Development and application of reversible addition reaction of endohedral metallofullerenes

• Project/Area Number: 19750027
• Research Category: Grant-in-Aid for Young Scientists (B)
• Allocation Type: Single-year Grants
• Research Field: Organic chemistry
• Research Institution: Tokyo Gakugei University
• Principal Investigator: MAEDA Yutaka Tokyo Gakugei University, 教育学部, 准教授 (10345324)
• Co-Investigator(Renkei-kenkyūsha): AKASAKA Takeshi 筑波大学, 先端学際領域研究センター, 教授 (60089810)
• Project Period (FY): 2007 – 2008
• Project Status: Completed (Fiscal Year 2008)
• Budget Amount: ¥3,700,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥300,000); Fiscal Year 2008: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000); Fiscal Year 2007: ¥2,400,000 (Direct Cost: ¥2,400,000)
• Keywords: フラーレン / 金属内包フラーレン / 可逆付加反応 / 付加反応

Research Abstract

金属内包フラーレンおよびフラーレンに対し、ジエン、カルベン、ラジカル種等を用いた化学反応を検討したところ、種々の対応する付加体の合成に成功した。付加体のキャラクタリゼーションを行い、新規誘導体の構造と特性の評価を試みた。ジエンを鍵とする、金属内包フラーレンの可逆付加反応系の構築を目的とし、研究を推進したところ、1)高い位置選択性で付加反応が進行すること、2)化学反応性を用いるジエンの置換基にて制御し得ること、3)結晶構造解析にて構造を決定し、フラーレンケージの歪みおよび電荷密度が高選択的付加反応の因子であること、4)結晶中において、付加体のスピン密度によってはダイマー構造をとること、を明らかにした。さらに、世界に先駆けて異なる2つの官能基を高い位置選択性で金属内包フラーレンに導入することに成功し、金属内包フラーレンを核とする三分子系機能性分子の構築に向けたモデルを提案することができた。

Research Products

• [Journal Article] Radical Coupling Reaction of Parama gnetic Endohedral Metallofullerene La@C82 (2008)
  • Author(s): Y. Takano, A. Yomogida, H. N ikawa, M. Yamada, T. Wakahara, T. T suchiya, M. O. Ishitsuka, Y. Maeda, T. Akasaka, T. Kato, Z. Slanina, N. Mizorogi, S. Nagase
  • Journal Title: J. Am. Chem. Soc. 130 Pages: 16224-16230
• [Journal Article] Does Gd@C82 Have an Anomalous Endohe dral Structure? Synthesis and Singl e Crystal X-ray Structure of the Ca rbene Adduct (2008)
  • Author(s): T. Akasaka, T. Kono, Y. Takematsu, H. Nikawa, T. Nakahod o, T. Wakahara, M. O. Ishitsuka, T. Tsuchiya, Y. Maeda, M. T. H. Liu, K. Yoza, T. Kato, K. Yamamoto, N. M izorogi, Z. Slanina, S. Nagase
  • Journal Title: J. Am. Chem. Soc. 130 Pages: 12840-12841
• [Journal Article] Chemical Understanding of a Non-IPR Metallofullerene: Stabilization of Encaged Metals on Fused-pentagon B onds in La2@C72 (2008)
  • Author(s): X. Lu, H. Nikawa, T. Nakahodo, T. Tsuchiya, M. O. Ishit suka, Y. Maeda, T. Akasaka, M. Toki, H. Sawa, Z. Slanina, N. Mizorogi, S. Nagase
  • Journal Title: J. Am. Chem. Soc. 130 Pages: 9129-9136
• [Journal Article] Metal Atoms Collinear with the Spir o Carbon of 6,6-Open Adducts, M2@C80 (Ad) (M = La and Ce, Ad = Adamantyl idene) (2008)
  • Author(s): M. Yamada, C. Someya, T. Wa kahara, T. Tsuchiya, Y. Maeda, T. A kasaka, K. Yoza, E. Horn, M. T. H. Liu, N. Mizorogi, S. Nagase
  • Journal Title: J. Am. Chem. Soc. 130 Pages: 1171-1176
• [Journal Article] Addition of Adamantylidene to La2@C 78: Isolation and Single-Crystal Xray Structural Determination of the Monoadducts (2008)
