Structural Tuning and Template Effect of Surface Nanospace by using Planer π-Conjugated Molecules

• Project/Area Number: 19750033
• Research Category: Grant-in-Aid for Young Scientists (B)
• Allocation Type: Single-year Grants
• Research Field: Organic chemistry
• Research Institution: Osaka University
• Principal Investigator: TAHARA Kazukuni Osaka University, 大学院・基礎工学研究科, 助教 (40432463)
• Project Period (FY): 2007 – 2009
• Project Status: Completed (Fiscal Year 2009)
• Budget Amount: ¥3,900,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥600,000); Fiscal Year 2009: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000); Fiscal Year 2008: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000); Fiscal Year 2007: ¥1,300,000 (Direct Cost: ¥1,300,000)
• Keywords: 自己組織化 / 走査型プローブ顕微鏡 / 有機化学 / 表面・界面物性 / 固液界面 / 走査プローブ顕微鏡

Research Abstract

To the surface nanospace of 2D porous molecular network formed by π-conjugated molecules at a liquid/solid interface, we investigated an expansion by insertion of spacer molecule, fixation via covalent bonding by chemical reaction on the surface, and formation of multi-component alignment by guest co-adsorption. As a result, in the former two projects, important results toward the final goal of these projects were obtained. We also achieved the construction of multi-component alignment. These results are very important for the development in field of nanotechnology.

Research Products

• [Journal Article] 2D Networks of Rhombic-Shaped Fused Dehydrobenzo[12]annulenes: Structural Variations under Concentration Control (2009)
  • Author(s): Tahara, K., Okuhata, S., Adisoejoso, J., Lei, S., Fujita, T., De Feyter, S., Tobe, Y.
  • Journal Title: J. Am. Chem. Soc. 131 Pages: 17583-17590
  • Peer Reviewed
• [Journal Article] 2D Crystal Engineering: a Four-Component Archtecture at a Liquid-Solid Interface (2009)
  • Author(s): Adisoejoso, J., Tahara, K., Okuhata, S., Lei, S., Tobe, Y., De Feyter, S.
  • Journal Title: Angew. Chem. Int. Ed. 48 Pages: 7353-7357
  • Peer Reviewed
• [Journal Article] Two-Dimensional Crystal Engineering : A Four-Component Architecture at a Liquid-Solid Interface (2009)
  • Author(s): Jinne Adisoejoso, et al.
  • Journal Title: Angewandte Chemie International Edition 48 Pages: 7353-7357
  • Peer Reviewed
• [Journal Article] 有機分子を固体表面に並べて作る幾何学模様 (2009)
  • Author(s): 戸部義人
  • Journal Title: 機能材料 29 Pages: 6-15
• [Journal Article] Programmable Hierarchical Three-Component 2D Assembly at a Liquid-Solid Interface: Recognition, Selection, and Transformation (2008)
  • Author(s): Lei, S., Surin, M., Tahara, K., Adisoejoso, J., Lazzaroni, R., Tobe, Y., De Feyter, S.
  • Journal Title: Nano Lett. 8 Pages: 2541-2546
  • Peer Reviewed
• [Journal Article] Giant Molecular Wheels in Giant Voids; Two-Dimensional Molecular Self-Assembly Goes Big (2008)
  • Author(s): Tahara, K., Lei, S., Mossinger, D., Kozuma, S., Inukai, K., De Schryver, F.C., Hoger, S., Tobe, Y., De Feyer, S.
  • Journal Title: Chem. Commun. Pages: 3897-3899
  • Peer Reviewed
• [Journal Article] Molecular Clusters in Two-Dimensional Surface-Confined Nanoporous Molecular Networks: Structure Rigidity and Dynamics (2008)
  • Author(s): Lei, S., Tahara, K., Feng, X., Furukawa, S., De Schryver, F.C., Mullen, K., Tobe, Y., De Feyter, S.
  • Journal Title: J. Am. Chem. Soc. 130 Pages: 7119-7129
  • Peer Reviewed
• [Journal Article] Site-Selective Guest Inclusion in Molecular Networks of Butadiyne-Bridged Pyridino and Benzo Square Macorcycles on a Surface (2008)
  • Author(s): Tahara, K., Lei, S., Mamdouh, W., Yamaguchi, Y., Ichikawa, T., Uji-i, H., Sonoda, M., Hirose, K., De Schryver, F.C., De Feyter, S., Tobe, Y.
