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Fabrication of an oriented glass-ceramics electrolyte

Research Project

Project/Area Number 19560681
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Inorganic materials/Physical properties
Research InstitutionUniversity of Hyogo

Principal Investigator

MINESHIGE Atsushi  University of Hyogo, 大学院・工学研究科, 助教 (00285339)

Co-Investigator(Kenkyū-buntansha) YAZAWA Tetsuo  兵庫県立大学, 大学院・工学研究科, 教授 (50347522)
Project Period (FY) 2007 – 2009
Project Status Completed (Fiscal Year 2009)
Budget Amount *help
¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2009: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2008: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2007: ¥3,250,000 (Direct Cost: ¥2,500,000、Indirect Cost: ¥750,000)
Keywordsアパタイト / イオン伝導体 / 燃料電池 / ガラスセラミックス
Research Abstract

Oxyapatite-type La-Ca-Si-Al-O solid electrolytes were fabricated from melted glasses containing these oxides via crystallization process. Sliced glass plates were annealed in a furnace at above its crystallization temperature in order to obtain ceramics solid electrolytes. According to an XRD measurement, the main phase of the crystallized glass was oxyapatite, whose space group was the same as that for a high oxide-ion conductor, lanthanum silicates, La_<9.33+x>Si_6O_<26+1.5x>,. In addition, under certain conditions, an oriented ceramics exhibiting superior ionic conductivity could be obtained.

Report

(4 results)
  • 2009 Annual Research Report   Final Research Report ( PDF )
  • 2008 Annual Research Report
  • 2007 Annual Research Report
  • Research Products

    (7 results)

All 2009 2008

All Journal Article (3 results) (of which Peer Reviewed: 3 results) Presentation (2 results) Patent(Industrial Property Rights) (2 results)

  • [Journal Article] Solid oxide fuel cell employing a new class of solid electrolytes, La9. 33+x(Si6-yAly)O26+1. 5x-0. 5y2009

    • Author(s)
      A. Mineshige, T. Nakao, Y. Ohnishi, M. Kobune, T. Yazawa, H. Yoshioka
    • Journal Title

      Electrochemistry 77

      Pages: 146-148

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Electrical properties of La10Si6O27-based oxides2008

    • Author(s)
      A. Mineshige, T. Nakao, M. Kobune, T. Yazawa, H. Yoshioka
    • Journal Title

      Solid State Ionics 179

      Pages: 1009-1012

    • NAID

      130006973481

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Chemical stability of La10Si6O27 and its application to electrolytes for solid oxide fuel cells2008

    • Author(s)
      T. Nakao, A. Mineshige, M. Kobune, T. Yazawa, H. Yoshioka
    • Journal Title

      Solid State Ionics 179

      Pages: 1567-1569

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Presentation] 溶融シリケートガラスの結晶化によるオキシアパタイトセラミックスの作製2009

    • Author(s)
      嶺重温, ほか
    • Organizer
      第35回固体イオニクス討論会
    • Place of Presentation
      グランキューブ大阪(大阪府)
    • Year and Date
      2009-12-07
    • Related Report
      2009 Annual Research Report
  • [Presentation] 溶融シリケートガラスの結晶化によるオキシアパタイトセラミックスの作製2009

    • Author(s)
      嶺重温, 中尾孝之, 森兼孝善, 大幸裕介, 小舟正文, 矢澤哲夫, 福塚友和, 内本喜晴
    • Organizer
      第35回固体イオニクス討論会講演要旨集
    • Related Report
      2009 Final Research Report
  • [Patent(Industrial Property Rights)] イオン伝導性配向セラミックスの製造方法およびそのイオン伝導体を用いた燃料電池2009

    • Inventor(s)
      嶺重温, 矢澤哲夫, 中尾孝之
    • Industrial Property Rights Holder
      兵庫県
    • Industrial Property Number
      2009-185885
    • Filing Date
      2009-08-10
    • Acquisition Date
      2009-08-10
    • Related Report
      2009 Final Research Report
  • [Patent(Industrial Property Rights)] イオン伝導性配向セラミックスの製造方法およびそのイオン伝導体を用いた燃料電池2009

    • Inventor(s)
      嶺重温, ほか
    • Industrial Property Rights Holder
      兵庫県
    • Industrial Property Number
      2009-185885
    • Filing Date
      2009-08-10
    • Related Report
      2009 Annual Research Report

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Published: 2007-04-01   Modified: 2016-04-21  

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