Application of the internal magneticfieldof nano-size coordinati on space to create new reaction fields.
| Project/Area Number |
19710079
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Single-year Grants |
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| Research Field |
Nanostructural science
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| Research Institution | Hiroshima University |
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Principal Investigator |
AKITA Motoko Hiroshima University, 大学院・理学研究科, 助教 (30370125)
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| Project Period (FY) |
2007 – 2009
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| Project Status |
Completed (Fiscal Year 2009)
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| Budget Amount *help |
¥3,840,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥540,000)
Fiscal Year 2009: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2008: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2007: ¥1,500,000 (Direct Cost: ¥1,500,000)
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| Keywords | ナノ反応場 / 磁場効果 / 分子性磁性体 / 金属錯体 / 配位空間 / 水熱合成 / ナノ磁性空間 / 層状化合物 / 層状化合 |
|---|
| Research Abstract |
A series of layered molecular-based magnets were synthesized, and their crystal structure and magnetic properties were studied. Trisnitroxide radicals(TRs) have three ligating sites and give the 2:3 complex TR_2M(II)_3 with transition metal ions. Hydrothermal synthesis of D-, L-, and DL-amino acid with several transition metals gave a variety of molecular-based magnets which shows ferromagneism, antiferromagnetism and weak-ferromagnetism.
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Report
(4 results)
Research Products
(13 results)
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[Journal Article] Metal-Organic Frameworks from Copper Dimers with cis- and trans-1, 4-Cyclohexanedicarboxylate and cis, cis-1, 3, 5-Cyclohexanetricarboxylat 552007
Author(s)
H. Kumagai, M. Akita-Tanaka, K. Inoue, K. Takahashi, H. Kobayashi, S. Vilminot, M. Kurmoo
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Journal Title
Inorg. Chem. 46
Pages: 5949-5956
Related Report
Peer Reviewed
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