Ultrafast spectroscopy of a single molecule using a light-coupled scanning tunneling microscopy light emission

• Project/Area Number: 19750001
• Research Category: Grant-in-Aid for Young Scientists (B)
• Allocation Type: Single-year Grants
• Research Field: Physical chemistry
• Research Institution: Tohoku University
• Principal Investigator: KATANO Satoshi Tohoku University, 電気通信研究所, 助教 (00373291)
• Project Period (FY): 2007 – 2008
• Project Status: Completed (Fiscal Year 2008)
• Budget Amount: ¥3,570,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥270,000); Fiscal Year 2008: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000); Fiscal Year 2007: ¥2,400,000 (Direct Cost: ¥2,400,000)
• Keywords: 走査トンネル顕微鏡 / トンネル発光 / 高速分光 / 単一分子化学 / 分子エレクトロニクス

Research Abstract

走査トンネル顕微鏡(STM)は、試料表面の原子構造の観察だけでなく、探針と試料間の電位制御により個々の原子・分子の分光が可能である。しかしながら、トンネル電流を検出する装置上の制約により、STMの時間分解能はせいぜい数十ミリ秒程度に限られている。本研究では、従来のSTM装置に高い時間分解能を有するレーザー光を組み合わせたトンネル顕微鏡を構築することを目的とした。単一ナノ構造および有機分子を用いた自己組織化単分子膜構造の形成過程を明らかにし、それらの局所領域における動的過程を明らかにすることができた。

Research Products

• [Journal Article] Effect of the Substituent Position on the Molecular Assembly : The Hydrogen-bonded Arrangement of Aminobenzoates Adsorbed on Cu(110) (2009)
  • Author(s): S. Katano, M. Hori, C. Rabot, Y. Kim and M. Kawai
  • Journal Title: Japanese Journal of Applied Physics 48(In press)
  • NAID: 210000067322
  • Peer Reviewed
• [Journal Article] Self-assembly of meta-aminobenzoate on Cu(110) (2009)
  • Author(s): C. Rabot, M. Hori, S. Katano, Y. Kim and M. Kawai
  • Journal Title: Langmuir 25 Pages: 5504-5508
  • Peer Reviewed
• [Journal Article] Self-assembly of meta-aminobenzoate on Cu(110) (2009)
  • Author(s): Caroline Rabot, 他
  • Journal Title: Langmuir (印刷中)
  • Peer Reviewed
• [Journal Article] Effect of the Substituent on the Molecular Assembly : The Hydrogen-bonded Arrangement of Aminobenzoate Adsorbed on Cu(110) (2009)
  • Author(s): Satoshi Katano, 他
  • Journal Title: Japanese Journal of Applied Physics (印刷中)
  • Peer Reviewed
• [Journal Article] Time-Resolved Spectroscopy of Laser-Induced Light Emission from an Evaporated Au Film in the Kretschmann Geometry (2008)
  • Author(s): T. Sanbongi, S. Katano, Y. Uehara and S. Ushioda
  • Journal Title: Japanese Journal of Applied Physics, 47 Pages: 6114-6116
  • Peer Reviewed
• [Journal Article] Self Assembly and STM Tip-induced Motion of Ferrocene Adamantane Trithiolate Adsorbed on Au(111) (2008)
  • Author(s): S. Katano Y. Kim, T. Kitagawa and M. Kawai
  • Journal Title: Japanese Journal of Applied Physics, 47 Pages: 6156-6159
  • Peer Reviewed
• [Journal Article] Surface Diffusion and Interaction of Metastable Formate on Ni(110) Investigated by Low-Temperature Scanning Tunneling Microscopy (2008)
  • Author(s): S. Katano Y. Kim, Y. Kagata and M. Kawai
  • Journal Title: Chemistry Letters 37 Pages: 914-915
  • NAID: 10024282026
  • Peer Reviewed
