Theoretical study on the stereoselectivity of the chiral phosphoric acids catalyzed reaction and making database of the transition structures

• Project/Area Number: 19550047
• Research Category: Grant-in-Aid for Scientific Research (C)
• Allocation Type: Single-year Grants
• Section: 一般
• Research Field: Organic chemistry
• Research Institution: Gifu University
• Principal Investigator: ANDO Kaori Gifu University, 工学部, 教授 (70211018)
• Project Period (FY): 2007 – 2009
• Project Status: Completed (Fiscal Year 2009)
• Budget Amount: ¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000); Fiscal Year 2009: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000); Fiscal Year 2008: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000); Fiscal Year 2007: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
• Keywords: 分子軌道計算 / 立体選択性 / 遷移状態構造 / 汎密度関数法 / 不斉Friedel-Crafts反応 / 汎密度関数計算 / 不斉Mannich反応

Research Abstract

キラルリン酸触媒を用いるイミンとアセチルアセトンのMannich反応について、遷移状態構造を計算により求めた。しかし、高い選択性の得られるキラルリン酸には多数の配座異性体が存在し多数の遷移状態構造があることが分かった。実際そのほとんどを計算したが、立体制御因子の解明には至らなかった。そこで、触媒構造の自由度の小さい系での研究を行なうこととし、キラルロジウム2核錯体を用いるα-アルキル-α-ジアゾエステルとフェニルアセチレンの不斉シクロプロペン化反応の立体選択性に関する研究を行なった。触媒はハロゲン結合のために唯一つの形に固定されいることが分かった。触媒とα-アルキル-α-ジアゾエステルから得られるカルベン錯体とフェニルアセチレンとの反応の遷移状態を計算し4つの遷移状態構造を得た。不斉炭素のため触媒はらせん構造をとり、アセチレンの近づく向きにより大きなエステル部分との立体障害により立体が決まっていることが分かった。

Research Products

• [Journal Article] Solvent-free Horner-Wadsworth-Emmons reaction using DBU (2010)
  • Author(s): Ando, K., Yamada, K.
  • Journal Title: Tetrahedron Lett. 51 Pages: 3297-3299
• [Journal Article] Z-selective Intramolecular Horner-Wadsworth-Emmons Reaction for the Synthesis of Macrocyclic Lactones. (2010)
  • Author(s): Ando, K., Narumiya, K., Takada, H., Teruya, T.
  • Journal Title: Org. Lett. 12 Pages: 1460-1463
• [Journal Article] New polymer-supported phosphonate reagents for the synthesis of Z-α, β-unsaturated esters. (2010)
  • Author(s): Ando, K, Suzuki, Y.
  • Journal Title: Tetrahedron Lett. 51 Pages: 2323-2325
• [Journal Article] Z-selective Intramolecular Horner-Wadsworth-Emmons Reaction for the Synthesis of Macrocyclic Lactones. (2010)
  • Author(s): Ando, K.; Nagaya, K.; Takada, H.; Teruya, T.
  • Journal Title: Org.Lett. 12 Pages: 1460-1463
  • Peer Reviewed
• [Journal Article] New polymer-supported phosphonate reagents for the synthesis of Z-α, β-unsaturated esters. (2010)
  • Author(s): Ando, K.; Suzuki
  • Journal Title: Tetrahedron Letters 51 Pages: 2323-2325
  • Peer Reviewed
• [Journal Article] Pentacoordinate Organoantimony Compounds that isomerizes by Trunstile Rotation (2009)
  • Author(s): Matsukawa, S., Yamamichi, H., Yamamoto, Y., Ando, K.
  • Journal Title: J. Am. Chem. Soc. 131 Pages: 3418-3419
• [Journal Article] Nucleophilic substitution reaction at an sp2 carbon of vinyl halides with an intramolecular thiol moiety: synthesis of thio-heterocycles. (2009)
  • Author(s): Lei, M.-Y., Xiao, Y.-J., Liu, W.-M., Fukamizu, K., Chiba, S., Ando, K., Narasaka, K.
  • Journal Title: Tetrahedron 65 Pages: 6888-6902
• [Journal Article] Bis(2-t-butylphenyl)phosphonoacetates for the highly cis-selective synthesis ofα, β-unsturated amides. (2009)
  • Author(s): Ando, K., Nagaya, S., Tarumi, Y.
