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Synthesis of Propellane-Type Heterocycles Using Tandem Cyclization

Research Project

Project/Area Number 19550046
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Organic chemistry
Research InstitutionKumamoto University

Principal Investigator

NISHINO Hiroshi  Kumamoto University, 大学院・自然科学研究科, 教授 (50145281)

Project Period (FY) 2007 – 2009
Project Status Completed (Fiscal Year 2009)
Budget Amount *help
¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2009: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2008: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2007: ¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000)
Keywordsタンデム環化反応 / 複素環プロペラン類 / 酸化反応 / ラジカル反応 / プロペラ型化合物 / ビシクロ化合物 / Lewis酸 / 分子内環化反応
Research Abstract

Tandem cyclization is a successive intramolecular cyclization when the cyclization is once started, and important for the synthesis of organic cyclization compounds as an efficient synthetic technique. In the research project, the synthesis of novel propellane-type heterocyclic compounds and cyclophane-type macrolides using manganese (III) acetate-based oxidative radical tandem cyclization was studied. The biological activities and physicochemical interests of these compounds are expected.

Report

(4 results)
  • 2009 Annual Research Report   Final Research Report ( PDF )
  • 2008 Annual Research Report
  • 2007 Annual Research Report
  • Research Products

    (112 results)

All 2010 2009 2008 2007 Other

All Journal Article (35 results) (of which Peer Reviewed: 25 results) Presentation (72 results) Remarks (5 results)

  • [Journal Article] Efficient macrocyclization using methylene-tethered terminal dienes and bis(manganese(III)-enolate)s2010

    • Author(s)
      Yosuke Ito, Tomomi Yoshinaga, Hiroshi Nishino
    • Journal Title

      Tetrahedron 66

      Pages: 2683-2694

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of Macrocyclic Amides Using Manganese(III)-Based Intramolecular Cyclization of N-(・-Alkenyl)-3-oxobutan-amides2010

    • Author(s)
      Yosuke Ito, Hiroshi Nishino
    • Journal Title

      Heterocycl. Commun 16(in press)

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Reaction of 2-Pentene-1, 4-diones with Cyclic 1, 3-Dicarbonyl Compounds in the Presence of BF3 and the Related Reaction2010

    • Author(s)
      Akemi Kakehashi, Hiroshi Nishino
    • Journal Title

      Cryogenics Report of Kumamoto University 20(in press)

    • NAID

      110009573835

    • Related Report
      2009 Final Research Report
  • [Journal Article] Formation of 1,2-Dioxan-3-ol Derivatives from Manganese(III)-Based Oxidative Reaction Using Diarylethenes, Diketene, and Ethanol2010

    • Author(s)
      Van-Ha Nuyen
    • Journal Title

      Cryogenics Report of Kumamoto University 20(印刷中)

    • Related Report
      2009 Annual Research Report
  • [Journal Article] Reaction of 2-Pentene-1,4-diones with Cyclic 1,3-Dicarbonyl Compounds in the Presence of BF_3 and the Related Reaction2010

    • Author(s)
      Akemi Kakehashi
    • Journal Title

      Cryogenics Report of Kumamoto University 20(印刷中)

    • Related Report
      2009 Annual Research Report
  • [Journal Article] Synthesis of Macrocyclic Amides Using Manganese(III)-Based Intramolecular Cyclization of N-(ω-Alkenyl)-3-oxobutanamides2010

    • Author(s)
      Yosuke Ito
    • Journal Title

      Heterocycl.Commun. 16(印刷中)

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Efficient macrocyclization using methylene-tethered terminal dienes and bis(manganese(III)-enolate)s2010

    • Author(s)
      Yosuke Ito
    • Journal Title

      Tetrahedron 66

      Pages: 2683-2694

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Formation of 1, 2-Dioxan-3-ol Derivatives from Manganese(III)-Based Oxidative Reaction Using Diarylethenes2009

    • Author(s)
      Diketene, Ethanol, Van-Ha Nuyen, Hiroshi Nishino
    • Journal Title

      Cryogenics Report of Kumamoto University 20(in press)

    • Related Report
      2009 Final Research Report
  • [Journal Article] Manganese(III)-mediated facile synthesis of 3, 4-dihydro-2(1H)-quinolinones. Selectivity of the 6-endo and 5-exo cyclization2009

    • Author(s)
      Takuma Tsubusaki, Hiroshi Nishino
    • Journal Title

      Tetrahedron 65

      Pages: 9448-9459

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of Dibenz[b, f]oxepins via Manganese(III)-Based Oxidative 1, 2-Radical Rearrangement2009

    • Author(s)
      Zhiqi Cong, Takumi Miki, Osamu Urakawa, Hiroshi Nishino
    • Journal Title

      J. Org. Chem 74(10)

      Pages: 3978-3981

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Formation of 1, 2-Dioxolanes Using Mn(III)-Based Reaction of Various Arylacetylenes with 2, 4-Pentanedione and Related Reaction2009

    • Author(s)
      Takuma Tsubusaki, Hiroshi Nishino
    • Journal Title

      Tetrahedron 65

      Pages: 3745-3752

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of Unusual Naphto[2, 1-b] furans and Novel 1H-Benz[e]indolinones via Selective Intramolecular Cyclization2009