• [Journal Article] Partial Hydrogenation of 1,3-Butadiene on Hydrogen-Precovered Pd(110) in the Balance of pi-bonded C4 Hydrocarbon Reactions (2008)
  • Author(s): S. Katano, H. S. Kato, M. Kawai and K. Domen
  • Journal Title: Journal of Physical Chemistry C 112 Pages: 17219-17224
  • Peer Reviewed
• [Journal Article] Effect of the Substituent on Metal-Molecule Hybridization (2008)
  • Author(s): M. Hori, S. Katano, Y. Kim and M. Kawai
  • Journal Title: Surface Science 602 Pages: 3140-3143
  • Peer Reviewed
• [Journal Article] Time-Resolved Spectroscopy of Laser-Indliced Light Emission from an Evaporated Au Film in the Kretschmann Geometry (2008)
  • Author(s): Tomonori Sanbongi, 他
  • Journal Title: Japanese Journal of Applied Physics 47 Pages: 6114-6116
  • Peer Reviewed
• [Journal Article] Self Assembly and STM Tip-induced Motion of Ferrocene Adamantane rithiolate Adsorbed on Au(111) (2008)
  • Author(s): Satoshi Katano, 他
  • Journal Title: Japanese Journal of Applied Physics 47 Pages: 6156-6159
  • Peer Reviewed
• [Journal Article] Surface Diffusion and Interaction of Metastable Formate on Ni(110) estigated by Low-Temperature Scanning Tunneling Microscopy (2008)
  • Author(s): Satoshi Katano, 他
  • Journal Title: Chemistry Letters 37 Pages: 914-915
  • Peer Reviewed
• [Journal Article] Effect of the Substituent on Metal-molecule hybridization (2008)
  • Author(s): Masafumi Hori, 他
  • Journal Title: Surface Science 602 Pages: 3140-3143
  • Peer Reviewed
• [Journal Article] Partial Hydrogenation of 1, 3-Butadiene on Hydrogen-Precovered Pd (110) in the Balance of pi-bonded C4 Hydrocarbon Reactions (2008)
  • Author(s): Satoshi Katano, 他
  • Journal Title: Journal of Physical Chemistry C 112 Pages: 17219-17224
  • Peer Reviewed
• [Journal Article] Time-Resolved Spectroscopy of Laser-Induced Light Emission from an Evaporated Au Film in the Kretschmann Geometry (2008)
  • Author(s): Tomonori Sanbongi, 他
  • Journal Title: Japanese Journal of Applied Physics (印刷中)
  • Peer Reviewed
• [Journal Article] Effect of the Substituent on Metal-molecule hybridization (2008)
  • Author(s): Masafumi Hori, 他
  • Journal Title: Surface Science (印刷中)
  • Peer Reviewed
• [Journal Article] Hierarchical Chiral Framework Based on a Rigid Adamantane Tripod on Au(111) (2007)
  • Author(s): S. Katano, Y. Kim, H. Matsubara, T. Kitagawa and M. Kawai
  • Journal Title: Journal of the American Chemical Society 129 Pages: 2511-2515
  • Peer Reviewed
• [Journal Article] Reversible Control of Hydrogenation of a Single Molecule (2007)
  • Author(s): S. Katano, Y. Kim, M. Hori, M Trenary and M. Kawai
  • Journal Title: Science 316 Pages: 1883-1886
  • Peer Reviewed
• [Journal Article] Geometrical characterization of adenine and guanine on Cu(110) by NEXAFS, XPS, and DFT calculation (2007)
  • Author(s): M. Furukawa, T. Yamada, S. Katano, M. Kawai, H. Ogasawara and A. Nilsson
  • Journal Title: Surface Science 601 Pages: 5433-5440
  • Peer Reviewed
