Design and syntheses of functional nano-structured ionic crystals

• Project/Area Number: 19685011
• Research Category: Grant-in-Aid for Young Scientists (A)
• Allocation Type: Single-year Grants
• Research Field: Functional materials chemistry
• Research Institution: The University of Tokyo
• Principal Investigator: UCHIDA Sayaka The University of Tokyo, 大学院・総合文化研究科, 准教授 (10361510)
• Project Period (FY): 2007 – 2009
• Project Status: Completed (Fiscal Year 2009)
• Budget Amount: ¥26,000,000 (Direct Cost: ¥20,000,000、Indirect Cost: ¥6,000,000); Fiscal Year 2009: ¥3,250,000 (Direct Cost: ¥2,500,000、Indirect Cost: ¥750,000); Fiscal Year 2008: ¥8,190,000 (Direct Cost: ¥6,300,000、Indirect Cost: ¥1,890,000); Fiscal Year 2007: ¥14,560,000 (Direct Cost: ¥11,200,000、Indirect Cost: ¥3,360,000)
• Keywords: ナノ構造体 / 多孔体 / 吸着 / 触媒 / ポリオキソメタレート化合物 / ポリオキソメタレート / イオン性結晶 / 粉末及び単結晶X線構造解析 / 収着・分離 / 親水性・疎水性 / 細孔構造制御 / 不均一系触媒

Research Abstract

The construction of nano-structured materials with advanced functions by the self-organization of molecular building blocks is one of the key topics in modern material chemistry. In this work, polyoxometalate-based ionic crystals with controlled pore size, volume, and shape are synthesized, and their functions are presented.

Research Products

• [Journal Article] N. Mizuno, S. Uchida, K. Uehara (2009)
  • Author(s): Hierarchical Design of Nano-Structured Materials based on Polyoxometalates
  • Journal Title: Pure Appl. Chem. 81 Pages: 2369-2376
• [Journal Article] W. Bu, S. Uchida, Noritaka Mizuno (2009)
  • Author(s): Micelles, Vesicles Formed by Polyoxometalate-Block Copolymer Composites
  • Journal Title: Angew. Chem. Int. Ed. 48 Pages: 8281-8284
• [Journal Article] H. Tagami, S. Uchida, N. Mizuno (2009)
  • Author(s): Size-Selective Sorption of Small Organic Molecules in One-Dimensional Channel of Organic-Inorganic Hybrid Ionic Crystal Stabilized byπ-πInteraction
  • Journal Title: Angew. Chem. Int. Ed. 48 Pages: 6160-6164
• [Journal Article] Y. Ogasawara, S. Uchida, K. Yamaguchi, N. Mizuno (2009)
  • Author(s): A Tin-Tungsten Mixed Oxide as an Efficient Heterogeneous Catalyst for C-C Bond-Forming Reactions
  • Journal Title: Chem. Eur. J. 15 Pages: 4343-4349
• [Journal Article] X. Fang, P. Kogerler, L. Isaacs, S. Uchida, N. Mizuno (2009)
  • Author(s): Cucurbit[n]uril-Polyanion Hybrids
  • Journal Title: J. Am. Chem. Soc. 131 Pages: 432-433
• [Journal Article] Micelles and Vesicles Formed by Polyoxometalate-Block Copolymer Composites (2009)
  • Author(s): Weifeng Bu, Sayaka Uchida, Noritaka Mizuno
  • Journal Title: Angewandte Chemie International Edition 48 Pages: 8281-8284
  • Peer Reviewed
