Development of higher-boride type super hard materials
Project/Area Number |
19550189
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Research Category |
Grant-in-Aid for Scientific Research (C)
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Allocation Type | Single-year Grants |
Section | 一般 |
Research Field |
Inorganic industrial materials
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Research Institution | Tohoku University |
Principal Investigator |
SHISHIDO Toetsu Tohoku University, 金属材料研究所, 准教授 (50125580)
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Co-Investigator(Kenkyū-buntansha) |
SHISHIDO Toetsu 東北大学, 金属材料研究所, 准教授 (50125580)
YUBUTA Kunio 東北大学, 金属材料研究所, 助教 (00302208)
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Project Period (FY) |
2007 – 2008
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Project Status |
Completed (Fiscal Year 2008)
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Budget Amount *help |
¥3,640,000 (Direct Cost: ¥2,800,000、Indirect Cost: ¥840,000)
Fiscal Year 2008: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2007: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
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Keywords | super hard material / higher-boride / molten metal flux growth / solution growth / single crystal / hardness / boride / higher boride / flux growth method / ハイヤーボライド / 超硬物質 / 硬度 / 溶融金属フラックス法 / 微細単結晶 |
Research Abstract |
従来の高温・高圧の極端条件を用いず、より安全で経済的な溶融金属フラックス法を適用することで、3元系の新しい超硬(ミクロビッカース硬度値 : 25~40GPa)ハイヤーボライドを合成出来た。例えば、AlMB_(14)(M=Li, Mg, Na)を実用可能な微細単結晶の形で得た。微細単結晶は結晶欠陥が少ないため、通常の多結晶ボライド粉末に比較すると、厳しい使用環境下でも性能劣化しづらい。
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Report
(3 results)
Research Products
(107 results)
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[Journal Article] Synthesis, boron solubility and properties of perovskite-type rare earth palladium borides2008
Author(s)
T.Shishido, J.Ye, T.Sasaki, S.Okada, K.Kudou, Y.Ishizawa, T.Mori, Y.Sawada, N.Nogi, M.Tanaka, N.Ohtsu, T.Amano, R.Sahara, K.Yubuta, V.Kumar, K.Fujiwara, N.Usami, K.Hayashi, A.Nomura, T.Sugawara, S.Kohiki, K.Teshima, S.Oishi, Y.Kawazoe and K.Nakajima
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Journal Title
Journal of Flux Growth 3[2]
Pages: 68-71
Related Report
Peer Reviewed
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[Journal Article] Synthesis, boron solubility and properties of perovskite-type rare earth palladium borides2008
Author(s)
T. Shishido, J. Ye, T. Sasaki, S. Okada, K. Kudou, Y. Ishizawa, T. Mori, Y. Sawada, N. Nogi, M. Tanaka, N. Ohtsu, T. Amano, R. Sahara, K. Yubuta, V. Kumar, K. Fujiwara, N. Usami, K. Hayashi, A. Nomura, T. Sugawara, S. Kohiki, K. Teshima, S. Oishi, Y. Kawazoe and K. Nakajima
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Journal Title
Journal of Flux Growth 3[2]
Pages: 68-71
Related Report
Peer Reviewed
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[Journal Article] Ab initio studies of structural, elastic and electronic properties of RRh_3B_x (R=Sc, Y, La and Ce)2007
Author(s)
H.Kojima, R.Sahara, T.Shishido, A.Nomura, K.Kudou, S.Okada, V.Kumar, K.Nakajima and Y.Kawazoe
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Journal Title
Applied Physics Letter 91
Related Report
Peer Reviewed
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[Journal Article] Molten metal flux growth and study of properties and chemical state of a new compound PrRh_<4.8>B2007
Author(s)
T.Shishido, M.Oku, S.Okada, N.Nogi, T.Amano, J.Ye, T.Mori, M.Tanaka, K.Shimamura, A.Yoshikawa, R.Sahara, K.Yubuta, V.Kumar, A.Nomura, T.Sugawara, S.Tozawa, K.Obara, N.Ohtsu, K.Hayashi, K.Fujiwara, N.Usami, S.Kohiki, K.Teshima, S.Oishi, Y.Kawazoe and K.Nakajima
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Journal Title
Journal of Flux Growth 2[2]
Pages: 87-92
Related Report
Peer Reviewed
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[Journal Article] Hardness and oxidation resistance, magnetic properties of REB_<48>Si_2 (RE = Y, Tb, Dy, Ho, Er, Lu) compounds obtained by arc melting2007
Author(s)