• [Journal Article] Reversible Control of Hydrogenation of a Single Molecule (2007)
  • Author(s): Satoshi Katano, 他
  • Journal Title: Science 316 Pages: 1883-1886
  • Peer Reviewed
• [Journal Article] Hierarchical Chiral Framework Based on a Rigid Adamantane Tripod on Au (111) (2007)
  • Author(s): Satoshi Katano, 他
  • Journal Title: Journal of the American Chemical Society 129 Pages: 2511-2515
  • Peer Reviewed
• [Journal Article] Geometrical characterization of adenine and guanine on Cu (110) by NEXAFS, XPS, and DFT calculation (2007)
  • Author(s): Masashi Furukawa, 他
  • Journal Title: Surface Science 601 Pages: 5433-5440
  • Peer Reviewed
• [Presentation] ピコ秒の時間分解能と原子位置分解能を併せ持つ光学計測法の開発 (2009)
  • Author(s): 上原洋一,三本木智則,片野諭,坂本謙二,潮田資勝
  • Organizer: 2009年春季第56回応用物理学関係連合講演会
  • Place of Presentation: 筑波大学,つくば市
  • Year and Date: 2009-03-30
• [Presentation] Ge_2Sb_2Te_5およびSb_2Te_3薄膜のSTM発光測定 (2009)
  • Author(s): 桑原正史,上原洋一,片野諭
  • Organizer: 2009年春季第56回応用物理学関係連合講演会
  • Place of Presentation: 筑波大学,つくば市
  • Year and Date: 2009-03-30
• [Presentation] ピコ秒の時間分解能と原子位置分解能を併せ持つ光学計測法の開発 (2009)
  • Author(s): 上原洋一, 他
  • Organizer: 第56回応用物理学関係連合講演会
  • Place of Presentation: 筑波大学
  • Year and Date: 2009-03-30
• [Presentation] Ge2Sb2Te5およびSb2Te3薄膜のSTM発光測定 (2009)
  • Author(s): 桑原正史, 他
  • Organizer: 第56回応用物理学関係連合講演会
  • Place of Presentation: 筑波大学
  • Year and Date: 2009-03-30
• [Presentation] Ge_2Sb_2Te_5とSb_2Te_3のSTM発光分光 (2009)
  • Author(s): 片野諭,上原洋一,桑原正史,潮田資勝
  • Organizer: 第64回年次大会(春)日本物理学会
  • Place of Presentation: 立教大学,東京都
  • Year and Date: 2009-03-29
• [Presentation] ピコ秒レーザー照射下のSTM発光スペクトル (2009)
  • Author(s): 上原洋一,三本木智則,片野諭,潮田資勝
  • Organizer: 第64回年次大会(春)日本物理学会
  • Place of Presentation: 立教大学,東京都
  • Year and Date: 2009-03-29
• [Presentation] ピコ秒レーザー照射下のSTM発光スペクトル (2009)
  • Author(s): 上原洋一, 他
  • Organizer: 第64回年次大会(春)日本物理学会
  • Place of Presentation: 立教大学
  • Year and Date: 2009-03-29
• [Presentation] Ge2Sb2Te5とSb2Te3のSTM発光分光 (2009)
  • Author(s): 片野諭, 他
  • Organizer: 第64回年次大会(春)日本物理学会
  • Place of Presentation: 立教大学
  • Year and Date: 2009-03-29
• [Presentation] 走査トンネル顕微鏡を用いた金属表面における水素原子拡散の局所観察 (2009)
  • Author(s): 片野諭,金有沫,川合真紀
  • Organizer: 第89春季年会日本化学会
  • Place of Presentation: 日本大学,船橋市
  • Year and Date: 2009-03-28
• [Presentation] 走査トンネル顕微鏡を用いた金属表面における水素原子拡散の局所観察 (2009)
  • Author(s): 片野諭, 他
  • Organizer: 第89春季年会日本化学会
  • Place of Presentation: 日本大学
  • Year and Date: 2009-03-28
• [Presentation] Quantum Diffusion of Hydrogen Atoms on Ni(110) Studied by Scanning Tunneling Microscopy (2009)
  • Author(s): S. Katano, Y. Kim, M. Kawai and Y. Uehara
  • Organizer: The 4th International Symposium on Medical, Bio- and Nano-Electronics
  • Place of Presentation: Tohoku University, Sendai, Japan
  • Year and Date: 2009-03-05
• [Presentation] Quantum Diffusion of Hydrogen Atoms on Ni (110)Studied by Scanning Tunneling Microscony (2009)
  • Author(s): Satoshi Katano, 他