• [Journal Article] Size-Selective Sorption of Small Organic Molecules in One-Dimensional Channel of Organic-Inorganic Hybrid Ionic Crystal Stabilized by π-π Interaction (2009)
  • Author(s): Hanae Tagami, Sayaka Uchida, Noritaka Mizuno
  • Journal Title: Angewandte Chemie International Edition 48 Pages: 6160-6165
  • Peer Reviewed
• [Journal Article] Hierarchical Design of Nano-Structured Materials based on Polyoxometalates (2009)
  • Author(s): Noritaka Mizuno, Sayaka Uchida, Kazuhiro Uehara
  • Journal Title: Pure and Applied Chemistry 81 Pages: 2369-2376
  • Peer Reviewed
• [Journal Article] Y. Kikukawa, S. Yamaguchi, Y. Nakagawa, K. Uehara, S. Uchida, K. Yamaguchi, N. Mizuno (2008)
  • Author(s): Synthesis of a Dialuminum-Substituted Silicotungstate, the Diastereoselective Cyclization of Citronellal Derivatives
  • Journal Title: J. Am. Chem. Soc. 130 Pages: 15872-15878
• [Journal Article] S. Uchida, R. Kawamoto, H. Tagami, Y. Nakagawa, N. Mizuno (2008)
  • Author(s): Highly Selective Sorption of Small Unsaturated Hydrocarbons by Non-Porous Flexible Framework with Silver Ion
  • Journal Title: J. Am. Chem. Soc. 130 Pages: 12370-12376
• [Journal Article] A. Lesbani, R. Kawamoto, S. Uchida, N. Mizuno (2008)
  • Author(s): Control of Structures, Sorption Properties of Ionic Crystals of A2[Cr3O(OOCC2H5)6(H2O)3]2 [α-SiW12O40] (A = Na, K, Rb, NH4, Cs, TMA)
  • Journal Title: Inorg. Chem. 47 Pages: 3349-3357
• [Journal Article] Highly Selective Sorption of Small Unsaturated Hydrocarbons by Non-Porous Flexible Framework with Silver Ion (2008)
  • Author(s): S. Uchida, R. Kawamoto, H. Tagami, Y. Nakagawa, N. Mizuno
  • Journal Title: Journal of the American Chemical Society 130 Pages: 12370-12378
  • Peer Reviewed
• [Journal Article] Synthesis of a Dialuminun-Substituted Silicotungstate and the Diastereoselective Cyclization of Citronellal Derivatives (2008)
  • Author(s): Y. Kikukawa, S. Yamaguchi, Y. Nakagawa, K. Uehara, S. Uchida, K. Yamaguchi N
  • Journal Title: Journal of the American Chemical Society 130 Pages: 15872-15878
  • Peer Reviewed
• [Journal Article] Control of Structures and Sorption Properties of Ionic Crystals (2008)
  • Author(s): A. Lesbani, R. Kawamoto, S. Uchida, N. Mizuno
  • Journal Title: Inorganic Chemistry 130 Pages: 3349-3357
  • Peer Reviewed
• [Journal Article] Control of Structures and Sorption Properties of Ionic Crystals of A_2「Cr_3O(OOCC_2H_5)_6(H_2O)_3」「α-SiW_<12>O_<40>」(A=Na, K, Rb, NH_4, Cs, TMA) (2008)
  • Author(s): A. Lesbani, R. Kawamoto, S. Uchida, N. Mizuno
  • Journal Title: Inorganic Chemistry 47 Pages: 3349-3357
  • Peer Reviewed
• [Journal Article] K. Okamoto, S. Uchida, T. Ito, N. Mizuno (2007)
