Solid-state NMR study of dynamics of molecules in an nanospace
| Project/Area Number |
19550075
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Inorganic chemistry
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| Research Institution | National Institute of Advanced Industrial Science and Technology |
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Principal Investigator |
HAYASHI Shigenobu National Institute of Advanced Industrial Science and Technology, 計測フロンティア研究部門, 主任研究員 (00344185)
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| Research Collaborator |
KOJIMA Natsuko 独立行政法人産業技術総合研究所, 計測フロンティア研究部門, テクニカルスタッフ
CHIBA Ryo 独立行政法人産業技術総合研究所, 計測フロンティア研究部門, 特別研究員
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| Project Period (FY) |
2007 – 2009
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| Project Status |
Completed (Fiscal Year 2009)
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| Budget Amount *help |
¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2009: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2008: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2007: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
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| Keywords | 固体NMR / ナノ空間 / ダイナミクス / 酸塩基性質 / 固体触媒 / プローブ分子 / in situ測定 |
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| Research Abstract |
Porous materials with nanometer-sized pores inside have functions such as adsorption, separation and catalysis. The properties of the inner surface of the nanospace are closely correlated with those functions. In the present study, we have measured solid-state NMR spectra of probe molecules interacting with the inner surface after introducing the molecules into the nanospace in order to reveal the inner-surface properties of the nanospace. We selected trimethylphosphine oxide as a probe molecule. We obtained NMR spectra reflecting the acid properties of the inner surface because the selected molecule has a basic property.
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Report
(4 results)
Research Products
(30 results)
