| Project/Area Number |
19560759
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Properties in chemical engineering process/Transfer operation/Unit operation
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| Research Institution | University of Hyogo |
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Principal Investigator |
FUKUI Keisuke University of Hyogo, 工学研究科, 教授 (50047635)
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| Co-Investigator(Kenkyū-buntansha) |
前田 光治 兵庫県立大学, 大学院・工学研究科, 准教授 (00264838)
朝熊 裕介 兵庫県立大学, 大学院・工学研究科, 助教 (40364038)
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| Co-Investigator(Renkei-kenkyūsha) |
MAEDA Kouji 兵庫県立大学, 工学研究科, 準教授 (00264838)
ASAKUMA Yusuke 兵庫県立大学, 工学研究科, 準教授 (40364038)
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| Project Period (FY) |
2007 – 2010
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| Project Status |
Completed (Fiscal Year 2010)
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| Budget Amount *help |
¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2010: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2009: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2008: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2007: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
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| Keywords | 高圧力 / 晶析操作 / 核発生 / ナノ結晶 / 溶液熱力学 / High pressure / Crystallization / Electrolyte solution / Dilute solubility / Nanometer size crystal / Thermodynamics / Nucleation / Crystal Growth / nanometer size / crystallization / high pressure / nucleation / crystal growth / Thermodnamics / Crystal growth / Electrolte solution |
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| Research Abstract |
The advantages of high pressure crystallization are to distinguish the nucleation process from complicated crystallization processes, and to change the solubility of solute at atmosphere pressure. The pressure can expand into the system at speed of sound, and that is quite different from concentration and temperature which speeds are limited by diffusivity and thermal conductivity. We could have the new apparatus to investigate the solution at more than 4000 bar. The solution can be easily changed in the free-piston type vial. We first observed the nucleation of two ammonium salts at high pressure, and found that the solubility of two ammonium salts could be decreased as pressure increased. Those two salts could be crystallized by high pressure. Moreover, two ammonium salts in aqueous ethanol solution were nucleated at supersaturated solution by high pressure, and the metastable zones for two ammonium salts were found in high pressure crystallization. The width of metastable zone was large when the solubility of salt was small in the solution. The viscosity of ethanol solution that influences the growth of crystal nuclei was also measured at high pressure by DLS method. The viscosity of aqueous ethanol solution became very large as pressure increased, and that could limit the growth of crystal nuclei. In addition, electric conductivity of aqueous ethanol solution was also measured at high pressure. We could developed new high pressure cell having dipoles. The electric conductivities of two ammonium salts in aqueous ethanol solution decreased considerably at high pressure. As a results of this project, we could have new method to charge electron in battery at high speed at high pressure by nucleation process for further project.
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