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Preparation of nano structured catalysts over silicon microchannel by mist thermal decomposition method

Research Project

Project/Area Number 19360364
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Catalyst/Resource chemical process
Research InstitutionNagoya University

Principal Investigator

TAGAWA Tomohiko  Nagoya University, 大学院・工学研究科, 教授 (10171571)

Co-Investigator(Kenkyū-buntansha) YAMADA Hiroshi  名古屋大学, 大学院・工学研究科, 助教 (70293644)
Project Period (FY) 2007 – 2009
Project Status Completed (Fiscal Year 2009)
Budget Amount *help
¥18,330,000 (Direct Cost: ¥14,100,000、Indirect Cost: ¥4,230,000)
Fiscal Year 2009: ¥3,380,000 (Direct Cost: ¥2,600,000、Indirect Cost: ¥780,000)
Fiscal Year 2008: ¥3,250,000 (Direct Cost: ¥2,500,000、Indirect Cost: ¥750,000)
Fiscal Year 2007: ¥11,700,000 (Direct Cost: ¥9,000,000、Indirect Cost: ¥2,700,000)
Keywordsマイクロリアクタ / 触媒調製 / 顕微赤外分光法 / 脱水素反応 / シリコンマイクロチャンネル / 表面吸着種 / ミスト熱分解法 / マイクロリアクター / 質量分析法 / 触媒用in situ赤外分光セル / 白金-アルミナ触媒 / シリコンマイクロチャネル
Research Abstract

Microchannel reactors with diameters of several hundred micrometers for chemical reactions attract considerable attentions. In order to apply the microchannel reactors for high temperature gaseous reactions, catalyst nano-particles were prepared over microchannel wall constructed on silicon plate with mist decomposition method. Aqueous solution of catalyst materials were atomized into mist by ultrasonic, which is thermally decomposed on the heated microchannel wall. Thus prepared catalytic microreactor was tested by dehydrogenation reaction and characterized with FT-IR microscope. Reaction intermediates on the catalyst and reaction path along with microchannel were discussed. Fundamental studies for low temperature liquid phase reaction also have been carried out on the basis of above studies.

Report

(4 results)
  • 2009 Annual Research Report   Final Research Report ( PDF )
  • 2008 Annual Research Report
  • 2007 Annual Research Report
  • Research Products

    (29 results)

All 2010 2009 2008 2007

All Journal Article (12 results) (of which Peer Reviewed: 12 results) Presentation (17 results)

  • [Journal Article] Effect of Support Materials upon Platinum Catalyst Prepared on the Wall Surface of Silicon Microchannel2009

    • Author(s)
      Tomohiko Tagawa, Arata. Kanemoto, Hideyuki Itoh, Hiroshi Yamada
    • Journal Title

      Catalysis Today 147S

      Pages: 536-540

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Rate Enhanced and Green Ethoxylation of p-Chloronitrobenzene in a microchannel rector2009

    • Author(s)
      Salah Aljbour, Hiroshi Yamada, Tomohiko Tagawa
    • Journal Title

      Journal of Chemical Engineering of Japan S1

      Pages: 90-95

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Ultrasound Assisted Capillary Micro reactor for Aqueous-Organic Systems Hydrodynamincs Study2009

    • Author(s)
      Salah Aljbour, Tomohiko Tagawa, Hiroshi Yamada
    • Journal Title

      Journal of Chemical Engineering of Japan 42

      Pages: 400-406

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Effect of Support Materials upon Platinum Catalyst Prepared on the Wall Surface of Silicon Microchannel2009

    • Author(s)
      Tomohiko Tagawa
    • Journal Title

      Catalysis Today 147S

      Pages: 536-540

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Rate Enhanced and Green Ethoxylation of p-Chloronitrobenzene in a microchannel rector2009

    • Author(s)
      Salah Aljbour, Tomohiko Tagawa
    • Journal Title

      Journal of Chemical Engineering of Japan S1

      Pages: 90-95

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Ultrasound Assisted Capillary Microreactor for Aqueous-Organic Systems Hydrodynamincs Study2009

    • Author(s)
      Salah Aljbour, Tomohiko Tagawa
    • Journal Title

      Journal of Chemical Engineering of Japan 42

      Pages: 400-406

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Preparation of supported platinum catalyst on the wall of silicon micro-channel reactor; Proc2008