  • Journal Title: J. Am. Chem. Soc. 130 Pages: 7119-7129
  • Peer Reviewed
• [Journal Article] One Building Block, Two Different Supramolecular Surface-Confined Patterns: Concentration in Control at the Solid/liquid Interface (2008)
  • Author(s): Lei, S., Tahara, K., De Schryver, F.C., Van der Auweraer, M., Tobe, Y., De Feyter, S.
  • Journal Title: Angew. Chem. Int. Ed. 47 Pages: 2964-2968
  • Peer Reviewed
• [Journal Article] Site-Selective Guest Inclusion in Molecular Networks of Butadiyne-Bridged Pyridino and Benzeno Square Macrocycles on a Surface (2008)
  • Author(s): Tahara Kazukuni, et.al.
  • Journal Title: Journal of American Chemical Society 130 Pages: 6666-6667
  • Peer Reviewed
• [Journal Article] Molecular Clusters in Two-Dimensional Surface-Confined Nanoporous Molecular Networks : Structure, Rigidity, and Dynamics (2008)
  • Author(s): Lei Shengbin, et.al.
  • Journal Title: Journal of American Chemical Society 130 Pages: 7119-7129
  • Peer Reviewed
• [Journal Article] Giant Molecular Spoked Wheels in Giant Voids : Two-Dimensional Molecular Self-Assembly Goes Big (2008)
  • Author(s): Tahara Kazukuni, et.al.
  • Journal Title: Chemical Communication Pages: 3897-3899
  • Peer Reviewed
• [Journal Article] One Building Block, Two Different Supramolecular Surface-Confined Patterns: Concentration in Control at the Solid/liquid Interface (2008)
  • Author(s): Lei. S., et. al.
  • Journal Title: Angew. Chem. Int. Ed. In press
  • Peer Reviewed
• [Presentation] アゾベンゼン部位を含むデヒドロベンゾ[12]アヌレン誘導体の多孔性2次元ネットワーク:ゲスト共吸着に及ぼすアゾベンゼン部位の影響 (2010)
  • Author(s): 犬飼晃司, 田原一邦, Steven De Feyter, 戸部義人
  • Organizer: 日本化学会第90春季年会
  • Place of Presentation: 東大阪
  • Year and Date: 2010-03-26
• [Presentation] ブタジイン架橋四角形マクロサイクルのモジュール式分子ネットワーク形成 (2010)
  • Author(s): 後藤田潤, 田原一邦, Steven De Feyter, 戸部義人
  • Organizer: 日本化学会第90春季年会
  • Place of Presentation: 東大阪
  • Year and Date: 2010-03-26
• [Presentation] 2D Crystal Engineering : a Four-Component Architecture at a Liquid-Solid Interface (2009)
  • Author(s): Kazukuni Tahara
  • Organizer: GCOE Symposium, International Symposium on Bio-Enviromental Chemistry
  • Place of Presentation: 吹田市(大阪府)
  • Year and Date: 2009-12-19
• [Presentation] Modular Molecular Networks of Butadiyne-Bridged Macrocycles (2009)
  • Author(s): Kazukuni Tahara, Jun Gotoda, Calden N. Stimpson, Jinne Adisoejoso, Steven De Feyter, Yoshito Tobe
  • Organizer: The 11th International Kyoto Conference on New Aspects of Organic Chemistry
  • Place of Presentation: Kyoto, Japan
  • Year and Date: 2009-11-10
• [Presentation] ブタジイン架橋マクロサイクルのモジュール式分子ネットワーク形成 (2009)
  • Author(s): 後藤田潤, Calden N. Stimpson, 田原一邦, 戸部義人
  • Organizer: 第20回基礎有機討論会
  • Place of Presentation: 桐生
  • Year and Date: 2009-09-28
• [Presentation] アゾベンゼンユニットを側鎖に含むデヒドロベンゾ[12]アヌレン誘導体の固液界面における2次元分=Fネットワーク (2009)
  • Author(s): 犬飼晃司
  • Organizer: 第20回基礎有機討論会
  • Place of Presentation: 群馬大学(群馬県)
  • Year and Date: 2009-09-28
• [Presentation] 固液界面における複雑2次元分子配列の構築 (2009)
  • Author(s): 田原一邦
  • Organizer: 表面科学技術協会 第120回講演大会