    • Author(s)
      Zhi-qi Cong, Hiroshi Nishino
    • Journal Title

      Heterocycles 78(2)

      Pages: 397-413

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of Bicyclo[3. 1. 0]hexan-2-ones Using Manganese(III) Oxidation in Ethanol2009

    • Author(s)
      Kentaro Asahi, Hiroshi Nishino
    • Journal Title

      Synthesis 2009

      Pages: 409-423

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Convenient Synthesis of 3, 4-Dihydro-2(1H)-quinolinones from Malonate Derivatives2009

    • Author(s)
      Takuma Tsubusaki, Hiroshi Nishino
    • Journal Title

      Heterocycl. Commun 15(No.1)

      Pages: 79-83

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Convenient Synthesis of 3, 4-Dihydro-2(1H)-quinolinones from Malonate Derivatives2009

    • Author(s)
      Takuma Tsubusaki
    • Journal Title

      Heterocycl.Commun. 15

      Pages: 79-83

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of Bicyclo[3.1.0]hexan-2-ones Using Manganese(III)Oxidation in Ethanol2009

    • Author(s)
      Kentaro Asahi
    • Journal Title

      Synthesis 2009

      Pages: 409-423

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of Unusual Naphto [2,1-b] furans and Novel 1H-Benz [e]-indolinones via Selective Intramolecular Cyclization2009

    • Author(s)
      Zhi-qi Cong
    • Journal Title

      Heterocycles 78(2)

      Pages: 397-413

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Formation of 1,2-Dioxolanes Using Mn(III)-Based Reaction of Various Arylacetylenes with 2,4-Pentanedione and Related Reaction2009

    • Author(s)
      Takuma Tsubusaki
    • Journal Title

      Tetrahedron 65

      Pages: 3745-3752

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of Dibenz[b,f]oxepins via Manganese(III)-Based Oxidative 1,2-Radical Rearrangement2009

    • Author(s)
      Zhi-qi Cong
    • Journal Title

      J.Org.Chem. 74(10)

      Pages: 3978-3981

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Convenient Synthesis of 3, 4-Dihydro-2(1H)-quinolinones from Malonate Derivatives2009

    • Author(s)
      Takuma Tsubusaki
    • Journal Title

      Heterocycl. Commun. 15(印刷中)

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthetic Study of Macrocycles Using Manganese(III)-Based Oxidative Radical Cyclization2008

    • Author(s)
      Yosuke Ito, Hiroshi Nishino
    • Journal Title

      Cryogenics Report of Kumamoto University 19

      Pages: 27-28

    • NAID

      110007198401

    • Related Report
      2009 Final Research Report
  • [Journal Article] Mn(III)-Based Synthesis of 1, 2-Dioxolanes, Reaction Mechanism, and Related Reaction2008

    • Author(s)
      Takuma Tsubusaki, Kazu Kurosawa, Hiroshi Nishino
    • Journal Title

      Cryogenics Report of Kumamoto University 19

      Pages: 17-26

    • NAID

      110007198402

    • Related Report
      2009 Final Research Report
  • [Journal Article] Synthesis of Dibenz[b, f]oxepins via Manganese(III)-Based Oxidative 1, 2-Aryl Radical Rearrangement2008

    • Author(s)
      Zhiqi Cong, Takumi Miki, Osamu Urakawa, Hiroshi Nishino
    • Journal Title

      Cryogenics Report of Kumamoto University 19

      Pages: 9-15

    • NAID

      110007198403

    • Related Report
      2009 Final Research Report
  • [Journal Article] Manganese(III)-Mediated Direct Introduction of 3-Oxobutanamides into Methoxynaphthalenes2008

    • Author(s)
      Zhi-qi Cong, Hiroshi Nishino
    • Journal Title

      Synthesis

      Pages: 2686-2694

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Facile endoperoxypropellane synthesis using manganese(III) acetate-catalyzed aerobic oxidation2008

    • Author(s)
      Kentaro Asahi, Hiroshi Nishino
    • Journal Title

      Eur. J. Org. Chem

      Pages: 2404-2416

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Manganese(III)-Based Dioxapropellane Synthesis Using Tricarbonyl Compounds2008

    • Author(s)
      Kentaro Asahi, Hiroshi Nishino
    • Journal Title

      Tetrahedron 23590

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Selective synthesis of trioxapropellanes using manganese(III) acetate2008

    • Author(s)
      Kentaro Asahi, Hiroshi Nishino
    • Journal Title

      Heterocycl. Commun 14(1-2)

      Pages: 21-26

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Selective synthesis of trioxapropellanes using manganese(III)acetate2008

    • Author(s)
      Kentaro Asahi
    • Journal Title

      Heterocycl. Commun. 14

      Pages: 21-26

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Manganese(III)-Based Dioxapropellane Synthesis Using Tricarbonyl Compounds2008

    • Author(s)
      Kentaro Asahi
    • Journal Title

      Tetrahedron 64(8)

      Pages: 1620-1634

    • Related Report
      2008 Annual Research Report 2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Facile endoperoxypropellane synthesis using manganese(III) acetate-catalyzed aerobic oxidation2008