    • Author(s)
      Tomohiko Tagawa, Hiroki Watanab, Hiroshi Yamada
    • Journal Title

      Int. Cong. Catalysis

      Pages: 397-397

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Investigating the microchannel flow reactor configuration on the liquid phase synthesis of tert-amyl methyl ester catalyzed by sulfuric acid2008

    • Author(s)
      Mohammed Matouq Zaid Al-Anber, Tomohiko Tagawa, Salah Aljbour, Hiroshi Yamada
    • Journal Title

      Journal of Applied Scienecs 8

      Pages: 601-607

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Preparation of supported platinum catalyst on the wall of silicon microchannel reactor2008

    • Author(s)
      Tomohiko Tagawa, 他3名
    • Journal Title

      14^<th> Intern. Congr. catalysis PII

      Pages: 397-397

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Investigating the microchannel flow reactor configuration on the liquid phase synthesis of tert-amyl methyl ester catalyzed by sulfuric acid2008

    • Author(s)
      M. Matouq, 他4名
    • Journal Title

      Journal of Applied Scienecs 8

      Pages: 601-607

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Micro channel reactor with guideline structure for organic aqueous binary system2007

    • Author(s)
      Tomohiko Tagawa, Salah Aljbour, Mohammed Matouq, Hiroshi Yamada
    • Journal Title

      Chemical Engineering Science 62

      Pages: 5123-5126

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Micro channel reactor with guideline structure for organic aqueous binary system2007

    • Author(s)
      Tomohiko Tagawa, 他3名
    • Journal Title

      Chemical Engineering Science 62

      Pages: 5123-5126

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Presentation] Evaluation of the Catalyst Prepared in Microchannel with in situ FT-IR microscopy2010

    • Author(s)
      Masashi Tanaka, Mikiko Isobe, Hiroshi Yamada, Tomohiko Tagawa
    • Organizer
      11th International Conference on Microreaction Technology
    • Place of Presentation
      京都リサーチパー
    • Year and Date
      2010-03-09
    • Related Report
      2009 Final Research Report
  • [Presentation] Microchannel reactor with guidline structure for organic-aueous-organic multiphase systems2010

    • Author(s)
      Salah Aljbour, Hiroshi Yamada, Tomohiko Tagawa
    • Organizer
      11th International Conference on Microreaction Technology
    • Place of Presentation
      京都リサーチパーク(京都)
    • Year and Date
      2010-03-09
    • Related Report
      2009 Final Research Report
  • [Presentation] Evaluation of the Catalyst Prepared in Microchannel with in situ FT-IR microscopy2010

    • Author(s)
      田中将, 田川智彦
    • Organizer
      11^<th> International Conference on Microreaction Technology
    • Place of Presentation
      京都リサーチパーク (京都)
    • Year and Date
      2010-03-09
    • Related Report
      2009 Annual Research Report
  • [Presentation] 顕微赤外分光分光法によるマイクロチャンネル内に調製した触媒のin situ評価2009

    • Author(s)
      礒部美紀子、山田博史、田川智彦
    • Organizer
      第39回石油・石油化学討論会
    • Place of Presentation
      アクトシティー浜松(浜松)
    • Year and Date
      2009-10-23
    • Related Report
      2009 Final Research Report
  • [Presentation] マイクロチャンネル内への白金触媒調製におけるアルミナ担体の影響2009

    • Author(s)
      田中将、山田博史、田川智彦
    • Organizer
      第39回石油・石油化学討論会
    • Place of Presentation
      アクトシティー浜松(浜松)
    • Year and Date
      2009-10-23
    • Related Report
      2009 Final Research Report
  • [Presentation] 顕微赤外分光分光法によるマイクロチャンネル内に調製した触媒の in situ 評価2009

    • Author(s)
      礒部美紀子, 田川智彦
    • Organizer
      第39回石油・石油化学討論会
    • Place of Presentation
      アクトシティー浜松 (浜松)
    • Year and Date
      2009-10-23
    • Related Report
      2009 Annual Research Report
  • [Presentation] マイクロチャンネル内への白金触媒調製におけるアルミナ担体の影響2009

