Synthesis of ordered nano-structured carbons by a organic template

• Project/Area Number: 19710093
• Research Category: Grant-in-Aid for Young Scientists (B)
• Allocation Type: Single-year Grants
• Research Field: Nanomaterials/Nanobioscience
• Research Institution: Osaka University
• Principal Investigator: NISHIYAMA Norikazu Osaka University, 大学院・基礎工学研究科, 准教授 (10283730)
• Project Period (FY): 2007 – 2009
• Project Status: Completed (Fiscal Year 2009)
• Budget Amount: ¥3,860,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥660,000); Fiscal Year 2009: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000); Fiscal Year 2008: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000); Fiscal Year 2007: ¥1,000,000 (Direct Cost: ¥1,000,000)
• Keywords: カーボン / ナノ細孔 / キャパシタ / キャパシター / キャパシタンス / 周期構造

Research Abstract

Ordered mesoporous carbons were synthesized by an organic-organic self-assembly method using resorcinol/formaldehyde and two kinds of triblock copolymers (Pluronic F127 and P123). The pore size and pore structure of the mesostructured polymers and carbons were affected by the composition of the triblock copolymers which act as soft templates. The mesoporous carbon activated with KOH showed superior capacitances. Ordered mesoporous carbon films prepared using 1,5-dihydroxynaphthalene shows higher thermal stability than the previous carbons prepared using resorcinol. Ultrathin carbon films with a monolayer of uniform mesopores were synthesized on a silicon substrate by contacting triblock copolymer films with benzyl alcohol vapor followed by carbonization.

Research Products

• [Journal Article] KOH activation of ordered mesoporous carbons prepared by a soft-templating method and their enhanced electrochemical properties (2010)
  • Author(s): Jin Jin, Shunsuke Tanaka, Yasuyuki Egashira, Norikazu Nishiyama
  • Journal Title: Carbon 48 Pages: 1985-1989
  • Peer Reviewed
• [Journal Article] Pore structure and pore size controls of ordered mesoporous carbons prepared from resorcinol/ formaldehyde/ triblock polymers (2009)
  • Author(s): Jin Jin, Norikazu Nishiyama, Yasuyuki Egashira, Korekazu Ueyama
  • Journal Title: Micropor. Mesopor. Mater. 118 Pages: 218-223
  • Peer Reviewed
• [Journal Article] Vapor phase synthesis of ultrathin carbon films with a mesoporous monolayer by a soft-templating method (2009)
  • Author(s): Jin Jin, Norikazu Nishiyama, Yasuyuki Egashira, Korekazu Ueyama
  • Journal Title: Chem. Commun. 2009(11) Pages: 1371-1373
  • Peer Reviewed
• [Journal Article] Ordered mesoporous carbon films prepared from 1, 5-dihydroxynaphthalene/ triblock copolymer composites (2009)
  • Author(s): Fidelis Hubertson Simanjuntak, Jin Jin, Norikazu Nishiyama, Yasuyuki Egashira, Korekazu Ueyama
  • Journal Title: Carbon 47 Pages: 2531-2533
  • Peer Reviewed
• [Journal Article] Ordered mesoporous carbon films prepared from 1,5-dihydroxynaphthalene/triblock copolymer composites (2009)
  • Author(s): Fidelis Hubertson Simanjuntak
  • Journal Title: Carbon 47 Pages: 2531-2533
  • Peer Reviewed
• [Journal Article] Vapor phase synthesis of ultrathin carbon films with a mesoporous monolayer by a soft-templating method (2009)
  • Author(s): Jin Jin
  • Journal Title: Chem.Commun. 2009 Pages: 1371-1373
  • Peer Reviewed
• [Journal Article] Pore structure and pore size controls of ordered mesoporous carbons prepared from resorcinol/formaldehyde/triblock polymers (2009)
  • Author(s): Jin Jin
  • Journal Title: Micropor. Mesopor. Mater 118 Pages: 218-223
  • Peer Reviewed
• [Presentation] Vapor phase synthesis of ultrathin carbon films with a mesoporous monolayer by a soft-templating method (2009)
  • Author(s): Jin Jin, Norikazu Nishiyama, Yasuyuki Egashira, Korekazu Ueyama
  • Organizer: ZMPC2009
  • Place of Presentation: Tokyo, Japan
  • Year and Date: 2009-08-03
• [Presentation] Vapor phase synthesis of ultrathin carbon films with a mesoporous monolayer by a soft-temulatine method (2009)
  • Author(s): Jin Jin
  • Organizer: ZMPC2009
  • Place of Presentation: 早稲田大学(東京都)
  • Year and Date: 2009-08-03
• [Presentation] 有機鋳型法による周期構造メソポーラス炭素の合成 (2007)
  • Author(s): 金 津
  • Organizer: 化学工学会秋季大会
  • Place of Presentation: 札幌・北海道大学
  • Year and Date: 2007-09-14