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Development of photoreactions by functional catalysts which contain a visible-light sensitizing unit

Research Project

Project/Area Number 19750042
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeSingle-year Grants
Research Field Inorganic chemistry
Research InstitutionTokyo Institute of Technology

Principal Investigator

TAKAO Akiko  Tokyo Institute of Technology, 資源化学研究所, 助教 (00345357)

Project Period (FY) 2007 – 2009
Project Status Completed (Fiscal Year 2009)
Budget Amount *help
¥3,930,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥630,000)
Fiscal Year 2009: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2008: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2007: ¥1,200,000 (Direct Cost: ¥1,200,000)
Keywords太陽光・ルテニウム / 触媒反応 / 太陽光 / 光増感 / ルテニウムポリピリジル / パラジウム / バイクロモフォア / ルテニウム / 可視光増感
Research Abstract

Various transition-metal complexes containing visible-light absorbing Ru(II) polypyridyl moiety have been synthesized. Systematic studies on the catalytic activities of the Ru-Pd catalysts revealed that the introduction of electron donating group on the bipyridyl ligands and the electron withdrawing group on the bridging ligand led to the drastic rate acceleration. The origin of the acceleration is most probably due to the expansion of energy gap between the LUMO+1 and LUMO orbitals which lead to the preferencial MLCT toward the bridging ligand.

Report

(4 results)
  • 2009 Annual Research Report   Final Research Report ( PDF )
  • 2008 Annual Research Report
  • 2007 Annual Research Report
  • Research Products

    (76 results)

All 2010 2009 2008 2007

All Journal Article (20 results) (of which Peer Reviewed: 18 results) Presentation (55 results) Book (1 results)

  • [Journal Article] Photocatalytic Styrene Polymerization by Novel Bichromophoric Pd Catalyst having Long Excited-state Lifetime.2010

    • Author(s)
      Kei Murata, Masaharu Ito, Akiko Inagaki, Munetaka Akita
    • Journal Title

      In revision, manuscript No.CL-100440

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Visible-light Promoted Bimetallic Catalysis2010

    • Author(s)
      Akiko Inagaki, Munetaka Akita
    • Journal Title

      Coord. Chem. Rev. 254

      Pages: 1220-1239

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Munetaka Akita. Photochromic Organometallics with a Dithienylethene (DTE) Bridge, M-C-DTE-C-C-M [M = MCp*(dppe)]: Photoswitchable Molecular Wire (M = Fe) vs. Dual Photo- and Electro-chromism (M = Ru).2010

    • Author(s)
      Yuya Tanaka, Takuya Ishisaka, Akiko Inagaki, Takashi Koike, Claude Lapinte
    • Journal Title

      Chem. Eur. J. 16

      Pages: 4762-4776

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Visible-light Promoted Bimetallic Catalysis2010

    • Author(s)
      Akiko Inagaki, Munetaka Akita
    • Journal Title

      Coordination Chemistry Review 254

      Pages: 1220-1239

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Photochromic Organometallics with a Dithienylethene(DTE)Bridge, M-C-DTE-C-C-M[M=MCp^*(dppe)] : Photoswitchable Molecular Wire(M=Fe) vs.Dual Photo- and Electro-chromism(M=Ru)2010

    • Author(s)
      Yuya Tanaka, Takuya Ishisaka, Akiko Inagaki, Takashi Koike, Claude Lapinte, Munetaka Akita
    • Journal Title

      Chemistry, A European Journal (in press)

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Syntheses and photophysical properties of visible-light-absorbing Ru(II) polypyridyl complexes possessing (pyridylpyrazolyl)metal tethers.2009

    • Author(s)
      Tomohide Saita, Hiroyuki Nitadori, Akiko Inagaki, Munetaka Akita
    • Journal Title

      Journal of Organomet. Chem. 694(19)

      Pages: 3125-3133

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] 可視光エネルギーを利用した触媒的分子変換2009

    • Author(s)
      稲垣昭子・穐田宗隆
    • Journal Title

      光化学 40巻1号

      Pages: 18-25

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Syntheses and photophysical properties of visible-light-absorbing Ru(II)polypyridyl complexes possessing(pyridylpyrazolyl)metal tethers2009