  • Place of Presentation: 幕張メッセ(千葉)
  • Year and Date: 2009-09-17
• [Presentation] Engineering of Multi-Component 2D Crystals at a Liquid-Solid Interface (2009)
  • Author(s): Kazukuni Tahara
  • Organizer: China-Japan Joint Symposium on Functional Supramolecular Architectures
  • Place of Presentation: 札幌市(北海道)
  • Year and Date: 2009-08-03
• [Presentation] 2D Crystal Engineering: a Four-Component Architecture at a Liquid-Solid Interface (2009)
  • Author(s): Kazukuni Tahara, Jinne Adisoejoso, Satoshi Okuhata, Shengbin Lei, Steven De Feyter, Yoshito Tobe
  • Organizer: 13th International Symposium on Novel Aromatic Compounds
  • Place of Presentation: Luxembourg, Luxembourg
  • Year and Date: 2009-07-20
• [Presentation] Formation of Modular Molecular Networks of Butaiyne-Bridged Macrocycles (2009)
  • Author(s): Jun Gotoda, Kazukuni Tahara, Yoshito Tobe
  • Organizer: 13th International Symposium on Novel Aromatic Compounds
  • Place of Presentation: Luxembourg, Luxembourg
  • Year and Date: 2009-07-20
• [Presentation] 2D Crystal Engineering : a Four-Component Architecture at a Liquid-Solid Interface (2009)
  • Author(s): Kazukuni Tahara
  • Organizer: 13th International Symposium of Novel Aromatic Compounds
  • Place of Presentation: ルクセンブルク市(ルクセンブルク)
  • Year and Date: 2009-07-20
• [Presentation] ブタジイン架橋マクロサイクルのモジュール式分子ネットワーク形成に関する研究 (2009)
  • Author(s): 後藤田潤, 田原一邦, 戸部義人
  • Organizer: 第5回ホスト・ゲスト化学シンポジウム
  • Place of Presentation: 宇都宮
  • Year and Date: 2009-05-31
• [Presentation] 固液界面における4成分分子ネットワークの構築 (2009)
  • Author(s): 田原一邦
  • Organizer: 第5回ホスト・ゲスト化学シンポジウム
  • Place of Presentation: 宇都宮大学(栃木県)
  • Year and Date: 2009-05-31
• [Presentation] 異なるアルコキシ基により置換された非対称デヒドロベンゾ[12]アヌレンの形成する単層膜 (2009)
  • Author(s): 田原一邦, Shengbin Lei, 犬飼晃司, Steven De Feyter, Frans C. De Schryver, 戸部義人
  • Organizer: 日本化学会第89春季年会
  • Place of Presentation: 千葉
  • Year and Date: 2009-03-30
• [Presentation] 多孔性分子ネットワークによる4成分2次元配列制御 (2009)
  • Author(s): 奥畑智, Jinne Adisoejoso, Shengbin Lei, 田原一邦, Frans C. De Schryver, Steven De Feyter, 戸部義人
  • Organizer: 日本化学会第89春季年会
  • Place of Presentation: 千葉
  • Year and Date: 2009-03-30
• [Presentation] ブタジイン架橋デヒドロベンゾ[12]アヌレンの固液界面における分子配列と反応性 (2009)
  • Author(s): 犬飼晃司, 原典孝, 田原一邦, Charles A. Johnson II, Michael M. Haley, 戸部義人
  • Organizer: 日本化学会第89春季年会
  • Place of Presentation: 千葉
  • Year and Date: 2009-03-29
• [Presentation] パイ共役分子のコアの形状ならびにアルキル鎖の置換様式が与える2次元分子ネットワーク形成への影響 (2009)
  • Author(s): 松下稔, 片山直浩, 田原一邦, Charles A. Johnson II, Michael M. Haley, 戸部義人
  • Organizer: 日本化学会第89春季年会
  • Place of Presentation: 千葉
  • Year and Date: 2009-03-29
• [Presentation] 菱形の形状を有する縮環型デヒドロベンゾ[12]アヌレンの多孔性2次元分子ネットワーク:構造とゲスト共吸着 (2008)
  • Author(s): 田原一邦, 奥畑智, Shengbin Lei, Jinne Adisoejoso, Frans C. De Schryver, Steven De Feyter, 戸部義人
  • Organizer: 第19回基礎有機化学討論会
  • Place of Presentation: 吹田
  • Year and Date: 2008-10-04
• [Presentation] 共有結合で結ばれた2次元分子ネットワークの合成に向けて (2008)
  • Author(s): 犬飼晃司, Shengbin Lei, 田原一邦, Frans C. De Schryver, Steven De Feyter, 戸部義人
