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Preparation of Multinuclear Complexes Containing the Linear Triplatinum Core with P-Ligands as New Metallaligands

Research Project

Project/Area Number 19750043
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeSingle-year Grants
Research Field Inorganic chemistry
Research InstitutionTokyo Institute of Technology

Principal Investigator

TANABE Makoto  Tokyo Institute of Technology, 資源化学研究所, 助教 (80376962)

Project Period (FY) 2007 – 2008
Project Status Completed (Fiscal Year 2008)
Budget Amount *help
¥3,690,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2008: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2007: ¥2,000,000 (Direct Cost: ¥2,000,000)
Keywords白金 / メタラリガンド / 有機リン化合物 / 多核錯体 / 分子軌道計算 / 三核錯体 / パラジウム
Research Abstract

本研究の目的は,遷移金属錯体に必要な新しい配位子として,複数の遷移金属を含む錯体配位子(メタラリガンド)の合成である.具体的には,基質配位点としてのリン原子を持つ三核白金錯体の合成と機能発現を探求し,合成反応条件の確立やメタラリガンドとしての有用性を見出した.金属骨格周辺に嵩高い配位子を持つ多核錯体は,特異的なリン原子の環境が創出され,全く新しい構造をもつ多核錯体が見出された.

Report

(3 results)
  • 2008 Annual Research Report   Final Research Report ( PDF )
  • 2007 Annual Research Report
  • Research Products

    (44 results)

All 2009 2008 2007

All Journal Article (15 results) (of which Peer Reviewed: 15 results) Presentation (27 results) Book (2 results)

  • [Journal Article] Planar Tetranuclear and Dumbbell-shaped Octanuclear Pd Complexes with Bridging Silylene Ligands2009

    • Author(s)
      山田哲行, 馬渡あかね, 田邊真, 小坂田耕太郎, 棚瀬知明
    • Journal Title

      Angew. Chem. Int. Ed 48

      Pages: 568-571

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Dialkyl- and diaryl-platinum(II) complexes with secondary phosphines. Preparation, structure and thermal reaction giving the metallopolymer2009

    • Author(s)
      掛谷正輝, 田邊真, 中村義之, 小坂田耕太郎
    • Journal Title

      J. Organomet. Chem 649

      Pages: 2270-2278

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Planar Tetranuclear and Dumbbell-shaped Octanuclear Pd Complexes with BridgingSilylene Ligands2009

    • Author(s)
      Tetsuyuki Yamada, Akane Mawatari, Makoto Tanabe, Kohtaro Osakada, and Tomoaki Tanase
    • Journal Title

      Angewandte Chemie International Edition 48

      Pages: 568-571

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Dialkyl- and diaryl-platinum(II) complexes with secondary phosphines. Preparation, structure and thermal reaction giving the metallopolymer2009

    • Author(s)
      Masaki Kakeya, Makoto Tanabe, Yoshiyuki Nakamura, Kohtaro Osakada
    • Journal Title

      Journal of Organometallic Chemistry (掲載決定)

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Ligand Exchange of Diplatinum Complexes with Bridging Silyl Ligands Involving Si-H Bond Cleavage and Formation2008

    • Author(s)
      田邊真, 伊藤大輔, 小坂田耕太郎
    • Journal Title

      Organometallics 28

      Pages: 2258-2267

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Mono- and Dinuclear Germapalladacycles Obtained via the Ge-Ge Bond Forming Reactions Promoted by Pd Complexes2008

    • Author(s)
      田邊真, 石川尚子, 半沢公也, 小坂田耕太郎
    • Journal Title

      Organometallics 27

      Pages: 5152-5158

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Mono- and Dinuclear Germapalladacycles Obtained via the Ge-Ge Bond Forming Reactions Promoted by Pd Complexes2008

    • Author(s)
      Makoto Tanabe, Naoko Ishikawa, Masaya Hanzawa, Kohtaro Osakada
    • Journal Title

      Organometallics 27

      Pages: 5152-5158

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Strain-Controlled, Photochemically, or Thermally Promoted Haptotropic Shifts of Cyclopentadienyl Ligands in Group 8 Metallocenophanes2008

    • Author(s)
      David E. Herbert, Makoto Tanabe, Sara C. Bourke, Alan J. Lough, Ian Manners
    • Journal Title

      Journal of the American Chemical Society 130

      Pages: 4166-4176

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Preparation and NMR Studies of Palladium Complexes with a Silsesquioxanate Ligand2008

