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Nanofabrication of Highly Functionalized Polymer Surface

Research Project

Project/Area Number 19550120
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Polymer chemistry
Research InstitutionTokyo Institute of Technology

Principal Investigator

SUGIYAMA Kenji  Tokyo Institute of Technology, 大学院・理工学研究科, 助教 (20282840)

Project Period (FY) 2007 – 2008
Project Status Completed (Fiscal Year 2008)
Budget Amount *help
¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2008: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2007: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
Keywords高分子合成 / 高分子構造・物性 / 自己組織化 / ナノ材料 / 表面・界面物性 / リビングアニオン重合 / パーフルオロアルキル基 / 官能基化ポリマー / 表面解析 / X線光電子分光法 / 接触角測定 / 撥油性 / 撥水性
Research Abstract

申請者らが新規に開発した, アニオンリビング重合に基づく繰り返し法を適用することで, 高反応性のベンジルブロミド基, およびアミノ基を鎖末端に2, 4, 8個の有するポリスチレン(PS-Amn)の精密合成に初めて成功した. これにより, 繰り返し法による末端官能基導入法を拡張することで, 種々の官能基導入が可能であることが示された. また, 本手法が従来の高分子合成法よりも優れた機能性ポリマーの合成法であることが示された

Report

(3 results)
  • 2008 Annual Research Report   Final Research Report ( PDF )
  • 2007 Annual Research Report
  • Research Products

    (26 results)

All 2008 2007 Other

All Journal Article (15 results) (of which Peer Reviewed: 15 results) Presentation (10 results) Remarks (1 results)

  • [Journal Article] Synthesis of well defined dendritic hyperbranched polymers by iterative methodologies using living/controlled polymerizations2008

    • Author(s)
      Hirao, K. Sugiyama, A. Matsuo, Y. Tsunoda, T. Watanabe
    • Journal Title

      Polym. Int 57

      Pages: 554-570

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Living Anionic Polymerization of Styrene Derivatives para Substituted with π-Conjugated Oligo(fluorene) Moieties2008

    • Author(s)
      K. Sugiyama, A. Hirao, J.-C. Hsu, Y.-C. Tung, and W.-C. Chen
    • Journal Title

      Macromolecules 41

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Living Anionic Polymerization of 4 (α Alkylvinyl)styrene Derivatives2008

    • Author(s)
      K. Sugiyama, K. Watanabe, A. Hirao, M. Hayashi
    • Journal Title

      Macromolecules 41(12)

      Pages: 4235-4244

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Complex Macromolecular Chimeras2008

    • Author(s)
      Karatzas, H. Iatrou, N. Hadjichristidis, K. Inoue, K, Sugiyama, A. Hirao
    • Journal Title

      Biomacromolecules 9

      Pages: 2072-2080

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Convenient approaches for the synthesis and characterization of well defined linear dendritic diblock copolymers having a definite number of peripheral primary amino groups : Exact control of numbers introduced and dendritic distribution to enhance co operative effect2008

    • Author(s)
      A. El-Shehawy, K.Sugiyama, A. Hirao
    • Journal Title

      Reactive and Functional Polymers 68

      Pages: 1682-1695

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] A Versatile Method for Adjusting Thermoresponsivity : Synthesis and'Click' Reaction of an Azido End Functionalized Poly(Nisopropylacrylamide)2008

    • Author(s)
      A. Narumi, K. Fuchise, R. Kakuchi, A. Toda, T. Satoh, S. Kawaguchi, K. Sugiyama, A. Hirao, T. Kakuchi
    • Journal Title

      Macromol. Rapid Commun 29

      Pages: 1126-1133

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Precise Synthesis and Surface and Bulk Properties of Architectural Perand Semifluorinated Polymers with Well Defined Structures2008

    • Author(s)
      Hirao, K. Sugiyama, H. Yokoyama
    • Journal Title

      Prog. Polym.Sci 32

      Pages: 1393-1438

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of Asymmetric Star Branched Polymers Having Two Polyacetylene Arms by Means of Living Anionic Polymerization Using1,1-Diphenylethylene Derivatives2008

    • Author(s)
      Y. Zhao, T. Higashihara, K. Sugiyama, A. Hirao
    • Journal Title

      Macromolecules 40

      Pages: 228-238

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Complex Macromolecular Chimeras2008

    • Author(s)
      A. Karatzas, H. Iatrou, N. Hadjichristidis, K. Inoue, K, Sugiyama, A. Hirao
    • Journal Title

      Biomacromolecules 9

      Pages: 2072-2080

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Living Anionic Polymerization of 4-(α -Alkylvinyl)styrene Derivatives2008

    • Author(s)
      K. Sugiyama, K. Watanabe, A. Hirao, M. Hayashi
    • Journal Title

      Macromolecules 41

      Pages: 4235-4244

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A Versatile Method for Adjusting Thermoresponsivity: Synthesis and 'Click' Reaction of an Azido End-Functionalized Poly(N-isopropyiacrylamide)2008

