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Study on the new preparation method for LPG-reforming catalysts

Research Project

Project/Area Number 19560772
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Catalyst/Resource chemical process
Research InstitutionEhime University

Principal Investigator

YAHIRO Hidenori  Ehime University, 大学院・理工学研究科, 教授 (90200568)

Project Period (FY) 2007 – 2008
Project Status Completed (Fiscal Year 2008)
Budget Amount *help
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2008: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2007: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
Keywords担持触媒 / 金属銅 / 白金 / 燃料電池 / シフト反応 / 水素製造 / スパッタリング / アルミナ / 遷移金属酸化物 / 一酸化炭素 / 触媒調製
Research Abstract

固体高分子形燃料電池用の水素燃料は都市ガス(メタン)の水蒸気改質, COシフト反応によって得られるが, この両反応に対して耐久性に優れた触媒は高価な貴金属触媒以外はほとんど報告されていない. そこで, 本研究では貴金属フリーあるいは低減した耐久性の高い触媒を開発するために新しいコンセプトの触媒調製法について検討した. また, 得られた触媒をLPG 燃料へ応用するための基礎的なデータ収集を行った.

Report

(3 results)
  • 2008 Annual Research Report   Final Research Report ( PDF )
  • 2007 Annual Research Report
  • Research Products

    (27 results)

All 2009 2008 2007 Other

All Journal Article (13 results) (of which Peer Reviewed: 13 results) Presentation (13 results) Remarks (1 results)

  • [Journal Article] Catalytic activity of multi-metallic perovskite-type oxide prepared by the thermal decomposition of heteronuclear cyano complex, Sm[Fe_xCo_<1-x>(CN)6]・nH_2O2009

    • Author(s)
      M. Asamoto, N. Harada, Y. Iwamoto, H. Yamaura, Y. Sadaoka, and H. Yahiro
    • Journal Title

      Topics in Catal 52(6-7)

      Pages: 823-827

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Effect of Transition Metal Oxide Additives for Water-gas-shift Reaction over Supported Copper Catalyst2009

    • Author(s)
      K. Sagata, Y. Kawanishi, M. Asamoto, H. Yamaura, and H. Yahiro
    • Journal Title

      Chem. Lett. 38

      Pages: 172-173

    • NAID

      10025119399

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Effect of Transition Metal Oxide Additives for Water-gas-shift Reaction over Supported Copper Catalyst2009

    • Author(s)
      K. Sagata
    • Journal Title

      Chemistry Letters 38

      Pages: 172-173

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Promotion effect of FeOx addition on the catalytic activity of supported Cu catalysts for the water-gas shift reaction2008

    • Author(s)
      H. Yahiro, K. Sagata, T. Yamamoto, K. Saiki, M. Asamoto, and H. Yamaura
    • Journal Title

      Catal. Lett 124(3-4)

      Pages: 233-237

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Effect of preparation routes on the catalytic activity over SmFeO_3 oxide2008

    • Author(s)
      M. Mori, Y. Iwamoto, M. Asamoto, Y. Itagaki, H. Yahiro, Y. Sadaoka, S. Takase, Y. Shimizu, M. Yuasa, K. Shimanoe, H. Kusaba, and Y. Teraoka
    • Journal Title

      Catal. Today 139

      Pages: 125-129

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] New Catalytic System for Producing Pure Hydrogen-Water-gas-shift Reaction of Supported Copper Catalysts-2008

    • Author(s)
      H. Yahiro, K. Saiki, T. Yamamoto, K. Sagata, M. Asamoto, and H. Yamaura
    • Journal Title

      Clean Technology 2008

      Pages: 290-293

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Effect of Supported Transition Metal on CO Sensing Performance Using SnO_2 in Reducing Atmosphere2008

    • Author(s)
      H. Yamaura, M. Nakaoka, and H. Yahiro
    • Journal Title

      Adv. Mater. Research 47-50

      Pages: 1518-1521

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Promotion effect of FeO_x addition on the catalytic activity of supported Cu catalysts for the water-gas shift reaction2008

    • Author(s)
      H. Yahiro
    • Journal Title

      Catalysis Letters 124

      Pages: 233-237

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] New Catalytic System for Producing Pure Hydrogen-Water-gas-shift Reaction of Supported Copper Catalysts-2008

    • Author(s)
      H. Yahiro
    • Journal Title

      Clean Technology 2008 2008

      Pages: 290-293

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Study on the supported Cu-based catalyst for the low-temperature water-gas shift reaction2007

    • Author(s)
      H. Yahiro, K. Murawaki, K. Saiki, T. Yamamoto, and H. Yamaura
    • Journal Title

      Catal. Today 126

      Pages: 436-440

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Study on the supported Cu-based catalyst for the low-temperature water-gas shift reaction2007

    • Author(s)
      H. Yahiro
    • Journal Title

      Catalysis Today 126

      Pages: 284-289

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Effect of preparation routes on the catalytic activity over SmFeO_3 oxide

