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Study on the evolution of super-protonic conduction in phosphate glasses

Research Project

Project/Area Number 19560010
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Applied materials science/Crystal engineering
Research InstitutionIbaraki University

Principal Investigator

TAKAHASHI Haruyuki  Ibaraki University, 理工学研究科, 教授 (30202154)

Project Period (FY) 2007 – 2009
Project Status Completed (Fiscal Year 2009)
Budget Amount *help
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2009: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2008: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2007: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Keywordsリン酸塩 / ガラス / プロトン伝導 / 固体電解質 / 非晶質 / リン酸塩ガラス / ガラス構造 / 燃料電池
Research Abstract

The origin of super-protonic conduction in phosphate glasses has been investigated. High proton conduction was obtained in glasses synthesized by low-temperature melting or by annealing in humid atmosphere below the glass transition temperature. It is considered that the high proton conduction is caused by proton hopping via water molecules incorporated in the glass during melting or annealing. The guide to the preparation of glasses compatible with both high proton conduction and chemical durability was also developed.

Report

(4 results)
  • 2009 Annual Research Report   Final Research Report ( PDF )
  • 2008 Annual Research Report
  • 2007 Annual Research Report
  • Research Products

    (38 results)

All 2010 2009 2008 2007 Other

All Journal Article (17 results) (of which Peer Reviewed: 17 results) Presentation (17 results) Remarks (4 results)

  • [Journal Article] Proton Conduction Mechanism of Phosphate Glasses2010

    • Author(s)
      H. Takahashi, A. Shimizu, T. Sakuma
    • Journal Title

      J.Phys.Soc.Jpn. Vol. 79, Suppl. A

      Pages: 115-117

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Calorimetric Study of Kinetic Glass Transition in Various Glasses2010

    • Author(s)
      Y. Hiki, H. Takahashi
    • Journal Title

      J.Phys.Soc.Jpn. Vol. 79

      Pages: 34604-34604

    • NAID

      40017011736

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Temperature dependence of intermediate-range orders in the viscosity-temperature relationship of supercooled liquids and glasses2010

    • Author(s)
      H. Kobayashi, H. Takahashi
    • Journal Title

      J.Chem.Phys. Vol. 132

      Pages: 104504-104504

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Electrical Conduction in theVitreous and Crystallized Li_2O-V_2O_5-P_2O_5 System2010

    • Author(s)
      H. Takahashi, T. Karasawa, T. Sakuma, J. E. Garbarczyk
    • Journal Title

      Solid State Ionics Vol. 181

      Pages: 27-32

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Oscillatory diffuse X-ray scattering from lead chalcogenides2010

    • Author(s)
      Xianglian, T. Sakuma, K. Basar, H. Takahashi
    • Journal Title

      J.Thermal Anal.Cal. Vol. 99

      Pages: 65-69

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Proton Conduction Mechanism of Phosphate Glasses2010

    • Author(s)
      H.Takahashi, A.Shimizu, T.Sakuma
    • Journal Title

      J.Phys.Soc.Jpn.Suppl.A 79

      Pages: 115-117

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Calorimetric Study of Kinetic Glass Transition in Various Glasses2010

    • Author(s)
      Y.Hiki, H.Takahashi
    • Journal Title

      J.Phys.Soc.Jpn. 79

    • NAID

      40017011736

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Temperature Dependence of Intermediate-range Orders in the Viscosity-temperature Relationship of Supercooled Liquids and Glasses2010

    • Author(s)
      H.Kobayashi, H.Takahashi
    • Journal Title

      J.Chem.Phys. 132

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Electrical Conduction in the Vitreous and Crystallized Li_2O-V_2O_5-P_2O_5 System2010

    • Author(s)
      H.Takahashi, T.Karasawa, T.Sakuma, J.Garbarczyk
    • Journal Title

      Solid State Ionics 181

      Pages: 27-32

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Inter-atomic distance and temperature dependence of correlation effects among thermal displacements2009

    • Author(s)
      Xianglian, S. Siagian, K. Basar, T. Sakuma, H. Takahashi, N. Igawa, Y. Ishii
    • Journal Title

      Solid State Ionics Vol. 180

      Pages: 480-482

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Inter-atomic Distance and Temperature Dependence of Correlation Effects Among Thermal Displacements2009

    • Author(s)
      Xianglian, S.Siagian, K.Basar, T.Sakuma, H.Takahashi, N.Igawa, Y.Ishii
    • Journal Title

