Synthesis of novel polymer complexes constructed with dinitrogen

• Project/Area Number: 19685009
• Research Category: Grant-in-Aid for Young Scientists (A)
• Allocation Type: Single-year Grants
• Research Field: Polymer chemistry
• Research Institution: Kyoto University
• Principal Investigator: SHIOTSUKI Masashi Kyoto University, 大学院・工学研究科, 助教 (30362453)
• Project Period (FY): 2007 – 2009
• Project Status: Completed (Fiscal Year 2009)
• Budget Amount: ¥25,220,000 (Direct Cost: ¥19,400,000、Indirect Cost: ¥5,820,000); Fiscal Year 2009: ¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000); Fiscal Year 2008: ¥5,720,000 (Direct Cost: ¥4,400,000、Indirect Cost: ¥1,320,000); Fiscal Year 2007: ¥14,560,000 (Direct Cost: ¥11,200,000、Indirect Cost: ¥3,360,000)
• Keywords: 高分子合成 / 高分子錯体 / 窒素 / 共役ポリマー / ロジウム / イリジウム / 二核錯体

Research Abstract

Novel synthetic methods for the polymer complexes constructed ith dinitrogen were developed. The obtained polymer complexes constructed with initrogen and group 9 transition metals involving Ir and Rh were revealed to be insoluble n common organic solvents. IR spectra of the polymers indicated that dinitrogen is ncorporated in the polymers' main chain.

Research Products

• [Presentation] 窒素分子を構成部位とする高分子の合成方法の開発 (2009)
  • Author(s): 鈴木健一郎, 塩月雅士, 三田文雄, 増田俊 夫
  • Organizer: 第58回高分子学会年次大会
  • Place of Presentation: 神戸国際会議場
  • Year and Date: 2009-05-27
• [Presentation] 窒素分子をキーモノマーとする特異ポリマーの合成方法の開発 (2008)
  • Author(s): 鈴木健一郎, 塩月雅士, 三田文雄, 増田俊 夫
  • Organizer: 第57回高分子討論会
  • Place of Presentation: 大阪市立大学杉本キャンパス
  • Year and Date: 2008-09-25
• [Remarks]
  • URL: http://adv.polym.kyoto-u.ac.jp/