| Budget Amount *help |
¥26,390,000 (Direct Cost: ¥20,300,000、Indirect Cost: ¥6,090,000)
Fiscal Year 2009: ¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2008: ¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2007: ¥17,290,000 (Direct Cost: ¥13,300,000、Indirect Cost: ¥3,990,000)
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| Research Abstract |
We have successfully developed a novel environmentally friendly electrolytic system based on the acid-base reactions between protic solvents or carboxylic acids as substrates and solid-supported bases. Furthermore, we have successfully applied the electrolytic system using solid-supported bases to a flow cell and parallel electrosynthesis. On the other hand, in the series of studies, we found that solid-supported bases are not oxidized at the anode. On the basis of the finding, we proposed the concept of site isolation in organic electrosynthesis. It can be defined as solid-supported reagents are not subject to electrochemical destruction at electrodes.
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