    • Author(s)
      M. Mori
    • Journal Title

      Catalysis Today (印刷中)

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Promotion effect of FeO_x addition on the catalytic activity of supported Cu catalysts for the water-gas shift reaction

    • Author(s)
      H. Yahiro
    • Journal Title

      Catalysis Letters (印刷中)

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Presentation] スパッタリング法により球状アルミナに貴金属を担持した触媒の評価2009

    • Author(s)
      八尋秀典
    • Organizer
      第103回触媒討論会
    • Place of Presentation
      埼玉
    • Year and Date
      2009-03-31
    • Related Report
      2008 Annual Research Report 2008 Final Research Report
  • [Presentation] スパッタリング法により担持したPt触媒の評価2008

    • Author(s)
      八尋秀典
    • Organizer
      2008年日本化学会西日本大会
    • Place of Presentation
      長崎
    • Year and Date
      2008-11-15
    • Related Report
      2008 Annual Research Report 2008 Final Research Report
  • [Presentation] アルミナ担持Cu-遷移金属酸化物触媒のWGS 活性2008

    • Author(s)
      八尋秀典
    • Organizer
      第38回石油・石油化学討論会
    • Place of Presentation
      東京
    • Year and Date
      2008-11-06
    • Related Report
      2008 Final Research Report
  • [Presentation] アルミナ担持Cu-遷移金属酸化物触媒のWGS活性2008

    • Author(s)
      八尋秀典
    • Organizer
      第38回石油・石油化学討論会
    • Place of Presentation
      東京
    • Year and Date
      2008-11-06
    • Related Report
      2008 Annual Research Report
  • [Presentation] 水性ガスシフト反応に活性なアルミナ担持Cu触媒への遷移金属酸化物の添加効果2008

    • Author(s)
      八尋秀典
    • Organizer
      第102回触媒討論会
    • Place of Presentation
      名古屋
    • Year and Date
      2008-09-26
    • Related Report
      2008 Annual Research Report 2008 Final Research Report
  • [Presentation] Water-gas shift reaction of alumina supported Cu-based catalysts2008

    • Author(s)
      H. Yahiro
    • Organizer
      第14 回国際触媒会議
    • Place of Presentation
      韓国(ソウル)
    • Year and Date
      2008-07-17
    • Related Report
      2008 Final Research Report
  • [Presentation] Water-gas shift reaction of alumina supported Cu-based catalysts calcined at high temperature2008

    • Author(s)
      H. Yahiro
    • Organizer
      第14回国際触媒会議
    • Place of Presentation
      韓国(ソウル)
    • Year and Date
      2008-07-17
    • Related Report
      2008 Annual Research Report
  • [Presentation] COシフト反応に活性な担持Cu-Fe 触媒の開発2007

    • Author(s)
      八尋秀典
    • Organizer
      2007年日本化学会西日本大会
    • Place of Presentation
      岡山
    • Year and Date
      2007-11-10
    • Related Report
      2008 Final Research Report
  • [Presentation] COシフト反応に活性な担持Cu-Fe触媒の開発2007

    • Author(s)
      八尋 秀典
    • Organizer
      2007年日本化学会西日本大会
    • Place of Presentation
      岡山
    • Year and Date
      2007-11-10
    • Related Report
      2007 Annual Research Report
  • [Presentation] 拡散反射赤外分光法によるCu/Al_2O_3触媒のCO吸着挙動の検討2007

    • Author(s)
      八尋秀典
    • Organizer
      100回触媒討論会
    • Place of Presentation
      札幌
    • Year and Date
      2007-09-19
    • Related Report
      2008 Final Research Report
  • [Presentation] 拡散反射赤外分光法によるCU/Al_2O_3触媒のCO吸着挙動の検討2007

    • Author(s)
      八尋 秀典
    • Organizer
      第100回触媒討論会
    • Place of Presentation
      札幌
    • Year and Date
      2007-09-19
    • Related Report
      2007 Annual Research Report
  • [Presentation] 水性ガスシフト反応におけるCu/Al_2O_3触媒へのFeOxの添加効果2007

    • Author(s)
      八尋秀典
    • Organizer
      100回触媒討論会
    • Place of Presentation
      札幌
    • Year and Date
      2007-09-18
    • Related Report
      2008 Final Research Report
  • [Presentation] 水性ガスシフト反応におけるCU/Al_2O_3触媒へのFeOxの添加効果2007

    • Author(s)
      八尋 秀典
    • Organizer
      第100回触媒討論会
    • Place of Presentation
      札幌
    • Year and Date
      2007-09-18
    • Related Report
      2007 Annual Research Report
  • [Remarks]

    • URL

      http://www.ehime-u.ac.jp/~achem/solid/

    • Related Report
      2008 Final Research Report

URL: 

Published: 2007-04-01   Modified: 2016-04-21  

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