  • Organizer: The 4th International Symposium on Medical, Bio-and Nano-Electronics
  • Place of Presentation: Tohoku University, Sendai
  • Year and Date: 2009-03-05
• [Presentation] 走査トンネル顕微鏡で探る金属表面に吸着した水素原子のトンネル拡散(招待講演) (2009)
  • Author(s): 片野諭
  • Organizer: 東北大学多元物質科学研究所・先端計測開発センター主催先端計測シンポジウム09-走査プローブ顕微鏡分光の最前線-
  • Place of Presentation: 東北大学多元物質科学研究所,仙台
  • Year and Date: 2009-02-13
• [Presentation] 走査トンネル顕微鏡で探る金属表面に吸着した水素原子のトンネル拡散 (2009)
  • Author(s): 片野諭他
  • Organizer: 先端計測シンポジウム09-走査プローブ顕微鏡分光の最前線-
  • Place of Presentation: 東北大学(招待講演)
  • Year and Date: 2009-02-13
• [Presentation] 単一分子ダイナミクスの開拓(招待講演) (2009)
  • Author(s): 片野諭
  • Organizer: 独創する若手研究者の融合-表面・界面が創成する融合科学,平成20年度東北大国際高等研究教育機構研究会第55回応用物理学関係連合講演会
  • Place of Presentation: 片平さくらホール,東北大学,仙台
  • Year and Date: 2009-01-15
• [Presentation] 単一分子ダイナミクスの開拓 (2009)
  • Author(s): 片野諭他
  • Organizer: 独創する若手研究者の融合-表面・界面が創成する融合科学, 平成20年度東北大国際高等研究教育機構研究会
  • Place of Presentation: 東北大学(招待講演)
  • Year and Date: 2009-01-15
• [Presentation] Geometrical Control of Aminobenzoate Adsorbed on Cu(110) Using Benzoate Template (2008)
  • Author(s): S. Katano, M. Hori, Y. Kim and M. Kawai
  • Organizer: The 16th international colloquium on scanning probe microscopy (ICSPM16)
  • Place of Presentation: Atagawa House, Shizuoka, Japan
  • Year and Date: 2008-12-11
• [Presentation] Light Emission Spectroscopy of Single-Walled Carbon Nanotube Adsorbed on Au(111) Studied by Scanning Tunneling Microscopy (2008)
  • Author(s): S. Katano, S. Hayashi, and Y. Uehara
  • Organizer: The 16th international colloquium on scanning probe microscopy (ICSPM16)
  • Place of Presentation: Atagawa House, Shizuoka, Japan
  • Year and Date: 2008-12-11
• [Presentation] Light Emission Spectroscopy of Single-Walled Carbon Nanotube Adsorbed on Au(111) Studied by Scanning Tunneling Microscopy (2008)
  • Author(s): Satoshi Katano, 他
  • Organizer: The 16th international colloquium on scanning probe microscopy (ICSPM16)
  • Place of Presentation: Atagawa House, Shizuoka
  • Year and Date: 2008-12-11
• [Presentation] Geometrical Control of Aminobenzoate Adsorbed on Cu(110) Using Benzoate Template (2008)
  • Author(s): Satoshi Katano, 他
  • Organizer: The 16th international colloquium on scanning probe microscopy (ICSPM16)
  • Place of Presentation: Atagawa House, Shizuoka
  • Year and Date: 2008-12-11
• [Presentation] Defect Creation and Light Emission Spectroscopy of Single-Walled Carbon Nanotube Adsorbed on Au(111) Studied by Scanning Tunneling Microscopy (2008)
  • Author(s): S. Katano, S. Hayashi, and Y. Uehara
  • Organizer: International Symposium on Surface Science and Nanotechnology 5 (ISSS5)
  • Place of Presentation: Waseda University, Japan
  • Year and Date: 2008-11-11
• [Presentation] Defect Creation and Light Emission Spectroscopy of Single-Walled Carbon Nanotube Adsorbed on Au(111) Studied by Scanning Tunneling Microscopy (2008)
  • Author(s): Satoshi Katano, 他