  • Author(s): B. Cao, H. Nikawa, T. Nakahodo, T. Tsuchiya, Y. Maeda, T. Akasaka, H. Sawa, Z. Slanina, N. M izorogi, S. Nagase
  • Journal Title: J. Am. Chem. Soc. 130 Pages: 983-989
• [Journal Article] Nanorods of Endohedral Metallofulle rene Derivative (2008)
  • Author(s): T. Tsuchiya, R. Ku mashiro, K. Tanigaki, Y. Matsunaga, M. O. Ishitsuka, T. Wakahara, Y. M aeda, Y. Takano, M. Aoyagi, T. Akas aka, M. T. H. Liu, T. Kato, K. Suen aga, J. S. Jeong, S. Iijima, F. Kim ura, T. Kimura, S. Nagase
  • Journal Title: J. Am. Chem. Soc. 130 Pages: 450-451
• [Journal Article] Bis-carbene Adducts of Non-IPR La2@ C72: Localization of High Reactivity around Fused-pentagons and Toward Controllable Tuning of Electrochemi cal Properties of Metallofullerenes (2008)
  • Author(s): X. Lu, H. Nikawa, T. Tsuchiya, Y. Maeda, M. O. Ishitsuka, T. Akasaka, M. Toki, H. Sawa, Z. Slanina, N. M izorogi, S. Nagase
  • Journal Title: Angew. Chem. Int. Ed. 47 Pages: 8642-8645
• [Journal Article] Observation of 13C NMR Chemical Shifts of Metal Carbides Encapsulated in Fullerenes: Sc2C2@C82, Sc2C2@C84, and Sc3C2@C80 (2008)
  • Author(s): Y. Yamazaki, K. Nakajima, T. Wakahara, T. Tsuchiya, M. O. Ishitsuka, Y. Maeda, T. Akasaka, M. Waelchili, N. Mizorogi, S. Nagase
  • Journal Title: Angew. Chem. Int. Ed. 47 Pages: 7905-7908
• [Journal Article] [2+1]-Cycloaddition of Nitrene onto C60 Revisited: Interconversion between Aziridinofullerene and Azafulleroid (2008)
  • Author(s): T. Nakahodo, M. Okada, H. Morita, T. Yoshimura, M. O. Ishitsuka, T. Tsuchiya, Y. Maeda, H. Fujihara, T. Akasaka, X. Gao, S. Nagase
  • Journal Title: Angew. Chem. Int. Ed. 47 Pages: 1298-1300
• [Journal Article] Location of the Metal Atoms in Ce2@C78 and its Bis-silylated Derivative (2008)
  • Author(s): M. Yamada, T. Wakahara, T. Tsuchiya, Y. Maeda, M. Kako, T. Akasaka, K. Yoza, E. Horn, N. Mizorogi, S. Nagase
  • Journal Title: Chem. Commun. Pages: 558-560
• [Journal Article] Spectroscopic and Theoretical Study of Endohedral Dimetallofullerene Having a Non-IPR Fullerene Cage: Ce2@C72 (2008)
  • Author(s): M. Yamada, T. Wakahara, T. Tsuchiya, Y. Maeda, T. Akasaka, N. Mizorogi, S. Nagase
  • Journal Title: J. Phys. Chem. A 112 Pages: 7627-7631
• [Journal Article] Isolation and Characterization of Carbene Derivatives of La@C82(Cs) (2008)
  • Author(s): T. Akasaka, T. Kono, Y. Matsunaga, T. Wakahara, T. Nakahodo, M. O. Ishitsuka, Y. Maeda, T. Tsuchiya, T. Kato, M. T. H. Liu, N. Mizorogi, Z. Slanina, S. Nagase
  • Journal Title: J. Phys. Chem. A 112 Pages: 1294-1297
• [Journal Article] Synthesis of Selenylfullerene with Selenium-containing Dibenzo[b, g]cyclooctane Moiety (2008)
  • Author(s): T. Nakahodo, K. Takahashi, M. O. Ishitsuka, T. Tsuchiya, Y. Maeda, H. Fujihara, S. Nagase, T. Akasaka
  • Journal Title: Tetrahedron Lett. 49 Pages: 2302-2305
• [Journal Article] Radical Coupling Reaction of Paramagnetic Endohedral Metallofullerene La@C82 (2008)