      Solid State Ionics 180

      Pages: 480-482

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Viscosity-temperature relationship of glasses with low melting points obtained by wide-range measurement2008

    • Author(s)
      H. Kobayashi, H. Takahashi
    • Journal Title

      J.Ceram.Soc.Jpn. Vol. 116

      Pages: 855-859

    • NAID

      110006862028

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Sodium ion motion in NaI-AgPO_3 glasses2008

    • Author(s)
      H. Takahashi, H. Nakanii, T. Sakuma
    • Journal Title

      Solid State Ionics Vol. 179

      Pages: 2137-2141

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Oscillatory diffuse scattering study by time-of-flight neutron scattering2008

    • Author(s)
      Khairul Basar, et.al.
    • Journal Title

      Physica B 403

      Pages: 2557-2560

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Viscosity-temperature relationship of glasses with low melting points obtained by wide-range measurement2008

    • Author(s)
      Hiroshi Kobayashi and Haruyuki Takahashi
    • Journal Title

      J. Ceram. Soc. Jpn 116

      Pages: 855-858

    • NAID

      110006862028

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Sodium ion motion in NaI-AgPO3 glasses2008

    • Author(s)
      Haruyuki Takahashi, et.al.
    • Journal Title

      Solid State Ionics 179

      Pages: 2137-2141

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Low-Temperature Phase in Superionic Conductor Ag_3SBr_xI_<1-x>2007

    • Author(s)
      Xianglian, et. al.
    • Journal Title

      Journal of the Physical Society of Japan 76

      Pages: 114603-114605

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Presentation] AgI-Ag20-V205ガラスの構造解析2010

    • Author(s)
      高橋東之, 飯田将来, 佐久間隆, 小原真司
    • Organizer
      日本物理学会第65回年会
    • Place of Presentation
      岡山大学
    • Year and Date
      2010-03-22
    • Related Report
      2009 Final Research Report
  • [Presentation] AgI-Ag_2O-V_2O_5ガラスの構造解析2010

    • Author(s)
      高橋東之、飯田将来、佐久間隆、小原真司
    • Organizer
      日本物理学会第65回年会
    • Place of Presentation
      岡山大学
    • Year and Date
      2010-03-22
    • Related Report
      2009 Annual Research Report
  • [Presentation] 中性子回折によるリチウムイオン伝導体Li1+xAlxGe2-x(P04)3の構造解析2009

    • Author(s)
      藤田泰裕, 高橋東之, 佐久間隆, 井川直樹
    • Organizer
      日本中性子科学会
    • Place of Presentation
      いばらき量子ビーム研究センター(東海村)
    • Year and Date
      2009-12-10
    • Related Report
      2009 Final Research Report
  • [Presentation] 中性子回折によるリチウムイオン伝導体Li_<1+x>Al_xGe_<2-x> (PO_4)_3の構造解析2009

    • Author(s)
      藤田泰裕、高橋東之、佐久間隆、井川直樹
    • Organizer
      日本中性子科学会
    • Place of Presentation
      いばらき量子ビーム研究センター(東海村)
    • Year and Date
      2009-12-10
    • Related Report
      2009 Annual Research Report
  • [Presentation] Proton Conduction Mechanism of Phosphate Glasses2009

    • Author(s)
      H. Takahashi, A. Shimizu, T. Sakuma
    • Organizer
      The 3rd International Conference on Physics of Solid State Ionics (ICPSSI-3)
    • Place of Presentation
      熊本大学
    • Year and Date
      2009-10-27
    • Related Report
      2009 Final Research Report
  • [Presentation] Proton Conduction Mechanism of Phosphate Glasses2009

    • Author(s)
      高橋東之, A.Shimizu, 佐久間隆
    • Organizer
      The 3rd International Conference on Physics of Solid State Ionics(ICPSSI-3)
    • Place of Presentation
      熊本大学
    • Year and Date
      2009-10-27
    • Related Report
      2009 Annual Research Report
  • [Presentation] Proton conduction in phosphate glasses2009

    • Author(s)
      H. Takahashi, A. Shimizu, T. Sakuma
    • Organizer
      17th International Conference on Solid State Ionics
    • Place of Presentation
      Toronto
    • Year and Date
      2009-07-01
    • Related Report
      2009 Final Research Report
  • [Presentation] 12Sr0-12Ba0-12Pb0-64P205ガラスにおけるプロトン伝導機構2008