    • Author(s)
      Tomohide Saita, Hiroyuki Nitadori, Akiko Inagaki, Munetaka Akita
    • Journal Title

      Journal of Organometallic Chemistry 694

      Pages: 3125-3133

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 可視光エネルギーを利用した触媒的分子変換2009

    • Author(s)
      稲垣昭子・穐田宗隆
    • Journal Title

      光化学 40(1)

      Pages: 18-25

    • Related Report
      2008 Annual Research Report
  • [Journal Article] Synthesis of Pd complexes directly linked to the light-absorbing [(bpy)3Ru]2+ unit and their photochemical reactions toward styrenes.2008

    • Author(s)
      Akiko Inagaki, Hiroki Nakagawa, Munetaka Akita, Keiichi Inoue, Makoto Sakai, Masaaki Fujii
    • Journal Title

      Dalton Trans.

      Pages: 6709-6723

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Syntheses of Di- and Trinucleating Ligands having Triethylbenzene Core with N, N-Bidentate Tethers. Their Complexation toward Pd and Rh Organometallic Fragments.2008

    • Author(s)
      Gou Higashihara, Akiko Inagaki, Munetaka Akita
    • Journal Title

      Dalton Trans.

      Pages: 1888-1898

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of Pd complexes directly linked to the light-absorbing [(bpy)_3Ru]^<2+> unit and their photochemical reactions toward styrenes2008

    • Author(s)
      Akiko Inagaki, Hiroki Nakagawa, Munetaka Akita, Keiichi Inoue, Makoto Sakai, and Masaaki Fujii
    • Journal Title

      Dalton Transactions

      Pages: 6709-6723

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Syntheses of Di- and Trinucleating Ligands having Triethylbenzene Core with N,N-Bidentate Tethers.Their Complexation toward Pd and Rh Organometallic Fragments2008

    • Author(s)
      Gou Higashihara, Akiko Inagaki, Munetaka Akita*
    • Journal Title

      Dalton transactions

      Pages: 1888-1898

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Preparation and Photochemical Behavior of Organoruthenium Derivatives of Photochromic Dithienylethene (DTE): DTE-(RMLm)n (RMLm= (η6-C6H5)Ru(h5-C5Me5), (η6-C6H5)RuCl2(PPh3), (η5-C5Me4)Ru(CO)2; n= 1, 2).2007

    • Author(s)
      Kazunori Uchida, Akiko Inagaki, Munetaka Akita
    • Journal Title

      Organometallics 26

      Pages: 5030-5041

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of Pd Complexes Combined with Photosensitizing of a Ruthenium(II) Polypyridyl Moiety through a Series of Substituted Bipyrimidine Bridges. Substituent Effect of the Bridging Ligand on the Photocatalytic Dimerization of α-Methylstyrene.2007

    • Author(s)
      Akiko Inagaki, Shinichi Yatsuda, Shinichi Edure, Akiko Suzuki, Takeshi Takahashi, Munetaka Akita
    • Journal Title

      Inorg. Chem. 46

      Pages: 2432-2445

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Redox-active Polyiron Complexes with Tetra(ethynylphenyl)ethene and [2, 2]Paracyclophane Spacers Containing Ethynylphenyl Units: Extension to Higher Dimensional Molecular Wires.2007

    • Author(s)
      Yuya Tanaka, Takehiro Ozawa, Akiko Inagaki, Munetaka Akita
    • Journal Title

      Dalton Trans

      Pages: 928-933

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] A photoswitchable molecular wire with the dithienylethene (DTE) linker, (dppe)(η5-C5Me5)Fe-C≡C-DTE-C≡C-Fe(hη5- C5Me5)(dppe).2007

    • Author(s)
      Yuya Tanaka, Akiko Inagaki, Munetaka Akita
    • Journal Title

      Chem. Commun.