  • Organizer: International Symposium on Surface Science and Nanotechnology 5(ISSS5)
  • Place of Presentation: Waseda University, Tokyo
  • Year and Date: 2008-11-11
• [Presentation] Self-assembly of meta-aminobenzoate on Cu(110) investigated with scanning tunneling microscopy and X-ray absorption spectroscopy (2008)
  • Author(s): C. Rabot, M. Hori, S. Katano, S. Doi, Y. Kim, M. Kawai, Y. Takata, J. Miyawaki, and S. Shin
  • Organizer: International Symposium on Surface Science and Nanotechnology 5 (ISSS5)
  • Place of Presentation: Waseda University, Japan
  • Year and Date: 2008-11-10
• [Presentation] Self-assembly of meta-aminobenzoate on Cu(110) investigated with scanning tunneling microscopy and X-ray absorption spectroscopy (2008)
  • Author(s): Caroline Rabot, 他
  • Organizer: International Symposium on Surface Science and Nanotechnology 5(ISSS5)
  • Place of Presentation: Waseda University, Tokyo
  • Year and Date: 2008-11-10
• [Presentation] ナローギャップ半導体Ge_2Sb_2Te_5のSTM発光分光 (2008)
  • Author(s): 片野諭,上原洋一,桑原止史,潮田資勝
  • Organizer: 第2回東北大学光科学技術フォーラム
  • Place of Presentation: 東北大学,仙台市
  • Year and Date: 2008-11-06
• [Presentation] ナローギャップ半導体Ge2Sb2Te5の STM発光分光 (2008)
  • Author(s): 片野諭他
  • Organizer: 第2回東北大学光科学技術フォーラム
  • Place of Presentation: 東北大学
  • Year and Date: 2008-11-06
• [Presentation] ナノスケールにおける水素原子の表面拡散およびマニピュレーション (2008)
  • Author(s): 片野 諭,金 有洙,川合 眞紀
  • Organizer: 第2回分子科学討論会
  • Place of Presentation: 福岡国際会議場,福岡市
  • Year and Date: 2008-09-27
• [Presentation] ナノスケールにおける水素原子の表面拡散およびマニピュレーション (2008)
  • Author(s): 片野諭他
  • Organizer: 第2回分子科学討論会
  • Place of Presentation: 福岡国際会議場
  • Year and Date: 2008-09-27
• [Presentation] Superstructures of meta-aminobenzoate on Cu(110) investigated with scanning tunneling microscopy and X-ray absorption spectroscopy Rabot Caroline (2008)
  • Author(s): 土肥 真路,宮脇 淳,高田 恭孝,堀 雅史,片野 諭,金 有洙,辛 埴,川合 眞紀
  • Organizer: 第2回分子科学討論会
  • Place of Presentation: 福岡国際会議場,福岡市
  • Year and Date: 2008-09-26
• [Presentation] Superstructures of meta-aminobenzoate on Cu (110) investigated with scanning tunneling microscopy and X-rav absorption spectroscopy (2008)
  • Author(s): Caroline Rabot, 他
  • Organizer: 第2回分子科学討論会
  • Place of Presentation: 福岡国際会議場
  • Year and Date: 2008-09-26
• [Presentation] Anisotropic Surface Diffusion of Hydrogen atoms on Ni(110) Studied by Scanning Tunneling Microscopy (2008)
  • Author(s): S. Katano, Y. Kim, and M. Kawai
  • Organizer: 25th European Conference on Surface Science, (ECOSS 25)
  • Place of Presentation: University of Liverpool, UK
  • Year and Date: 2008-07-28
• [Presentation] Anisotropic Surface Diffusion of Hydrogen atoms on Ni (110) Studied by Scanning Tunneling Microscopy (2008)
  • Author(s): Satoshi Katano, 他
  • Organizer: 25th European Conference on Surface Science, (ECOSS 25)
  • Place of Presentation: University of Liverpool, UK
  • Year and Date: 2008-07-28
• [Presentation] 走査トンネル顕微鏡による水素原子の微視的な表面拡散過程の解明(招待講演) (2008)
  • Author(s): 片野諭,金有洙,川合眞紀