  • Author(s): Self-Organization of All-Inorganic Dodecatungstophosphate Nanocrystallites
  • Journal Title: J. Am. Chem. Soc. 129 Pages: 7378-7384
• [Journal Article] Y. Ogasawara, S. Uchida, N. Mizuno (2007)
  • Author(s): States of Water in Ionic Crystals of [Cr3O(OOCH)6(H2O)3]+ Macrocation, α-Keggin-type Polyoxometalate
  • Journal Title: J. Phys. Chem. C 111 Pages: 8218-8227
• [Journal Article] S. Uchida, S. Hikichi, T. Akatsuka, T. Tanaka, R. Kawamoto, A. Lesbani, Y. Nakagawa, K. Uehara, N. Mizuno (2007)
  • Author(s): Preparation of Monodispersed Nanoparticles by Electrostatic Assembly of Keggin-Type Polyoxometalates, 1, 4, 7-Triazacyclononate-Based Transition-Metal Complexes
  • Journal Title: Chem. Mater. 19 Pages: 4694-4701
• [Journal Article] Design and Syntheses of Nano-structured Ionic Crystals with Selective Sorption Properties (2007)
  • Author(s): S. Uchida, N. Mizuno
  • Journal Title: Coordination Chemistry Reviews 251 Pages: 2537-2546
  • Peer Reviewed
• [Journal Article] 分子の貯蔵・分離,変換場となる機能性物質の創製 (2007)
  • Author(s): 水野哲孝, 内田さやか
  • Journal Title: 化学 63 Pages: 76-77
• [Journal Article] Self-Organization of All-lnorganic Dodecatungstophosphate Nanocrystallites (2007)
  • Author(s): K. Okamoto, S. Uchida, T. Ito, N. Mizuno
  • Journal Title: Journal of the American Chemical Society 129 Pages: 7378-7384
  • Peer Reviewed
• [Journal Article] States of Water in Ionic Crystals of[Cr_3O(OOCH)_6(H_2O)_3]^+ Macrocation and α-Keggin-type Polyoxometalates (2007)
  • Author(s): Y. Ogasawara, S. Uchida, N. Mizuno
  • Journal Title: Journal of the Physical Chemistry C 111 Pages: 8218-8227
  • Peer Reviewed
• [Journal Article] Preparation of Monodispersed Nano-particles Electrostatic Assembly of Keggin-type Polyoxometalates and tacn-Based Transition Metal Complexes (2007)
  • Author(s): S. Uchida, S. Hikichi, T. Akatsuka, T. Tanaka, R. Kawamoto, A. Lesbani, Y. Nakagawa, K. Uehala, N. Mizuno
  • Journal Title: Chemistry of Materials 19 Pages: 4694-4701
  • Peer Reviewed
• [Presentation] 分子の収着・分離、変換場となるポリオキソメタレート複合体の創製 (2009)
  • Author(s): 内田さやか, 水野哲孝
  • Organizer: 第3回日本化学会関東支部大会
  • Place of Presentation: 東京
  • Year and Date: 2009-09-05
• [Presentation] Ag(I)を含む柔軟性ナノ構造体の設計と不飽和炭化水素分子の高選択的収着特性 (2009)
  • Author(s): 内田さやか・河本亮介・田上英恵・中川善直・水野哲孝
  • Organizer: 第103回触媒討論会
  • Place of Presentation: 日本大学船橋キャンパス
  • Year and Date: 2009-03-31
• [Presentation] 芳香族配位子を導入した有機-無機多孔体の創製と形状選択的分子収着特性 (2009)
  • Author(s): 内田さやか, 田上英恵, 水野哲孝
  • Organizer: 第59回錯体化学討論会
  • Place of Presentation: 長崎
• [Presentation] 分子の貯蔵・分離, 変換場となる有機-無機ナノハイブリッド物質の創製 (2009)
  • Author(s): 内田さやか, 水野哲孝
  • Organizer: 第89回日本化学会年会シンポジウム「革新的ハイブリッド物性を実現するナノ物質科学～金属錯体から次世代ナノハイブリッド材料への展開と展望～」