  • Author(s): Y. Takano, A. Yomogida, H. Nikawa, M. Yamada, T. Wakahara, T. Tsuchiya, M. O. Ishitsuka, Y. Maeda, T. Akasaka, T. Kato, Z. Slanina, N. Mizorogi, S. Nagase
  • Journal Title: J. Am. Chem. Soc 130 Pages: 16224-16230
  • NAID: 130004645465
  • Peer Reviewed
• [Journal Article] Chemical Understanding of a Non-IPR Metallofullerene : Stabilization of Encaged Metals on Fused-Pentagon Bonds in La2@C72 (2008)
  • Author(s): X. Lu, H. Nikawa, T. Nakahodo, T. Tsuchiya, M. O. Ishitsuka, Y. Maeda, T. Akasaka, M. Told, H. Sawa, Z. Slanina, N. Mizorogi, S
  • Journal Title: J. Am. Chem. Soc 130 Pages: 9129-9136
  • Peer Reviewed
• [Journal Article] Addition of Adamantylidene to La2@C78 Isolation and Single-Crystal X-ray Structural Determination of the Monoadducts (2008)
  • Author(s): B. Cao, H. Nikawa, T. Nakahodo, T. Tsuchiya, Y. Maeda, T. Akasaka, H. Sawa, Z. Slanina, N. Mizorogi, S. Nagase
  • Journal Title: Am. Chem. Soc 130 Pages: 983-989
  • Peer Reviewed
• [Journal Article] Metal Atoms Collinear with the Spiro Carbon of 6,6-Open Adducts, M2@C80(Ad)(M)La and Ce, Ad)Adamantylidene) (2008)
  • Author(s): M., Yamada, C. Someya, T. Wakahara, T. Tsuchiya, Y. Maeda, T. Akasaka, K. Yoza, E. Horn, M. T. H. Liu, N. Mizorogi, S. Nagase
  • Journal Title: J. Am. Chem. Soc 130 Pages: 1171-1176
  • Peer Reviewed
• [Journal Article] Does Gd@C82 Have an Anomalous Endohedral Structure? Synthesis and Single Crystal X-ray Structure of the Carbene Adduct (2008)
  • Author(s): T. Akasaka, T. Kono, Y. Takematsu, H. Nikawa, T. Nakahodo, T. Wakahara, M. 0. Ishitsuka, T. Tsuchiya, Y. Maeda, M. T. H. Liu, K. Yoza, T. Kato, K. Yamamoto, N. Mizorogi, Z. Slanina, S. Nagase Slanina, Shigeru Nagase
  • Journal Title: J. Am. Chem. Soc 130 Pages: 12840-12841
  • Peer Reviewed
• [Journal Article] Nanorods of Endohedral Metallofullerene Derivative (2008)
  • Author(s): T. Tsuchiya, R. Kumashiro, K. Tanigaki, Y. Matsunaga, M. O. Ishitsuka, T. Wakahara, Y. Maeda, Y. Takano, M. Aoyagi, T. Akasaka, M. T. H. Liu, T. Kato, K. Suenaga, J. S. Jeong, S. Iijima, F. Kimura, T. Kimura, S. Nagase
  • Journal Title: J. Am. Chem. Soc 130 Pages: 450-451
  • Peer Reviewed
• [Journal Article] Bis-Carbene Adducts of Non-IPR La2@C72 : Localization of HighReactivity around Fused Pentagons and Electrochemical Properties (2008)
  • Author(s): X. Lu, H. Nikawa, T. Tsuchiya, Y. Maeda, M. O. Ishitsuka, T. Akasaka, M. Toki, H. Sawa, Z. Slanina, N. Mizorogi, S. Nagase
  • Journal Title: Angew. Chem. Int, Ed 47 Pages: 8642-8645
  • Peer Reviewed
• [Journal Article] [2+1] Cycloaddition of Nitrene onto C60 Revisited : Interconversion between an Aziridinofullerene and an Azafulleroid (2008)
  • Author(s): T. Nakahodo, M. Okada, H. Morita, T. Yoshimura, M. O. Ishitsuka, T. Tsuchiya, Y. Maeda, H. Fujihara, T. Akasaka, X. Gao, S. Nagase
  • Journal Title: Angew. Chem. Int. Ed 47 Pages: 1298-1300
  • Peer Reviewed
• [Journal Article] Observation of 13C NMR Chemical Shifts of Metal Carbides Encapsulated in Fullerenes : Sc2C2@C82, Sc2C2@C84, and Sc3C2@C80 (2008)