      Pages: 1169-1171

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] C-C Coupling of Permetallated Ethene, (μ4-C=C)Ru2(FeCp*)2(CO)10, with Alkynes, and Isolation of Labile MeCN Adduct, (μ4-C=C)Ru2(FeCp*)2(CO)8(NCMe)2.2007

    • Author(s)
      Gou Higashihara, Masako Terada, Akiko Inagaki, Munetaka Akita
    • Journal Title

      Organometallics 26

      Pages: 439-444

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Ruthenium and Chromium Complexes Bearing pH-indicators as theη6-Arene Ligand: Synthesis, Characterization, and Protonation Behavior2007

    • Author(s)
      Miyuki Hirasa, Akiko Inagaki, Munetaka Akita
    • Journal Title

      J. Organomet. Chem. 692

      Pages: 93-110

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] 可視光を駆動力とする触媒的分子変換反応2007

    • Author(s)
      穐田家隆・稲垣昭子
    • Journal Title

      化学 62(8)

      Pages: 70-71

    • Related Report
      2007 Annual Research Report
  • [Presentation] 芳香族およびルテニウムポリピリジルバイクロモフォアを有するパラジウム錯体の合成とスチレン類の触媒的光オリゴメリゼーション2010

    • Author(s)
      村田慧・稲垣昭子・穐田宗隆
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      近畿大学
    • Year and Date
      2010-03-29
    • Related Report
      2009 Final Research Report
  • [Presentation] 可視光増感性Ru(II)錯体を複合化させたNi触媒によるアリールハライドの触媒的脱ハロゲン化反応2010

    • Author(s)
      板倉亮・稲垣昭子・穐田宗隆・大沢正 久
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      近畿大学
    • Year and Date
      2010-03-29
    • Related Report
      2009 Final Research Report
  • [Presentation] ルテニウムポルフィリンを光捕集ユニットとして含むパラジウムアルキル錯体の合成と物性2010

    • Author(s)
      安祐輔・稲垣昭子・穐田宗隆
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      近畿大学
    • Year and Date
      2010-03-29
    • Related Report
      2009 Final Research Report
  • [Presentation] Development of visible-light-driven catalytic transformation system of organic molecules2010

    • Author(s)
      Akiko Inagaki
    • Organizer
      International Symposium on Chemical Conversion of Light Energy.
    • Place of Presentation
      Kinki Univ., Osaka.
    • Year and Date
      2010-03-28
    • Related Report
      2009 Final Research Report
  • [Presentation] Development of visible-light-driven catalytic transformation system of organic molecules2010

    • Author(s)
      稲垣昭子
    • Organizer
      国際シンポジウム 光エネルギーと物質変換:人工光合成の未来
    • Place of Presentation
      近畿大学本部キャンパス大阪
    • Year and Date
      2010-03-28
    • Related Report
      2009 Annual Research Report
  • [Presentation] ルテニウムポルフィリンを光捕集ユニットとして含むパラジウムアルキル錯体の合成と物性2010

    • Author(s)
      安祐輔・稲垣昭子・穐田宗隆
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      近畿大学本部キャンパス大阪
    • Year and Date
      2010-03-28
    • Related Report
      2009 Annual Research Report
  • [Presentation] 芳香族およびルテニウムポリピリジルバイクロモフォアを有するパラジウム錯体の合成とスチレン類の触媒的光オリゴメリゼーション2010

    • Author(s)
      村田慧・稲垣昭子・穐田宗隆
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      近畿大学本部キャンパス大阪
    • Year and Date
      2010-03-28
    • Related Report
      2009 Annual Research Report
  • [Presentation] 可視光増感性Ru(II)錯体を複合化させたNi触媒によるアリールハライドの触媒的脱ハロゲン化反応2010

    • Author(s)
      板倉亮・稲垣昭子・穐田宗隆・大沢正久
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      近畿大学本部キャンパス大阪
    • Year and Date
      2010-03-28
    • Related Report
      2009 Annual Research Report
  • [Presentation] Syntheses and Photophysical Properties of Pd Complexes Containing a Bichromophoric Moiety: Extended Photocatalytic Activity under UV-vis Irradiation2009

    • Author(s)
      Kei Murata・Akiko Inagaki・Munetaka Akita
    • Organizer
      5th International Symposium on Molecular Materials: Electronics, Photonics and Spintronics
    • Place of Presentation
      Rennes, France
    • Year and Date
      2009-10-30
    • Related Report
      2009 Final Research Report
  • [Presentation] Catalytic alkene activation by visible-light sensitive palladium complexes.2009

