Construction of Functional Supramolecular Hybrids Using Macrocyclic Host Molecules

• Project/Area Number: 19750110
• Research Category: Grant-in-Aid for Young Scientists (B)
• Allocation Type: Single-year Grants
• Research Field: Functional materials chemistry
• Research Institution: Kanazawa University
• Principal Investigator: OGOSHI Tomoki Kanazawa University, 物質化学系, 助教 (00447682)
• Project Period (FY): 2007 – 2008
• Project Status: Completed (Fiscal Year 2008)
• Budget Amount: ¥3,790,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥390,000); Fiscal Year 2008: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000); Fiscal Year 2007: ¥2,100,000 (Direct Cost: ¥2,100,000)
• Keywords: SWNT / CD / カリックスアレーン / ククルビツリル / ホスト-ゲスト包接錯体 / ナノ材料 / カーボンナノチューブ / シクロデキストリン / 超分子化学 / 環状化合物 / ホストーゲスト包接錯体

Research Abstract

環状ホスト分子であるシクロデキストリン(CD)を用いて単層カーボンナノチューブ(SWNT)の可溶化を行った。CDのみ、もしくはゲスト分子のみでは、SWNTを溶解させることができなかったが、CD-ゲスト包接錯体を用いた場合、SWNTを可溶化できることが分かった。また、ククルビツリル、水溶性カリックスアレーン、ピレン基を導入したCD誘導体を利用し、SWNTの周りに環状ホスト分子を導入した超分子複合体を得ることにも成功した。