    • Author(s)
      Kentaro Asahi
    • Journal Title

      Eur. J. Org. Chem. 2008

      Pages: 2404-2416

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Manganese(III)-Mediated Direct Introduction of 3-Oxobutanamides into Methoxynaphthalenes2008

    • Author(s)
      Zhi-qi Cong
    • Journal Title

      Synthesis 2008

      Pages: 2686-2694

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Manganese(III)-Based Oxidative Dual Cyclization of 4, 4-Diaryl-3-butenyl-3-oxobutanoates2007

    • Author(s)
      Mitsuru Takatsuji, Hiroshi Nishino
    • Journal Title

      Cryogenics Report of Kumamoto University 18

      Pages: 15-17

    • NAID

      110007198289

    • Related Report
      2009 Final Research Report
  • [Journal Article] Mn(III)-Based Oxidative Cyclization of 1, 1-Disubstituted Butadienes with Cyclic 1, 3-Dicarbonyl Compounds2007

    • Author(s)
      Ryoichi Hamada, Hiroshi Nishino
    • Journal Title

      Cryogenics Report of Kumamoto University 18

      Pages: 11-13

    • NAID

      110007198290

    • Related Report
      2009 Final Research Report
  • [Journal Article] Synthesis of Macrocyclic Compounds Using Oxidative Radical Cyclization2007

    • Author(s)
      Yousuke Itoh, Hiroshi Nishino
    • Journal Title

      Cryogenics Report of Kumamoto University 18

      Pages: 5-9

    • NAID

      110007198291

    • Related Report
      2009 Final Research Report
  • [Journal Article] Selective synthesis of trioxapropellanes using manganese(III) acetate2007

    • Author(s)
      Kentaro Asahi
    • Journal Title

      Heterocycl.Commun. 13(印刷中)

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Presentation] マンガン(III)に基づく環状ヒドロキシエノン類とチエニル置換アルケン類のラジカル環化反応2010

    • Author(s)
      西野宏
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      近畿大学本部キャンパス
    • Year and Date
      2010-03-27
    • Related Report
      2009 Annual Research Report
  • [Presentation] 酢酸マンガン(III)による3-オキソブタンアミド類の酸化的分子内環化反応2010

    • Author(s)
      菊枝信孝・西野宏
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      近畿大学本部キャンパス
    • Related Report
      2009 Annual Research Report 2009 Final Research Report
  • [Presentation] Manganese(III)-Based Radical Cyclization of Cyclic Hydroxyenones with Thienyl-Substituted Alkenes2010

    • Author(s)
      Mehtap Yakut, Hiroshi Nishino
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      近畿大学本部キャンパス
    • Related Report
      2009 Final Research Report
  • [Presentation] 酢酸マンガン(III)による4-ペンテニル=3-オキソブタノエート類の酸化的分子内タンデム環化反応2010

    • Author(s)
      松井佑樹・西野宏
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      近畿大学本部キャンパス
    • Related Report
      2009 Annual Research Report 2009 Final Research Report
  • [Presentation] Synthesis of Hydroperoxy-2,4-pyrrolidinediones Using Manganese(III)-Catalyzed Aerobic Oxidation2009

    • Author(s)
      西野宏
    • Organizer
      The Third International Student Conference on Advanced Science and Technology, ICAST 2009 Seol
    • Place of Presentation
      Ewa Womans University, Korea
    • Year and Date
      2009-12-12
    • Related Report
      2009 Annual Research Report
  • [Presentation] Manganese(III)Acetae-Based Intramolecular Cyclization of N-(Oligomethylene)butanamides2009

    • Author(s)
      西野宏
    • Organizer
      The Third International Student Conference on Advanced Science and Technology, ICAST 2009 Seol
    • Place of Presentation
      Ewa Womans University, Korea
    • Year and Date
      2009-12-12
    • Related Report
      2009 Annual Research Report
  • [Presentation] Manganese(III)-Catalyzed Aerobic Oxidation of 2,4-Pyrrolidinedione Derivatives2009

    • Author(s)
      西野宏
    • Organizer
      The Eleventh International Kyoto Conference on New Aspects of Organic Chemistry(IKCOC-11)
    • Place of Presentation
      Rihga Royal Hotel Kyoto
    • Year and Date
      2009-11-11
    • Related Report
      2009 Annual Research Report
  • [Presentation] Dihydrofurylnaphthalene 類の酸化による 4H-furo[2,3-d]-naphtha [2,1-b] pyran-4-one 類の合成2009

    • Author(s)
      西野宏
    • Organizer
      2009年日本化学会西日本大会
    • Place of Presentation
      愛媛大学城北キャンパス
    • Year and Date
      2009-11-08
    • Related Report
      2009 Annual Research Report
  • [Presentation] マロン酸誘導体の酸化的分子内環化反応を利用したキノリン類の合成2009

    • Author(s)
      西野宏
    • Organizer
      2009年日本化学会西日本大会
    • Place of Presentation
      愛媛大学城北キャンパス
    • Year and Date
      2009-11-08
    • Related Report
      2009 Annual Research Report
  • [Presentation] 2-プロペニル=2-(2-オキソエチル)-3-オキソブタノエート類の酸化的分子内タンデム環化反応における選択性2009