    • Author(s)
      Akiko Inagaki
    • Organizer
      4th International Symposium for Young Elements Chemists, 2009 Workshop on Organometallic Chemistry
    • Place of Presentation
      Kyushu University.
    • Year and Date
      2009-10-28
    • Related Report
      2009 Final Research Report
  • [Presentation] Syntheses and Photophysical Properties of Pd Complexes Containing a Bichromophoric Moiety : Extended Photocatalytic Activity under UV-vis Irradiation2009

    • Author(s)
      村田慧・稲垣昭子・穐田宗隆
    • Organizer
      International Symposium on Molecular Materials : Electronics, Photonics and Spintronics
    • Place of Presentation
      Rennes, France
    • Year and Date
      2009-10-28
    • Related Report
      2009 Annual Research Report
  • [Presentation] 光増感性Ru(II)錯体とNi錯体を複合化させた触媒によるアリールハライドの触媒的カップリング反応2009

    • Author(s)
      板倉亮・稲垣昭子・穐田宗隆・大沢正 久
    • Organizer
      第59回錯体化学討論会
    • Place of Presentation
      長崎大学文教キャンパス
    • Year and Date
      2009-09-27
    • Related Report
      2009 Annual Research Report 2009 Final Research Report
  • [Presentation] 可視光増感ポリピリジルルテニウム及び芳香族クロモフォアを複合化したバイクロモフォアを有するPd錯体の合成と反応性2009

    • Author(s)
      村田慧・稲垣昭子・穐田宗隆
    • Organizer
      第59回錯体化学討論会
    • Place of Presentation
      長崎大学文教キャンパス
    • Year and Date
      2009-09-27
    • Related Report
      2009 Annual Research Report 2009 Final Research Report
  • [Presentation] Photo-catalytic Reactions of Olefins by Pd Complexes with Photosensitizing Ru(II) Polypyridyl Moiety2009

    • Author(s)
      A. Inagaki・S. Yatsuda・H. Nitadori・M. Akita
    • Organizer
      18th ISPPCC
    • Place of Presentation
      Gateau Kingdom Sapporo
    • Year and Date
      2009-07-08
    • Related Report
      2009 Final Research Report
  • [Presentation] Photo-catalytic Reactions of Olefins by Pd Complexes with Photosensitizing Ru(II)Polypyridyl Moiety2009

    • Author(s)
      A.Inagaki・S.Yatsuda・H.Nitadori・M.Akita
    • Organizer
      18^<th> ISPPCC
    • Place of Presentation
      Gateau Kingdom Sapporo
    • Year and Date
      2009-07-08
    • Related Report
      2009 Annual Research Report
  • [Presentation] Substituent Effect of the Photosensitizing Ruthenium-Palladium Complexes on the Photocatalytic Dimerization of α-Methylstyrene.2009

    • Author(s)
      H. Nitadori・A. Inagaki・M. Akita
    • Organizer
      18th ISPPCC
    • Place of Presentation
      Gateau Kingdom Sapporo
    • Year and Date
      2009-07-06
    • Related Report
      2009 Final Research Report
  • [Presentation] Syntheses and Photophysical Properties of Pd Complexes Containing a Bichromophoric Moiety: Extended Photocatalytic Activity Under UV-vis Irradiation.2009

    • Author(s)
      K. Murata・A. Inagaki・M. Akita
    • Organizer
      18th ISPPCC
    • Place of Presentation
      Gateau Kingdom Sapporo
    • Year and Date
      2009-07-06
    • Related Report
      2009 Final Research Report
  • [Presentation] Substituent Effect of the Photosensitizing Ruthenium-Palladium Complexes on the Photocatalytic Dimerization of alpha-Methylstyrene2009

    • Author(s)
      H.Nitadori・A.Inagaki・M.Akita
    • Organizer
      18^<th> ISPPCC
    • Place of Presentation
      Gateau Kingdom Sapporo
    • Year and Date
      2009-07-05
    • Related Report
      2009 Annual Research Report
  • [Presentation] Syntheses and Photophysical Properties of Pd Complexes Containing a Bichromophoric Moiety : Extended Photocatalytic Activity Under UV-vis Irradiation2009

