Novel host molecule-metal ion complexes for developing artificial enzymes and their application to environmental decontamination

• Project/Area Number: 19710065
• Research Category: Grant-in-Aid for Young Scientists (B)
• Allocation Type: Single-year Grants
• Research Field: Environmental technology/Environmental materials
• Research Institution: Nagoya University
• Principal Investigator: MATSUMIYA Hiroaki Nagoya University, 大学院・工学研究科, 助教 (10362287)
• Project Period (FY): 2007 – 2008
• Project Status: Completed (Fiscal Year 2008)
• Budget Amount: ¥3,510,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥210,000); Fiscal Year 2008: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000); Fiscal Year 2007: ¥2,600,000 (Direct Cost: ¥2,600,000)
• Keywords: 複核金属錯体 / リン酸エステル / 加水分解 / 界面活性剤 / アドミセル / 起泡分離 / チアカリックスアレーン / セリウム / 複核錯体 / 気泡分離

Research Abstract

水中の汚染物質を吸着材に捕集して水質浄化し、さらに捕集した汚染物質をそのまま分解・無害化する高効率な環境浄化システムの構築を目指した。汚染物質のモデルとなる化学物質を用いた分解能力の評価および分解能力の向上、各種汚染物質の吸着材への取り込み、吸着材と浄化水の迅速な分離回収などについて、実用的システムを構築する上で基礎となる有用な知見が得られた。

Research Products

• [Journal Article] Solid-phase extraction followed by HPLC for the determination of phosphorus(V) and arsenic(V) (2009)
  • Author(s): H. Matsumiya, T. Kikai, M. Hiraide
  • Journal Title: Anal. Sci. 25(2) Pages: 207-210
  • NAID: 10025210130
  • Peer Reviewed
• [Journal Article] Solid-phase extraction followed by HPLC for the determination of phosphorus (V) and arsenic (V) (2009)
  • Author(s): Hiroaki Matsumiya, Takaaki Kikai, Masataka Hiraide
  • Journal Title: Analytical Sciences 25 Pages: 207-210
  • NAID: 10025210130
  • Peer Reviewed
• [Journal Article] Extraction of metal-APDC chelates into admicelles followed by flotation for water analysis (2007)
  • Author(s): H. Matsumiya, Y. Yatsuya, M. Hiraide
  • Journal Title: J. Ion Exchange 18(4) Pages: 378-383
  • NAID: 130004162454
  • Peer Reviewed
• [Journal Article] Admicelle-mediated collection followed by flotation for the preconcentration of trace metals in fresh waters (2007)
  • Author(s): H. Matsumiya, Y. Yatsuya, M. Hiraide
  • Journal Title: Anal. Chim. Acta 588(1) Pages: 82-87
  • Peer Reviewed
• [Journal Article] Admicelle-mediated collection followed by flotation for the pre-concentration of trace metals in fresh waters (2007)
  • Author(s): Hiroaki Matsumiya, Yosuke Yatsuya, Masataka Hiraide
  • Journal Title: Anal. Chim. Acta 588 Pages: 82-87
  • Peer Reviewed
• [Journal Article] Extraction of metal-APDC chelates into admicelles followed by flotation for water analysis (2007)
  • Author(s): Hiroaki Matsumiya, Yosuke Yatsuya, Masataka Hiraide
  • Journal Title: J. Ion Exchange 18 Pages: 378-383
  • NAID: 130004162454
  • Peer Reviewed
• [Presentation] Surfactant-mediated separation techniques for the analysis of environmental water and high-purity materials (2008)
  • Author(s): M. Hiraide, T. Saitoh, H. Matsumiya
  • Organizer: The 7th World Surfactants Congress
  • Place of Presentation: Palais des Congres (Paris, France)
• [Presentation] チアカリックスアレーン金属錯体を用いる腫瘍マーカーのイムノアッセイ (2008)
  • Author(s): 永井真二, 松宮弘明, 平出正孝
  • Organizer: 第69回分析化学討論会
  • Place of Presentation: 名古屋国際会議場(愛知県名古屋市)
• [Presentation] アドミセル-フローテーションによる水中微量元素の分離濃縮 (2008)
  • Author(s): 北方謙吾, 松宮弘明, 平出正孝
  • Organizer: 第69回分析化学討論会
  • Place of Presentation: 名古屋国際会議場(愛知県名古屋市)
• [Presentation] アドミセル吸着分離/HPLC吸光検出による鉄鋼分析 (2008)
  • Author(s): 鬼海高明, 松宮弘明, 平出正孝
  • Organizer: 第69回分析化学討論会
  • Place of Presentation: 名古屋国際会議場(愛知県名古屋市)
• [Presentation] Surfactant-mediated separation techniques for the analysis of environmental water and high-purity materials (2008)
  • Author(s): Masataka Hiraide, Tohru Saitoh, Hiroaki Matsumiya
  • Organizer: The 7 th World Surfactants Congress
  • Place of Presentation: Palais des Congres (Paris, France)
• [Presentation] Use of cerium(IV)-thiacalix[4]arene complexes for the immunoassay of tumor marker proteins (2007)
  • Author(s): S. Nagai, H. Nakamura, H. Matsumiya, M. Hiraide
  • Organizer: International Symposium on Metallomics 2007
  • Place of Presentation: 名古屋国際会議場(愛知県名古屋市)
• [Presentation] 腫瘍マーカー検出におけるチアカリックスアレーン金属錯体の利用 (2007)
  • Author(s): 永井真二, 中村紘子, 松宮弘明, 平出正孝
  • Organizer: 第38回中部化学関係学協会支部連合秋季大会
  • Place of Presentation: 三重大学(三重県津市)
• [Presentation] Extraction of metal-APDC chelates into admicelles followed by flotation for water analysis (2007)
  • Author(s): H. Matsumiya, Y. Yatsuya, M. Hiraide
  • Organizer: The 4th International Conference on Ion Exchange
  • Place of Presentation: 千葉大学(千葉県千葉市)
• [Presentation] Design and application of admicelle-mediated separation techniques for trace analysis (2007)
  • Author(s): M. Hiraide, T. Saitoh, H. Matsumiya
  • Organizer: Euroanalysis XIV
  • Place of Presentation: University of Antwerp (Antwerp, Belgium)
• [Presentation] チアカリックスアレーン金属錯体の加水分解触媒活性とそのイムノアッセイへの応用 (2007)
  • Author(s): 松宮弘明, 中村紘子, 平出正孝
  • Organizer: 第68回分析化学討論会
  • Place of Presentation: 宇都宮大学(栃木県宇都宮市)
• [Presentation] Extraction of metal-APDC chelates into admicelles followed by flotation for water analysis (2007)
  • Author(s): Hiroaki Matsumiya, Yosuke Yatsuya, Masataka Hiraide
  • Organizer: The 4th International Conference on Ion Exchange
  • Place of Presentation: Chiba University (Chiba, Japan)
• [Presentation] Use of cerium(IV)-thiacalix[4]arene complexes for the immunoassay of tumor marker proteins (2007)
  • Author(s): Shinji Nagai, Hiroko Nakamura, Hiroaki Matsumiya, Masataka Hiraide
  • Organizer: International Symposium on Metallomics 2007
  • Place of Presentation: Nagoya Congress Center (Nagoya, Japan)