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Solid-state NMR study of dynamics of molecules in an nanospace

Research Project

Project/Area Number 19550075
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Inorganic chemistry
Research InstitutionNational Institute of Advanced Industrial Science and Technology

Principal Investigator

HAYASHI Shigenobu  National Institute of Advanced Industrial Science and Technology, 計測フロンティア研究部門, 主任研究員 (00344185)

Research Collaborator KOJIMA Natsuko  独立行政法人産業技術総合研究所, 計測フロンティア研究部門, テクニカルスタッフ
CHIBA Ryo  独立行政法人産業技術総合研究所, 計測フロンティア研究部門, 特別研究員
Project Period (FY) 2007 – 2009
Project Status Completed (Fiscal Year 2009)
Budget Amount *help
¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2009: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2008: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2007: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Keywords固体NMR / ナノ空間 / ダイナミクス / 酸塩基性質 / 固体触媒 / プローブ分子 / in situ測定
Research Abstract

Porous materials with nanometer-sized pores inside have functions such as adsorption, separation and catalysis. The properties of the inner surface of the nanospace are closely correlated with those functions. In the present study, we have measured solid-state NMR spectra of probe molecules interacting with the inner surface after introducing the molecules into the nanospace in order to reveal the inner-surface properties of the nanospace. We selected trimethylphosphine oxide as a probe molecule. We obtained NMR spectra reflecting the acid properties of the inner surface because the selected molecule has a basic property.

Report

(4 results)
  • 2009 Annual Research Report   Final Research Report ( PDF )
  • 2008 Annual Research Report
  • 2007 Annual Research Report
  • Research Products

    (30 results)

All 2010 2009 2008 2007

All Journal Article (7 results) (of which Peer Reviewed: 7 results) Presentation (22 results) Book (1 results)

  • [Journal Article] Acid properties of H-type mordenite studied by solid-state NMR2009

    • Author(s)
      林繁信, 小島奈津子
    • Journal Title

      Micropor. Mesopor. Mater (印刷中)

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Adsorption of trimethylphosph ine oxide molecules from the gas phas e to probe surface acidity by solid-s tate NMR2009

    • Author(s)
      林繁信
    • Journal Title

      Chem. Lett Vol.38、No.10

      Pages: 960-961

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Sealing effect of magic-anglespinning rotors in solid-state NMR2009

    • Author(s)
      林繁信
    • Journal Title

      Anal. Sci Vol.25、No.1

      Pages: 133-136

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Adsorption of trimethylphosphine oxide molecules from the gas phase to probe surface acidity by solid-state NMR2009

    • Author(s)
      林繁信
    • Journal Title

      Chemistry Letters 38

      Pages: 960-961

    • NAID

      10025547040

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Sealing effect of magic-angle-spinning rotors in solid-state NMR2009

    • Author(s)
      林繁信
    • Journal Title

      Analytical Sciences 25

      Pages: 133-136

    • NAID

      10025209817

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 固体NMRによる多孔質材料のナノ空間における分子の運動の解析2008

    • Author(s)
      林繁信
    • Journal Title

      ゼオライト Vol.25、No.3

      Pages: 102-108

    • NAID

      40016237748

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] 固体NMRによる多孔質材料のナノ空間における分子の運動の解析2008

    • Author(s)
      林繁信
    • Journal Title

      ゼオライト 25

      Pages: 102-108

    • NAID

      40016237748

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Presentation] 固体NMRによるゼオライトに吸着したジクロロメタンの量と骨格構造との関連2010

    • Author(s)
      林繁信, 小島奈津子
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      東大阪
    • Year and Date
      2010-03-26
    • Related Report
      2009 Annual Research Report 2009 Final Research Report
  • [Presentation] 固体nmr測定における雰囲気制御2010

    • Author(s)
      林繁信
    • Organizer
      第13回固体nmr技術交流会
    • Place of Presentation
      千葉
    • Year and Date
      2010-03-17
    • Related Report
      2009 Final Research Report
  • [Presentation] 固体NMR測定における雰囲気制御2010

    • Author(s)
      林繁信
    • Organizer
      第13回固体NMR技術交流会
    • Place of Presentation
      千葉
    • Year and Date
      2010-03-17
    • Related Report
      2009 Annual Research Report
  • [Presentation] 固体NMRによるジクロロメタンのゼオライトへの吸着及び動的挙動2009

    • Author(s)
      小島奈津子, 林繁信
    • Organizer
      第25回ゼオライト研究発表会
    • Place of Presentation
      北九州
    • Year and Date
      2009-11-26
    • Related Report
      2009 Annual Research Report 2009 Final Research Report
  • [Presentation] ゼオライトに吸着したジクロロメタンの観測2009

    • Author(s)
      小島奈津子, 林繁信
    • Place of Presentation
      福岡
    • Year and Date
      2009-11-10
    • Related Report
      2009 Final Research Report
  • [Presentation] ゼオライトに吸着したジクロロメタンの観測2009

    • Author(s)
      小島奈津子、林繁信
    • Organizer
      第48回NMR討論会
    • Place of Presentation
      福岡
    • Year and Date
      2009-11-10
    • Related Report
      2009 Annual Research Report
  • [Presentation] Adsorption of dichloromethane on zeolites observed by solid-state NMR2009

