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Construction of ion conduction channel of hierarchic structure and its application to high power battery materials

Research Project

Project/Area Number 19360438
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Energy engineering
Research InstitutionKyoto University

Principal Investigator

YAO Takeshi  Kyoto University, エネルギー科学研究科, 教授 (50115953)

Co-Investigator(Kenkyū-buntansha) HIBINO Mitsuhiro  京都大学, エネルギー科学研究科, 准教授 (20270910)
Project Period (FY) 2007 – 2008
Project Status Completed (Fiscal Year 2008)
Budget Amount *help
¥19,890,000 (Direct Cost: ¥15,300,000、Indirect Cost: ¥4,590,000)
Fiscal Year 2008: ¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2007: ¥14,950,000 (Direct Cost: ¥11,500,000、Indirect Cost: ¥3,450,000)
Keywordsハイパワー電池 / リチウムイオン電池 / 燃料電池 / 高イオン伝導 / 複合材料 / コバルトバナジウム酸化物 / バリウムインジウム酸化物 / 一室式燃料電池 / グラファイト層間化合物
Research Abstract

ハイパワー電池材料を得るために様々なイオン伝導チャンネルをもつ構造体の構築を目指した。一次元系サブナノ伝導チャンネル物質CoV3O8 について構造を精密に調べ、リチウム挿入サイトをほぼ決定した。二次元系伝導チャンネル物質のグラファイト層間化合物においてリチウムの挿入過程及び引き抜き過程における構造変化を詳細に調べた。さらに、三相界面に適した複合伝導チャンネル構造を探索し、部分酸化反応とガス拡散とを両立した高い出力特性の燃料極支持型一室式燃料電池を作製した。

Report

(3 results)
  • 2008 Annual Research Report   Final Research Report ( PDF )
  • 2007 Annual Research Report
  • Research Products

    (52 results)

All 2009 2008 2007 Other

All Journal Article (9 results) (of which Peer Reviewed: 9 results) Presentation (39 results) Remarks (4 results)

  • [Journal Article] Lithium Intercalation Behavior of Cobalt Vanadium Oxide CoV_3O_8 Studied on the Basis of Rietveld Analysis2009

    • Author(s)
      Shin-nosuke Ichikawa, Mitsuhiro Hibino, and Takeshi Yao
    • Journal Title

      Journal of the Electrochemical Society 156

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Lithium Intercalation Behavior of Cobalt Vanadium Oxide CoV308 Studied on the Basis of Rietveld Analysis2009

    • Author(s)
      Shin-nosuke Ichikawa, Mitsuhiro Hibind, Takeshi Yao
    • Journal Title

      Journal of the Electrochemical Society 156

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Electrode property of amorphous material of Li-Co-V-O system prepared by chemical lithium insertion in CoV_3O_82008

    • Author(s)
      Shin-nosuke Ichikawa, Mitsuhiro Hibino, Takeshi Yao
    • Journal Title

      Solid State Ionics 179

      Pages: 1688-1692

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Electrode property of amorphous material of Li-Co-V-O system prepared by chemical lithium insertion in CoV3082008

    • Author(s)
      Shin-nosuke Ichikawa, Mitsuhiro Hibino, Takeshi Yao
    • Journal Title

      Solid State Ionics 179

      Pages: 1688-1692

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Electrode property of amorphous material of Li-Co-V-O system prepared by chemical lithium insertion in CoV3082008

    • Author(s)
      Shin-nosuke Ichikawa, Mitsuhiro Hibino, Takeshi Yao
    • Journal Title

      Solid State Ionics(19年度中に掲載決定通知を受けている) (未定)

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Reversible and rapid discharge-charge performance of gamma-Fe_2O_3 prepared by aqueous solution method as the cathode for lithium-ion battery2007

    • Author(s)
      Mitsuhiro Hibino, Jumpei Terashima, Takeshi Yao
    • Journal Title

      Journal of the electrochemical society 154

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Electrode property of amorphous material of Li-Co-V-O system prepared by chemical lithium insertion in CoV_3O_82007

    • Author(s)
      Shin-nosuke Ichikawa, Mitsuhiro Hibino, Takeshi Yao
    • Journal Title

      Journal of the electrochemical society 154

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Electrode property of amorphous material of Li-Co-V-O system prepared by chemical lithium insertion in CoV3082007

    • Author(s)
      Shin-nosuke Ichikawa, Mitsuhiro Hibino, Takeshi Yao
    • Journal Title