    • Author(s)
      Makoto Tanabe, Kohji Mutou, NeliMintcheva, Kohtaro Osakada
    • Journal Title

      Organometailics 27

      Pages: 182-183

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Ligand Exchange of Diplatinum Complexes with Bridging Silyl Ligands Involving Si-H Bond Cleavage and Formation2008

    • Author(s)
      Makoto Tanabe, Daisuke lto, and Kohtaro Osakada
    • Journal Title

      Organometailics 28

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Arylpalladium Complexes with a Silsesquioxanate Ligand. Preparation and Structures in Solid State and in Solution2007

    • Author(s)
      Neli Mintcheva, 田邊真, 小坂田耕太郎
    • Journal Title

      Organometallics 26

      Pages: 1402-1410

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Dipalladium Complex with Bridging Silylene Ligands, [{Pd(dmpe)}_2(μ-SiPh_2)_2], Formed via Dimerization of Bis(silyl)palladium Complex2007

    • Author(s)
      田邊真, 馬渡あかね, 小坂田耕太郎
    • Journal Title

      Organometallics 26

      Pages: 2937-2940

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Preparation and NMR Studies of Palladium Complexes with a Silsesquioxanate Ligand2007

    • Author(s)
      田邊真, 武藤康二, Neli Mintcheva, 小坂田耕太郎
    • Journal Title

      Organometallics 27

      Pages: 182-183

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Arylpalladium Complexes with a Silsesquioxanate Ligand. Preparation and Structures in Solid State and in Solution2007

    • Author(s)
      Neli Mintcheva, Makoto Tanabe, and Kohtaro Osakada
    • Journal Title

      Organometallics 26

      Pages: 1402-1410

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Dipalladium Complex with Bridging Silylene Ligands, [{Pd(dmpe)}_2 )}_2(μ-SiPh_2)_2], Formed via Dimerization of Bis(silyl)palladium Complex2007

    • Author(s)
      Makoto Tanabe, Akane Mawatari, and Kohtaro Osakada
    • Journal Title

      Organometailics 26

      Pages: 2937-2940

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Presentation] 平面型四核パラジウムクラスターに橋架けするケイ素配位子の置換基効果2009

    • Author(s)
      田邊真, 星野剛, 小坂田耕太郎
    • Organizer
      日本化学会第89春季年会
    • Place of Presentation
      日本大学理工学部
    • Related Report
      2008 Final Research Report
  • [Presentation] 様々なシリレン橋架け配位子を持つ平面型四核パラジウムクラスターの合成2008

    • Author(s)
      星野剛, 田邊真, 馬渡あかね, 小坂田耕太郎
    • Organizer
      第58回錯体化学討論会
    • Place of Presentation
      金沢大学
    • Year and Date
      2008-09-21
    • Related Report
      2008 Annual Research Report
  • [Presentation] 平面型四核パラジウムクラスターに対する銅塩の熱可逆的な配位と解離2008

    • Author(s)
      福田智子, 田邊真, 星野剛, 小坂田耕太郎
    • Organizer
      第58回錯体化学討論会
    • Place of Presentation
      金沢大学
    • Year and Date
      2008-09-20
    • Related Report
      2008 Annual Research Report
  • [Presentation] Ge-Ge結合形成を伴うゲルマパラダサイクルの合成と触媒反応への展開2008

    • Author(s)
      半沢公也, 田邊真, 石川尚子, 小坂田耕太郎
    • Organizer
      第58回錯体化学討論会
    • Place of Presentation
      金沢大学
    • Year and Date
      2008-09-20
    • Related Report
      2008 Annual Research Report
  • [Presentation] Synthesis and Rearrangement of Tetrapalladium Clusters with Bridging Silylene or Germylene Ligands2008

    • Author(s)
      Makoto Tanabe, Akane Mawatari, Naoko Ishikawa, Kohtaro Osakada
    • Organizer
      Dalton Discussion 11 : The Renaissance of Main Group Chemistry
    • Place of Presentation
      University of California Berkeley
    • Year and Date
      2008-06-24
    • Related Report
      2008 Annual Research Report
  • [Presentation] Structures of Pt and Pd Complexes Containing Incompletely Condensed Silsesquio xanate Ligands in the Solid State and in Solution2008

