Synthesis of novel polymer complexes constructed with dinitrogen
| Project/Area Number |
19685009
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| Research Category |
Grant-in-Aid for Young Scientists (A)
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| Allocation Type | Single-year Grants |
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| Research Field |
Polymer chemistry
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| Research Institution | Kyoto University |
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Principal Investigator |
SHIOTSUKI Masashi Kyoto University, 大学院・工学研究科, 助教 (30362453)
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| Project Period (FY) |
2007 – 2009
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| Project Status |
Completed (Fiscal Year 2009)
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| Budget Amount *help |
¥25,220,000 (Direct Cost: ¥19,400,000、Indirect Cost: ¥5,820,000)
Fiscal Year 2009: ¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2008: ¥5,720,000 (Direct Cost: ¥4,400,000、Indirect Cost: ¥1,320,000)
Fiscal Year 2007: ¥14,560,000 (Direct Cost: ¥11,200,000、Indirect Cost: ¥3,360,000)
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| Keywords | 高分子合成 / 高分子錯体 / 窒素 / 共役ポリマー / ロジウム / イリジウム / 二核錯体 |
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| Research Abstract |
Novel synthetic methods for the polymer complexes constructed ith dinitrogen were developed. The obtained polymer complexes constructed with initrogen and group 9 transition metals involving Ir and Rh were revealed to be insoluble n common organic solvents. IR spectra of the polymers indicated that dinitrogen is ncorporated in the polymers' main chain.
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Report
(4 results)
Research Products
(3 results)