  • Journal Title: Tetrahedron Lett. 50 Pages: 5689-5691
• [Journal Article] Concerted nucleophilic substitution reactions at vinylic carbons (2009)
  • Author(s): Chiba, S., Ando, K., Narasaka, K.
  • Journal Title: Synlett Pages: 2549-2564
• [Journal Article] Pentacoordinate Organoantimony Compounds that isomerizes by Trunstile Rotation (2009)
  • Author(s): Matsukawa, S.; Yamamichi, H.; Yamamoto, Y.; Ando, K
  • Journal Title: J.Am.Chem.Soc. 131巻 Pages: 3418-3419
  • Peer Reviewed
• [Journal Article] Nucleophilic substitution reaction at an sp^2 carbon of vinyl halides with an intramolecular thiol moiety : synthesis of thio-heterocycles. (2009)
  • Author(s): Lei, M.-Y.; Xiao, Y.-J.; Liu, W.-M.; Fukamizu, K.; Chiba, S.; Ando, K.; Narasaka, K.
  • Journal Title: Tetrahedron 65 Pages: 6888-6902
  • Peer Reviewed
• [Journal Article] Bis (2-t-butylphenyl) phosphonoacetates for the highly cis-selective synthesis of α, β-unsturated amides. (2009)
  • Author(s): Ando, K.; Nagaya, S.; Tarumi, Y.
  • Journal Title: Tetrahedron Lett. 50 Pages: 5689-5691
  • Peer Reviewed
• [Journal Article] Concerted nucleophilic substitution reactions at vinylic carbons (2009)
  • Author(s): Chiba, S.; Ando, K.; Narasaka, K.
  • Journal Title: Synlett 2009 Pages: 2549-2564
  • Peer Reviewed
• [Journal Article] Pentacoordinate Organoantimony Compounds That Isomerize by Turnstile Rotation (2009)
  • Author(s): Matsukawa, S
  • Journal Title: J. Am. Chem. Soc. 1 3 1 Pages: 3418-3419
  • Peer Reviewed
• [Journal Article] Concerted Nucleophilic Substitution Reactions at Vinylic Carbons (2009)
  • Author(s): Shunsuke Chiba
  • Journal Title: Synlett (In press. )
  • Peer Reviewed
• [Journal Article] Nucelophilic Substitution at an sp2 Carbon of Vinyl Halides with an Intramolecular Thiolate Moieties: Synthesis of 2-Alkylidene-thietanes (2008)
  • Author(s): Lei, M.-Y., Fukamizu, K., Xiao, Y.-J., Liu, W.-M., Twiddy, S., Chiba, S., Ando, K., Narasaka, K.
  • Journal Title: Tetrahedron Lett. 49 Pages: 4125-4129
• [Journal Article] Nucelophilic Substitution at an sp^2 Carbon of Vinyl Halides with an Intramolecular Thiolate Moieties : Synthesis of 2-Alkylidenethietanes (2008)
  • Author(s): Mao-Yi Lei
  • Journal Title: Tetrahedron Letters 49 Pages: 4125-4129
  • Peer Reviewed
• [Journal Article] Highly Selective Recognition of Cytosine over Urasil and Adenine by a Guanine Analog, 2-N-Acetyl-3-deazaguanine, in 2'-O-Methyl-RNA/RNA Duplexes (2007)
  • Author(s): Seio, K., Sasami, T., Ohkubo, A., Ando, K., Sekine, M.
  • Journal Title: J. Am. Chem. Soc. 129(5) Pages: 1026-1027
• [Journal Article] Synthesis of Hetero-and Carbocycles by Nucleophilic Substitution at sp2 Carbon (2007)
  • Author(s): Miyauchi, H., Shunsuke Chiba, S., Ando, K., Narasaka, K.
  • Journal Title: Tetrahedron 63(26) Pages: 5940-5953
• [Journal Article] New Aspects of the Cyanoethyl Group at the Smallest-Sized Protecting Group of the 2'-Hydroxyl Function Capable of Smooth Condensation and Easy Protection-Deprotection under Mild Conditions in the Chemical Synthesis of RNA (2007)
  • Author(s): Saneyoshi, H., Ando, K., Seio, K., Sekine, M.
  • Journal Title: Tetrahedron 63(45) Pages: 11195-11203
• [Journal Article] New Aspects of the Cyanoethyl Group at the Smallest-Sized Protecting Group of the 2'-Hydroxyl Function Capable of Smooth Condensation and Easy Protection-Deprotection under Mild Conditions in the Chemical Synthesis of RNA (2007)
  • Author(s): Saneyoshi, H.
