| Budget Amount *help |
¥3,510,000 (Direct Cost: ¥2,700,000、Indirect Cost: ¥810,000)
Fiscal Year 2009: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2008: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2007: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
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| Research Abstract |
An azulene derivative possessing a diphenylphosphoryl and an amino group at the 2- and 6-positions, respectively, was synthesized. The X-ray structure analysis of this compound revealed that the bond alternation of the azulenyl skeleton appears clearly. This shows that the contribution of a quinoid structure is pronounced. The phosphoryl group is linked to the amino group by intermolecular hydrogen bonding to form an infinite chain structure.
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