    • Author(s)
      A. Narumi, K. Fuchise, R. Kakuchi, A. Toda, T. Satoh, S. Kawaguchi, K. Sugiyama, A. Hirao, T. Kakuchi
    • Journal Title

      Macromol. Rapid Commun. 29

      Pages: 1126-1133

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Convenient approaches for the synthesis and characterization of well-defined linear-dendritic diblock copolymers having a definite number of peripheral primary amino groups : Exact control of numbers introduced and dendritic distribution to enhance co-operative effect2008

    • Author(s)
      A. A. El-Shehawy, K. Sugiyama, A. Hirao
    • Journal Title

      Reactive and Functional Polymers 68

      Pages: 1682-1695

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of well-defined dendritic hyperbranched polymers by iterative methodologies using living/controlled polymerizations2008

    • Author(s)
      A. Hirao, K. Sugiyama, A. Matsuo, Y. Tsunoda, T. Watanabe
    • Journal Title

      Polym. Int. 57

      Pages: 554-570

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Precise Synthesis and Surface and Bulk Properties of Architectural Per-and Semifluorinated Polymers with Well-Defined Structures2007

    • Author(s)
      A. Hirao, K. Sugiyama, H. Yokoyama
    • Journal Title

      Prog. Polym. Sci. 32

      Pages: 1393-1438

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 鎖末端に複数のパーフルオロアルキル基を有するポリマーの精密合成と表面構造解析2007

    • Author(s)
      杉山賢次, 横山英明, 平尾明
    • Journal Title

      高分子論文集 64

      Pages: 665-675

    • NAID

      10019769552

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Presentation] Living Anionic Polymerization of Asymmetric Bifunctional Styrene Derivatives2008

    • Author(s)
      K. Sugiyama
    • Organizer
      2nd Japan Korea Joint Seminar 2008 and International Symposium : Synthesis and Application of Advanced Functional Materials
    • Place of Presentation
      Tokyo, Japan
    • Related Report
      2008 Final Research Report
  • [Presentation] Anionic polymerization of styrene derivatives containing π-conjugated moieties2008

    • Author(s)
      K. Sugiyama
    • Organizer
      MACRO2008
    • Place of Presentation
      Taipei, Taiwan
    • Related Report
      2008 Annual Research Report 2008 Final Research Report
  • [Presentation] Living Anionic Polymerization of Asymmetric Bifunctional Styrene Derivatives2008

    • Author(s)
      K. Sugiyama
    • Organizer
      2nd Japan-Korea Joint Seminar 2008 and International Symposium : Synthesis and Application of Advanced Functional Materials (JKIS 08)
    • Place of Presentation
      Tokyo, Japan
    • Related Report
      2008 Annual Research Report
  • [Presentation] π共役系ユニットを有するスチレン誘導体のリビングアニオン重合2008

    • Author(s)
      杉山賢次
    • Organizer
      第57回高分子討論会
    • Place of Presentation
      大阪市立大学
    • Related Report
      2008 Annual Research Report
  • [Presentation] ポリペプチドセグメントを含むスターポリマーの精密合成2008

    • Author(s)
      杉山賢次
    • Organizer
      第57回高分子討論会
    • Place of Presentation
      大阪市立大学
    • Related Report
      2008 Annual Research Report
  • [Presentation] 側鎖にπ共役系ユニットを含むモノマー類のアニオン重合2008

    • Author(s)
      杉山賢次
    • Organizer
      第57回高分子学会年次大会
    • Place of Presentation
      横浜
    • Related Report
      2008 Annual Research Report
  • [Presentation] 置換フェニルビニルスルホキシド誘導体のアニオン重合2008

    • Author(s)
      杉山賢次
    • Organizer
      第57回高分子学会年次大会
    • Place of Presentation
      横浜
    • Related Report
      2008 Annual Research Report
  • [Presentation] Living Anionic Polymerization of 4 (α-Alkylvinyl)styrenes2007

    • Author(s)
      K. Sugiyama
    • Organizer
      Advanced Polymers via Macromolecular Engineering
    • Place of Presentation
      Florida, USA
    • Related Report
      2008 Final Research Report
  • [Presentation] Precise synthesis of polystyrenes functionalized with a definite number of perfluoroalkyl groups2007

    • Author(s)
      K. Sugiyama
    • Organizer
      International Symposium on Advanced Macromolecules and Nano materials with Precisely Designed Architectures
    • Place of Presentation
      Hokkaido University, Sapporo, Japan
    • Related Report
      2008 Final Research Report
  • [Presentation] Precise synthesis of polystyrenes functionalized with a definite number of perfluoroalkyl groups2007

    • Author(s)
      K. Sugiyama
    • Organizer
      International Symposium on Advanced Macromolecules and Nano-materials with Precisely Designed Architectures
    • Place of Presentation
      Hokkaido University, Sapporo. Japan,
    • Related Report
      2007 Annual Research Report
  • [Remarks]

    • URL

      http://t2r2.star.titech.ac.jp/cgi-bin/researcherpublicationlist.cgi?q_researcher_content_number=CTT100380498

    • Related Report
      2008 Annual Research Report

URL: 

Published: 2007-04-01   Modified: 2016-04-21  

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