| Project/Area Number |
19550154
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Environmental chemistry
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| Research Institution | Kinki University |
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Principal Investigator |
SASAKI Yo Kinki University, 理工学部, 講師 (70205871)
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| Co-Investigator(Kenkyū-buntansha) |
IWASAKI Mitsunobu 近畿大学, 理工学部, 准教授 (20278740)
MORIMOTO Jyunji 近畿大学, 理工学部, 教授 (30088471)
市原 潤子 大阪大学, 産業科学研究所, 助教 (60110772)
山口 後郎 大阪大学, 産業科学研究所, 助教 (40167698)
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| Co-Investigator(Renkei-kenkyūsha) |
ICHIHARA Junko 大阪大学, 産業科学研究所, 助教 (60110772)
YAMAGUCHI Syunro 大阪大学, 産業科学研究所, 助教 (40167698)
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| Project Period (FY) |
2007 – 2009
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| Project Status |
Completed (Fiscal Year 2009)
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| Budget Amount *help |
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2009: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2008: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2007: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
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| Keywords | グリーンケミストリー / 無溶媒反応 / 触媒 / 粉体分散媒 / 固体分散相 / 無溶媒有機合成反応 / エポキシ化 / ポリタングステン酸 / 不斉合成 / スルホキシド / 光学分割 / オレフィン / エポキシ化反応 / 水素化反応 |
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| Research Abstract |
We applied the solvent-free reaction system for cyclooctene photoepxdation under oxygenatomosphere irradiating of black light over mixture of SiO_2 powderdisperse and photocatalyst powder. we have previously developed A new synthetic method of sulfoxides and sulfones using solvent-free oxidations of sulfides with urea-hydrogen peroxide complex (urea-H_2O_2)and tetrabutylammonium phosphomolybdate catalyst on fluorapatite ((Bu_4N)_3[PMo_<12>O_<40>]/FAp). For chiral sulfoxides, our methodology included the use of chial auxiliaries that were shown to affect the asymmetric oxidations.
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