Research Products

• [Journal Article] Columnar Stacks of Starand Tadpole-Shaped Polyoxazolines Having Triphenylene Moiety and Their Applications for Synthesis of Wire-Assembled Gold Nanoparticles (2009)
  • Author(s): Ogoshi, T.; Hiramitsu, S.; Yamagishi, T.; Nakamoto, Y.
  • Journal Title: Macromolecules (in press)
  • Peer Reviewed
• [Journal Article] Solubilization of Single-Walled Carbon Nanotubes by Entanglements between Them and Hyperbranched Phenolic Polymer (2009)
  • Author(s): Ogoshi, T.; Saito, T.; Yamagishi, T.; Nakamoto, Y.
  • Journal Title: Carbon 47 Pages: 117-123
  • NAID: 120001008418
  • Peer Reviewed
• [Journal Article] Solubilization of Single-Walled Carbon Nanotubes by Entanglements between Them and Hyperbranched Phenolic Polymer (2009)
  • Author(s): 生越友樹、斉藤貴之、山岸忠明、中本義章
  • Journal Title: Carbon 47 Pages: 117-123
  • NAID: 120001008418
  • Peer Reviewed
• [Journal Article] Columnar Stacks of Star- and Tadpote-Shaped Polyoxazolines Having Triphenylene Moiety and Their Applications for Synthesis of Wire-Assembled Gold Nanoparticles (2009)
  • Author(s): 生越友樹、平光さち、山岸忠朋、中本義章
  • Journal Title: Macromolecules (印刷中)(掲載確定)
  • Peer Reviewed
• [Journal Article] Green Polymerization of Phenol in Ionic Liquids (2008)
  • Author(s): Ogoshi, T.; Onodera, T.; Yamagishi, T.; Nakamoto, Y.
  • Journal Title: Macromolecules 41 Pages: 8533-8536
  • Peer Reviewed
• [Journal Article] Enhancement of Water-Solubility of Single-Walled Carbon Nanotubes by Formation of Host-Guest Complexes of Cyclodextrins with Various Guest Molecules (2008)
  • Author(s): Ogoshi, T.; Ikeya, M.; Yamagishi, T.; Nakamoto, Y.; Harada, A.
  • Journal Title: J. Phys. Chem. C 112 Pages: 13079-13083
  • Peer Reviewed
• [Journal Article] Synthesis of Phenolic Polymer-Coated Gold Nanoparticles (2008)
  • Author(s): Ogoshi, T.; Umeda, K.; Yamagishi, T.; Nakamoto, Y.
  • Journal Title: Polym. J. 40 Pages: 942-943
  • NAID: 10024341843
  • Peer Reviewed
• [Journal Article] para-Bridged Symmetrical Pillar[5]arenes: Their Lewis Acid-Catalyzed Synthesis and Host-Guest Property (2008)
  • Author(s): Ogoshi, T.; Kanai, S.; Fujinami, S.; Yamagishi, T.; Nakamoto, Y.
  • Journal Title: J. Am. Chem. Soc. 130 Pages: 5022-5023
  • Peer Reviewed
• [Journal Article] Defection-Selective Solubilization and Chemically-Responsive Solubility Switching of Single-Walled Carbon Nanotubes with Cucurbit[7]uril (2008)
  • Author(s): Ogoshi, T.; Inagaki, A.; Yamagishi, T.; Nakamoto, Y.
  • Journal Title: Chem. Commun. Pages: 2245-2247
  • NAID: 120001130310
  • Peer Reviewed
• [Journal Article] Synthesis of Phenolic Polymer-Coated Gold Nanoparticles (2008)
  • Author(s): 生越友樹、梅田謙治、山岸忠明、中本義章
  • Journal Title: Polym. J. 40 Pages: 942-943
  • NAID: 10024341843
  • Peer Reviewed
• [Journal Article] Enhancement of Water-Solubility of Singlc-Walled Carbon Nanotubes by Formation of Host-Guest Complexes of Cyclodextrins with Various Guest Molecules (2008)
  • Author(s): 生越友樹、池谷光博、山岸忠明、中本義章、原田明
  • Journal Title: J. Phys. Chem. C 112 Pages: 13079-13083
  • Peer Reviewed
• [Journal Article] Chemical Sensors Based on Cyclodextrin (2008)
  • Author(s): 生越友樹、原田明
  • Journal Title: Sensors 8 Pages: 4961-4982
  • Peer Reviewed
• [Journal Article] Green Polymerization of Phenol in Ionic Liquids (2008)
  • Author(s): 生越友樹、梅田謙治、山岸忠明、中本義章
  • Journal Title: Macromolecules 41 Pages: 8533-8536
  • Peer Reviewed
• [Journal Article] Supramolecular Single-Walled Carbon Nanotubes (SWCNTs) Network Polymer Made by Hybrids of SWCNTs and Water Soluble Calix[8]arenes (2007)
  • Author(s): Ogoshi, T.; Yamagishi, T.; Nakamoto, Y.
  • Journal Title: Chem. Commun. Pages: 4776-4778
  • Peer Reviewed
• [Journal Article] Water Soluble Single-Walled Carbon Nanotubes Using Inclusion Complex of Cyclodextrin with an Adamantane Derivative (2007)
  • Author(s): Ogoshi, T.; Yamagishi, T.; Nakamoto, Y.; Harada, A.