  • Author(s): Y. Yamazaki, K. Nakajima, T. Wakahara, T. Tsuchiya, M. O. Ishitsuka, Y. Maeda, T. Akasaka, M. Waelchili, N. Mizorogi, S. Nagase
  • Journal Title: Angew. Chem. Int. Ed 47 Pages: 7905-7908
  • Peer Reviewed
• [Journal Article] Location of the metal atoms in Ce2@C78 and its bis-silylated derivative (2008)
  • Author(s): M. Yamada, T. Wakahara, T. Tsuchiya, Y. Maeda, M. Kako, T. Akasaka, K. Yoza, E. Horn, N. Mizorogi, S. Nagase
  • Journal Title: ChemComm Pages: 558-560
  • Peer Reviewed
• [Journal Article] Spectroscopic and Theoretical Study of Endohedral Dimetallofullerene Having a Non-IPR Fullerene Cage : Ce2@C72 (2008)
  • Author(s): M. Yamada, T. Wakahara, T. Tsuchiya, Y. Maeda, T. Akasaka, N. Mizorogi, S. Nagase
  • Journal Title: J. Phys. Chem. A 112 Pages: 7627-7631
  • Peer Reviewed
• [Journal Article] Synthesis of selenylfullerene with selenium-containing dibenzo[b, g]cyclooctane moiety (2008)
  • Author(s): T. Nakahodo, K. Takahashi, M. O. Ishitsuka, T. Tsuchiya, Y. Maeda, H. Fujihara, S. Nagase, T. Akasaka
  • Journal Title: Tetrahedron Letters 49 Pages: 2302-2305
  • Peer Reviewed
• [Journal Article] Experimental and Theoretical Studie s of the Scandium Carbide Endohedral Metallofullerene Sc2C2@C82 and Its Carbene Derivative (2007)
  • Author(s): Y. Iiduka, T. Wakahara, K. Nakajima, T. Nakahodo, T. Tsuchiya, Y. Maeda, T. Akasaka, K. Yoza, M. T. H. Liu, N. Mizorogi, S. Nagase
  • Journal Title: Angew. Chem. Int. Ed. 46 Pages: 5562-5564
• [Journal Article] Two-dimensional Hopping Motion of Encapsulated La Atoms in Silylated La2@C80 (2007)
  • Author(s): T. Wakahara, M. Yamada, S. Takahashi, T. Nakahodo, T. Tsuchiya, Y. Maeda, T. Akasaka, M. Kako, K. Yoza, E. Horn, N. Mizorogi, S. Nagase
  • Journal Title: Chem. Commun. Pages: 2680-2682
• [Journal Article] Experimental and theoretical Studies of the Studies of the Scandium Caribide Endhedral Metall ofullerene S_c2C_2@C_82and Its Carbene Derivative (2007)
  • Author(s): Y. liduka, T. Wakahara, K. Nakajima, T. Nakahodo, T.Maeda, T. Akasaka, K. Yoza, M. T. H. Liu, N. Mizorogi, S. Nagase
  • Journal Title: Angew. Chem. Int. Ed. 46 Pages: 5562-5564
  • Peer Reviewed
• [Journal Article] Two-dimensional Hopping Motion of Encapsulated La Atoms in Silylated La_2@C_80 (2007)
  • Author(s): T. Wakahara, M. Yamada, S. Takahashi, T. Nakahodo, T. Tsuchiya, Y. Maeda, T. Akasada, M. Kako, K. Yoza, E. Horn, N. Mizorogi, S. Nagase
  • Journal Title: Chem. Commun. Pages: 2680-2682
  • Peer Reviewed
• [Presentation] 2 つの異なる置換基によるLa@C82の化学修飾のおける位置選択性 (2009)
  • Author(s): 佐藤 悟・前田 優・稲田 浩二・山田 道夫・土屋敬広・石塚 みどり・長谷川 正・赤阪 健・加藤 立久・溝呂木 直美・Zdenek, Slanina・永瀬 茂
  • Organizer: 日本化学会第89 回春季年会
  • Place of Presentation: 船橋
• [Presentation] 常磁性金属内包フラーレンLa@C82 におけるラジカルカップリング反応 (2009)
  • Author(s): 高野 勇太・蓬田 知行・二川 秀史・若原 孝次・土屋 敬広・石塚 みどり・前田 優・赤阪 健・加藤 立久・スラニナ ズデネク・溝呂木 直美・永瀬 茂