      Journal of the electrochemical society 154

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Reversible and rapid discharge-charge performance of gamma-Fe203 prepared by aqueous solution method as the cathode for lithium-ion battery2007

    • Author(s)
      Mitsuhiro Hibino, Jumpei Terashima, Takeshi Yao
    • Journal Title

      Journal of the electrochemical society 154

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Presentation] 遷移金属置換Ba-In系酸化物の導電特性2009

    • Author(s)
      小林輝明、長谷坂彰史、高橋景子、日比野光宏、八尾健
    • Organizer
      電気化学秋季大会
    • Place of Presentation
      東工大大岡山
    • Year and Date
      2009-09-19
    • Related Report
      2008 Final Research Report
  • [Presentation] バナジウムコバルト酸化物CoV3O8のリチウムインターカレーション特性2008

    • Author(s)
      市川慎之介、日比野光宏、八尾健
    • Organizer
      第34回固体イオニクス討論会
    • Place of Presentation
      東京
    • Year and Date
      2008-12-05
    • Related Report
      2008 Final Research Report
  • [Presentation] バナジウムコバルト酸化物CoV308のリチウムインターカレーション特性2008

    • Author(s)
      市川慎之介, 日比野光宏, 八尾健
    • Organizer
      第34回固体イオニクス討論会
    • Place of Presentation
      東京
    • Year and Date
      2008-12-05
    • Related Report
      2008 Annual Research Report
  • [Presentation] Electrochemcial Lithiation Property of γ-Fe_2O_3/Carbon2008

    • Author(s)
      Mitsuhiro Hibino, Naomi Okazaki, Hiroshi Kawada and Takeshi Yao
    • Organizer
      第34 回固体イオニクス討論会・Japan-Korea Joint Session
    • Place of Presentation
      東京
    • Year and Date
      2008-12-04
    • Related Report
      2008 Final Research Report
  • [Presentation] Electrochemcial Lithiation Property of γ-Fe203/Carbon2008

    • Author(s)
      Mitsuhiro Hibino, Naomi Okazaki, Hiroshi Kawada, Takeshi Yao
    • Organizer
      第34回固体イオニクス討論会・Japan-Korea Joint Session
    • Place of Presentation
      東京
    • Year and Date
      2008-12-04
    • Related Report
      2008 Annual Research Report
  • [Presentation] γ-Fe_2O_3/炭素複合体リチウムイオン二次電池正極の高速充放電特性2008

    • Author(s)
      日比野光宏、岡崎直美、川田浩史、八尾健
    • Organizer
      第49 回電池討論会
    • Place of Presentation
      大阪
    • Year and Date
      2008-11-05
    • Related Report
      2008 Final Research Report
  • [Presentation] 電気化学的にリチウムイオンを挿入したγ-Fe_2O_3 の結晶構造解析2008

    • Author(s)
      山内智、日比野光宏、八尾健
    • Organizer
      第49回電池討論会
    • Place of Presentation
      大阪
    • Year and Date
      2008-11-05
    • Related Report
      2008 Final Research Report
  • [Presentation] γ-Fe203/炭素複合体リチウムイオン二次電池正極の高速充放電特性2008

    • Author(s)
      日比野光宏, 岡崎直美, 川田浩史, 八尾健
    • Organizer
      第49回電池討論会
    • Place of Presentation
      大阪
    • Year and Date
      2008-11-05
    • Related Report
      2008 Annual Research Report
  • [Presentation] 電気化学的にリチウムイオンを挿入した γ-Fe203の結晶構造解析2008

    • Author(s)
      山内智, 日比野光宏, 八尾健
    • Organizer
      第49回電池討論会
    • Place of Presentation
      大阪
    • Year and Date
      2008-11-05
    • Related Report
      2008 Annual Research Report
  • [Presentation] Analysis of Fe Valence in Li Inserted γ-Fe_2O_3 by X-ray Absorption Edge Measurement2008

    • Author(s)
      Akifumi Hasesaka, Mitsuhiro Hibino, Takeshi Yao
    • Organizer
      214th Electrochemical society Meeting
    • Place of Presentation
      ハワイ
    • Year and Date
      2008-10-13
    • Related Report
      2008 Final Research Report
  • [Presentation] γ-Fe_2O_3/carbon Composite Synthesized by Aqueous Solution Method as Cathode for Lithium-ion Battery2008