  • Journal Title: Tetrahedron 63 Pages: 11195-11203
  • Peer Reviewed
• [Journal Article] Synthesis of Hetero- and Carbocycles by Nucleophilic Substitution at sp^2 Carbon (2007)
  • Author(s): Miyauchi, H.
  • Journal Title: Tetrahedron 63 Pages: 5940-5953
  • Peer Reviewed
• [Journal Article] Highly Selective Recognition of Cytosine over Urasil and Adenine by a Guanine Analog, 2-N-Acetyl-3-deazaguanine, in 2'-O-Methyl-RNA/RNA Duplexes (2007)
  • Author(s): Seio, K.
  • Journal Title: J. Am. Chem. Soc. 129 Pages: 1026-1027
  • Peer Reviewed
• [Presentation] Theoretical study on the stereoselectivity of chiral phosphoric acid-catalyzed Mannich reaction (2010)
  • Author(s): Kaori Ando
  • Organizer: International Symposium on Molecular Theory for Real Systems
  • Place of Presentation: Kyoto(poster)
• [Presentation] Theoretical study on the stereoselectivity of chiral phosphoric acid-catalyzed Mannich reaction (2010)
  • Author(s): Kaori Ando
  • Organizer: International Synposium on theory of molecular structure, function and reactivity
  • Place of Presentation: 京都
• [Presentation] ポリマー担持Z選択的HWE試薬の開発 (2009)
  • Author(s): 鈴木雄策、安藤香織
  • Organizer: 有機典型元素討論会
  • Place of Presentation: 鳥取
  • Year and Date: 2009-12-11
• [Presentation] Z選択的分子内Horner-Wadsworth-Emmons反応を用いる大環状ラクトンの合成 (2009)
  • Author(s): 成宮健次、高田和宏、照屋太司、安藤香織
  • Organizer: 天然有機化合物討論会
  • Place of Presentation: 名古屋
  • Year and Date: 2009-10-08
• [Presentation] Theoretical Study on the Gold-catalyzed C-S Bond Formation ofα-Thioallenes. (2009)
  • Author(s): Kaori Ando
  • Organizer: International Synposium on theory of molecular structure, function and reactivity
  • Place of Presentation: Kyoto(poster)
  • Year and Date: 2009-07-20
• [Presentation] 理論計算で何が分かるのか、どう利用する?(招待講演) (2009)
  • Author(s): 安藤香織
  • Organizer: 有機反応若手の会
  • Place of Presentation: 上尾
  • Year and Date: 2009-07-20
• [Presentation] 高Z選択的HWEアミド試薬の開発 (2009)
  • Author(s): 長屋茂朗、樽見裕子、安藤香織
  • Organizer: 有機合成化学シンポジウム
  • Place of Presentation: 東京
  • Year and Date: 2009-07-20
• [Presentation] Theoretical Study on the Gold-catalyzed C-S Bond Formation of α-Thioallenes (2009)
  • Author(s): Kaori Ando
  • Organizer: International Synposium on theory of molecular structure, function and reactivity
  • Place of Presentation: 京都
  • Year and Date: 2009-07-20
• [Presentation] 理論計算で何が分かるのか、どう利用する? (2009)
  • Author(s): 安藤香織
  • Organizer: 有機反応若手の会
  • Place of Presentation: 上尾
  • Year and Date: 2009-07-10
• [Presentation] α-チオアレンの2, 5-ジヒドロチオフェンへの金触媒環化反応に関する理論研究 (2009)
  • Author(s): 安藤香織
  • Organizer: 実在系の分子理論」平成21年度第1回公開シンポジウム
  • Place of Presentation: 東京
  • Year and Date: 2009-05-30
• [Presentation] ポリマー担持z選択的hwe試薬の開発 (2009)
  • Author(s): 鈴木雄策, 安藤香織
  • Organizer: 第36回有機典型元素化学討論会
  • Place of Presentation: 鳥取(口頭発表)
• [Presentation] Solventfree Horner-Wadsworth-Emmons反応 (2009)
  • Author(s): 山田恭平, 鈴木雄策, 安藤香織
  • Organizer: 第40回中部地化学関係学協会支部連合秋季大会
  • Place of Presentation: 岐阜(口頭発表)