  • Organizer: 日本化学会第89 回春季年会
  • Place of Presentation: 船橋
• [Presentation] Synthesis and Characterization of Sc@C82 Derivatives (2009)
  • Author(s): M. Hachiya, Y. Yamazaki, M. O. Ishitusuka, T. Tsuchiya, Y. Maeda, T. Akasaka, N. Mizorogi, S. Nagase
  • Organizer: プレ戦略イニシアティブ「機能分子創成研究拠点」シンポジウム
  • Place of Presentation: つくば
• [Presentation] Unconventional Bingel adducts of the open-shell metallofullerene La@C82 (2009)
  • Author(s): L. Feng, T. Tsuchiya, T. Wakahara, T. Nakahodo, Q. Piao, Y. Maeda, T. Akasaka, T. Kato, K. Yoza, E. Horn, N. Mizorogi, S. Nagase
  • Organizer: プレ戦略イニシアティブ「機能分子創成研究拠点」シンポジウム
  • Place of Presentation: つくば
• [Presentation] Reversible Addition Reaction of Endohedral Metallofullerene La@C82 (2009)
  • Author(s): S. Sato, Y. Maeda, K. Inada, H. Nikawa, M. Yamada, N. Mizorogi, T. Hasegawa, T. Tsuchiya, T. Akasaka, T. Kato, Z. Slanina, S. Nagase
  • Organizer: プレ戦略イニシアティブ「機能分子創成研究拠点」シンポジウム
  • Place of Presentation: つくば
• [Presentation] Radical Coupling Reaction of Parama gnetic Endohedral Metallofullerene La@C82 (2009)
  • Author(s): Y. Takano, A. Yomogida, H. Nikawa, T. Wakahara, T. Tsuchiya, M. O. Ishitsuka, Y. Maeda, T. Akasaka, T. Kato, Z. Slanina, N. Mizorogi, S. Nagase
  • Organizer: The 2nd International Symposium on Interdisciplinary Material Science (ISIMS-2009)
  • Place of Presentation: Tsukuba, Japan
• [Presentation] Reversible Addition Reaction of Endohedral Metallofullerene La@C82 (2009)
  • Author(s): S. Sato, Y. Maeda, K. Inada, H. Nikawa, M. Yamada, N. Mizorogi, T. Hasegawa, T. Tsuchiya, T. Akasaka, T. Kato, Z. Slanina, S. Nagase
  • Organizer: he 2nd International Symposium on Interdisciplinary Material Science (ISIMS-2009)
  • Place of Presentation: Tsukuba, Japan
• [Presentation] Reversible Addition Reaction of Endohedral Metallofullerene La@Cs2 (2009)
  • Author(s): S. Sato, Y. Maeda, K. Inada, H. Nikawa, M. Yamada, N. Mizorc T. Hasegawa, T. Tsuchiya, T. Akasaka, T. Kato, Z. Slanina, S. Nagase
  • Organizer: The 2^<nd> International Symposium on Interdisciplinary Material Science(ISIMS-2009)
  • Place of Presentation: EPOCHAL TSUKUBA, Tsukuba, Japan
• [Presentation] Radical Coupling Reaction of Paramagnetic Endohedral Metallofullerene La@C_<82> (2009)
  • Author(s): Y. Takano, A. Yomogida, H. Nikawa, T. Wakahara, T. Tsuchiya, M. O. Ishitsuka, Y. Maeda, T. Akasaka, T. Kato, Z. Slanina, N. Mizorogi, S. Nagase
  • Organizer: The 2^<nd> International Symposium on Interdisciplinary Material Science(ISIMS-2009)
  • Place of Presentation: EPOCHAL TSUKUBA, Tsukuba, Japan
• [Presentation] 2つの異なる置換基によるLa@C_<82>の化学修飾のおける位置選択性 (2009)
  • Author(s): 佐藤悟・前田優・稲田浩二・山田道夫・土屋敬広・石塚みどり・長谷川正・赤阪健・加藤立久・溝呂木直美・Zdenek, Slanina・永瀬茂
  • Organizer: 日本化学会第89回春季年会
  • Place of Presentation: 日本大学理工学部船橋キャンパス, 船橋
• [Presentation] 常磁性金属内包フラーレンLa@C_<82>におけるラジカルカップリング反応 (2009)
  • Author(s): 高野勇太・蓬田知行・二川秀史・若原孝次・土屋敬広・石塚みどり・前田優・赤阪健・加藤立久・スラニナズデネク・溝呂木直美・永瀬茂
  • Organizer: 日本化学会第89回春季年会