    • Author(s)
      西野宏
    • Organizer
      2009年日本化学会西日本大会
    • Place of Presentation
      愛媛大学城北キャンパス
    • Year and Date
      2009-11-08
    • Related Report
      2009 Annual Research Report
  • [Presentation] 四置換 pyrrole 類の光環化反応による多官能基化された3H-benz [e] indole 類の合成2009

    • Author(s)
      西野宏
    • Organizer
      2009年日本化学会西日本大会
    • Place of Presentation
      愛媛大学城北キャンパス
    • Year and Date
      2009-11-08
    • Related Report
      2009 Annual Research Report
  • [Presentation] アセトアセトアニリド類の酸化的分子内環化反応を用いたインドリノン類の合成2009

    • Author(s)
      菊枝信孝・西野宏
    • Organizer
      第46回化学関連支部合同九州大会外国人研究者交流国際シンポジウム
    • Place of Presentation
      北九州国際会議場イベントホール
    • Year and Date
      2009-07-11
    • Related Report
      2009 Annual Research Report 2009 Final Research Report
  • [Presentation] マンガン(III)に基づくクルクミン誘導体の酸化的分子内環化反応2009

    • Author(s)
      町田和哉・西野宏
    • Organizer
      第46回化学関連支部合同九州大会外国人研究者交流国際シンポジウム
    • Place of Presentation
      北九州国際会議場イベントホール
    • Year and Date
      2009-07-11
    • Related Report
      2009 Annual Research Report 2009 Final Research Report
  • [Presentation] Manganese(III)- Catalyzed Hydroperoxidation of Pyrrolidine-2, 4-dione Derivatives, Md2009

    • Author(s)
      Aminul Haque, Hiroshi Nishino
    • Organizer
      第46回化学関連支部合同九州大会外国人研究者交流国際シンポジウム
    • Place of Presentation
      北九州国際会議場イベントホール
    • Year and Date
      2009-07-11
    • Related Report
      2009 Final Research Report
  • [Presentation] Manganese(III)-Catalyzed Hydroperoxidation of Pyrrolidine-2,4-dione Derivatives2009

    • Author(s)
      西野宏
    • Organizer
      第46回化学関連支部合同九州大会外国人研究者交流国際シンポジウム
    • Place of Presentation
      北九州国際会議場イベントホール
    • Year and Date
      2009-07-11
    • Related Report
      2009 Annual Research Report
  • [Presentation] マンガン(III)により誘起されたマクロ環化反応に関する研究2009

    • Author(s)
      伊藤洋輔・西野宏
    • Organizer
      第19回万有福岡シンポジウム
    • Place of Presentation
      九州大学医学部百年講堂
    • Year and Date
      2009-05-23
    • Related Report
      2009 Annual Research Report 2009 Final Research Report
  • [Presentation] Mn(III)に基づくトリカルボニル化合物やテトラカルボニル化合物のタンデム環化反応2009

    • Author(s)
      鬼塚睦弥
    • Organizer
      日本化学会第89春季年会
    • Place of Presentation
      日本大学理工学部船橋キャンパス
    • Year and Date
      2009-03-28
    • Related Report
      2008 Annual Research Report
  • [Presentation] 2-(2, 2-ジアリールエテニル)-l, 3-シクロアルカンジオン類を用いるベンソ[b]フラン類とクリセンジオン誘導体の選択的合成2009

    • Author(s)
      百武孝洋
    • Organizer
      日本化学会第89春季年会
    • Place of Presentation
      日本大学理工学部船橋キャンパス
    • Year and Date
      2009-03-28
    • Related Report
      2008 Annual Research Report
  • [Presentation] 2-ペンテン-1, 4-ジオン類を用いるベンソフラン誘導体の合成および関連反応2009

    • Author(s)
      西野 宏
    • Organizer
      日本化学会第89春季年会
    • Place of Presentation
      日本大学理工学部船橋キャンパス
    • Year and Date
      2009-03-28
    • Related Report
      2008 Annual Research Report
  • [Presentation] Ewa Womans University, 3-6o Synthesis of Hydroperoxy-2, 4-pyrrolidinediones Using Manganese (III)-Catalyzed Aerobic Oxidation, Md2009

    • Author(s)
      Aminul Haque, Hiroshi Nishino
    • Organizer
      The Third International Student Conference on Advanced Science and Technology
    • Place of Presentation
      ICAST 2009 Seol, Korea
    • Related Report
      2009 Final Research Report
  • [Presentation] Ewa Womans University, 3-7o Manganese(III) Acetae-Based Intramolecular Cyclization of N-(Oligo-methylene)butanamides2009

    • Author(s)
      Yosuke Ito, Hiroshi Nishino, Abstracts
    • Organizer
      The Third International Student Conference on Advanced Science and Technology
    • Place of Presentation
      ICAST 2009 Seol, Korea
    • Related Report
      2009 Final Research Report
  • [Presentation] Manganese(III)-Catalyzed Aerobic Oxidation of 2, 4-Pyrrolidinedione Derivatives, Md2009

