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Investigation on the segregation behavior of rare-earth ions at the silicon nitried-grain boundary phase interface

Research Project

Project/Area Number 19560684
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Inorganic materials/Physical properties
Research InstitutionFukuoka Institute of Technology

Principal Investigator

KITAYAMA Mikito  Fukuoka Institute of Technology, 工学部, 教授 (10330945)

Project Period (FY) 2007 – 2009
Project Status Completed (Fiscal Year 2009)
Budget Amount *help
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2009: ¥390,000 (Direct Cost: ¥300,000、Indirect Cost: ¥90,000)
Fiscal Year 2008: ¥130,000 (Direct Cost: ¥100,000、Indirect Cost: ¥30,000)
Fiscal Year 2007: ¥3,640,000 (Direct Cost: ¥2,800,000、Indirect Cost: ¥840,000)
Keywords窒化ケイ素 / 粒界 / 界面 / 希土類イオン / 偏析 / セラミックス / 表面・界面物性 / 希土類元素
Research Abstract

As the sintering additive, La and Lu oxides that have the largest and the smallest, respectively, ionic radii among the lanthanide were selected. Silicon nitride sintered bodies were fabricated using the composition of (1-x)La_2O_3+xLu_2O_3(x=0, 0.1, 0.2, 0.3, …, 1), and their activation energies of the…transformation were determined. It was found that the energy value of x=0.3 was close to the one of x=1, which strongly suggests that rare-earth elements with small ionic radii would bond more strongly at the silicon nitried grain boundary interface.

Report

(4 results)
  • 2009 Annual Research Report   Final Research Report ( PDF )
  • 2008 Annual Research Report
  • 2007 Annual Research Report
  • Research Products

    (27 results)

All 2010 2009 2008 2007 Other

All Journal Article (7 results) (of which Peer Reviewed: 7 results) Presentation (13 results) Book (3 results) Remarks (4 results)

  • [Journal Article] Anisotropic Ostwald Ripening in Silicon Nitride: On the Reaction-Controlled Kinetics2010

    • Author(s)
      北山幹人
    • Journal Title

      Materials Science Forum 638-642

      Pages: 2598-2603

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Anisotropic Ostwald Ripening in Silicon Nitride : On the Reaction-Controlled Kinetics2010

    • Author(s)
      M.Kitayama
    • Journal Title

      Materials Science Forum 638-642

      Pages: 2598-2603

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Development of Porous Silicon Nitride with Tailor-made Pore Structure for Bio-Filter: II. Development of Tape Casting Process and Strength of Porous Body2009

    • Author(s)
      松岡剛、白石諒、太田能生、北山幹人
    • Journal Title

      J. MMIJ 125

      Pages: 502-6

    • NAID

      10025312904

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Development of Porous Silicon Nitride with Tailor-made Pore Structure for Bio-Filter : II. Development of Tape Casting Process and Strength of Porous Body2009

    • Author(s)
      T.Matsuoka, R.Shiraishi, Y.Ohta, M.Kitayama
    • Journal Title

      J.MMIJ 125

      Pages: 502-506

    • NAID

      10025312904

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Development of Porous Silicon Nitride with Tailor-Made Pore Structure for Bio-Filter: I. Search of Sintering Aids2008

    • Author(s)
      阿南努、太田能生、北山幹人
    • Journal Title

      J. MMIJ 124

      Pages: 245-48

    • NAID

      10021121513

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Detection and Control of Crystallization by means of In-situ Measurement of Capacitance2008

    • Author(s)
      Y. Ohta, M. Kitayama
    • Journal Title

      Ceramics 43

      Pages: 1027-1030

    • NAID

      10024784504

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Development of Porous Silicon Nitride with Tailor-Made Pore Structure for Bio-Filter : I. Search of Sintering Aids2008

    • Author(s)
      T. Anan, M. Kitayama, Y. Ohta
    • Journal Title

      J. MMIJ 24

      Pages: 245-248

    • NAID

      10021121513

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Presentation] ナノーマイクロ複合細孔構造を有する窒化ケイ素多孔体の開発2009

    • Author(s)
      松岡剛、白石諒、太田能生、北山幹人
    • Organizer
      日本セラミックス協会第22回秋季シンポジウム
    • Place of Presentation
      愛媛大学
    • Year and Date
      2009-09-18
    • Related Report
      2009 Final Research Report
  • [Presentation] ナノ-マイクロ複合細孔構造を有する窒化ケイ素多孔体の開発2009

    • Author(s)
      松岡剛、白石諒、太田能生、北山幹人
    • Organizer
      日本セラミックス協会第22回秋季シンポジウム
    • Place of Presentation
      愛媛大学
    • Year and Date
      2009-09-18
    • Related Report
      2009 Annual Research Report
  • [Presentation] Anisotropic Ostwald Ripening in Silicon Nitride: On the Reaction-Controlled Kinetics2009

    • Author(s)
      北山幹人
    • Organizer
      International Conference on Processing & Manufacturing of Advanced Materials
    • Place of Presentation
      ベルリン
    • Year and Date
      2009-08-29
    • Related Report
      2009 Final Research Report
  • [Presentation] Anisotropic Ostwald Ripening in Silicon Nitride : On the Reaction-Controlled Kinetics2009