    • Author(s)
      村田慧・稲垣昭子・穐田宗隆
    • Organizer
      18^<th> ISPPCC
    • Place of Presentation
      Gateau Kingdom Sapporo
    • Year and Date
      2009-07-05
    • Related Report
      2009 Annual Research Report
  • [Presentation] 可視光増感ポリピリジルルテニウム及び紫外光吸収ユニットを複合化したバイクロモフォアを有するPd錯体の合成と光化学特性2009

    • Author(s)
      村田慧・稲垣昭子・穐田宗隆
    • Organizer
      日本化学会第89春季年会
    • Place of Presentation
      日本大学理工学部船橋キャンパス
    • Year and Date
      2009-03-28
    • Related Report
      2009 Final Research Report 2008 Annual Research Report
  • [Presentation] 光増感性Ru(II)錯体とNi錯体を組み合わせたハロゲン化アリールの触媒的ホモカップリング反応2009

    • Author(s)
      板倉亮・稲垣昭子・穐田宗隆・大沢正 久
    • Organizer
      日本化学会第89春季年会
    • Place of Presentation
      日本大学理工学部船橋キャンパス
    • Year and Date
      2009-03-28
    • Related Report
      2009 Final Research Report 2008 Annual Research Report
  • [Presentation] 可視光エネルギーを利用した触媒的分子変換2008

    • Author(s)
      稲垣昭子
    • Organizer
      第5回触媒相模セミナー
    • Place of Presentation
      相模中央研究所
    • Year and Date
      2008-11-13
    • Related Report
      2009 Final Research Report
  • [Presentation] 可視光エネルギーを利用した触媒的分子変換反応2008

    • Author(s)
      稲垣昭子
    • Organizer
      第5回相模触媒セミナー
    • Place of Presentation
      相模中央研究所
    • Year and Date
      2008-11-13
    • Related Report
      2008 Annual Research Report
  • [Presentation] 可視光増部位をC-Cシグマ結合で連結したビピリジルパラジウム錯体の合成と触媒的光反応2008

    • Author(s)
      稲垣昭子・中川裕揮・穐田宗隆
    • Organizer
      第102回触媒討論会
    • Place of Presentation
      名古屋大学
    • Year and Date
      2008-09-25
    • Related Report
      2009 Final Research Report
  • [Presentation] 可視光増部位をC-Cシグマ結合で連結したビピリジルパラジウム錯体の合成と触媒的光反応可視光増部位をC-Cシグマ結合で連結したビピリジルパラジウム錯体の合成と触媒的光反応2008

    • Author(s)
      稲垣昭子・中川裕揮・穐田宗隆
    • Organizer
      第102回触媒討論会
    • Place of Presentation
      名古屋大学東山キャンパス
    • Year and Date
      2008-09-25
    • Related Report
      2008 Annual Research Report
  • [Presentation] 可視光増感性ポリピリジルルテニウム-パラジウム錯体を用いたスチレン類との光二量化反応における配位子の置換基効果2008

    • Author(s)
      似鳥広幸・稲垣昭子・穐田宗隆
    • Organizer
      第58回錯体化学討論会
    • Place of Presentation
      金沢大学角間キャンパス
    • Year and Date
      2008-09-22
    • Related Report
      2009 Final Research Report
  • [Presentation] 可視光増感性ポリピリジルルテニウムーパラジウム錯体を用いたスチレン類との光二量化反応における配位子の置換基効果2008

    • Author(s)
      似鳥広幸・稲垣昭子・穐田宗隆
    • Organizer
      第58回錯体化学討論会
    • Place of Presentation
      金沢大学角間キャンパス
    • Year and Date
      2008-09-21
    • Related Report
      2008 Annual Research Report
  • [Presentation] 可視光増感性ポリピリジルルテニウム-パラジウム錯体を用いたオレフィン類との光二量化反応における配位子の置換基効果2008

    • Author(s)
      似鳥広幸・稲垣昭子・穐田宗隆
    • Organizer
      第21回配位化合物の光化学討論会
    • Place of Presentation
      北里大学相模原キャンパス
    • Year and Date
      2008-08-06
    • Related Report
      2009 Final Research Report
  • [Presentation] オレフィン類との光二量化反応における配位子の置換基効果2008