    • Author(s)
      Aminul Haque, Hiroshi Nishino
    • Organizer
      The Eleventh International Kyoto Conference on New Aspects of Organic Chemistry (IKCOC-11)
    • Place of Presentation
      Rihga Royal Hotel Kyoto, Japan
    • Related Report
      2009 Final Research Report
  • [Presentation] Dihydrofurylnaphthalene類の酸化による4H-furo[2, 3-d]naphtha[2, 1-b]- pyran-4-one類の合成2009

    • Author(s)
      川上智之・西野宏
    • Organizer
      2009年日本化学会西日本大会
    • Place of Presentation
      愛媛大学城北キャンパス
    • Related Report
      2009 Final Research Report
  • [Presentation] Mn(III)に基づく酸化的分子内環化反応を利用したジヒドロイソキノリン類とジヒドロオキサジノン類の選択的合成2009

    • Author(s)
      井上沙弥香・西野宏
    • Organizer
      2009年日本化学会西日本大会
    • Place of Presentation
      愛媛大学城北キャンパス
    • Related Report
      2009 Annual Research Report 2009 Final Research Report
  • [Presentation] Mn(III)を用いた環状1, 3-ジカルボニル化合物の有酸素酸化反応2009

    • Author(s)
      五十嵐光・西野宏
    • Organizer
      2009年日本化学会西日本大会
    • Place of Presentation
      愛媛大学城北キャンパス
    • Related Report
      2009 Annual Research Report 2009 Final Research Report
  • [Presentation] マロン酸誘導体の酸化的分子内環化反応を利用したキノリン類の合成2009

    • Author(s)
      永島田貴之・西野宏
    • Organizer
      009年日本化学会西日本大会
    • Place of Presentation
      愛媛大学城北キャンパス
    • Related Report
      2009 Final Research Report
  • [Presentation] 2-プロペニル=2-(2-オキソエチル)-3-オキソブタノエート類の酸化的分子内タンデム環化反応における選択性2009

    • Author(s)
      鬼塚睦弥・西野宏
    • Organizer
      2009年日本化学会西日本大会
    • Place of Presentation
      愛媛大学城北キャンパス(ポスター発表)
    • Related Report
      2009 Final Research Report
  • [Presentation] 2-エテニル-1, 3-シクロアルカンジオン類を用いる酸化的環化反応2009

    • Author(s)
      百武孝洋・西野宏
    • Organizer
      2009年日本化学会西日本大会
    • Place of Presentation
      愛媛大学城北キャンパス
    • Related Report
      2009 Annual Research Report 2009 Final Research Report
  • [Presentation] N-(オリゴメチレン)ブタンアミド類の酸化的環化反応を利用したマクロアミド類の合成2009

    • Author(s)
      伊藤洋輔・西野
    • Organizer
      2009年日本化学会西日本大会
    • Place of Presentation
      愛媛大学城北キャンパス
    • Related Report
      2009 Annual Research Report 2009 Final Research Report
  • [Presentation] 四置換pyrrole類の光環化反応による多官能基化された3H-benz[e]indole類の合成2009

    • Author(s)
      川邉俊行・西野宏
    • Organizer
      2009年日本化学会西日本大会
    • Place of Presentation
      愛媛大学城北キャンパス
    • Related Report
      2009 Final Research Report
  • [Presentation] ブタンアミド類やアミノエチルマロネート類の酸化的分子内環化反応2009

    • Author(s)
      粒崎拓真、永島田貴之、井上沙弥香、菊枝信孝、西野宏
    • Organizer
      第39回複素環化学討論会
    • Place of Presentation
      さわやかちば県民プラザ
    • Related Report
      2009 Annual Research Report 2009 Final Research Report
  • [Presentation] Mn(III)に基づく2-(N-アリールアミノ)エチルマロン酸ジエステルの酸化的分子内環化反応。キノリン誘導体の合成2009

    • Author(s)
      永島田貴之・西野
    • Organizer
      日本化学会第89春季年会
    • Place of Presentation
      日本大学理工学部船橋キャンパス
    • Related Report
      2009 Final Research Report 2008 Annual Research Report
  • [Presentation] Mn(III)に基づく3-オキソブタンアミド類の酸化的分子内環化反応。ジヒドロイソキノリン類とジヒドロオキサジノン類の選択的合成2009

    • Author(s)
      井上沙弥香・西野宏
    • Organizer
      日本化学会第89春季年会
    • Place of Presentation
      日本大学理工学部船橋キャンパス
    • Related Report
      2009 Final Research Report 2008 Annual Research Report
  • [Presentation] . Mn(III)に基づくトリカルボニル化合物やテトラカルボニル化合物のタンデム環化反応2009

    • Author(s)
      鬼塚睦弥・西野宏
    • Organizer
      日本化学会第89春季年会
    • Place of Presentation
      日本大学理工学部船橋キャンパス
    • Related Report
      2009 Final Research Report
  • [Presentation] シクロアルカンジオン類を用いるベンゾ[b]フラン類とクリセンジオン誘導体の選択的合成2009

    • Author(s)
      百武孝洋・西野宏
    • Organizer
      日本化学会第89春季年会
    • Place of Presentation
      日本大学理工学部船橋キャンパス
    • Related Report
      2009 Final Research Report
  • [Presentation] 2PC-050. 2-ペンテン-1, 4-ジオン類を用いるベンゾフラン誘導体の合成および関連反応2009

