Ionics of Organoboron Electrolytes for Highly Selective Lithium Ion Transport

• Project/Area Number: 19685018
• Research Category: Grant-in-Aid for Young Scientists (A)
• Allocation Type: Single-year Grants
• Research Field: Functional materials/Devices
• Research Institution: Nagoya University
• Principal Investigator: MATSUMI Noriyoshi Nagoya University, 大学院・生命農学研究科, 准教授 (40323745)
• Project Period (FY): 2007 – 2009
• Project Status: Completed (Fiscal Year 2009)
• Budget Amount: ¥13,260,000 (Direct Cost: ¥10,200,000、Indirect Cost: ¥3,060,000); Fiscal Year 2009: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000); Fiscal Year 2008: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000); Fiscal Year 2007: ¥10,140,000 (Direct Cost: ¥7,800,000、Indirect Cost: ¥2,340,000)
• Keywords: リチウムイオン / 高分子電解質 / ホウ素 / イオン伝導 / 有機ホウ素化合物 / アニオンレセプター / イオン液体 / 高分子固体電解質 / ゲル電解質 / リチウムイオン二次電池 / シングルイオン伝導体 / 無機高分子

Research Abstract

A variety of organoboron electrolytes were synthesized as electrodes separator of lithium ion batteries. Their ion conductive properties were studied in detail. Novel organoboron ion-gel electrolytes were successfully prepared by condensation of cellulose with boric acids in the presence of LiOH aq. Moreover, in aim of controlling the nano-structure of ion conductive pathway, we have designed novel ion transporting matrix via self-assembly of ionic liquids.

Research Products

• [Journal Article] Synthesis of Supramoleeular Solid Polymer Electrolytes via Self-Assembly of Diborylated Ionic Liquid (2010)
  • Author(s): 松見紀佳、加賀田昭入、青井啓悟
  • Journal Title: Journal of Power Sources 195 Pages: 6182-6186
  • Peer Reviewed
• [Journal Article] Synthesis of Supramolecular Solid Polymer Electrolytes via Self-Assembly of Diborylated Ionic Liquid (2010)
  • Author(s): 松見紀佳、加賀田昭人、青井啓悟
  • Journal Title: Journal of Power Sources (印刷中)
  • Peer Reviewed
• [Journal Article] Enhanced Ionic Conduction in Organoboron Ion Gels Facilely Designed via Comdensation of Cellulose with Boric Acids in Ionic Liquids (2009)
  • Author(s): 松見紀佳、中村祐介、青井啓悟、渡辺武志、水雲智信、大野弘幸
  • Journal Title: Polymer Journal 41 Pages: 437-441
  • Peer Reviewed
• [Journal Article] Design and Evaluation of Imidazolium Cation-based Ionic Liquids Having Double-Armed Anions for Selective Cation Comduction (2009)
  • Author(s): 柴山亘、成田麻子、松見紀佳、大野弘幸
  • Journal Title: Journal of Organometallic Chemistty 694 Pages: 1642-1645
  • Peer Reviewed
• [Journal Article] Enhanced Ionic Conduction in Organoboron Ion Gels Facilely Designed via Condensation of Cellulose with Boric Acids in Ionic Liquids (2009)
  • Author(s): 松見紀佳、中村祐介、青井啓悟、渡辺武志、水雲智信、大野弘幸
  • Journal Title: Polymer Journal 41 Pages: 437-441
  • NAID: 10025092092
  • Peer Reviewed
• [Journal Article] Design and Evaluation of Imidazolium Cation-based Ionic Liquids Having Double-Armed Anions for Selective Cation Conduction (2009)
  • Author(s): 柴山亘、成田麻子、松見紀佳、大野弘幸
  • Journal Title: Journal of Organometallic Chemistry 694 Pages: 1642-1645
  • Peer Reviewed
• [Journal Article] Enhanced Ionic Conduction in Organoboron Ion Gels Facilely Designed via Condensation of Cellulose with Boric Acids in Ionic Liquid (2009)
  • Author(s): 松見紀佳、中村祐介、青井啓悟、渡辺武志、水雲智信、大野弘幸
  • Journal Title: Polymer Journal (印刷中)
  • NAID: 10025092092
  • Peer Reviewed
• [Journal Article] Preparation of Fluoride Anion Responsive Poly (N-vinylcarbazole)-borane Complexes (2009)
  • Author(s): 松見紀佳、川口佳大、広田陽介、青井啓悟
  • Journal Title: Journal of Organometallic Chemistry 694 Pages: 1776-1779
  • Peer Reviewed
• [Journal Article] Preparation of Ion Conductive Inorganic-Organic Hybrid Systemby in-situ Sol-Gel Reaction of Polymerizable Ionic Liquid (2008)
  • Author(s): 水雲智信、渡辺武志、松見紀佳、大野弘幸
  • Journal Title: Polymer for Advanced Technology 19 Pages: 1445-1450
  • Peer Reviewed
• [Journal Article] π-Conjugated Organoboron Polymers via the Vacant p-Orbital of the Boron Atom (Review Article) (2008)
  • Author(s): 松見紀佳、中條善樹
  • Journal Title: Polymer Journal 40 Pages: 77-89
  • Peer Reviewed
• [Journal Article] Organoboron Ion Conductive Materials for Target Cation Transport (Review Article) (2007)
  • Author(s): 松見紀佳、大野弘幸
  • Journal Title: Main Group Chemistry 5 Pages: 297-307
  • Peer Reviewed
• [Presentation] Synthesis of Solid Polymer Electrolytes via Self-Assembly of Diborylated Ionic Liquid (2009)
  • Author(s): 松見紀佳、加賀田昭人、青井啓悟
  • Organizer: 4th International Conference on Polymer Batteries and Fuel Cells
  • Place of Presentation: 横浜産業貿易センター
  • Year and Date: 2009-08-03
• [Presentation] Synthesis of Solid Polymer Electrolytes via Self-assembly of Polyborylated Ionic Liquid (2009)
  • Author(s): 加賀田昭人、松見紀佳、青井啓悟
  • Organizer: 4^<th> International Conference on Polymer Batteries and Fuel Cells
  • Place of Presentation: 横浜産業貿易センター
  • Year and Date: 2009-08-03
• [Presentation] Selective Lithium Cation Transport in Organoboron Molten Salts (2008)
  • Author(s): 松見紀佳・大野弘幸
  • Organizer: IMEBORON XIII(第13回ホウ素化学国際会議)
  • Place of Presentation: プラヤデアロ(スペイン)
  • Year and Date: 2008-09-24
• [Presentation] Synthesis of Ion-gels Bearing Lithium Borate via Condensation between Cellulose and Boric Acids In Ionic Liquid (2007)
  • Author(s): 中村祐介、松見紀佳、青井啓悟、渡辺武志、水雲智信、大野弘幸
  • Organizer: 第2回イオン液体国際会議(COIL-2)
  • Place of Presentation: パシフィコ横浜
  • Year and Date: 2007-08-07
• [Presentation] Organoboron Molten Salts for Selective Lithium Cation Transport (招待講演) (2007)
  • Author(s): 松見紀佳、大野弘幸
  • Organizer: 第2回イオン液体国際会議(COIL-2)
  • Place of Presentation: パシフィコ横浜
  • Year and Date: 2007-08-07
• [Book] Macromolecules Containing Metal and Metal-Like Elements (2007)
  • Author(s): 松見紀佳、大野弘幸
  • Publisher: John Wiley & Sons, Inc.