• [Presentation] ポリマー担持z選択的hwe試薬の開発 (2009)
  • Author(s): 鈴木雄策, 安藤香織
  • Organizer: 第40回中部地化学関係学協会支部連合秋季大会
  • Place of Presentation: 岐阜(ポスター)
• [Presentation] 高z選択的hweアミド試薬の開 (2009)
  • Author(s): 長屋茂朗, 樽見裕子, 安藤香織
  • Organizer: 第40回中部地化学関係学協会支部連合秋季大会
  • Place of Presentation: 岐阜(ポスター)
• [Presentation] z選択的分子内hwe反応の立体選択性に関する研究 (2009)
  • Author(s): 佐藤歌小里, 安藤香織
  • Organizer: 第40回中部地化学関係学協会支部連合秋季大会
  • Place of Presentation: 岐阜(poster)
• [Presentation] 高z択的分子内hwe反応による大環状ラクトンの合成 (2009)
  • Author(s): 成宮健次, 高田和宏, 照屋太司, 安藤香織
  • Organizer: 第40回中部地化学関係学協会支部連合秋季大会
  • Place of Presentation: 岐阜(ポスター)
• [Presentation] 高z選択的hweアミド試薬の開発 (2009)
  • Author(s): 長屋茂朗, 樽見裕子, 安藤香織
  • Organizer: 有機合成化学シンポジウム
  • Place of Presentation: 東京(口頭発表)
• [Presentation] z選択的分子内Horner-Wadsworth-Emmons反応を用いる大環状ラクトンの合成 (2009)
  • Author(s): 成宮健次, 高田和宏, 照屋太司, 安藤香織
  • Organizer: 第51回天然有機化合物討論会
  • Place of Presentation: 名古屋(oral+poster)
• [Presentation] 高2選択的分子内HWE反応による大環状ラクトンの合成 (2008)
  • Author(s): 山道秀映
  • Organizer: 有機典型元素化学討論会
  • Place of Presentation: 東京
  • Year and Date: 2008-12-12
• [Presentation] キラルリン酸によるカルボン酸のキラル識別における立体制御因子の解明 (2008)
  • Author(s): 安藤香織
  • Organizer: 特定領域研究「実在系の分子理論」A01, A03班合同研究交流会
  • Year and Date: 2008-11-14
• [Presentation] 高z選択的hweアミド試薬の開発 (2008)
  • Author(s): 長屋茂朗, 樽見裕子, 安藤香織
  • Organizer: 中部化学関係学協会支部連合秋季大会
  • Place of Presentation: 名古屋(口頭発表)
  • Year and Date: 2008-11-08
• [Presentation] 高Z選択的分子内HWE反応による大環状ラクトンの合成 (2008)
  • Author(s): 成宮健次, 高田和宏, 照屋太司, 安藤香織
  • Organizer: 中部化学関係学協会支部連合秋季大会
  • Place of Presentation: 名古屋(口頭発表)
  • Year and Date: 2008-11-08
• [Presentation] z選択的ポリマー担持hwe試薬の開発 (2008)
  • Author(s): 鈴木雄策, 安藤香織
  • Organizer: 中部化学関係学協会支部連合秋季大会
  • Place of Presentation: 名古屋(口頭発表)
  • Year and Date: 2008-11-08
• [Presentation] 高Z選択的HWEアミド試薬の開発 (2008)
  • Author(s): 長屋茂朗
  • Organizer: 中部化学関係学協会支部連合秋季大会
  • Place of Presentation: 名古屋
  • Year and Date: 2008-11-08
• [Presentation] Z選択的ポリマー担持HWE試薬の開発 (2008)
  • Author(s): 鈴木雄策
  • Organizer: 中部化学関係学協会支部連合秋季大会
  • Place of Presentation: 名古屋
  • Year and Date: 2008-11-08
• [Presentation] 高Z選択的分子内HWE反応による大環状ラクトンの合成 (2008)
  • Author(s): 成宮健次
  • Organizer: 中部化学関係学協会支部連合秋季大会
  • Place of Presentation: 名古屋
  • Year and Date: 2008-11-08
• [Presentation] 理論計算から始まる有機合成への挑戦 (2008)
  • Author(s): 安藤香織
  • Organizer: 機能性分子ミニシンポジウム
  • Place of Presentation: 筑波大学学際物質科学研究センター
  • Year and Date: 2008-10-25
• [Presentation] Theoretical study on the Mechanism of the Cleavage Reaction of Cyanoethyl Group from 2-Cyanoethyl Ether Derivatives Using Bu_4NF (2008)
  • Author(s): Kaori Ando
  • Organizer: The 2^<nd> International Symposium on "Molecular Theory for Real Systems"
  • Place of Presentation: Okazaki, Japan
  • Year and Date: 2008-08-05
• [Presentation] シス選択的hwe試薬の開発 (2008)
  • Author(s): 安藤香織
  • Organizer: 筑波大学先端学際領域研究センター主催
  • Place of Presentation: つくば講演会
  • Year and Date: 2008-08-01