    • Author(s)
      清水秋彦, 矢崎貴寛, 高橋東之, 佐久間隆
    • Organizer
      第34回固体イオニクス討論会
    • Place of Presentation
      東京大学生産技術研究所
    • Year and Date
      2008-12-05
    • Related Report
      2009 Final Research Report
  • [Presentation] 12SrO-12BaO-12PbO-64P_2O_5ガラスにおけるプロトン伝導機構2008

    • Author(s)
      清水秋彦、矢崎貴寛、高橋東之、佐久間隆
    • Organizer
      第34回固体イオニクス討論会
    • Place of Presentation
      東京大学生産技術研究所
    • Year and Date
      2008-12-05
    • Related Report
      2008 Annual Research Report
  • [Presentation] MO-P205系ガラスのプロトン伝導特性2008

    • Author(s)
      高橋東之, 清水秋彦, 矢崎貴寛, 佐久間隆
    • Organizer
      日本物理学会2008年秋季大会
    • Place of Presentation
      岩手大学
    • Year and Date
      2008-09-20
    • Related Report
      2009 Final Research Report
  • [Presentation] MO-P_2O_5系ガラスのプロトン伝導特性2008

    • Author(s)
      高橋東之、清水秋彦、矢崎貴寛、佐久間隆
    • Organizer
      日本物理学会2008年秋季大会
    • Place of Presentation
      岩手大学
    • Year and Date
      2008-09-20
    • Related Report
      2008 Annual Research Report
  • [Presentation] リン酸塩ガラスのプロトン伝導2008

    • Author(s)
      清水秋彦, 矢崎貴寛, 高橋東之, 佐久間隆
    • Organizer
      第49回固体イオニクス研究会
    • Place of Presentation
      山形市市民生活支援センター
    • Year and Date
      2008-06-26
    • Related Report
      2009 Final Research Report 2008 Annual Research Report
  • [Presentation] AgI系ガラスの中距離秩序2008

    • Author(s)
      高橋東之, 佐久間隆, 石井慶信
    • Organizer
      日本物理学会
    • Place of Presentation
      近畿大学
    • Year and Date
      2008-03-24
    • Related Report
      2009 Final Research Report 2007 Annual Research Report
  • [Presentation] Ionic and Electronic Conduction in Li_2O-V_2O_5-P_2O_5 glasses2007

    • Author(s)
      H. Takahashi, T. Karasawa, T. Sakuma
    • Organizer
      2nd Int.Conf.on Physics of Solid State Ionics
    • Place of Presentation
      東京工業大学
    • Year and Date
      2007-12-16
    • Related Report
      2009 Final Research Report
  • [Presentation] Ionic and Electronic Conduction in Li_2O-V_2O_5-P_2O_5 glasses.2007

    • Author(s)
      高橋東之, 他
    • Organizer
      2nd Int. Conf. on Physics of Solid State Ionics
    • Place of Presentation
      東京工業大学
    • Year and Date
      2007-12-16
    • Related Report
      2007 Annual Research Report
  • [Presentation] リン酸塩ガラスのプロトン伝導特性2007

    • Author(s)
      矢崎貴寛, 高橋東之, 佐久間隆
    • Organizer
      固体イオニクス学会
    • Place of Presentation
      名古屋国際会議場
    • Year and Date
      2007-12-06
    • Related Report
      2009 Final Research Report 2007 Annual Research Report
  • [Presentation] リン酸塩ガラスの電気伝導2007

    • Author(s)
      高橋東之, 矢崎貴寛, 佐久間隆
    • Organizer
      日本物理学会
    • Place of Presentation
      北海道大学
    • Year and Date
      2007-09-22
    • Related Report
      2009 Final Research Report 2007 Annual Research Report
  • [Remarks] ホームページ等

    • URL

      http://www.base.ibaraki.ac.jp/takahashi/

    • Related Report
      2009 Final Research Report
  • [Remarks]

    • URL

      http://info.ibaraki.ac.jp/scripts/websearch/index.htm

    • Related Report
      2009 Annual Research Report
  • [Remarks]

    • URL

      http://info.ibaraki.ac.jp/scripts/websearch/index.htm

    • Related Report
      2008 Annual Research Report
  • [Remarks] 茨城大学研究者情報総覧

    • URL

      http://info.ibaraki.ac.jp/scripts/websearch/index.htm

    • Related Report
      2007 Annual Research Report

URL: 

Published: 2007-04-01   Modified: 2016-04-21  

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