    • Author(s)
      Naomi Okazaki, Jumpei Terashima, Mitsuhiro Hibino, Takeshi Yao
    • Organizer
      214th Electrochemical society Meeting
    • Place of Presentation
      ハワイ
    • Year and Date
      2008-10-13
    • Related Report
      2008 Final Research Report
  • [Presentation] Structure Change Analysis in γ-Fe_2O_3/Carbon Composite in the Process of Electrochemical Lithium Insertion2008

    • Author(s)
      Satoshi Yamauchi, Mitsuhiro Hibino, Takeshi Yao
    • Organizer
      214th Electrochemical society Meeting
    • Place of Presentation
      ハワイ
    • Year and Date
      2008-10-13
    • Related Report
      2008 Final Research Report
  • [Presentation] Development of Single Chamber Solid Oxide Fuel Cell using BaLaIn_2O_<5.5>(BLI)Solid Electrolyte : Introduction of Sublimation Materials as Pore Former in Electrode Preparation2008

    • Author(s)
      Yuwa Chompoobutrgool, Hiroaki Suzuki, Mitsuhiro Hibino, Takeshi Yao
    • Organizer
      14th Electrochemical society Meeting
    • Place of Presentation
      ハワイ
    • Year and Date
      2008-10-13
    • Related Report
      2008 Final Research Report
  • [Presentation] Analysis of Fe Valence in Li Insert γ-Fe203 by X-ray Absorption Edge Measurement2008

    • Author(s)
      Akifumi Hasesaka, Mitsuhiro Hibino, Takeshi Yao
    • Organizer
      214th Electrochemical society Meeting
    • Place of Presentation
      ハワイ
    • Year and Date
      2008-10-13
    • Related Report
      2008 Annual Research Report
  • [Presentation] γ-Fe203/carbon Composite Synthesized by Aqueous Solution Method as Cathode for Lithium-ion Battery2008

    • Author(s)
      Naomi Okazaki, Jumpei Terashima, Mitsuhiro Hibino, Takeshi Yao
    • Organizer
      214th Electrochemical society Meeting
    • Place of Presentation
      ハワイ
    • Year and Date
      2008-10-13
    • Related Report
      2008 Annual Research Report
  • [Presentation] Structure Change Analysis in γ-Fe203/Carbon Composite in the Process of Electrochemical Lithium2008

    • Author(s)
      Satoshi Yamauchi, Mitsuhiro Hibino, Takeshi Yao
    • Organizer
      214th Electrochemical society Meeting
    • Place of Presentation
      ハワイ
    • Year and Date
      2008-10-13
    • Related Report
      2008 Annual Research Report
  • [Presentation] Development of Single Chamber Solid Oxide Fuel Cell using BaLaIn205.5 (BLI) Solid Electrolyte : Introduction of Sublimation Materials as Pore Former in Electrode Preparation2008

    • Author(s)
      Yuwa Chompoobutrgool, Hiroaki Suzuki, Mitsuhiro Hibino Takeshi Yao
    • Organizer
      214th Electrochemical society Meeting
    • Place of Presentation
      ハワイ
    • Year and Date
      2008-10-13
    • Related Report
      2008 Annual Research Report
  • [Presentation] gamma-Fe_2O_3/炭素複合体の合成条件とリチウムイオン二次電池電極特性との関係2008

    • Author(s)
      岡崎直美、寺島純平、日比野光宏、八尾健
    • Organizer
      電気化学会第75 回大会
    • Place of Presentation
      山梨大学
    • Year and Date
      2008-03-31
    • Related Report
      2008 Final Research Report
  • [Presentation] gamma-Fe_2O_3/炭素複合体のリチウムイオン二次電池正極特性2008

    • Author(s)
      日比野光宏、寺島純平、八尾 健
    • Organizer
      電気化学会第75 回大会
    • Place of Presentation
      山梨大学
    • Year and Date
      2008-03-31
    • Related Report
      2008 Final Research Report
  • [Presentation] gamma-Fe203/炭素複合体の合成条件とリチウムイオン二次電池電極特性との関係2008

    • Author(s)
      岡崎直美、寺島純平、日比野光宏、八尾 健
    • Organizer
      電気化学会第75回大会
    • Place of Presentation
      山梨大学
    • Year and Date
      2008-03-31
    • Related Report
      2007 Annual Research Report
  • [Presentation] gamma-Fe203/炭素複合体のリチウムイオン二次電池正極特性2008

