Construction and application of enzyme-mimetic model based on molecular recognition of sulfur-containing oligophenols.
| Project/Area Number |
19750104
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Single-year Grants |
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| Research Field |
Functional materials chemistry
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| Research Institution | Yamagata University |
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Principal Investigator |
KATAGIRI Hiroshi Yamagata University, 大学院・理工学研究科, 助教 (40447206)
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| Project Period (FY) |
2007 – 2010
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| Project Status |
Completed (Fiscal Year 2010)
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| Budget Amount *help |
¥3,950,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥450,000)
Fiscal Year 2010: ¥520,000 (Direct Cost: ¥400,000、Indirect Cost: ¥120,000)
Fiscal Year 2009: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2008: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2007: ¥2,000,000 (Direct Cost: ¥2,000,000)
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| Keywords | 分子認識 / 酵素モデル / 芳香族オリゴマー / 構造制御 / 水素結合 / スルホキシド / アニリン / スルホン / フェノール / 不斉触媒反応 |
|---|
| Research Abstract |
Structural control of flexible aromatic oligomers have been achieved by using of the properties of sulfur atoms. Particularly, peptide-like hydrogen bonds between amino and sulfonyl groups promoted the intramolecular charge transfer (ICT) in aniline-based oligomers, which can be expected as a promising new class of fluorescent materials.
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Report
(6 results)
Research Products
(57 results)