• [Presentation] Highly cis-selective synthesis of α, β-unsaturated amides by Horner-Wadsworth-Emmons reaction (2008)
  • Author(s): Kaori Ando
  • Organizer: The First International Symposium on Process Chemistry
  • Place of Presentation: Kyoto, Japan
  • Year and Date: 2008-07-30
• [Presentation] Turnstile stereomutation of pentacoordinate organoantimony compounds bearing a rigid tridentate ligand (2008)
  • Author(s): Kaori Ando
  • Organizer: Houk65 Symposium : Computational Chemistry : Orgo, Bio, Nano
  • Place of Presentation: Loss Angels, USA (invited lecture)
  • Year and Date: 2008-06-27
• [Presentation] Highly cis-selective synthesis of α, β-unsaturated amides by Horner-Wadsworth-Emmons reaction (2008)
  • Author(s): Kaori Ando
  • Organizer: The 3^<rd> International Conference on Advanced Organic Synthesis Directed toward the Ultimate Efficiency and Practicability
  • Place of Presentation: Ohtsu, Japan
  • Year and Date: 2008-05-27
• [Presentation] 強固な三座配位子を有する5配位アンチモン化合物の異性化機構の解明 (2008)
  • Author(s): 山道秀映, 松川史郎, 山本陽介, 安藤香織
  • Organizer: 日本化学会第88春季年会
  • Place of Presentation: 東京(口頭発表)
  • Year and Date: 2008-03-27
• [Presentation] 強固な三座配位子を有する5配位アンチモン化合物の異性化機構の解明 (2008)
  • Author(s): 山道秀映
  • Organizer: 日本化学会第88春季年会(2008)
  • Place of Presentation: 東京
  • Year and Date: 2008-03-27
• [Presentation] キラルリン酸による分子認識と反応制御機構の解明 (2008)
  • Author(s): 安藤香織
  • Organizer: 特定領域研究「実在系の分子理論」成果報告会
  • Place of Presentation: 札幌
• [Presentation] 5配位アンチモン化合物のTurnstile Rotation機構による異性化における溶媒および配位子サイズの影響 (2008)
  • Author(s): 山道秀映, 諏沢宏, 松川史郎, 山本陽介, 安藤香織
  • Organizer: 有機典型元素化学討論会
  • Place of Presentation: 東京
• [Presentation] Theoretical Study on the Mechanism of the Cleavage Reaction of Cyanoethyl Group from Cyanoethyl Ether Derivatives Using Bu4NF (2008)
  • Author(s): Kaori Ando
  • Organizer: The 2nd International Symposium on "Molecular Theory for Real Systems"
  • Place of Presentation: Okazaki(poster)
• [Presentation] Highly cis-selctive synthesis ofα, β-unsaturated amides by Horner- Wadsworth-Emmons reaction (2008)
  • Author(s): Kaori Ando, Yuko Tarumi
  • Organizer: The First International Symposium on Process Chemistr
  • Place of Presentation: Kyoto(poster)
• [Presentation] Turnstile stereomutation of pentacoordinate organoantimony compounds bearing a rigid tridentate ligand (2008)
  • Author(s): Loss Angels, Kaori Ando
  • Organizer: Houk65 Symposium: Computational Chemistry: Orgo, Bio
  • Place of Presentation: Nano(invited lecture)
• [Presentation] hwe反応によるオレフィンのez立体制御法の確立 (2008)
  • Author(s): 安藤香織
  • Organizer: 特定領域研究「炭素資源の高度分子変換」第5回公開シンポジウム
  • Place of Presentation: 仙台
• [Presentation] Highly cis-selective synthesis ofα, β-unsaturated amides by Horner- Wadsworth-Emmons reaction (2008)
  • Author(s): Kaori Ando, Yuko Tarumi
  • Organizer: The 3rd International Conference on Advanced Organic Synthesis Directed toward the Ultimate Efficiency and Practicability
  • Place of Presentation: Ohtsu(poster)