    • Author(s)
      Kohtaro Osakada, Makoto Tanabe, Kohii Mutou, Neli Mintcheva
    • Organizer
      The 15th Internatinonal Symposium on Organosilicon Chemistry (ISOS XV)
    • Place of Presentation
      Jeju, Korea
    • Year and Date
      2008-06-04
    • Related Report
      2008 Annual Research Report
  • [Presentation] Mutinuclear Platinum and Palladium Complexes with Bridging Si-ligands. New Bridging Structures and Chemical Properties2008

    • Author(s)
      Makoto Tanabe, Akane Mawatari, Daisuke Ito, Kohatro Osakada
    • Organizer
      The 15th Internatinonal Symposium on Organosilicon Chemistry (ISOS XV)
    • Place of Presentation
      Jeju, Korea
    • Year and Date
      2008-06-03
    • Related Report
      2008 Annual Research Report
  • [Presentation] Preparation of Tetrapalladium Clusters with Various Diarylsilylene Ligands2008

    • Author(s)
      Tsuyoshi Hoshino, Makoto Tanabe, Akane Mawatari, Kohtaro Osakada
    • Organizer
      The 15th Internatinonal Symposium on Organosilicon Chemistry (ISOS XV)
    • Place of Presentation
      Jeju, Korea
    • Year and Date
      2008-06-02
    • Related Report
      2008 Annual Research Report
  • [Presentation] Structural Rearrangement of Tetrapalladium Clusters with Bridging Germylene Ligands2008

    • Author(s)
      Masaya Hanazawa, Makoto Tanabe, Naoko Ishikawa, Kohtaro Osakada
    • Organizer
      The 15th Internatinonal Symposium on Organosilicon Chemistry (ISOS XV)
    • Place of Presentation
      Jeju, Korea
    • Year and Date
      2008-06-02
    • Related Report
      2008 Annual Research Report
  • [Presentation] 11族金属錯体を含む平面型四核パラジウムクラスターの構造と溶液中における動的挙動2008

    • Author(s)
      福田智子・星野剛・田邊真・小坂田耕太郎
    • Organizer
      日本化学会第89春季年会
    • Place of Presentation
      日本大学理工学部
    • Year and Date
      2008-03-29
    • Related Report
      2008 Annual Research Report
  • [Presentation] 平面型四核パラジウムクラスターに橋架けするケイ素配位子の置換基効果2008

    • Author(s)
      田邊真・星野剛・小坂田耕太郎
    • Organizer
      日本化学会第89春季年会
    • Place of Presentation
      日本大学理工学部
    • Year and Date
      2008-03-29
    • Related Report
      2008 Annual Research Report
  • [Presentation] 後周期遷移金属錯体による連続的Ge-Ge結合形成反応の開発2008

    • Author(s)
      半深公也・田邊真・小坂田耕太郎
    • Organizer
      日本化学会第89春季年会
    • Place of Presentation
      日本大学理工学部
    • Year and Date
      2008-03-29
    • Related Report
      2008 Annual Research Report
  • [Presentation] 単核及び二核ゲルマパラダサイクルの合成とその生成機構の考察2008

    • Author(s)
      田邊真, 半沢公也, 石川尚子, 小坂田耕太郎
    • Organizer
      第55回有機金属討論会
    • Place of Presentation
      大阪府立大学
    • Related Report
      2008 Annual Research Report 2008 Final Research Report
  • [Presentation] Synthesis and Rearrangement of Tetrapalladium Clusters with Bridging Silylene or Germylene Ligands2008

    • Author(s)
      田邊真, 馬渡あかね, 石川尚子, 小坂田耕太郎
    • Organizer
      Dalton Discussion 11: The Renais sance of Main Group Chemistry
    • Place of Presentation
      University of California Berkeley
    • Related Report
      2008 Final Research Report
  • [Presentation] Mutinuclear Platinum and Palladium Complexes with Bridging Si-ligands. New Bridging Structures and Chemical Properties2008

    • Author(s)
      田邊真, 馬渡あかね, 伊藤大輔, 小坂田耕太郎
    • Organizer
      The 15th Internatinonal Symposium on Organosilicon Chemistry(ISOS XV)
    • Place of Presentation
      Jeju, Korea
    • Related Report
      2008 Final Research Report
  • [Presentation] アザフェロセンを配位子とする銅・パラジウム錯体の合成とその電気化学的性質2008

    • Author(s)
      田邊真, 林真実, 小坂田耕太郎
    • Organizer
      日本化学会第88春季年会
    • Place of Presentation
      立教大学
    • Related Report
      2008 Final Research Report 2007 Annual Research Report
  • [Presentation] 様々なジアリールシリレン基を持つ四核パフシワム錯体の合成2008