    • Author(s)
      桟明美・西野宏
    • Organizer
      日本化学会第89春季年
    • Place of Presentation
      日本大学理工学部船橋キャンパス
    • Related Report
      2009 Final Research Report
  • [Presentation] Manganese (III)-Mediated Reactions of Aromatic Compounds with 1, 3-Dicarbonyl Species2008

    • Author(s)
      Zhiqi Cong
    • Organizer
      The Second International Student Conference on Advanced Science and Technology, ICAST 2008 Beijing, China
    • Place of Presentation
      Peking University, China
    • Year and Date
      2008-12-22
    • Related Report
      2008 Annual Research Report
  • [Presentation] マンガン(III)に基づく酸化的環化反応を利用したクラウンエーテル型化合物の合成と機能性2008

    • Author(s)
      伊藤洋輔
    • Organizer
      2008年日本化学会西日本大会
    • Place of Presentation
      長崎大学文教地区キャンパス
    • Year and Date
      2008-11-16
    • Related Report
      2008 Annual Research Report
  • [Presentation] マロン酸ジエチル誘導体の酸化的分子内環イヒ反応を利用した3, 4-ジヒドロ-2(1H)-キノリノン類の合成2008

    • Author(s)
      粒崎拓真
    • Organizer
      2008年日本化学会西日本大会
    • Place of Presentation
      長崎大学文教地区キャンパス
    • Year and Date
      2008-11-16
    • Related Report
      2008 Annual Research Report
  • [Presentation] Mn(III)に基づく環状α-ヒドロキシケトン類のBaeyer-Villiger型酸化反応2008

    • Author(s)
      井邉裕介
    • Organizer
      2008年日本化学会西日本大会
    • Place of Presentation
      長崎大学文教地区キャンパス
    • Year and Date
      2008-11-16
    • Related Report
      2008 Annual Research Report
  • [Presentation] Synthesis of Macrocyclic Compounds Using the Manganese (III)-Based Radical Cyclization2008

    • Author(s)
      Yosuke Ito
    • Organizer
      The 6th Kumamoto University Forum, Surabaya, Indonesia
    • Place of Presentation
      Surabaya, Indonesia
    • Year and Date
      2008-11-05
    • Related Report
      2008 Annual Research Report
  • [Presentation] Manganese (III)-Mediated Tandem Cyclization of Di-, Tri-, and Tetra-carbonyl System2008

    • Author(s)
      Hiroshi Nishino
    • Organizer
      The 6th Kumamoto University Forum, Surabaya, Indonesia
    • Place of Presentation
      Surabaya, Indonesia
    • Year and Date
      2008-11-05
    • Related Report
      2008 Annual Research Report
  • [Presentation] study of Manganese (III)-Based Tandem Cyclization2008

    • Author(s)
      Hiroshi Nishino
    • Organizer
      第25回有機合成化学セミナー
    • Place of Presentation
      阿蘇プラザホテル
    • Year and Date
      2008-09-09
    • Related Report
      2008 Annual Research Report
  • [Presentation] 酸化的ラジカル環化反応を用いる大環状化合物の合成に関する研究2008

    • Author(s)
      伊藤洋輔
    • Organizer
      第25回有機合成化学セミナー
    • Place of Presentation
      阿蘇プラザホテル
    • Year and Date
      2008-09-09
    • Related Report
      2008 Annual Research Report
  • [Presentation] study of Manganese (III)-Mediated Oxidation of Aromatic Compounds in the Presence of 1, 3-Dicarbonyl Species2008

    • Author(s)
      Zhiqi Cong
    • Organizer
      第25回有機合成化学セミナー
    • Place of Presentation
      阿蘇プラザホテル
    • Year and Date
      2008-09-09
    • Related Report
      2008 Annual Research Report
  • [Presentation] 4_5. 041.酢酸マンガン(III)によるジヒドロフリルナフタレン類の酸化反応2008

    • Author(s)
      川上智之・西野宏
    • Organizer
      第45回化学関連支部合同九州大会外国人研究者交流国際シンポジウム
    • Place of Presentation
      北九州国際会議場イベントホール
    • Year and Date
      2008-07-05
    • Related Report
      2009 Final Research Report
  • [Presentation] 4_5. 049.光環化反応を用いるpyrrole誘導体の3H-benzo[e]indole類への変換2008

    • Author(s)
      川邉裕介・西野宏
    • Organizer
      第45回化学関連支部合同九州大会外国人研究者交流国際シンポジウム
    • Place of Presentation
      北九州国際会議場イベントホール
    • Year and Date
      2008-07-05
    • Related Report
      2009 Final Research Report
  • [Presentation] 4_5. 054. BF3存在下における2-pent-ene-1, 4-dione類と環状1, 3-ジカルボニル化合物の反応と応用2008

    • Author(s)
      桟明美・西野宏
    • Organizer
      第45回化学関連支部合同九州大会外国人研究者交流国際シンポジウム
    • Place of Presentation
      北九州国際会議場イベントホール
    • Year and Date
      2008-07-05
    • Related Report
      2009 Final Research Report
  • [Presentation] 酢酸マンガン(III)によるジヒドロフリルナフタレン類の酸化反応2008

