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Synthesis of functional hybrid materials of inorganic nanosheet and organic polymer with entropy-driven meso-structure

Research Project

Project/Area Number 19750189
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeSingle-year Grants
Research Field Polymer/Textile materials
Research InstitutionFukuoka Institute of Technology

Principal Investigator

MIYAMOTO Nobuyoshi  Fukuoka Institute of Technology, 工学部, 講師 (80391267)

Project Period (FY) 2007 – 2008
Project Status Completed (Fiscal Year 2008)
Budget Amount *help
¥3,710,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥210,000)
Fiscal Year 2008: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2007: ¥2,800,000 (Direct Cost: ¥2,800,000)
Keywordsブレンド・複合材料 / 無機層状物質 / 無機ナノシート液晶 / 粘土-高分子複合体 / 温度応答性高分子 / ポリNイソプロピルアクリルアミド / ポリNイソプロピレアクリルアミド
Research Abstract

粘土鉱物系の2種類のナノシート液晶系を新たに見いだし、これらをポリN-イソプロピルアクリルアミドと複合化したゲルを合成した。得られたゲルには、マクロ配向した巨大メソゲンの無機ナノシート液晶が埋め込まれているため、屈折率異方性や異方的な熱誘起体積相転移などの興味深い物性が発現した。低分子液晶を用いて得られる従来の液晶ゲルとは原理的に大きく異なった新しいタイプの液晶ゲルが得られた。

Report

(3 results)
  • 2008 Annual Research Report   Final Research Report ( PDF )
  • 2007 Annual Research Report
  • Research Products

    (19 results)

All 2009 2008 Other

All Journal Article (2 results) Presentation (15 results) Remarks (2 results)

  • [Journal Article] "Isotropic?Liquid Crystal Transiti on of Fluorohectorite Colloid"2008

    • Author(s)
      N. Miyamoto, H. Ohkubo, H. Iijima,
    • Journal Title

      福岡工業大学環境科学研究所所報 第2巻

      Pages: 17-20

    • Related Report
      2008 Final Research Report
  • [Journal Article] Isotropic-Liquid Crystal Transition of Fluorohectorite Colloid2008

    • Author(s)
      N. Miyamoto, H. Ohkubo, H. Iijima
    • Journal Title

      福岡工業大学環境科学研究所所報 第2巻

      Pages: 17-20

    • Related Report
      2008 Annual Research Report
  • [Presentation] 中性子小角散乱法による粘土鉱物ナノシート液晶の構造解析2009

    • Author(s)
      宮元展義、飯島宏和、山口大輔
    • Organizer
      日本化学会第89春季年会
    • Place of Presentation
      日本大学理工学部・船橋キャンパス
    • Year and Date
      2009-03-29
    • Related Report
      2008 Final Research Report
  • [Presentation] 中性子小角散乱法による粘土鉱物ナノシート液晶の構造解析2009

    • Author(s)
      宮元展義、飯島宏和、山口大輔
    • Organizer
      日本化学会第89春季年会
    • Place of Presentation
      日本大学理工学部・船橋キャンパス(千葉)
    • Year and Date
      2009-03-29
    • Related Report
      2008 Annual Research Report
  • [Presentation] "Anisotropic Volume Phase Transition of Poly(N-Isopropylacrylamide) Hydrogel Hybridized with Inorganic Nan osheet Liquid Crystal"2009

    • Author(s)
      Nobuyoshi Miyamoto, Morio Shintate, Yasutomo Hoshida, Ryuhei Motokawa,
    • Organizer
      The 4th LSW Symposium on Soft and Wet Matter,
    • Place of Presentation
      Ho kkaido Univ.
    • Year and Date
      2009-01-09
    • Related Report
      2008 Final Research Report
  • [Presentation] Anisotropic Volume Phase Transition of Poly(N-Isopropylacrylamide) Hydrogel Hybridized with Inorganic Nanosheet Liquid Crystal2009

    • Author(s)
      Nobuyoshi Miyamoto, Morio Shintate, Yasutomo Hoshida, Ryuhei Motokawa
    • Organizer
      The 4th LSW Symposium on Soft and Wet Matter
    • Place of Presentation
      北海道大学・百記念会館(北海道)
    • Year and Date
      2009-01-09
    • Related Report
      2008 Annual Research Report
  • [Presentation] "Anisotropic Volume Phas e Transition of Poly(N-Isopropyla crylamide) Hydrogel Hybridized with Inorganic Nanosheet Liquid Crystal"2008

