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Molecular Study of Associating Polymer Rheology

Research Project

Project/Area Number 19740259
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeSingle-year Grants
Research Field Biophysics/Chemical physics
Research InstitutionYamagata University (2008-2009)
Kyoto University (2007)

Principal Investigator

INDEI Tsutomu  Yamagata University, 大学院・理工学研究科, 研究支援員 (30420409)

Project Period (FY) 2007 – 2009
Project Status Completed (Fiscal Year 2009)
Budget Amount *help
¥3,670,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥570,000)
Fiscal Year 2009: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2008: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2007: ¥1,200,000 (Direct Cost: ¥1,200,000)
Keywords高分子 / 液晶 / 会合高分子 / レオロジー / 架橋構造 / 疎水性凝集 / 界面活性剤
Research Abstract

Rheology of associating polymer systems was theoretically studied. (1) The influence of low-molecular-weight surfactants : It was shown that the peak height appeared in the zero-shear viscosity and the relaxation time strongly depends on the synergism in the mixed micelle formation. (2) Effect of the number of associative groups per chain : It was shown that if the average number of associative groups per chain in bound state is large, viscoelastic relaxation behavior is well described in terms of the Rouse model. (3) Effect of the junction structure : Due to the cooperativity effect of the association/dissociation processes, the longest relaxation regime was shown to deviate from the Maxwell behavior depending on the length of the junction zone.

Report

(4 results)
  • 2009 Annual Research Report   Final Research Report ( PDF )
  • 2008 Annual Research Report
  • 2007 Annual Research Report
  • Research Products

    (14 results)

All 2009 2008 2007

All Journal Article (5 results) (of which Peer Reviewed: 5 results) Presentation (9 results)

  • [Journal Article] Effects of Surfactants on the Linear Rheology of Telechelic Associating Polymers2009

    • Author(s)
      Tsutomu Indei
    • Journal Title

      Progress in Colloid & Polymer Science 136

      Pages: 23-31

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Effects of Surfactants on the Linear Rheology ofTelechelic Associating Polymers2009

    • Author(s)
      Tsutomu Indei
    • Journal Title

      Progress in Colloid & Polymer Science 136

      Pages: 23-31

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Effects of Surfactants on the Linear Rheology of Telechelic Associating Polymers2009

    • Author(s)
      印出井努
    • Journal Title

      Progress in Colloid & Polymer Science (印刷中)

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Rheological study of transient networks with junctions of limited multiplicity. II. Sol/gel transition and rheology2007

    • Author(s)
      Tsutomu Indei
    • Journal Title

      Journal of Chemical Physics 127

      Pages: 144905-144905

    • Related Report
      2009 Final Research Report 2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Rheological study of transient networks with junctions of limited multiplicity2007

    • Author(s)
      Tsutomu Indei
    • Journal Title

      Journal of Chemical Physics 127

      Pages: 144904-144904

    • Related Report
      2009 Final Research Report 2007 Annual Research Report
    • Peer Reviewed
  • [Presentation] 複数の会合基を持つ高分子の粘弾性2009

    • Author(s)
      印出井努・滝本淳一
    • Organizer
      第57回レオロジー討論会
    • Place of Presentation
      宇部全日空ホテル(宇部市)
    • Year and Date
      2009-10-05
    • Related Report
      2009 Annual Research Report 2009 Final Research Report
  • [Presentation] テレケリック会合高分子の線形・非線形粘弾性2009

    • Author(s)
      印出井努
    • Organizer
      第58回高分子討論会
    • Place of Presentation
      熊本大学(熊本市)
    • Year and Date
      2009-09-18
    • Related Report
      2009 Annual Research Report 2009 Final Research Report
  • [Presentation] 界面活性剤が会合高分子ネットワークのレオロジーに及ぼす効果2008

    • Author(s)
      印出井努
    • Organizer
      田中豊一記念シンポジウム
    • Place of Presentation
      アルカディア市ヶ谷(千代田区)
    • Year and Date
      2008-09-12
    • Related Report
      2009 Final Research Report 2008 Annual Research Report
  • [Presentation] テレケリック会合高分子の粘弾性-界面活性剤添加の効果-2008

    • Author(s)
      印出井努
    • Organizer
      第二回ソフトマター物理若手勉強会
    • Place of Presentation
      東京大学(文京区)
    • Year and Date
      2008-08-21
    • Related Report
      2009 Final Research Report 2008 Annual Research Report
  • [Presentation] Rheological Study of Transient Gels with Junctions of Limitted Multiplicity2008

    • Author(s)
      印出井努
    • Organizer
      International Symposium on Non-Equilibrium Soft Matter
    • Place of Presentation
      京都大学(京都市)
    • Year and Date
      2008-06-02
    • Related Report
      2009 Final Research Report 2008 Annual Research Report
  • [Presentation] 会合高分子の線形粘弾性におよぼす界面活性剤の効果II2008

    • Author(s)
      印出井努
    • Organizer
      日本物理学会第63回年次大会
    • Place of Presentation
      近畿大学(東大阪市)
    • Year and Date
      2008-03-25
    • Related Report
      2009 Final Research Report 2007 Annual Research Report
  • [Presentation] 界面活性剤が会合高分子ゲルの線型粘弾性におよぼす効果2007

    • Author(s)
      印出井努
    • Organizer
      第55回レオロジー討論会
    • Place of Presentation
      金沢大学(金沢市)
    • Year and Date
      2007-11-02
    • Related Report
      2009 Final Research Report 2007 Annual Research Report
  • [Presentation] 会合高分子の線形粘弾性に及ぼす界面活性剤の効果2007

    • Author(s)
      印出井努
    • Organizer
      日本物理学会第62回年次大会
    • Place of Presentation
      北海道大学(札幌市)
    • Year and Date
      2007-09-24
    • Related Report
      2009 Final Research Report 2007 Annual Research Report
  • [Presentation] テレケリック高分子のゾル・ゲル転移と粘弾性2007

    • Author(s)
      印出井努
    • Organizer
      第56回高分子学会年次大会
    • Place of Presentation
      京都国際会館(京都市)
    • Year and Date
      2007-05-31
    • Related Report
      2009 Final Research Report 2007 Annual Research Report

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Published: 2007-04-01   Modified: 2016-04-21  

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