    • Author(s)
      川上智之
    • Organizer
      第45回化学関連支部合同九州大会外国人研究者交流国際シンポジウム
    • Place of Presentation
      北九州国際会議場イベントホール
    • Year and Date
      2008-07-05
    • Related Report
      2008 Annual Research Report
  • [Presentation] 光環化反応を用いるpyrrole誘導体の3H-benzo[e]indole類への変換2008

    • Author(s)
      川邉裕介
    • Organizer
      第45回化学関連支部合同九州大会外国人研究者交流国際シンポジウム
    • Place of Presentation
      北九州国際会議場イベントホール
    • Year and Date
      2008-07-05
    • Related Report
      2008 Annual Research Report
  • [Presentation] BF_3存在下における2-pentene-1, 4-dione類と環状1, 3-ジカルボニル化合物の反応と応用2008

    • Author(s)
      桟 明美
    • Organizer
      第45回化学関連支部合同九州大会外国人研究者交流国際シンポジウム
    • Place of Presentation
      北九州国際会議場イベントホール
    • Year and Date
      2008-07-05
    • Related Report
      2008 Annual Research Report
  • [Presentation] Overseas Exchange Center, Peking University, Beijing, China, Manganese(III)- Mediated Reactions of Aromatic Compounds with 1, 3-Dicarbonyl Species2008

    • Author(s)
      Zhiqi Cong, Hiroshi Nishino, Abstracts
    • Organizer
      The Second International Student Conference on Advanced Science and Technology
    • Place of Presentation
      ICAST 2008 Beijing, China
    • Related Report
      2009 Final Research Report
  • [Presentation] 2H-03.マンガン(III)に基づく酸化的環化反応を利用したクラウンエーテル型化合物の合成と機能性2008

    • Author(s)
      伊藤洋輔・西野宏
    • Organizer
      2008年日本化学会西日本大会
    • Place of Presentation
      長崎大学文教地区キャンパス
    • Related Report
      2009 Final Research Report
  • [Presentation] 2H-06.マロン酸ジエチル誘導体の酸化的分子内環化反応を利用した3, 4-ジヒドロ-2(1H)-キノリノン類の合成2008

    • Author(s)
      粒崎拓真・西野宏
    • Organizer
      2008年日本化学会西日本大会
    • Place of Presentation
      長崎大学文教地区キャンパス
    • Related Report
      2009 Final Research Report
  • [Presentation] 2P-50. Mn(III)に基づく環状α-ヒドロキシケトン類のBaeyer-Villiger型酸化反応2008

    • Author(s)
      井邉裕介・西野宏
    • Organizer
      2008年日本化学会西日本大会
    • Place of Presentation
      長崎大学文教地区キャンパス
    • Related Report
      2009 Final Research Report
  • [Presentation] P-12. Study of Manganese(III)- Based Tandem Cyclization2008

    • Author(s)
      Hiroshi Nishino, Kentaro Asahi, Van-Ha Nguyen, Hiroyasu Yamakawa, Mitsuru Takatsuji, Susumu Wakamiya, Mutsumi Onizuka, Abstracts
    • Organizer
      第25回有機合成化学セミナー
    • Place of Presentation
      阿蘇プラザホテル
    • Related Report
      2009 Final Research Report
  • [Presentation] P-14.酸化的ラジカル環化反応を用いる大環状化合物の合成に関する研究2008

    • Author(s)
      伊藤洋輔・西野宏、Abstracts
    • Organizer
      第25回有機合成化学セミナー
    • Place of Presentation
      阿蘇プラザホテル
    • Related Report
      2009 Final Research Report
  • [Presentation] P-15. Study of Manganese(III)- Mediated Oxidation of Aromatic Compounds in the Presence of 1, 3-Dicarbonyl Species2008

    • Author(s)
      Zhiqi Cong, Hiroshi Nishino, Abstracts
    • Organizer
      第25回有機合成化学セミナー
    • Place of Presentation
      阿蘇プラザホテル
    • Related Report
      2009 Final Research Report
  • [Presentation] マロン酸エステルを用いたジベンズ[b, f]オキセピン類の合成2008

    • Author(s)
      ジュウ志奇・西野宏
    • Organizer
      日本化学会第88春季年会
    • Place of Presentation
      立教大学池袋キャンパス
    • Related Report
      2009 Final Research Report
  • [Presentation] 3PB-057酢酸マンガン(III)存在下における1, 1-ジフェニルエテンとテトラケトン類の反応2008

    • Author(s)
      鬼塚睦弥・西野宏
    • Organizer
      日本化学会第88春季年会
    • Place of Presentation
      立教大学池袋キャンパス
    • Related Report
      2009 Final Research Report
  • [Presentation] 3PB-058 3-オキソブタンアミド類の酸化的分子内環化反応を用いたジヒドロイソキノリン類とジヒドロオキサジノン類の選択的合成2008

    • Author(s)
      井上沙弥香・清田基・西野宏
    • Organizer
      日本化学会第88春季年会
    • Place of Presentation
      立教大学池袋キャンパス
    • Related Report
      2009 Final Research Report
  • [Presentation] 3PB-059 2-(N-アリールアミノ)エチルマロン酸ジエステルの酸化的分子内環化反応を利用したジヒドロキノリンジカルボキシレート類の合成2008