    • Author(s)
      似鳥広幸・稲垣昭子・穐田宗隆
    • Organizer
      第21回配位化合物の光化学討論会
    • Place of Presentation
      北里大学
    • Year and Date
      2008-08-06
    • Related Report
      2008 Annual Research Report
  • [Presentation] Syntheses and Photocatalytic Reactions by Pd Complexes Containing Ru(II) Trisbipyridyl Moiety as a Visible-Light Absorbing Unit2008

    • Author(s)
      A. Inagaki, T. Takahashi, H. Nakagawa, S. Yatsuda, M. Akita
    • Organizer
      ICC 14 Pre-Symposium
    • Place of Presentation
      京都大学
    • Year and Date
      2008-07-10
    • Related Report
      2008 Annual Research Report
  • [Presentation] Syntheses and Photocatalytic Reactions by Pd Complexes Containing Ru(II) Trisbipyridyl Moiety as a Visible-Light Absorbing Unit2008

    • Author(s)
      Akiko Inagaki, Takeshi. Takahashi, Hiroki. Nakagawa, Shinichi. Yatsuda, Munetaka. Akita
    • Organizer
      ICC 14 Pre-Symposium Kyoto
    • Place of Presentation
      Kyoto University
    • Year and Date
      2008-07-09
    • Related Report
      2009 Final Research Report
  • [Presentation] 可視光増感性ルテニウムポリピリジルユニットにピレニル基を導入したバイクロモフォアを含むパラジウム錯体の合成2008

    • Author(s)
      村田慧・稲垣昭子・穐田宗隆
    • Organizer
      日本化学会第88春季年会
    • Place of Presentation
      立教大学池袋キャンパス
    • Year and Date
      2008-03-29
    • Related Report
      2009 Final Research Report
  • [Presentation] 可視光増感性ルテニウムポリピリジルュニツトにピレニル基を導入したバイクロモフォアを含むパラジウム錯体の合成(4PA-154).2008

    • Author(s)
      村田慧・稲垣昭子・穐田宗隆
    • Organizer
      第54回有機金属討論会
    • Place of Presentation
      立教大学池袋キャンパス
    • Year and Date
      2008-03-29
    • Related Report
      2007 Annual Research Report
  • [Presentation] Photocatalytic Reactions of Pd Complexes Containing a Visible-Light Sensitive Ru(II) Moiety2008

    • Author(s)
      Akiko Inagaki, Shinichi Edure, Shinichi Yatsuda, Akiko Suzuki, Takahashi Takeshi, Munetaka Akita
    • Organizer
      日本化学会第88春季年会Asian Symposium
    • Place of Presentation
      立教大学池袋キャンパス
    • Year and Date
      2008-03-28
    • Related Report
      2009 Final Research Report
  • [Presentation] Photocatalytic Reactions of Pd Complexes Containing aVisible-Light Sensitive Rudl) Moiety. (3E6-34)2008

    • Author(s)
      O Akiko Inagaki, ShinichiEdure, Shinichi Yatsuda, Akiko Suzuki, TakahashiTakesM, Munetaka Akita
    • Organizer
      日本化学会第88春季年会・アジアシンポジウム
    • Place of Presentation
      立教大学池袋キャンパス
    • Year and Date
      2008-03-28
    • Related Report
      2007 Annual Research Report
  • [Presentation] ビピリミジンを架橋配位子とするポリピリジルルテニウム-パラジウム錯体の合成と光増感部位の置換基効果2008

    • Author(s)
      高橋健・稲垣昭子・穐田宗隆
    • Organizer
      日本化学会第88春季年会
    • Place of Presentation
      立教大学池袋キャンパス
    • Year and Date
      2008-03-27
    • Related Report
      2009 Final Research Report
  • [Presentation] 光増感性ポリピリジルルテニウム-パラジウム錯体を用いたスチレン類の触媒的光二量化反応における光増感ユニットの置換基効果の検討2008

