Development of a Novel Environmentally Friendly Electrolytic System Using Solid-Supported Bases and Its Application
Project/Area Number |
19685014
|
Research Category |
Grant-in-Aid for Young Scientists (A)
|
Allocation Type | Single-year Grants |
Research Field |
Environmental chemistry
|
Research Institution | Tokyo Institute of Technology |
Principal Investigator |
TAJIMA Toshiki Tokyo Institute of Technology, グローバルエッジ研究院, テニュア・トラック助教 (50361770)
|
Project Period (FY) |
2007 – 2009
|
Project Status |
Completed (Fiscal Year 2009)
|
Budget Amount *help |
¥26,390,000 (Direct Cost: ¥20,300,000、Indirect Cost: ¥6,090,000)
Fiscal Year 2009: ¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2008: ¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2007: ¥17,290,000 (Direct Cost: ¥13,300,000、Indirect Cost: ¥3,990,000)
|
Keywords | 固体塩基 / 酸塩基反応 / 電解反応システム / 電解アルコキシ化 / 電解アセトキシ化 / 電解トリフルオロアセトキシ化 / 活性点分離 / 炭素-炭素結合形成反応 / コルベ電解 / 電解メトキシ化 / パラレル雷解合成 / 非コルベ反応 / 有機電解合成 / 後続化学反応 |
Research Abstract |
We have successfully developed a novel environmentally friendly electrolytic system based on the acid-base reactions between protic solvents or carboxylic acids as substrates and solid-supported bases. Furthermore, we have successfully applied the electrolytic system using solid-supported bases to a flow cell and parallel electrosynthesis. On the other hand, in the series of studies, we found that solid-supported bases are not oxidized at the anode. On the basis of the finding, we proposed the concept of site isolation in organic electrosynthesis. It can be defined as solid-supported reagents are not subject to electrochemical destruction at electrodes.
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Report
(4 results)
Research Products
(18 results)