    • Author(s)
      星野剛・田邊真・小坂田耕太郎
    • Organizer
      日本化学会第88春季年会
    • Place of Presentation
      立教大学
    • Related Report
      2007 Annual Research Report
  • [Presentation] ブレンステッド酸との反応による平面型四核パラジウムクラスターの骨格変換2008

    • Author(s)
      半沢公也・石川尚子・田邊真・小坂田耕太郎
    • Organizer
      日本化学会第88春季年会
    • Place of Presentation
      立教大学
    • Related Report
      2007 Annual Research Report
  • [Presentation] Preparation and Butterfly-type Structure of Tetranuclear Palladium Clusters Containing Bridging Silylene and Thiolato Groups2007

    • Author(s)
      田邊真, 馬渡あかね, 小坂田耕太郎
    • Organizer
      1st Asian Silicon Symposium
    • Place of Presentation
      蔵王ハイツ
    • Related Report
      2008 Final Research Report 2007 Annual Research Report
  • [Presentation] Hexagonal Tetrapalladium Clusters with Bridging Silylene or Germylene Ligands2007

    • Author(s)
      田邊真, 石川尚子, 馬渡あかね, 小坂田耕太郎
    • Organizer
      XVII EuCheMS Conference on Organometallic Chemistry(COMC-17)
    • Place of Presentation
      Sofia Bulgaria
    • Related Report
      2008 Final Research Report
  • [Presentation] Hexagonal Tetrapalladium Clusters with Bridging Silylene or Germylene Ligands2007

    • Author(s)
      Makoto Tanabe・Naoko lshikawa・Aakane Mawatari・Kohtaro Osakada
    • Organizer
      XVII EuCheMS Conference on Organometallic Chemistry (COMC-17)
    • Place of Presentation
      Sofia Bulgaria
    • Related Report
      2007 Annual Research Report
  • [Presentation] 平面六角型Pd4Ge3クラスターの合成と反応性2007

    • Author(s)
      半沢公也・石川尚子・田邊真・小坂田耕太郎
    • Organizer
      第57回錯体化学討論会
    • Place of Presentation
      名古屋工業大学
    • Related Report
      2007 Annual Research Report
  • [Presentation] 平面六角型Pd4Si3クラスターに対する酸化的付加反応2007

    • Author(s)
      小林里江子・馬渡あかね・田邊真・小坂田耕太郎
    • Organizer
      第57回錯体化学討論会
    • Place of Presentation
      名古屋工業大学
    • Related Report
      2007 Annual Research Report
  • [Presentation] 非対称ジシリル基を持つビス(シリル)パラジウム錯体の合成と反応2007

    • Author(s)
      星野剛・田邊真・小坂田耕太郎
    • Organizer
      第57回錯体化学討論会
    • Place of Presentation
      名古屋工業大学
    • Related Report
      2007 Annual Research Report
  • [Presentation] パラダシルセスキオキサン錯体の合成とその熱分解2007

    • Author(s)
      武藤康二・田邊真・Mintcheva Neli・小坂田耕太郎
    • Organizer
      第57回錯体化学討論会
    • Place of Presentation
      名古屋工業大学
    • Related Report
      2007 Annual Research Report
  • [Presentation] シリレン架橋平面型パラジウム四核錯体の合成とカルコゲンとの反応性2007

    • Author(s)
      馬渡あかね・田邊真・小坂田耕太郎
    • Organizer
      第57回錯体化学討論会
    • Place of Presentation
      名古屋工業大学
    • Related Report
      2007 Annual Research Report
  • [Presentation] Syntheses of Mononuclear Platinum(II) Complexes with Secondary Phosphine Ligands and their Reactivity2007

    • Author(s)
      Masaki Kakeya, Makoto Tanabe, Kohtaro Osakada
    • Organizer
      Singapore International Chemistry Conference 5 (SICC-5)
    • Place of Presentation
      Suntec Singapore
    • Related Report
      2007 Annual Research Report
  • [Book] シルセスキオキサンの合成と応用展開2007

    • Author(s)
      田邊真, 小坂田耕太郎
    • Publisher
      シーエムシー出版
    • Related Report
      2008 Final Research Report
  • [Book] 「シルセスキオキサンの合成と応用展開」2007

    • Author(s)
      田邊真, 小坂田耕太郎
    • Publisher
      シーエムシー出版
    • Related Report
      2007 Annual Research Report

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Published: 2007-04-01   Modified: 2016-04-21  

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