  • Place of Presentation: 日本大学理工学部船橋キャンパス, 船橋
• [Presentation] Synthesis and Characterization of Sc@C_<82> Derivatives (2009)
  • Author(s): M. Hachiya, Y. Yamazaki, M. O Ishitusuka, T. Tsuchiya, Y Maeda, T. Akasaka, N. Mizorogi, S. Nagase
  • Organizer: プレ戦略イニシアティブ「機能分子創成研究拠点」シンポジウム
  • Place of Presentation: つくば国際会議場, つくば
• [Presentation] Unconventional Bingel adducts of the open-shell metallofullerene La@C_<82> (2009)
  • Author(s): L. Feng, T. Tsuchiya, T. Wakahara, T. Nakahodo, Q. Piao, Y. Maeda, T. Akasaka, T. Kato, K. Yoza, E. Horn, N. Mizoxogi, S. Nagase
  • Organizer: プレ戦略イニシアティブ「機能分子創成研究拠点」シンポジウム
  • Place of Presentation: つくば国際会議場, つくば
• [Presentation] Reversible Addition Reaction of Endohedral Metallofullerene La@C_<82> (2009)
  • Author(s): S. Sato, Y. Maeda, K. Inada, H. Ni kawa, M. Yamada, N. Mizorogi, T. Hasegawa, T. Tsuchiya, T. Akasaka, T. Kato, Z. Slanina, S. Nagase
  • Organizer: プレ戦略イニシアティブ「機能分子創成研究拠点」シンポジウム
  • Place of Presentation: つくば国際会議場, つくば
• [Presentation] Deils-Alder Reaction of Endohedral Metallorullerene La@C_<82> (2008)
  • Author(s): 佐藤悟・前田優・稲田浩司・山田道夫・土屋敬広・長谷川正・赤阪健・加藤立久・講呂木直美・永瀬茂
  • Organizer: 日本化学会第88春季年会
  • Place of Presentation: 立教大学 池袋
  • Year and Date: 2008-03-28
• [Presentation] La@C_<82>とシククロペンダジエン誘導体の反応 (2008)
  • Author(s): 佐藤悟・前田優・稲田浩司・長谷川正・劫山田道夫・土屋敬広・赤阪健・加藤立久・講呂木直美・永瀬茂
  • Organizer: 第34回フラーレン・ナノチューブ総合シンポジウム
  • Place of Presentation: 名城大学 名古屋
  • Year and Date: 2008-03-03
• [Presentation] Reversible Addition Reaction of Endohedral Metallofullerene La@C82 (2008)
  • Author(s): S. Sato, Y. Maeda, K. Inada, M. Yamada, T. Tsuchiya, M. O. Ishitsuka, T. Hasegawa, T. Akasaka, T. Kato, N. Mizorogi, S. Nagase
  • Organizer: PRiME 2008 (Pacific Rim Meeting, 214th ECS Meeting)
  • Place of Presentation: Honolulu, USA.
• [Presentation] 常磁性金属内包フラーレンLa@C82 におけるラジカルカップリング反応 (2008)
  • Author(s): 高野勇太・蓬田知行・二川秀史・若原孝次・土屋敬広・生沼みどり・前田 優・赤阪 健・加藤立久・Zdenek Slanina・溝呂木 直美・永瀬 茂
  • Organizer: 第19 回基礎有機化学討論会
  • Place of Presentation: 吹田市
• [Presentation] 金属内包フラーレンLa@C82 の可逆反応 (2008)
  • Author(s): 佐藤 悟・前田 優・稲田浩司・山田道夫・土屋敬広・生沼みどり・長谷川 正・赤阪 健・加藤立久・溝呂木直美・Zdenek Slanina・永瀬 茂
  • Organizer: 第19 回基礎有機化学討論会
  • Place of Presentation: 吹田市
• [Presentation] 金属内包フラーレンLa@C82 の可逆付加反応 (2008)
  • Author(s): 佐藤 悟・前田 優・稲田浩司・山田道夫・土屋敬広・生沼みどり・長谷川 正・赤阪 健・加藤立久・溝呂木直美・永瀬 茂
  • Organizer: 第2回日本化学会関東支部大会
  • Place of Presentation: 桐生市
• [Presentation] Sc@C82 とその誘導体の合成と物性解明 (2008)
  • Author(s): 蜂屋 誠・山崎裕子・土屋敬広・前田 優・赤阪 健・溝呂木直美・永瀬 茂
  • Organizer: 第2回日本化学会関東支部大会、桐生市
  • Place of Presentation: 桐生市
• [Presentation] Radical Coupling Reaction of Paramagnetic Endohedral Metallofullerene La@C82 (2008)
  • Author(s): Y. Takano, A. Yomogida, H. Nikawa, T. Wakahara, T. Tsuchiya, M. O. Ishitsuka, Y. Maeda, T. Akasaka, T. Kato, Z. Slanina, N. Mizorogi, S. Nagase
  • Organizer: 第35 回記念フラーレン・ナノチューブ総合シンポジウム
  • Place of Presentation: 東京
• [Presentation] Bis-carbene Derivatives of a Non-IPR Metallofullerene: La2@C72 (2008)