    • Author(s)
      似鳥広幸・稲垣昭子・穐田宗隆
    • Organizer
      日本化学会第88春季年会
    • Place of Presentation
      立教大学池袋キャンパス
    • Year and Date
      2008-03-27
    • Related Report
      2009 Final Research Report
  • [Presentation] 可視光増感部位をC-Cシグマ結合を介して基質活性化部位に連結させたビピリジルパラジウム、ロジウム錯体の合成と連結様式に関する考察2008

    • Author(s)
      中川裕揮・稲垣昭子・穐田宗隆
    • Organizer
      日本化学会第88春季年会
    • Place of Presentation
      立教大学池袋キャンパス
    • Year and Date
      2008-03-27
    • Related Report
      2009 Final Research Report
  • [Presentation] ビピリミシンを架橋配位子とするポリピリシルルテニウムーパフシウム錯体の合成と光増誘部位の置換基効果(2E8-35)2008

    • Author(s)
      高橋健・稲垣昭子・穐田宗隆
    • Organizer
      日本化学会第88春季年会
    • Place of Presentation
      立教大学池袋キャンパス
    • Year and Date
      2008-03-27
    • Related Report
      2007 Annual Research Report
  • [Presentation] 光増感性ポリピリジルルテニウムーパラジウム錯体を用いたスチレン類の触媒的光二量化反応における光増殖ユニットの置換基効果の検討(2E8-36)2008

    • Author(s)
      似島広幸・稲垣昭子・穐田宗隆
    • Organizer
      日本化学会第88春季年会
    • Place of Presentation
      立教大学池袋キャンパス
    • Year and Date
      2008-03-27
    • Related Report
      2007 Annual Research Report
  • [Presentation] 可視光増殖部位をC-Cシグマ結合を介して基質活性化部位に連結させたビピリジルバラジウム、ロジウム総体の合成と連結様式に関すろ考察(2E8-37)2008

    • Author(s)
      中川裕揮・稲垣昭子・穐田宗隆
    • Organizer
      F1本化学会第88春季年会
    • Place of Presentation
      立教大学池袋キャンパス
    • Year and Date
      2008-03-27
    • Related Report
      2007 Annual Research Report
  • [Presentation] 可視光増感性ルテニウムポリピリジルユニットを有する有機金属錯体の合成と光反応2008

    • Author(s)
      稲垣昭子・穐田宗隆
    • Organizer
      文部科学省科学研究費特定領域研究「元素相乗系化合物の化学」第3回若手コロキウム
    • Place of Presentation
      大阪
    • Year and Date
      2008-03-15
    • Related Report
      2009 Final Research Report
  • [Presentation] 可視光増感ユニットをもつパラジウム錯体による触媒的光反応2007

    • Author(s)
      稲垣昭子
    • Organizer
      分子科学研究所シンポジウム
    • Place of Presentation
      岡崎
    • Year and Date
      2007-12-04
    • Related Report
      2009 Final Research Report
  • [Presentation] 可視光増感ルテニウムポリピリジル部位を有するパラジウム錯体の合成と触媒的光反応2007

    • Author(s)
      稲垣昭子・谷津田伸一・高橋健・穐田 宗隆
    • Organizer
      第54回有機金属討論会
    • Place of Presentation
      広島大学
    • Year and Date
      2007-10-28
    • Related Report
      2009 Final Research Report
  • [Presentation] 可視光増感ルテニウムポリピリジル部位を有するパラジウム錯体の合成と触媒的光反応(A205)2007

    • Author(s)
      稲垣昭子・谷津田伸一・高橋健・穐田宗隆
    • Organizer
      第54回有機金属討論会
    • Place of Presentation
      広島大学東広島キヤンノベス
    • Year and Date
      2007-10-28
    • Related Report
      2007 Annual Research Report
  • [Presentation] σ(C-C)結合を介してポリピリジルユニットを導入したパラジウムおよびロジウム錯体の合成と光反応2007

    • Author(s)
      中川裕揮・稲垣昭子・穐田宗隆
    • Organizer
      日本化学会第1回関東支部大会
    • Place of Presentation
      首都大学東京南大沢キャンパス
    • Year and Date
      2007-09-28
    • Related Report
      2009 Final Research Report
  • [Presentation] トリフルオロメチル基を有する新規架橋配位子を導入したポリピリジルルテニウム-遷移金属複核錯体の合成と置換基効果の検討2007

