 Final Research Report
  • [Presentation] Liquid phase Diffusivity of Benzene within Mesoporous Materials Measured by Laser Raman Technique2008

    • Author(s)
      Y. Nakasaka, T. Tago, K. Yano and T.Masuda
    • Organizer
      20th International Symposium on Chemical Reaction Engineering
    • Place of Presentation
      Kyoto, Kyoto International Conference Center, Japan
    • Related Report
      2008 Final Research Report
  • [Presentation] Synthesis of hydrophilicsilicalite-1 nanocrystal-layered membranesfor separation of water from aqueous alcoholsolutions by pervaporation2008

    • Author(s)
      Y. Nakasaka, T. Tago, T. Ichikawa, and T. Masuda
    • Organizer
      10th International Conferences on Inorganic Membranes
    • Place of Presentation
      Tokyo, Waseda University, Japan
    • Related Report
      2008 Final Research Report
  • [Presentation] Synthesis of Nano-Sized MORZeolite in Water/Surfactant/Organic Solvent2008

    • Author(s)
      T. Tago, D. Aoki, M. Ohori, K. Iwakai, T.Masuda
    • Organizer
      ICC14 Pre-Symposium
    • Place of Presentation
      Kyoto, Kyoto University, Japan
    • Related Report
      2008 Final Research Report
  • [Presentation] Preparation for Size-Controlled MOR Zeolite Nanocrystal using Water / Surfactant / Organic Solvent2008

    • Author(s)
      Tago T., Aoki D., Iwakai K., and Masuda T.
    • Organizer
      International Symposium on Creation and Control of Advanced Selective Catalysis
    • Place of Presentation
      Kyoto University Kyoto, Japan
    • Related Report
      2008 Annual Research Report
  • [Presentation] Preparation of Mono-Dispersed MFI-type Zeolite Nanocrystals via Hydrothermal Synthesis in Water/ Surfactant/Oil Solution2007

    • Author(s)
      K. Iwakai, D. Aoki, T. Tago and T. Masuda
    • Organizer
      20th International Symposium on Chemical Engineering
    • Place of Presentation
      Daejeon, HanbatNational University, Korea
    • Related Report
      2008 Final Research Report
  • [Presentation] In-situ measurement of intracrystalline diffusivity of benzene withinsilicalite-1 in liquid phase2007

    • Author(s)
      Y. Nakasaka, T. Tago, K. Odate and T. Masuda
    • Organizer
      20th International Symposium on Chemical Engineering
    • Place of Presentation
      Daejeon, Hanbat National University, Korea (2007)
    • Related Report
      2008 Final Research Report
  • [Presentation] Preparation of hydrophilicsilicalite-1 nanocrystal-layered membranesand their application to separating waterfrom water-acetone solution2007

    • Author(s)
      T. Tago, A. Kayoda, K. Iwakai, Y. Nakasaka and T. Masuda
    • Organizer
      4th International Zeolite Membrane Meeting
    • Place of Presentation
      Zaragoza, University of Zaragoza, Spain
    • Related Report
      2008 Final Research Report
  • [Presentation] Preparation of Size-controlled ZSM-5 Zeolite Nanocrystals via Hydrothermal Synthesis using Water/Surfactant/Oil Solution2007

    • Author(s)
      T. Tago, K. Iwakai, M. Nishi and T. Masuda
    • Organizer
      11th Korean-Japan Symposiumon Catalyst
    • Place of Presentation
      Seoul, Yonsei University, Korea
    • Related Report
      2008 Final Research Report
  • [Presentation] ゼオライトナノクリスタル新規合成法の開発とアセトンからのオレフィン選択合成2007

    • Author(s)
      多湖輝興・岩貝和幸・坂元真梨子・増田隆夫
    • Organizer
      第100回触媒討論会
    • Place of Presentation
      北海道大学(札幌市)
    • Related Report
      2007 Annual Research Report
  • [Presentation] 水/界面活性剤/有機溶媒を利用したモルデナイト機能性ナノクリスタルの開発2007

    • Author(s)
      青木大地・多湖輝興・増田隆夫
    • Organizer
      第100回触媒討論会
    • Place of Presentation
      北海道大学(札幌市)
    • Related Report
      2007 Annual Research Report
  • [Patent(Industrial Property Rights)] Inorganic Separation Membrane and Method for Manufacturing the Same2008

    • Inventor(s)
      T. Masuda, T. Tago, 他3名
    • Industrial Property Rights Holder
      北海道大学・日本碍子
    • Filing Date
      2008-02-29
    • Related Report
      2007 Annual Research Report
    • Overseas

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Published: 2007-04-01   Modified: 2016-04-21  

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