  • Author(s): X. Lu, H. Nikawa, M. O. Ishitsuka, T. Tsuchiya, Y. Maeda, T. Akasaka, Z. Slanina, N. Mizorogi, S. Nagase
  • Organizer: 第35 回記念フラーレン・ナノチューブ総合シンポジウム
  • Place of Presentation: 東京
• [Presentation] Reversible and Regioselective Reaction of La@C82 with 1,2,3,4,5-Pentamethylcyclopentadiene (2008)
  • Author(s): S. Sato, Y. Maeda, K. Inada, M. Yamada, T. Tsuchiya, M. O. Ishitsuka, T. Hasegawa, T. Akasaka, T. Kato, N. Mizorogi, Z. Slanina, S. Nagase
  • Organizer: 第35 回記念フラーレン・ナノチューブ総合シンポジウム
  • Place of Presentation: 東京
• [Presentation] Positional Control of Encapsulated Atoms Inside a Fullerene Cage by Exohedral Chemical Functionalization (2008)
  • Author(s): M. Yamada, C. Someya, T. Wakahara, T. Tsuchiya, T. Akasaka, Y. Maeda, K. Yoza, N. Mizorogi, S. Nagase
  • Organizer: 213th ECS Meeting
  • Place of Presentation: Phoenix, USA
• [Presentation] La@C82 とシクロペンタジエン誘導体の反応 (2008)
  • Author(s): 佐藤悟・前田優・稲田浩司・長谷川正・山田道夫・土屋敬広・赤阪健・加藤立久・溝呂木直美・永瀬茂
  • Organizer: 第34 回フラーレン・ナノチューブ総合シンポジウム
  • Place of Presentation: 名古屋
• [Presentation] Diels-Alder Reaction of Endohedral Metallofullerene La@C82 (2008)
  • Author(s): 佐藤悟・前田優・稲田浩司・山田道夫・土屋敬広・長谷川正・赤阪健・加藤立久・溝呂木直美・永瀬茂
  • Organizer: 日本化学会第88 春季年会
  • Place of Presentation: 池袋
• [Presentation] Reversible Addition Reaction of Endohedral Metallofullerene La@C_82 (2008)
  • Author(s): S. Sato, Y. Maeda, K. Inada, M. Yamada, T. Tsuchiya, M. O. Ishitsuka, T. Hasegawa,. T. Akasaka, T. Kato, N. Mizorogi, S. Nagase
  • Organizer: PRiME 2008(Pacific Rim Meeting, 214th ECS Meeting)
  • Place of Presentation: Hilton Hawaiian Village, Honolulu, USA
• [Presentation] Reversible and Regioselective Reaction of La@C_82 with 1, 2, 3, 4, 5-Pentamethylcyclopentadiene (2008)
  • Author(s): S. Sato, Y. Maeda, K. Inada, M. Yamada, T. Tsuchiya, M. O. Ishitsuka, T. Hasegawa, T. Akasaka, T. Kato, N. Mizorogi, Z. Slanina, S. Nagase
  • Organizer: 第35回記念フラーレン・ナノチューブ総合シンポジウム
  • Place of Presentation: 東京工業大学, 東京
• [Presentation] Positional Control of Encapsulated Atoms Inside a Fullerene Cage by Exohedral Chemical Functionalization (2008)
  • Author(s): M. Yamada, C. Someya, T. Wakahara, T. Tsuchiya, T. Akasaka, Y. Maeda, K. Yoza, N. Mizorogi, S. Nagase
  • Organizer: 213th ECS Meeting
  • Place of Presentation: Phoenix Convention Center, Phoenix, USA
• [Presentation] 常磁性金属内包フラーレンLa@C_<82>におけるラジヵルカップリング反応 (2008)
  • Author(s): 高野勇太・蓬田知行.二川秀史・若原孝次・土屋敬広・生沼みどり・前田優・赤阪健・加藤立久・Zdenek Slanina・溝呂木直美・永瀬茂
  • Organizer: 第19回基礎有機化学討論会
  • Place of Presentation: 大阪大学コンベンションセンター, 吹田市
• [Presentation] 金属内包フラーレンLa@C82の可逆反応 (2008)
  • Author(s): 佐藤悟・前田優・稲田浩司・山田道夫・土屋敬広・生沼みどり・長谷川正・赤阪健・加藤立久・溝呂木直美・Zdenek Slanina・永瀬茂
  • Organizer: 第19回基礎有機化学討論会
  • Place of Presentation: 大阪大学コンベンションセンター, 吹田市
• [Presentation] 金属内包フラーレンLa@C_<82>の可逆付加反応 (2008)
  • Author(s): 佐藤悟・前田優・稲田浩司・山田道夫・土屋敬広・生沼みどり・長谷川正・赤阪健・加藤立久・溝呂木直美・永瀬茂
  • Organizer: 第2回日本化学会関東支部大会