K.Kudou, S.Fukuda, S.Okada, T.Mori, K.Iizumi, T.Shishido and Y.Mantan
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Journal Title
Japanese Journal of Applied Physics 46[12]
Pages: 7803-7805
Related Report
Peer Reviewed
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[Journal Article] Ab initio studies of structural, elastic and electronic properties of RRh_3 B_x(R=Sc, Y, La andCe)2007
Author(s)
H. Kojima, R. Sahara, T. Shishido, A. Nomura, K. Kudou, S. Okada, V. Kumar, K, Nakajima and Y. Kawazoe
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Journal Title
Applied Physics Letter 91
Related Report
Peer Reviewed
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[Journal Article] Molten metal flux growth and study of properties and chemical state of a new compound PrRh_<4.8>B2007
Author(s)
T. Shishido, M. Oku, S. Okada, N. Nogi, T. Amano, J. Ye, T. Mori, M. Tanaka, K. Shimamura, A. Yoshikawa, R. Sahara, K. Yubuta, V. Kumar, A. Nomura, T. Sugawara, S. Tozawa, K. Obara, N. Ohtsu, K. Hayashi, K. Fujiwara, N. Usami, S. Kohiki, K. Teshima, S. Oishi, Y. Kawazoe and K. Nakajima
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Journal Title
Journal of Flux Growth 2[2]
Pages: 87-92
Related Report
Peer Reviewed
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[Journal Article] Hardness and oxidation resistance, magnetic properties of REB _48Si_2(RE=Y, Tb, Dy, Ho, Er, Lu)compounds obtained by arc melting2007
Author(s)
K. Kudou, S. Fukuda, S. Okada, T. Mori, K.Iizumi, T. Shishido and Y. Mantan
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Journal Title
Japanese Journal of Applied Physics 46[12]
Pages: 7803-7805
Related Report
Peer Reviewed
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[Presentation] Molten metal flux growth of rare earth rhodium borides and borocarbides2008
Author(s)
T.Shishido, S.Okada, J.Ye, K.Kudou, K.Iizumi, Y.Sawada, R.Sahara, K.Yubuta, V.Kumar, A.Nomura, T.Sugawara, K.Hayashi, K.Fujiwara, N.Usami, T.Mori, M.Tanaka, N.Nogi, K.Teshima, S.Kohiki, S.Oishi, Y.Kawazoe and K.Nakajima
Organizer
16th International Symposium on Boron, Borides and Related Materials (ISBB2008)
Place of Presentation
くにびきメッセ
Related Report
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[Presentation] Existence of intrinsic defects in rare earth borides and their effect on physical properties2008
Author(s)
T.Mori, H.Borrmann, A.Leithe-Jasper, S.Okada, K.Kudou, W.Schnelle, R.Cardoso, Y.Prots, U.Burkhardt, I.Veremchuk, T.Shishido and K.Nakajima
Organizer
16th International Conference on Solid Compounds of Transition Elements (SCTE2008)
Place of Presentation
Bellevue Hotel, Dresden, Germany
Related Report
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[Presentation] Arc melting synthesis and flux growth of Pr-Rh-B system compounds2008
Author(s)
T.Shishido, J.Ye, S.Okada, K.Kudou, K.Iizumi, Y.Sawada, R.Sahara, K.Yubuta, V.Kumar, A.Nomura, T.Sugawara, N.Ohtsu, K.Hayashi, K.Fujiwara, N.Usami, T.Mori, M.Tanaka, K.Teshima, S.Oishi, Y.Kawazoe and K.Nakajima
Organizer
The 4th Asian Conference on Crystal Growth and Crystal Technology (CGCT4)
Place of Presentation
仙台国際ホテル、東北大学片平キャンパス
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[Book] The Pacific Science Review,vol.10. No.1, Crystal growth by molten metal flux method of vanadium boride V_2B_32008
Author(s)
S.Okada, T.Shishido, H.Kanari, K.Nakajima
Publisher
A Cooperative Publication of Far-Eastern State Technical University, Russia, Harbin institute of Technology, P.R.China, Kangnam University, Republic of Korea and Kokushikan University, Japan
Related Report
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[Book] The Pacific Science Review, vol.10. No.1, Crystal growth by molten metal flux method of vanadium boride V_2B_32008
Author(s)
S. Okada, T. Shishido, H. Kanari, K. Nakajima
Publisher
A Cooperative Publication of Far-Eastern State Technical University, Russia, Harbin institute of Technology, P. R.China, Kangnam University, Republic of Korea and Kokushikan University, Janan
Related Report
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