  • Place of Presentation: 船橋
• [Presentation] イオン性結晶A_2「Cr_3O(OOCC_2H_5)_6(H_2O_)_3」_2「α-SiW_<12>O_<40>」(A=Na, K, Rb, NH_4, Cs, TMA)の構造と収着特性制御 (2008)
  • Author(s): 内田さやか, レスバニアルデス, 田上英恵, 河本亮介, 水野哲孝
  • Organizer: 第88回日本化学会春季年会
  • Place of Presentation: 東京
  • Year and Date: 2008-03-27
• [Presentation] ポリオキソメタレート化合物の合成, 構造と収着特性制御 (2008)
  • Author(s): 内田さやか, レスバニアルデス, 河本亮介, 田上英恵, 水野哲孝
  • Organizer: 第102回触媒討論会
  • Place of Presentation: 名古屋
• [Presentation] イオン性結晶A2[Cr3O(OOCC2H5)6 (H2O)3]2[α-SiW12O40] (A = Na, K, Rb, NH4, Cs, TMA)の構造と収着特性制御 (2008)
  • Author(s): 内田さやか, レスバニアルデス, 田上英恵, 河本亮介, 水野哲孝
  • Organizer: 第88回日本化学会春季年会
  • Place of Presentation: 東京
• [Presentation] Construction of Nano-Space by Arrangements of Macrocation-Polyoxo metalate (2007)
  • Author(s): S. Uchida, N. Mizuno
  • Organizer: 3rd International Symposium on Chemistry of Coordination Space
  • Place of Presentation: Awaji, Japan
  • Year and Date: 2007-12-11
• [Presentation] 分子の貯蔵・分離,変換場となるイオン性結晶の創製 (2007)
  • Author(s): 内田さやか, 水野哲孝
  • Organizer: 第57回錯体化学討論会シンポジウム「エネルギー・物質変換を志向した錯体化学の未来」
  • Place of Presentation: 名古屋
  • Year and Date: 2007-09-26
• [Presentation] イオン性結晶Rb_4「Cr_3O(OOCH)_6(H_2O)_3」「α-BW_<12>O_<40>」・16H_2Oの収着水の状態解明 (2007)
  • Author(s): 小笠原義之, 内田さやか, 水野哲孝
  • Organizer: 第100回触媒討論会
  • Place of Presentation: 札幌
  • Year and Date: 2007-09-19
• [Presentation] バナジウム二置換型ポリオキソメタレートを構成ブロックとしたイオン性結晶の構築とその触媒作用 (2007)
  • Author(s): 田上英恵, 内田さやか, 水野哲孝
  • Organizer: 第100回触媒討論会
  • Place of Presentation: 札幌
  • Year and Date: 2007-09-19
• [Presentation] Channel-Selective Sorption and Collection of Hydrophilic and Hydrophobic Molecules by Cs_2「Cr_3O(OOCC_2H_5)_6(H_2O)_3」_2「α-SiW_<12>O_<40>」Ionic Crystal (2007)
  • Author(s): S. Uchida, R. Kawamoto, A. Lesbani, C. Jiang, N. Mizuno
  • Organizer: 1st Asian Conference on Coordination Chemistry
  • Place of Presentation: Okazaki, Japan
  • Year and Date: 2007-07-30
• [Presentation] イオン性結晶の分子収着特性制御 (2007)
  • Author(s): 内田さやか, 河本亮介, 水野哲孝
  • Organizer: 第21回日本吸着学会
  • Place of Presentation: 東京
• [Presentation] イオン性結晶の自己組織化集合体の生成と機構解明 (2007)
  • Author(s): 内田さやか, 岡本啓吾, 伊藤建, 水野哲孝
  • Organizer: 第57回錯体化学討論会
  • Place of Presentation: 名古屋
• [Presentation] 無機イオン性結晶M3PW12O40自己組織化集合体の生成機構解明 (2007)
  • Author(s): 内田さやか, 岡本啓吾, 伊藤建, 水野哲孝
  • Organizer: 第100回触媒討論会
  • Place of Presentation: 札幌
• [Presentation] サブナノ空間を有するイオン性固体の創製 (2007)
  • Author(s): 内田さやか, 水野哲孝
  • Organizer: 錯体化学若手の会夏の学校
  • Place of Presentation: 箱根
• [Book] 細孔性ポリオキソメタレート集積体, 錯体化学選書7「超分子錯体」(藤田誠、塩谷光彦監修) (2009)
  • Author(s): 内田さやか, 水野哲孝
  • Publisher: 三共出版
• [Book] 多孔性無機錯体の合成, 配位空間の化学-最新技術と応用-(北川進監修) (2009)
  • Author(s): 内田さやか, 水野哲孝
  • Publisher: シーエムシー出版