Synthetic Study of New Metal Complexes Directed to Magnetic Properties of Spin-Orbit Coupling
| Project/Area Number |
19550074
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Inorganic chemistry
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| Research Institution | Kwansei Gakuin University |
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Principal Investigator |
MIKURIYA Masahiro Kwansei Gakuin University, 理工学部, 教授 (10157472)
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| Project Period (FY) |
2007 – 2009
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| Project Status |
Completed (Fiscal Year 2009)
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| Budget Amount *help |
¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
Fiscal Year 2009: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2008: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2007: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
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| Keywords | 金属錯体 / 磁性 / 自己組織化 / 超分子化学 / 分子性個体 / 磁気異方性 / 零磁場分裂 / コバルト / ルテニウム / 希土類 / 液晶性 / 窒素吸着 / スピン軌道相互作用 / ラジカル配位子 / 銅 / 液晶的性質 / シッフ塩基 / マンガン |
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| Research Abstract |
New dinuclear and polynuclear metal complexes were synthesized and characterized by magnetic susceptibility measurements for the first transition series such as copper, nickel, manganese, and cobalt to observe the effect of spin-orbit coupling. As for the second transition series, some polynuclear ruthenium complexes having metal-metal bonding which show a large zero-filed splitting and antiferromagnetic interaction were synthesized. Some lanthanide complexes having a large magnetic anisotropy were also prepared.
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Report
(4 results)
Research Products
(134 results)
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[Journal Article] A Dinuclear Zinc Complex, [Zn_2(μ-H_2THBQ)(TPA)_2](ClO_4)_2, [TPA = tris(2-pyridylmethyl)amine; H_2THBQ_2-=2,3,5,6-Tetrahydroxy-1,4-benzoquinonate], Exhibiting Two-proton Coupled Two-electron Donating Ability2009
Author(s)
Eiji Asato, Shoji Miyazato, Haruka Tohma, Satoshi Takara, Makoto Tadokoro, Yuji Miyazato, Daisuke Yoshioka, Masahiro Mikuriya
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Journal Title
Chem. Lett 38
Pages: 1170-1171
Related Report
Peer Reviewed
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[Journal Article] Synthesis, Magnetic and Spectral Properties, and Crystal Structure of Mixed-Valence Ruthenium(II, III) 3, 4, 5-Tributanoxybenzoate, Insights into Coordination (ed by M. Melnik, P. Segla, and M. Tatarko, Slovak Technical University Press, Bratislava)2009
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[Journal Article] Syntheses and Magnetic Properties of Polymer Complexes of Ruthenium(II, III) 3, 4, 5-Trialkoxybenzoate Linked by Chloro or Cyanato Ligand with Liquid-Crystalline Behavior(ed. by M. Melnik, J. Sima, and M. Tatarko (Slovak Technical University Press, Bratislava)2007
Author(s)
H. Ishida, M. Handa, I. Hiromitsu, S. Ujiie, M. Mikuriya
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Journal Title
Achievements in Coordination, Bioinorganic and Applied Inorganic Chemistry
Pages: 121-127
Related Report
Peer Reviewed
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