    • Author(s)
      田中将, 田川智彦
    • Organizer
      第39回石油・石油化学討論会
    • Place of Presentation
      アクトシティー浜松 (浜松)
    • Year and Date
      2009-10-23
    • Related Report
      2009 Annual Research Report
  • [Presentation] Effect of Support Materials upon Platinum Catalyst Prepared on the Wall Surface of Silicon Microchannel2009

    • Author(s)
      Tomohiko Tagawa, Arata. Kanemoto, Hideyuki. Itoh, Hiroshi. Yamada
    • Organizer
      3rd InternationalConference on Structured Catalysts and Reactors
    • Place of Presentation
      Ischia(イタリヤ)
    • Year and Date
      2009-09-28
    • Related Report
      2009 Final Research Report
  • [Presentation] Effect of Support Materials upon Platinum Catalyst Prepared on the Wall Surface of Silicon Microchannel2009

    • Author(s)
      田川智彦
    • Organizer
      3^<rd> International Conference on Structured Catalysts and Reactors
    • Place of Presentation
      Ischia (イタリヤ)
    • Year and Date
      2009-09-28
    • Related Report
      2009 Annual Research Report
  • [Presentation] マイクロチャンネル内に調製した触媒評価のためのin situ顕微赤外分光2009

    • Author(s)
      礒部美紀子、山田博史、田川智彦
    • Organizer
      化学工学会第41回秋季大会
    • Place of Presentation
      広島大学(東広島)
    • Year and Date
      2009-09-16
    • Related Report
      2009 Final Research Report
  • [Presentation] マイクロチャンネル内に調製した触媒評価のための in situ 顕微赤外分光2009

    • Author(s)
      礒部美紀子, 田川智彦
    • Organizer
      化学工学会 第41回秋季大会
    • Place of Presentation
      広島大学 (東広島)
    • Year and Date
      2009-09-16
    • Related Report
      2009 Annual Research Report
  • [Presentation] Evaluation of micro-catalytic reactor with in situ FT-IR microscopy2009

    • Author(s)
      Tomohiko Tagawa
    • Organizer
      5th Joint Japan/China Chemical Engineering Symposium(Plenary Lecture
    • Place of Presentation
      西安(中国)
    • Year and Date
      2009-07-22
    • Related Report
      2009 Final Research Report
  • [Presentation] Evaluation of micro-catalytic reactor with in situ FT-IR microscopy2009

    • Author(s)
      田川智彦
    • Organizer
      5th Joint Japan/China Chemical Engineering Symposium (Plenary Lecture)
    • Place of Presentation
      西安 (中国)
    • Year and Date
      2009-07-22
    • Related Report
      2009 Annual Research Report
  • [Presentation] マイクロチャンネル内に調製した触媒上の吸着種のin situ顕微赤外分光測定2009

    • Author(s)
      礒部美紀子、山田博史、田川智彦
    • Organizer
      化学工学会第74回年会
    • Place of Presentation
      横浜国立大学(横浜)
    • Year and Date
      2009-03-18
    • Related Report
      2009 Final Research Report
  • [Presentation] マイクロチャンネル内に調製した触媒上の吸着種の in situ 顕微赤外分光測定2009

    • Author(s)
      礒部美紀子, 田川智彦
    • Organizer
      化学工学会 第74回年会
    • Place of Presentation
      横浜国立大学 (横浜)
    • Year and Date
      2009-03-18
    • Related Report
      2009 Annual Research Report
  • [Presentation] マイクロチャンネル内に調製した触媒上の吸着種のin situ顕微赤外分光測定2009

    • Author(s)
      礒部美紀子, 山田博史, 田川智彦
    • Organizer
      化学工学会第74回年会
    • Place of Presentation
      横浜国立大学(横浜市)
    • Year and Date
      2009-03-18
    • Related Report
      2008 Annual Research Report
  • [Presentation] マイクロチャンネル内に調製した触媒のin situ顕微赤外分光測定2008

    • Author(s)
      礒部美紀子, 山田博史, 田川智彦
    • Organizer
      化学工学会第40回秋季大会
    • Place of Presentation
      東北大学(仙台市)
    • Year and Date
      2008-09-25
    • Related Report
      2008 Annual Research Report

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Published: 2007-04-01   Modified: 2016-04-21  

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