  • Journal Title: Chem. Lett. 36 Pages: 1026-1027
  • NAID: 10019744294
  • Peer Reviewed
• [Journal Article] Chemically-Responsive Sol-Gel Transition of Supramolecular Single-Walled Carbon Nanotubes (SWNTs) Hydrogel Made by Hybrids of SWNTs and Cyclodextrins (CDs) (2007)
  • Author(s): Ogoshi, T.; Takashima, Y.; Yamaguchi, H.; Harada, A.
  • Journal Title: J. Am. Chem. Soc. 129 Pages: 4878-4879
  • Peer Reviewed
• [Journal Article] Supramolecular Single-walled Carbon Nanotubes (SWCNTs) Network Polymer Made by Hybrids of SWCNTs and Water SolubleCalix[8]arenes (2007)
  • Author(s): 生越 友樹
  • Journal Title: Chem. Commun. Pages: 4776-4778
  • Peer Reviewed
• [Journal Article] Water Soluble Single-walled Carbon Nanotubes Using Inclusion Complex of Cyclodextrin with an Adamantane Derivative (2007)
  • Author(s): 生越 友樹
  • Journal Title: Chem. Lett. 36 Pages: 1026-1027
  • NAID: 10019744294
  • Peer Reviewed
• [Journal Article] Defection-Selective Solubilization and Chemically-Responsive Solubility Switching of Single-Walled Carbon Nanotubes with Cucurbit[7]uril
  • Author(s): 生越 友樹
  • Journal Title: Chem. Commun. (印刷中)
  • NAID: 120001130310
  • Peer Reviewed
• [Journal Article] para-Bridged Symmetrical Pillar[5]arenes: Their Lewis Acid-Catalyzed Synthesis and Host-Guest Property
  • Author(s): 生越 友樹
  • Journal Title: J. Am. Chem. Soc. (印刷中)
  • Peer Reviewed
• [Presentation] 環状ホスト分子を利用した単層カーボンナノチューブ超分子材料の創成 (2009)
  • Author(s): 生越 友樹
  • Organizer: 第89会春季日本化学会年会(若い世代の特別講演会)
  • Place of Presentation: 千葉・船橋市
  • Year and Date: 2009-03-28
• [Presentation] 環状ホスト分子を利用した単層カーボンナノチューブ超分子材料の創成 (2009)
  • Author(s): 生越友樹
  • Organizer: 第89会春季日本化学会年会
  • Place of Presentation: 千葉・船橋市
  • Year and Date: 2009-03-28
• [Presentation] Synthesis and Host-Guest Property of para-Bridged "Pillar[5]arene" (2008)
  • Author(s): Ogoshi, T.; Kanai, S.; Fujinami, S.; Yamagishi, T.; Nakamoto, Y.
  • Organizer: LXII Yamada Conference 2008
  • Place of Presentation: 兵庫・淡路島
  • Year and Date: 2008-09-03
• [Presentation] Enhancement of Water-Solubility of Single-Walled Carbon Nanotubes by Formation of Host-Guest Complexes of Cyclodextrins with Various Guest Molecules (2008)
  • Author(s): Ogoshi, T.; Ikeya, M.; Yamagishi, T.; Nakamoto, Y.; Harada, A.
  • Organizer: 14th International Cyclodextrins Symposium
  • Place of Presentation: 京都・京都市
  • Year and Date: 2008-05-10
• [Presentation] ホスト分子被覆π共役高分子・超分子の創成 (2007)
  • Author(s): 生越 友樹
  • Organizer: 平成19年度北陸地区高分子若手研究会(若手招待講演)
  • Place of Presentation: 富山・富山市
  • Year and Date: 2007-11-16
• [Presentation] Chemistry-Responsive Sol-Gel Transition of Supramolecular Single-Walled Carbon Nanotubes (SWNTs) Hydrogel Made by Hybrids of SWNTs-Cyclodextrins Hybrids (2007)
  • Author(s): Ogoshi, T.; Yamagishi, T.; Nakamoto, Y.; Harada, A.
  • Organizer: 2nd International Symposium on Macrocyclic and Supramolecular Chemistry
  • Place of Presentation: イタリア・Salice Terme
  • Year and Date: 2007-06-26
• [Presentation] Chemically-Responsive Sol-Gel Transition of Supramolecular Single-Walled Carbon Nanotubes (SWNTs) Hydrogel Made by SWNTs-Cyclodextrins Hybrids (2007)
  • Author(s): 生越 友樹
  • Organizer: 2nd International Symposium on Macrocyclic and Supramolecular Chemistry
  • Place of Presentation: イタリア、Salice Terme
  • Year and Date: 2007-06-26
• [Book] 環状ホスト分子を利用したカーボンナノチューブ超分子材料の創成, カーボンナノチューブの表面処理・分散処理技術(分担執筆) (2009)
  • Author(s): 生越 友樹、山岸 忠明、中本 義章、原田 明
  • Publisher: (掲載確定)
• [Book] 藻状ホスト分子を利用した単層カーボンナノチューブ超分子材料の創成 (2009)
  • Author(s): 生越友樹
  • Publisher: 技術情報協会(印刷中)掲載確定)
• [Book] 環状ホスト分子を利用したカーボンナノチューブの可溶化と応用、有機分散系の分散・凝集技術(分担執筆) (2008)
  • Author(s): 生越 友樹、山岸 忠明、中本 義章、原田 明
• [Book] 環状ホスト分子を利用した単層カーボンナノチューブの可溶化と応用 (2008)
  • Author(s): 生越友樹
  • Publisher: シーエムシー出版
• [Remarks] ホームページアドレス
  • URL: http://kohka.ch.t.kanazawa-u.ac.jp/lab3/lab3.html
• [Remarks]
  • URL: http://kohka.ch.t.kanazawa-u.ac.jp/lab3/lab3.html