    • Author(s)
      永島田貴之・大木健吾・西野宏
    • Organizer
      日本化学会第88春季年会
    • Place of Presentation
      立教大学池袋キャンパス
    • Related Report
      2009 Final Research Report
  • [Presentation] 3PB-066 Mn(III)-触媒有酸素酸化反応を用いるトリオキサビシクロ[4. 3. 0]ノネン類の合成2008

    • Author(s)
      西野宏・茂田誠・山川博益
    • Organizer
      日本化学会第88春季年会
    • Place of Presentation
      立教大学池袋キャンパス
    • Related Report
      2009 Final Research Report
  • [Presentation] 3PB-067 Mn(pic)3やPb(OAc)4を用いた2-(2, 2-ジアリールエテニル)-1, 3-シクロヘキサンジオン類の酸化反応2008

    • Author(s)
      百武孝洋・西野宏
    • Organizer
      日本化学会第88春季年会
    • Place of Presentation
      立教大学池袋キャンパス
    • Related Report
      2009 Final Research Report
  • [Presentation] ピペリジンジオン類や不飽和β-ジカルボニル化合物類のマンガン(III)に基づく酸化的環化反応に関する研究2007

    • Author(s)
      旭 健太郎
    • Organizer
      有機合成化学協会九州山口支部 第19回若手研究者のためのセミナー
    • Place of Presentation
      熊本火の国ハイツ
    • Year and Date
      2007-11-23
    • Related Report
      2007 Annual Research Report
  • [Presentation] 酢酸マンガン(III)を用いた2-プロペニル=2-(2-オキソエチル)-3-オキソブタノエート類の分子内タンデム環化反応2007

    • Author(s)
      若宮 進
    • Organizer
      2007年日本化学会西日本大会
    • Place of Presentation
      岡山大学津島キャンパス
    • Year and Date
      2007-11-11
    • Related Report
      2007 Annual Research Report
  • [Presentation] 2-(ベンジルオキシ)エチル=3-オキソブタノエート類を用いたコンテナ型分子の合成と機能性2007

    • Author(s)
      熊本 祥一
    • Organizer
      2007年日本化学会西日本大会
    • Place of Presentation
      岡山大学津島キャンパス
    • Year and Date
      2007-11-11
    • Related Report
      2007 Annual Research Report
  • [Presentation] 酢酸マンガン(III)存在下における3-アセチル-1-アリール-1,4-ペンタンジオン類と1,1-ジアリールエテン類の反応2007

    • Author(s)
      茂田 誠
    • Organizer
      2007年日本化学会西日本大会
    • Place of Presentation
      岡山大学津島キャンパス
    • Year and Date
      2007-11-11
    • Related Report
      2007 Annual Research Report
  • [Presentation] マンガン(III)酸化反応を用いるビシクロ[3.1.0]ヘキサン-2-オン類の合成2007

    • Author(s)
      旭 健太郎
    • Organizer
      2007年日本化学会西日本大会
    • Place of Presentation
      岡山大学津島キャンパス
    • Year and Date
      2007-11-10
    • Related Report
      2007 Annual Research Report
  • [Presentation] Mn(III)を用いる縮環複素環骨格の構築2007

    • Author(s)
      旭 健太郎
    • Organizer
      第17回万有福岡シンポジウム
    • Place of Presentation
      九州大学医学部百周年講堂
    • Year and Date
      2007-05-12
    • Related Report
      2007 Annual Research Report
  • [Presentation] P-18.ピペリジンジオン類や不飽和β-ジカルボニル化合物類のマンガン(III)に基づく酸化的環化反応に関する研究2007

    • Author(s)
      旭健太郎・西野宏
    • Organizer
      有機合成化学協会九州山口支部第19回若手研究者のためのセミナー
    • Place of Presentation
      火の国ハイツ
    • Related Report
      2009 Final Research Report
  • [Presentation] P-19. (9-キサンテニル)マロネート類の酢酸マンガン(III)による酸化反応に関する研究2007

    • Author(s)
      从志奇・西野宏
    • Organizer
      有機合成化学協会九州山口支部第19回若手研究者のためのセミナー
    • Place of Presentation
      火の国ハイツ
    • Related Report
      2009 Final Research Report
  • [Remarks]

    • URL

      http://www.nishino-labo.jp/http://www.gsst.kumamoto-u.ac.jp/kenkyu/index.html#rigaku

    • Related Report
      2009 Final Research Report
  • [Remarks]

    • URL

      http://www.nishino-labo.jp/

    • Related Report
      2009 Annual Research Report
  • [Remarks]

    • URL

      http://www.gsst.kumamoto-u.ac.jp/kenkyu/index.html#rigaku

    • Related Report
      2009 Annual Research Report
  • [Remarks]

    • URL

      http://www.gsst.kumamoto-u.ac.jp/kenkyu/index.html#rigaku

    • Related Report
      2008 Annual Research Report
  • [Remarks]

    • URL

      http://www.gsst.kumamoto-u.ac.jp/kenkyu/index.html#rigaku

    • Related Report
      2007 Annual Research Report

URL: 

Published: 2007-04-01   Modified: 2016-04-21  

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