  • Organizer: 第55回応用物理学関係連合講演会
  • Place of Presentation: 日本大学,船橋市
  • Year and Date: 2008-03-28
• [Presentation] 走査トンネル顕微鏡による水素原子の微視的な表面拡散過程の解明 (2008)
  • Author(s): 片野 諭, 他
  • Organizer: 第55回応用物理関連連合講演会
  • Place of Presentation: 日本大学
  • Year and Date: 2008-03-28
• [Presentation] 完全に孤立した金属微粒子のSTM発光分光 (2008)
  • Author(s): 道又淳一,片野諭,上原洋一,潮田資勝
  • Organizer: 第63回日本物理学会年次大会
  • Place of Presentation: 近畿大学,東大阪市
  • Year and Date: 2008-03-23
• [Presentation] 完全に孤立した金属微粒子のSTM発光分光 (2008)
  • Author(s): 道又 淳一, 他
  • Organizer: 第63回日本物理学会年次大会
  • Place of Presentation: 近畿大学
  • Year and Date: 2008-03-23
• [Presentation] Hierarchical Chiral Framework Based on a Rigid Adamantane Tripod on Au(111) (2007)
  • Author(s): S.Katano, Y. Kim, T. Kitagawa and M. Kawai
  • Organizer: The 15th international colloquium on scanning probe microscopy (ICSPM15)
  • Place of Presentation: Atagawa House, Shizuoka, Japan
  • Year and Date: 2007-12-06
• [Presentation] Time-resolved two photon light emission spectroscopy of gold thin film (2007)
  • Author(s): T. Sanbongi, S. Katano, Y. Uehara and S. Ushioda
  • Organizer: The 15th international colloquium on scanning probe microscopy (ICSPM15)
  • Place of Presentation: Atagawa House, Shizuoka, Japan
  • Year and Date: 2007-12-06
• [Presentation] Time-resolved two photon light emission spectroscopy of gold thin film (2007)
  • Author(s): Tomonori Sanbongi, 他
  • Organizer: The 15th international colloquium on scanning probe microscopy
  • Place of Presentation: Atagawa House
  • Year and Date: 2007-12-06
• [Presentation] Hierarchical Chiral Framework Based on a Rigid Adamantane Tripod on Au (111) (2007)
  • Author(s): Satoshi Katano, 他
  • Organizer: The 15th international colloquium on scanning probe microscopy
  • Place of Presentation: Atagawa House
  • Year and Date: 2007-12-06
• [Presentation] Single molecule chemistry using scanning tunneling microscope (invited) (2007)
  • Author(s): S. Katano
  • Organizer: International Workshop on Nanostructure and Nanoelectronics
  • Place of Presentation: Tohoku University, Sendai
  • Year and Date: 2007-11-21
• [Presentation] 金薄膜の2光子励起可視発光 (2007)
  • Author(s): 三本木 智則, 他
  • Organizer: 第1回分子科学討論会
  • Place of Presentation: 東北大学
  • Year and Date: 2007-09-17
• [Presentation] 剛直分子により形成された自己組織化単分子膜のキラル構造および電子状態の制御 (2007)
  • Author(s): 片野 諭, 他
  • Organizer: 第1回分子科学討論会
  • Place of Presentation: 東北大学
  • Year and Date: 2007-09-17
• [Presentation] Cu(110)表面状に吸着したCO分子のSTM誘起拡散機構 (2007)
  • Author(s): 金 有洙, 他
  • Organizer: 第1回分子科学討論会
  • Place of Presentation: 東北大学
  • Year and Date: 2007-09-17
• [Presentation] Ni(110)表面における水素原子対のトンネル拡散 (2007)
  • Author(s): 片野 諭, 他
  • Organizer: 第68回応用物理関連連合講演会
  • Place of Presentation: 北海道工業大学
  • Year and Date: 2007-09-07
• [Presentation] Ni (110)-(2X1) O表面の探針増強ラマン分光 (2007)
  • Author(s): 平田 侑治, 他
  • Organizer: 第68回応用物理関連連合講演会
  • Place of Presentation: 北海道工業大学
  • Year and Date: 2007-09-07