  • Organizer: 第19回基礎有機化学討論会
  • Place of Presentation: 吹田
  • Year and Date: 2008-10-03
• [Presentation] 菱形ピリジノファンの固液界面における二次元分子ネットワークの形成とゲスト分子の共吸着 (2008)
  • Author(s): 片山直浩, 田原一邦, 戸部義人
  • Organizer: 第3回ホスト・ゲスト化学シンポジウム
  • Place of Presentation: 東京
  • Year and Date: 2008-06-01
• [Presentation] 菱形の形状を有する縮環型デヒドロベンゾ[12]アヌレンの固液界面における自己集合 (2008)
  • Author(s): 奥畑智, 田原一邦, 藤田匠, Shengbin Lei, Jinne Adisoejoso, Frans C. De Schryver, Steven De Feyter, 戸部義人
  • Organizer: 第3回ホスト・ゲスト化学シンポジウム
  • Place of Presentation: 東京
  • Year and Date: 2008-06-01
• [Presentation] 菱形の形状を有する縮環型デヒドロベンゾ[12]アヌレンの固液界面における自己集合 (2008)
  • Author(s): 奥畑智, 藤田匠, Shengbin Lei, Yihong Lu, 田原一邦, Frans C. De Schryver, Steven De Feyter, 戸部義人
  • Organizer: 日本化学会第88春季年会
  • Place of Presentation: 東京
  • Year and Date: 2008-03-28
• [Presentation] 共有結合により結ばれた2次元分子ネットワークの合成に向けて (2008)
  • Author(s): 戸部 義人
  • Organizer: 日本化学会第88春季年会
  • Place of Presentation: 東京
  • Year and Date: 2008-03-28
• [Presentation] 菱形ピリジノファンの固液界面における2次元分子ネットワーク (2008)
  • Author(s): 戸部 義人
  • Organizer: 日本化学会第88春季年会
  • Place of Presentation: 東京
  • Year and Date: 2008-03-28
• [Presentation] 共有結合で結ばれた2次元分子ネットワークの合成に向けて (2008)
  • Author(s): 犬飼晃司, Lei, Shengbin, 田原一邦, De Schryver, Frans C., De Feyter, Steven, 戸部義人
  • Organizer: 第19回基礎有機化学討論会
  • Place of Presentation: 大阪
• [Presentation] 菱形の形状を有する縮環型デヒドロベンゾ[12]アヌレンの固液界面における自己集合 (2008)
  • Author(s): 片山直浩, 田原一邦, 戸部義人
  • Organizer: 第3回ホストゲスト化学シンポジウム
  • Place of Presentation: 東京
• [Presentation] 菱形ピリジノファンの合成と固液界面における分子ネットワークの形成 (2007)
  • Author(s): 片山直浩, 奥畑智, 藤田匠, 田原一邦, 戸部義人
  • Organizer: 第1回有機π電子系シンポジウム
  • Place of Presentation: 東京
  • Year and Date: 2007-12-08
• [Presentation] Substituent Effect on the Formation of the Kagome Network of Bis(dehydrobenzoannulene)s at the Solid-Liquid Interface (2007)
  • Author(s): Satoshi Okuhata, Takumi Fujita, Kazukuni Tahara, Yoshito Tobe
  • Organizer: International Symposium on Green Sustainable Biological and Chemical Processes
  • Place of Presentation: Osaka, Japan
  • Year and Date: 2007-11-16
• [Presentation] Cotroll of Spacing Arrangement of Guest Molecule on Two-Dimensional Molecular Network of Butadiyne-Bridged Square Macrocycle (2007)
  • Author(s): Kazukuni Tahara, Weal Mamdouh, Yui Yamaguchi, Hiroshi Uji-i, Ichikawa Tomoyuki, Motohiro Sonoda, Keiji Hirose, Steven De Feyter, Frans C. De Schryver, Yoshito Tobe
  • Organizer: 12th International Symposium on Novel Aromatic Compounds
  • Place of Presentation: Awaji, Japan
  • Year and Date: 2007-07-24
• [Presentation] Substituent Effect on the Formation of the Kagome Network of Bis(dehydrobenzoannulene)s at the Solid-Liquid Interface (2007)
  • Author(s): Satoshi Okuhata, Takumi Fujita, Kazukuni Tahara, Yoshito Tobe
  • Organizer: 12th International Symposium on Novel Aromatic Compounds
  • Place of Presentation: Awaji, Japan
  • Year and Date: 2007-07-23
• [Book] 有機分子を固体表面に並べて作る幾何学模様, 機能材料 (2009)
  • Author(s): 戸部義人, 田原一邦
• [Remarks]
  • URL: http://www.supra.chem.es.osaka-u.ac.jp/