• [Presentation] 3座配位子で固定された5配位アンチモン化合物の立体異性化機構に関する研究 (2007)
  • Author(s): 安藤香織
  • Organizer: 第34回有機典型元素化学討論会
  • Place of Presentation: 大阪
  • Year and Date: 2007-12-14
• [Presentation] 新規三座配位子を有する5配位アンチモン化合物の合成とその異性化 (2007)
  • Author(s): 山道秀映
  • Organizer: 第34回有機典型元素化学討論会
  • Place of Presentation: 大阪
  • Year and Date: 2007-12-14
• [Presentation] 理論計算から始まる有機合成への挑戦 (2007)
  • Author(s): 安藤香織
  • Organizer: 第38回中部化学関係学協会支部連合秋季大会特別討論会
  • Year and Date: 2007-11-11
• [Presentation] 理論計算から始まる有機合成への挑戦 (依頼講演) (2007)
  • Author(s): 安藤香織
  • Organizer: 第38回中部化学関係学協会支部連合秋季大会
  • Place of Presentation: 津
  • Year and Date: 2007-11-11
• [Presentation] Stereomutation of Pentacoordinate Organoantimony Compounds Bearing a Rigid Tridentate Ligand (2007)
  • Author(s): S. Matsukawa
  • Organizer: 8th International Conference on Heteroatom Chemistry
  • Place of Presentation: Riverside, USA
  • Year and Date: 2007-08-14
• [Presentation] Synthesis of a Rigid Tridentate Ligand and Construction of Pentacoodinate Organoantimony Compounds (2007)
  • Author(s): H. Yamamichi
  • Organizer: 8th International Conference on Heteroatom Chemistry
  • Place of Presentation: Riverside, USA
  • Year and Date: 2007-08-14
• [Presentation] Theoretical study on the stereoselectivity of chiral phosphoric acid-catalyzed Mannich reaction (2007)
  • Author(s): Kaori Ando
  • Organizer: International Conference on Asymmetric Organochatalysis
  • Place of Presentation: (poster)
  • Year and Date: 2007-05-29
• [Presentation] Theoretical study on the stereoselectivity of chiral phosphoric acid-catalyzed Mannich reaction (2007)
  • Author(s): Kaori Ando
  • Organizer: International Conference on Asymmetric Organochatalysis
  • Place of Presentation: 大津、JAPAN
  • Year and Date: 2007-05-29
• [Presentation] 3座配位子で固定された5配位アンチモン化合物の立体異性化機構に関する研究 (2007)
  • Author(s): 安藤香織, 山道秀映, 松川史郎, 山本陽介
  • Organizer: 第34回有機典型元素化学討論会
  • Place of Presentation: 大阪(口頭発表)
• [Presentation] 新規三座配位子を有する5配位アンチモン化合物の合成とその異性化 (2007)
  • Author(s): 山道秀映, 松川史郎, 山本陽介, 安藤香織
  • Organizer: 第34回有機典型元素化学討論会
  • Place of Presentation: 大阪(ポスター)
• [Presentation] Synthesis of a Rigid Tridentate Ligand and Construction of Pentacoodinate Organoantimony Compounds (2007)
  • Author(s): Hideaki Yamamichi, Shiro Matsukawa, Yohsuke Yamamoto, Kaori Ando
  • Organizer: 8th International Conference on Heteroatom Chemistry
  • Place of Presentation: Riverside, U.S.A.(poster)
• [Presentation] Stereomutation of Pentacoordinate Organoantimony Compounds Bearing a Rigid Tridentate Ligand (2007)
  • Author(s): Shiro Matskawa, Hideaki Yamamichi, Yohsuke Yamamoto, Kaori Ando
  • Organizer: 8th International Conference on Heteroatom Chemistry
  • Place of Presentation: Riverside, U.S.A.(poster)
• [Book] 使える!有機合成反応241実践ガイド
  • Author(s): 丸岡啓二
  • Publisher: 化学同人
• [Remarks] 安藤研究室ホームページ
  • URL: http://apchem.gifu-u.ac.jp/~kinou1/index.html
• [Remarks]
  • URL: http://apchem.gifu-u.ac.jp/~kinoul/publications/publications_Ando.htm