    • Author(s)
      日比野光宏、寺島純平、八尾 健
    • Organizer
      電気化学会第75回大会
    • Place of Presentation
      山梨大学
    • Year and Date
      2008-03-31
    • Related Report
      2007 Annual Research Report
  • [Presentation] gamma-Fe_2O_3/炭素複合体のリチウムイオン二次電池正極特性2007

    • Author(s)
      日比野光宏、寺島純平、八尾 健
    • Organizer
      第33 回固体イオニクス討論会
    • Place of Presentation
      名古屋国際会議場
    • Year and Date
      2007-12-06
    • Related Report
      2008 Final Research Report
  • [Presentation] 水溶液法によるコバルト添加酸化マンガンの合成とリチウム電池電極特性2007

    • Author(s)
      渡邉真吾、日比野光宏、八尾 健
    • Organizer
      第33回固体イオニクス討論会
    • Place of Presentation
      名古屋国際会議場
    • Year and Date
      2007-12-06
    • Related Report
      2007 Annual Research Report
  • [Presentation] gamma-Fe203/炭素複合体のリチウムイオン二次電池正極特性2007

    • Author(s)
      日比野光宏、寺島純平、八尾 健
    • Organizer
      第33回固体イオニクス討論会
    • Place of Presentation
      名古屋国際会議場
    • Year and Date
      2007-12-06
    • Related Report
      2007 Annual Research Report
  • [Presentation] Crystal Structure and Electrical Conductivity of BaIn1-xM_2O_<3-δ>(M=Ti, V, Cr, Mn, Fe, Co, Ni, Cu)2007

    • Author(s)
      Teruaki Kobayashi, Akifumi Hasesaka, Mitsuhiro Hibino, Takeshi Yao
    • Organizer
      International Symposium on Innovative Materials for Processes in Energy Systems
    • Place of Presentation
      京都リサーチパーク
    • Year and Date
      2007-10-28
    • Related Report
      2008 Final Research Report
  • [Presentation] Crystal Structure and Electrical Conductivity of BaInl-xM203-δ (M=Ti, V, Cr, Mn, Fe, Co, Ni, Cu)2007

    • Author(s)
      Teruaki Kobayashi, Akifumi Hasesaka, Mitsuhiro Hibino, Takeshi Yao
    • Organizer
      International Symposium on Innovative Materials for Processes in Energy Systems
    • Place of Presentation
      京都リサーチパーク
    • Year and Date
      2007-10-28
    • Related Report
      2007 Annual Research Report
  • [Presentation] Electrode Property of Gamma-Fe_2O_3 Prepared by Aqueous Solution Method as the Cathode for Lithium-Ion Battery2007

    • Author(s)
      Jumpei Terashima, Mitsuhiro Hibino, Takeshi Yao
    • Organizer
      212th Electrochemical Society Meeting
    • Place of Presentation
      ワシントンDC
    • Year and Date
      2007-10-12
    • Related Report
      2008 Final Research Report
  • [Presentation] Electrode Property of Gamma-Fe203 Prepared by Aqueous Solution Method as the Cathode for Lithium-Ion Battery2007

    • Author(s)
      Jumpei Terashima, Mitsuhiro Hibino, Takeshi Yao
    • Organizer
      212th Electrochemical Society Meeting
    • Place of Presentation
      ワシントンDC
    • Year and Date
      2007-10-12
    • Related Report
      2007 Annual Research Report
  • [Presentation] BaLa_2In_<5.5>Electrolyte Single Chamber Fuel Cell Using Ni Cermet Anode : Introduction of Barrier Layer Between the Electrolyte and the Anode2007

    • Author(s)
      Hiroaki Suzuki, Kenichi Kanatani, Naoki Fujita, Teruaki Kobayashi, Mitsuhiro Hibino, Takeshi Yao
    • Organizer
      212th Electrochemical Society Meeting
    • Place of Presentation
      ワシントンDC
    • Year and Date
      2007-10-10
    • Related Report
      2008 Final Research Report
  • [Presentation] BaLa2In5.5 Electrolyte Single Chamber Fuel Cell Using NiCermet Anode: Introduction of Barrier Layer Between the Electrolyte and the Anode2007

    • Author(s)
      Hiroaki Suzuki, Kenichi Kanatani, Naoki Fujita, Teruaki Kobayashi, Mitsuhiro Hibino, Takeshi Yao
    • Organizer
      212th Electrochemical Society Meeting
    • Place of Presentation
      ワシントンDC
    • Year and Date
      2007-10-10
    • Related Report
      2007 Annual Research Report
  • [Presentation] BaLaIn_2O_<5.5> 電解質一室型燃料電池へのBa-In 系酸化物カソードの適用2007