    • Author(s)
      Mikito Kitayama
    • Organizer
      International Conference on Processing & Manufacturing of Advanced Materials (THERMEC'2009)
    • Place of Presentation
      ドイツ・ベルリン
    • Year and Date
      2009-08-26
    • Related Report
      2009 Annual Research Report
  • [Presentation] ナノ-マイクロ細孔構造を有する窒化ケイ素多孔体の開発3.フィルター圧力損失-流量特性の評価2009

    • Author(s)
      白石諒、松岡剛、太田能生、北山幹人
    • Organizer
      資源・素材学会九州支部平成21年度春季例会
    • Place of Presentation
      九州大学
    • Year and Date
      2009-05-29
    • Related Report
      2009 Annual Research Report
  • [Presentation] ナノーマイクロ細孔構造を有する窒化ケイ素多孔体の開発2008

    • Author(s)
      阿南努、松岡剛、太田能生、北山幹人
    • Organizer
      日本セラミックス協会第21回秋季シンポジウム
    • Place of Presentation
      北九州蟹際会議場
    • Year and Date
      2008-09-19
    • Related Report
      2009 Final Research Report
  • [Presentation] ナノ-マイクロ細孔構造を有する窒化ケイ素多孔体の開発2008

    • Author(s)
      阿南努, 松岡剛, 太田能生, 北山幹人
    • Organizer
      日本セラミックス協会第21回秋季シンポジウム
    • Place of Presentation
      北九州国際会議場(福岡)
    • Year and Date
      2008-09-19
    • Related Report
      2008 Annual Research Report
  • [Presentation] ナノ-マイクロ細孔構造を有する窒化ケイ素多孔体の開発2. 多孔体強度の評価2008

    • Author(s)
      松岡剛, 阿南努, 太田能生, 北山幹人
    • Organizer
      資源・素材学会九州支部平成20年度春季例会
    • Place of Presentation
      九州大学(福岡)
    • Year and Date
      2008-05-30
    • Related Report
      2008 Annual Research Report
  • [Presentation] オゾンを利用した揮発性有機物質(VOC)分解除去技術の開発2008

    • Author(s)
      三浦美姫, 太田能生, 北山幹人
    • Organizer
      資源・素材学会九州支部平成20年度春季例会
    • Place of Presentation
      九州大学(福岡)
    • Year and Date
      2008-05-30
    • Related Report
      2008 Annual Research Report
  • [Presentation] Bi_2O_3-ZnO-SiO_2系鉛フリー低融点ガラスに対する遷移金属化合物の添加効果2007

    • Author(s)
      石本 亜由美、太田 能隼、北山 幹人
    • Organizer
      西日本腐蝕防蝕研究会第158回例会
    • Place of Presentation
      九州工業大学
    • Year and Date
      2007-12-07
    • Related Report
      2007 Annual Research Report
  • [Presentation] ビスマス系鉛フリーガラスに対する酸化マンガン添加効果2007

    • Author(s)
      石本 亜由美、太田 能生、北山 幹入、清水 史幸
    • Organizer
      (社)表面技術協会第116回講演大会
    • Place of Presentation
      長崎大学
    • Year and Date
      2007-09-18
    • Related Report
      2007 Annual Research Report
  • [Presentation] ナノーマイクロ細孔構造を有する窒化ケイ素多孔体の開発2007

    • Author(s)
      阿南 努、北山 幹人、太田 能生
    • Organizer
      資源・素材学会九州支部平成19年度春季例会
    • Place of Presentation
      九州大学
    • Year and Date
      2007-05-25
    • Related Report
      2007 Annual Research Report
  • [Presentation] 電気容量法によるナノ結晶の検出と結晶化過程2007

    • Author(s)
      馬場 健士、太田 能生、北山 幹人
    • Organizer
      資源・素材学会九州支部平成19年度春季例会
    • Place of Presentation
      九州大学
    • Year and Date
      2007-05-25
    • Related Report
      2007 Annual Research Report
  • [Book] 熱伝導率・熱拡散率の制御と測定評価方法2009

    • Author(s)
      北山幹人
    • Related Report
      2009 Final Research Report
  • [Book] 熱伝導率・熱拡散率の制御と測定評価方法第2章第2節〔3〕Si_3N_4セラミックスの高熱伝導率化2009

    • Author(s)
      北山幹人
    • Total Pages
      350
    • Publisher
      サイエンス&テクノロジー株式会社
    • Related Report
      2008 Annual Research Report
  • [Book] 各種手法による有機物の分解技術(第1章第8節担当)2007

    • Author(s)
      太田 能生、北山 幹人
    • Total Pages
      10
    • Publisher
      (株)情報機構
    • Related Report
      2007 Annual Research Report
  • [Remarks]

    • URL

      http://www.fit.ac.jp/~kitayama

    • Related Report
      2008 Annual Research Report
  • [Remarks]

    • URL

      http://www.fit.ac.jp/cro/hrc/index.htm

    • Related Report
      2008 Annual Research Report
  • [Remarks]

    • URL

      http://www.fit.ac.jp/~kitayama

    • Related Report
      2007 Annual Research Report
  • [Remarks]

    • URL

      http://www.fit.ac.jp/cro/hrc/index.htm

    • Related Report
      2007 Annual Research Report

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Published: 2007-04-01   Modified: 2016-04-21  

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