Development of Efficient Molecular Transformation Based on Silicon- Carbon or Borane-Carbon Bond Activation
| Project/Area Number |
19750071
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Single-year Grants |
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| Research Field |
Synthetic chemistry
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| Research Institution | University of Toyama |
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Principal Investigator |
HORINO Yoshikazu University of Toyama, 大学院・理工学研究部, 助教 (30447651)
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| Project Period (FY) |
2007 – 2009
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| Project Status |
Completed (Fiscal Year 2009)
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| Budget Amount *help |
¥3,620,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥420,000)
Fiscal Year 2009: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2008: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2007: ¥1,800,000 (Direct Cost: ¥1,800,000)
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| Keywords | ケイ素 / 金 / パラジウム / アルキン / クロスアルドール反応代替法 / 金触媒 / ブレンステッド酸 / アリルシラン / アリル化反応 / シラノール / クロスアルドール反応 / Claisen転位反応 / ルイス酸 / 炭素-炭素結合反応 / 触媒反応 / ビニルシリル化 / カチオン性金触媒 / アレン / 金カルベン / C-H挿入反応 |
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| Research Abstract |
Transition metal catalyzed novel carbon-carbon bond formation reactions based on silicon-carbon bond activation have been studied. The concept of combining gold catalysis and organocatalysis applied for intramolecular allylation of allylsilanes to ynones lead to the development of ketone-ketone cross-aldol surrogate reaction. On the other hand, we were able to get succeed in the generation of palladium carbenoide species from α-(trimethylsilyl)-π-allylpalladium intermediate under very mild reaction condition.
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Report
(4 results)
Research Products
(79 results)