  • Place of Presentation: 群馬大学桐生キャンパス, 桐生市
• [Presentation] Sc@C_<82>とその誘導体の合成と物性解明 (2008)
  • Author(s): 蜂屋誠・山崎裕子・土屋敬広・前田優・赤阪健・溝呂木直美・永瀬茂
  • Organizer: 第2回日本化学会関東支部大会
  • Place of Presentation: 群馬大学桐生キャンパス, 桐生市
• [Presentation] Radical Coupling Reaction of Paramagnetic Endohedral Metallofullerene La@C_<82> (2008)
  • Author(s): Y. Takano, A. Yomogida, H. Nikawa, T. Wakahara, T. Tsuchiya, M. O. Ishitsuka, Y. Maeda, T. Akasaka, T. Kato, Z. Slanina, N. Mizorogi, S. Nagase
  • Organizer: 第35回記念フラーレン・ナノチューブ総合シンポジウム
  • Place of Presentation: 東京工業大学, 東京
• [Presentation] Bis-carbene Derivatives of a Non-IPR Metallofullerene : La_2@C_<72> (2008)
  • Author(s): X. Lu, H. Nikawa, M. O. Ishitsuka, T. Tsuchiya, Y. Maeda, T. Akasaka, Z. Slanina, N. Mizorogi, S. Nagase
  • Organizer: 第35回記念フラーレン・ナノチューブ総合シンポジウム
  • Place of Presentation: 東京工業大学, 東京
• [Presentation] La@C_<82>とシククロペンダジエン誘導体の可逆反応 (2007)
  • Author(s): 佐藤悟・前田優・稲田浩司・長谷川正・劫山田道夫・土屋敬広・赤阪健・加藤立久・講呂木直美・永瀬茂
  • Organizer: 第18回日本化学会関東支部茨城地区研究交流会
  • Place of Presentation: 水戸市民会館 水戸
  • Year and Date: 2007-11-30
• [Presentation] La@C_<82>とシクロペンダジエン誘導体の可逆付加反応 (2007)
  • Author(s): 佐藤悟・前田優・稲田浩司・長谷川正・劫山田道夫・土屋敬広・赤阪健・加藤立久・講呂木直美・永瀬茂
  • Organizer: 第57回有機反応化学討論会
  • Place of Presentation: 広島大学 東広島
  • Year and Date: 2007-09-30
• [Presentation] La@C_<82>とシククロペンダジエン誘導体の可逆反応 (2007)
  • Author(s): 佐藤悟・前田優・稲田浩司・長谷川正・山地道夫・土屋敬広・赤阪健・加藤立久・講呂木直美・永瀬茂
  • Organizer: 日本化学会第1回関東支部大会
  • Place of Presentation: 首都大学東京 八王子
  • Year and Date: 2007-09-28
• [Presentation] Regioselective reaction of La@C_<82> (2007)
  • Author(s): Yutaka Maeda, Tadashi Hasegawa, TakTsuchiya, _2 tkatsugu Wakahara, TaAkasaka, Tatsuhisa Kato, Shigeru Nagas
  • Organizer: ISNA12th
  • Place of Presentation: 淡路夢舞台国際会議場淡路
  • Year and Date: 2007-07-24
• [Presentation] La@C_<82>とシクロペンダジエン誘導体の可逆反応 (2007)
  • Author(s): 佐藤悟・前田優・稲田浩司・長谷川正・山田道夫・土屋敬広・赤阪健・加藤立久・講呂木直美・永瀬茂
  • Organizer: 第33回フラーレン・ナノチューブ総合シンポジウム
  • Place of Presentation: 九州大学 福岡
  • Year and Date: 2007-07-13
• [Presentation] La@C82 とシクロペンタジエン誘導体の可逆反応 (2007)
  • Author(s): 佐藤悟・前田優・稲田浩司・長谷川正・山田道夫・土屋敬広・赤阪健・加藤立久・溝呂木直美・永瀬茂
  • Organizer: 第18 回日本化学会関東支部茨城地区研究交流会
  • Place of Presentation: 水戸
• [Presentation] La@C82 とシクロペンタジエン誘導体の可逆反応 (2007)
  • Author(s): 佐藤悟・前田優・稲田浩司・長谷川正・山田道夫・土屋敬広・赤阪健・加藤立久・溝呂木直美・永瀬茂
  • Organizer: 日本化学会第1回関東支部大会
  • Place of Presentation: 八王子
• [Presentation] La@C82 とシクロペンタジエン誘導体の可逆付加反応 (2007)
  • Author(s): 佐藤悟・前田優・稲田浩司・長谷川正・山田道夫・土屋敬広・赤阪健・加藤立久・溝呂木直美・永瀬茂
  • Organizer: 第57 回有機反応化学討論会
  • Place of Presentation: 東広島
• [Presentation] La@C82 とシクロペンタジエン誘導体の可逆反応 (2007)
  • Author(s): 佐藤悟・前田優・稲田浩司・長谷川正・山田道夫・土屋敬広・赤阪健・加藤立久・溝呂木直美・永瀬茂
  • Organizer: 第33 回フラーレン・ナノチューブ総合シンポ ジウム
  • Place of Presentation: 福岡
• [Presentation] Regioselective reaction of La@C82 (2007)
  • Author(s): Yutaka Maeda, Tadashi Hasegawa, Takahiro Tsuchiya, TakatsuguWakahara, Takeshi Akasaka, Tatsuhisa Kato,Shigeru Nagase
  • Organizer: ISNA12th
  • Place of Presentation: 淡路