    • Author(s)
      N. Miyamoto, M. Shintate, Y. Hoshida, R. Motokawa
    • Organizer
      International Union of Materials Research Science? International Conference in Asia (IUMRS?ICA2008)
    • Place of Presentation
      Nagoya(名古屋国際会議場)
    • Year and Date
      2008-12-12
    • Related Report
      2008 Final Research Report
  • [Presentation] Liquid Crystal Transition of Clay Mineral Nanosheet Colloids2008

    • Author(s)
      N. Miyalnoto, H. Iijilna, and H. Ohkub O
    • Organizer
      International Unionn of Materials Research Science- lnternational Conference in Asia(IUMRS-ICA2008)
    • Place of Presentation
      Nagoya(名古屋国際会議場)
    • Year and Date
      2008-12-12
    • Related Report
      2008 Final Research Report
  • [Presentation] Anisotropic Volume Phase Transition of Poly(N-Isopropylacrylamide) Hydrogel Hybridized with Inorganic Nanosheet Liquid Crystal2008

    • Author(s)
      N. Miyamoto, M. Shintate, Y. Hoshida, R. Motokawa
    • Organizer
      International Union of Materials Research Science-International Conference in Asia (IUMRS-ICA2008)
    • Place of Presentation
      名古屋国際会議場(愛知)
    • Year and Date
      2008-12-12
    • Related Report
      2008 Annual Research Report
  • [Presentation] Liquid Crystal Transition of Clay Mineral Nanosheet Colloids2008

    • Author(s)
      N. Miyamoto, H. Iijima, and H. Ohkubo
    • Organizer
      International Union of Materials Research Science-International Conference in Asia (IUMRS-ICA2008)
    • Place of Presentation
      名古屋国際会議場(愛知)
    • Year and Date
      2008-12-12
    • Related Report
      2008 Annual Research Report
  • [Presentation] 無機ナノシート液晶-ポリ(N-イソプロピルアクリルアミド)複合ゲルの合成と異方的な体積相転移2008

    • Author(s)
      宮元展義、新立盛生、元川竜平
    • Organizer
      第57回高分子討論会
    • Place of Presentation
      大阪市立大
    • Year and Date
      2008-09-24
    • Related Report
      2008 Final Research Report
  • [Presentation] 無機ナノシート液晶-ポリ(N-イソプロピルアクリルアミド)複合ゲルの合成と異方的な体積相転移2008

    • Author(s)
      宮元展義、新立盛生、元川竜平
    • Organizer
      第57回高分子討論会
    • Place of Presentation
      大阪市立大学(大阪)
    • Year and Date
      2008-09-24
    • Related Report
      2008 Annual Research Report
  • [Presentation] 無機ナノシートコロイドの液晶相転移挙動2008

    • Author(s)
      宮元展義、飯島宏和
    • Organizer
      第61回コロイドおよび界面化学討論会
    • Place of Presentation
      九州大学(福岡)
    • Year and Date
      2008-09-07
    • Related Report
      2008 Annual Research Report 2008 Final Research Report
  • [Presentation] 層状粘土鉱物コロイドの液晶転移2008

    • Author(s)
      飯島宏和、宮元展義
    • Organizer
      第52回粘土科学討論会
    • Place of Presentation
      沖縄ポートホテル(沖縄)
    • Year and Date
      2008-09-05
    • Related Report
      2008 Annual Research Report 2008 Final Research Report
  • [Presentation] 粘土鉱物ナノシート液晶/ポリN-イソプロピルアクリルアミド複合ゲルの合成2008

    • Author(s)
      宮元展義、星田泰智、元川竜平
    • Organizer
      第57回高分子学会年次大会
    • Place of Presentation
      パシフィコ横浜(神奈川)
    • Year and Date
      2008-05-30
    • Related Report
      2008 Annual Research Report
  • [Presentation] 粘土鉱物ナノシート液晶/ポリN-イソプロピルアクリルアミド複合ゲルの合成2008

    • Author(s)
      宮元展義、星田泰智、元川竜平
    • Organizer
      第57回高分子学会年次大会
    • Place of Presentation
      横浜
    • Related Report
      2008 Final Research Report
  • [Presentation] フルオロヘクトライトコロイドのゲル化を伴わない液晶転移2008

    • Author(s)
      宮元展義、大久保浩一
    • Organizer
      日本化学会第88春季年会
    • Place of Presentation
      立教大学
    • Related Report
      2008 Final Research Report 2007 Annual Research Report
  • [Remarks]

    • URL

      http://www.fit.ac.jp/~miyamoto/

    • Related Report
      2008 Final Research Report
  • [Remarks]

    • URL

      http://www.fit.ac.jp/miyamoto

    • Related Report
      2008 Annual Research Report

URL: 

Published: 2007-04-01   Modified: 2016-04-21  

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