    • Author(s)
      小島奈津子, 林繁信
    • Organizer
      The 3rd Asia-Pacific NMR Symposium
    • Place of Presentation
      韓国済州島
    • Year and Date
      2009-10-26
    • Related Report
      2009 Final Research Report
  • [Presentation] Adsorption of dichloromethane on zeolites observed by solid-state NMR2009

    • Author(s)
      小島奈津子、林繁信
    • Organizer
      The 3rd Asia-Pacific NMR Symposium
    • Place of Presentation
      済州島(韓国)
    • Year and Date
      2009-10-26
    • Related Report
      2009 Annual Research Report
  • [Presentation] Acidic properties of mordenites studied by solid-state NMR using trimethylphosphine oxide as a probe molecule2009

    • Author(s)
      林繁信
    • Organizer
      International Symposium on Zeolites and Microporous Crystals 2009
    • Place of Presentation
      東京
    • Year and Date
      2009-08-04
    • Related Report
      2009 Annual Research Report 2009 Final Research Report
  • [Presentation] Proton dynamics of CsHSO4 confined in mesoporous silica FSM-16 as studied by 1H solid-state NMR2008

    • Author(s)
      林繁信, 千葉亮
    • Organizer
      The IUMRS Internatiuonal Conference in Asia 2008
    • Place of Presentation
      名古屋
    • Year and Date
      2008-12-12
    • Related Report
      2009 Final Research Report
  • [Presentation] Proton dynamics of CsHSO_4 confined in mesoporous silica FSM-16 as studied by ^1H solid-state NMR2008

    • Author(s)
      林繁信, 千葉亮
    • Organizer
      IUMRS-ICA 2008
    • Place of Presentation
      名古屋
    • Year and Date
      2008-12-04
    • Related Report
      2008 Annual Research Report
  • [Presentation] モルデナイトに吸着したトリメチルホスフィンオキシドの固体NMR測定2008

    • Author(s)
      林繁信
    • Organizer
      第24回ゼオライト研究発表会
    • Place of Presentation
      東京
    • Year and Date
      2008-11-26
    • Related Report
      2009 Final Research Report 2008 Annual Research Report
  • [Presentation] MAS用ローターの気密性テスト方法2008

    • Author(s)
      林繁信
    • Organizer
      第47回nmr討論会
    • Place of Presentation
      つくば
    • Year and Date
      2008-11-12
    • Related Report
      2009 Final Research Report
  • [Presentation] MAS用ローターの気密性テスト方法2008

    • Author(s)
      林繁信
    • Organizer
      第47回NMR討論会
    • Place of Presentation
      つくば
    • Year and Date
      2008-11-12
    • Related Report
      2008 Annual Research Report
  • [Presentation] 固体nmrによる多孔質材料のキャラクタリゼーション2008

    • Author(s)
      林繁信
    • Organizer
      第16回ゼオライト夏の学校
    • Place of Presentation
      御殿場
    • Year and Date
      2008-09-05
    • Related Report
      2009 Final Research Report
  • [Presentation] 固体NMRによる多孔質材料のキャラクタリゼーション2008

    • Author(s)
      林繁信
    • Organizer
      第16回ゼオライト夏の学校(ゼオライト学会)
    • Place of Presentation
      御殿場
    • Year and Date
      2008-09-05
    • Related Report
      2008 Annual Research Report
  • [Presentation] 固体nmrによる多孔質材料のナノ空間における分子の運動の解析2007

    • Author(s)
      林繁信
    • Organizer
      第23回ゼオライト研究発表会
    • Place of Presentation
      秋田
    • Year and Date
      2007-11-07
    • Related Report
      2009 Final Research Report
  • [Presentation] 固体NMRによる多孔質材料のナノ空間における分子の運動の解析2007

    • Author(s)
      林 繁信
    • Organizer
      第23回ゼオライト研究発表会
    • Place of Presentation
      秋田
    • Year and Date
      2007-11-07
    • Related Report
      2007 Annual Research Report
  • [Presentation] 固体nmrによる多孔質材料のキャラクタリゼーション2007

    • Author(s)
      林繁信
    • Organizer
      第15回ゼオライト夏の学校
    • Place of Presentation
      大崎
    • Year and Date
      2007-09-06
    • Related Report
      2009 Final Research Report
  • [Presentation] 固体NMRによる多孔質材料のキャラクタリゼーション2007

    • Author(s)
      林 繁信
    • Organizer
      第15回ゼオライト夏の学校(ゼオライト学会)
    • Place of Presentation
      宮城県大崎市
    • Year and Date
      2007-09-06
    • Related Report
      2007 Annual Research Report
  • [Presentation] 多孔質材料のナノ空間における分子の運動2007

    • Author(s)
      林繁信
    • Organizer
      第41/6回固体nmr・材料フォーラム
    • Place of Presentation
      東京
    • Year and Date
      2007-05-08
    • Related Report
      2009 Final Research Report
  • [Presentation] 多孔質材料のナノ空間における分子の運動2007

    • Author(s)
      林 繁信
    • Organizer
      第41/6回固体NMR・材料フォーラム
    • Place of Presentation
      東京
    • Year and Date
      2007-05-08
    • Related Report
      2007 Annual Research Report
  • [Book] 多孔体の精密制御と機能・物性評価2008

    • Author(s)
      林繁信, サイエンス, テクノロジー
    • Related Report
      2009 Final Research Report

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Published: 2007-04-01   Modified: 2016-04-21  

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