    • Author(s)
      高橋健・稲垣昭子・穐田宗隆
    • Organizer
      日本化学会第1回関東支部大会
    • Place of Presentation
      首都大学東京南大沢キャンパス
    • Year and Date
      2007-09-28
    • Related Report
      2009 Final Research Report
  • [Presentation] ピリジルピラゾリル基を有する光増感性ポリピリジルルテニウム誘導体への遷移金属フラグメントの導入とプロトン化反応2007

    • Author(s)
      似鳥広幸・斎田智秀・稲垣昭子・穐田 宗隆
    • Organizer
      日本化学会第1回関東支部大会
    • Place of Presentation
      首都大学東京南大沢キャンパス
    • Year and Date
      2007-09-28
    • Related Report
      2009 Final Research Report
  • [Presentation] o(C-C)結合を介してポリピリジルュニットを導入したパラジウムおよびロジウム錯体の合成と光反応(2P-068)2007

    • Author(s)
      中川裕揮・稲垣昭子・穐田宗隆
    • Organizer
      日本化学会第1回関東支部大会
    • Place of Presentation
      首都大学東京南大沢キャンパス
    • Year and Date
      2007-09-28
    • Related Report
      2007 Annual Research Report
  • [Presentation] トリフルオロメチル基を有する新規架橋配位子を導入したポリピリジルルテニウムー遷移金属複核錯体の合成と置換基効果の検討(2P-069)2007

    • Author(s)
      高橋健・稲垣昭子・穐田宗隆
    • Organizer
      日本化学会第1回関東支部大会
    • Place of Presentation
      首都大学東京南大沢キャンパス
    • Year and Date
      2007-09-28
    • Related Report
      2007 Annual Research Report
  • [Presentation] ピリジルピラゾ仰レ基を有する光増感性ポリピリジルルテニウム誘導体への遷移金属フラグメントの導入とプロトン化反応(2P-070)2007

    • Author(s)
      似島広幸・斎田智秀・稲垣昭子・穐田宗隆
    • Organizer
      日本化学会第1回関東支部大会
    • Place of Presentation
      首都大学東泉南大沢キンパス
    • Year and Date
      2007-09-28
    • Related Report
      2007 Annual Research Report
  • [Presentation] 可視光増感性ユニットを持つ有機金属錯体による触媒的光反応2007

    • Author(s)
      稲垣昭子・穐田宗隆
    • Organizer
      第100回触媒討論会
    • Place of Presentation
      北海道大学
    • Year and Date
      2007-09-20
    • Related Report
      2009 Final Research Report
  • [Presentation] 可視光増感性ユニットを持つ有機金属錯体による触媒的光反応(4J31)2007

    • Author(s)
      稲垣昭子
    • Organizer
      第100回触媒討論会
    • Place of Presentation
      北海道大学理学研究科
    • Year and Date
      2007-09-20
    • Related Report
      2007 Annual Research Report
  • [Presentation] 可視光増感ルテニウムポリピリジル部位を含むアルキルパラジウム錯体によるオレフィン類の触媒的光二量化反応2007

    • Author(s)
      稲垣昭子・谷津田伸一・高橋健・穐田 宗隆
    • Organizer
      第20回配位化合物の光化学討論会
    • Place of Presentation
      シーサイドホテル舞子ビラ神戸
    • Year and Date
      2007-08-07
    • Related Report
      2009 Final Research Report
  • [Presentation] 可視光増殖ルテニウムポリピリジル部位を含むアルキルパラジウム錯体によるオレフィン類の触媒的光二重化反応(0-08)2007

    • Author(s)
      稲垣昭子・谷津田伸一・高橋健一・穐田宗隆
    • Organizer
      第20回配位化合物の光化学討論会
    • Place of Presentation
      シーサイドホテル舞子
    • Year and Date
      2007-08-07
    • Related Report
      2007 Annual Research Report
  • [Book] 化学2007

    • Author(s)
      穐田宗隆・稲垣昭子
    • Publisher
      化学同人
    • Related Report
      2009 Final Research Report

URL: 

Published: 2007-04-01   Modified: 2016-04-21  

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