    • Author(s)
      藤田直樹、鈴木博晶、日比野光宏、八尾健
    • Organizer
      電気化学秋季大会
    • Place of Presentation
      東工大大岡山
    • Year and Date
      2007-09-20
    • Related Report
      2008 Final Research Report
  • [Presentation] BaLaIn205.5電解質一室型燃料電池へのBa-In系酸化物カソードの適用2007

    • Author(s)
      藤田直樹、鈴木博晶、日比野光宏、八尾 健
    • Organizer
      電気化学秋季大会
    • Place of Presentation
      東京工業大学大岡山キャンパス
    • Year and Date
      2007-09-20
    • Related Report
      2007 Annual Research Report
  • [Presentation] 水溶液法により合成したgamma-Fe_2O_3/炭素複合体のリチウムイオン二次電池電極特性2007

    • Author(s)
      寺島純平、日比野光宏、八尾 健
    • Organizer
      電気化学秋季大会
    • Place of Presentation
      東工大大岡山
    • Year and Date
      2007-09-19
    • Related Report
      2008 Final Research Report
  • [Presentation] 水溶液法により合成したgamma-Fe203/炭素複合体のリチウムイオン二次電池電極特性2007

    • Author(s)
      寺島純平、日比野光宏、八尾 健
    • Organizer
      電気化学秋季大会
    • Place of Presentation
      東京工業大学大岡山キャンパス
    • Year and Date
      2007-09-19
    • Related Report
      2007 Annual Research Report
  • [Presentation] 遷移金属置換Ba-In系酸化物の導電特性2007

    • Author(s)
      小林輝明、長谷坂彰史、高橋景子、日比野光宏、八尾 健
    • Organizer
      電気化学秋季大会
    • Place of Presentation
      東京工業大学大岡山キャンパス
    • Year and Date
      2007-09-19
    • Related Report
      2007 Annual Research Report
  • [Presentation] Electrode property of amorphous material of Li-Co-V-O system prepared by chemical lithium insertion in CoV3O82007

    • Author(s)
      Shin-nosuke Ichikawa, Mitsuhiro Hibino, Takeshi Yao
    • Organizer
      16th International Conference on Solid State Ionics
    • Place of Presentation
      上海
    • Year and Date
      2007-07-05
    • Related Report
      2008 Final Research Report
  • [Presentation] Electrode property of transition metal incorporated manganese oxide prepared by aquous solution method2007

    • Author(s)
      Mitsuhiro Hibino, Shingo Watanabe, Takeshi Yao
    • Organizer
      16th International Conference on Solid State Ionics
    • Place of Presentation
      上海
    • Year and Date
      2007-07-05
    • Related Report
      2008 Final Research Report 2007 Annual Research Report
  • [Presentation] Electrode property of amorphous material of Li-Co-V-O system prepared by chemical lithium insertion in CoV3082007

    • Author(s)
      Shin-nosuke Ichikawa, Mitsuhiro Hibino, Takeshi Yao
    • Organizer
      16th International Conference on Solid State Ionics
    • Place of Presentation
      上海
    • Year and Date
      2007-07-05
    • Related Report
      2007 Annual Research Report
  • [Presentation] 水溶液法によるコバルト添加酸化マンガンの合成とリチウム電池電極特性2007

    • Author(s)
      渡邉真吾、日比野光宏、八尾 健
    • Organizer
      第33 回固体イオニクス討論会
    • Place of Presentation
      名古屋国際会議場
    • Related Report
      2008 Final Research Report
  • [Remarks]

    • URL

      http://fssc.energy.kyoto-u.ac.jp/index.htm

    • Related Report
      2008 Final Research Report
  • [Remarks] 受賞テクノ愛'08大学の部・アイデア賞「昇華性物質混合による高機能多孔性燃料電池電極の形成」Yuwa Chompoobutrgool

    • Related Report
      2008 Final Research Report
  • [Remarks]

    • URL

      http://fssc.energy.kyoto-u.ac.jp/index.htm

    • Related Report
      2008 Annual Research Report
  • [Remarks]

    • URL

      http://fssc.energy.kyoto-u.ac.jp/index.htm

    • Related Report
      2007 Annual Research Report

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Published: 2007-04-01   Modified: 2016-04-21  

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