Formation of high order structure with functionalized nanospace by hybridization using inorganic nanosheet

• Project/Area Number: 19760465
• Research Category: Grant-in-Aid for Young Scientists (B)
• Allocation Type: Single-year Grants
• Research Field: Inorganic materials/Physical properties
• Research Institution: University of Yamanashi
• Principal Investigator: TAKEI Takahiro University of Yamanashi, 大学院医学工学総合研究部, 准教授 (50324182)
• Project Period (FY): 2007 – 2008
• Project Status: Completed (Fiscal Year 2008)
• Budget Amount: ¥3,690,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥390,000); Fiscal Year 2008: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000); Fiscal Year 2007: ¥2,000,000 (Direct Cost: ¥2,000,000)
• Keywords: ナノシート / 機能性ナノスペース / 高次ナノ構造 / 電気化学 / キャパシタ / 複合化 / ナノスペース / ナノ材料 / 化学修飾 / 電気泳動 / 金属リン酸塩

Research Abstract

層状構造を持つ無機化合物を剥離させることで得られる非常に微細なナノシートを用いて、ナノ空間を有する構造の膜の作製に成功した。複数のリン酸ジルコニウムナノシート間に、電気伝導度が高く電解質を含む溶液中で電気の充放電が可能な導電性高分子と、支柱となる有機分子を共に挟み込んだナノレベルの構造を作製することで、導電性高分子の反応性が改善され、電気を充放電できる量を示すキャパシタ特性が大幅に向上した。

Research Products

• [Journal Article] Preparation of Oriented Titanium Phosphate and Tin Phosphate / Polyaniline Hybrid Films by Electrochemical Deposition (2008)
  • Author(s): Takahiro Takei
  • Journal Title: Langmuir 24 Pages: 8554-8560
  • Peer Reviewed
• [Journal Article] Anodic Electrodeposition of Redoxable Film from Manganese Oxide Nanosheet (2008)
  • Author(s): Takahiro Takei
  • Journal Title: J. Ceram. Soc. Jpn. 116 Pages: 1222-1227
  • NAID: 110006987520
  • Peer Reviewed
• [Journal Article] Preparation of Silylated α-Zirconium Phosphate, and Its Thermal Behavior (2008)
  • Author(s): Takahiro Takei, Nobuhiro Kumada, Nobukazu Kinomura, Hirokazu Nakayama, Mitsutomo Tsuhako
  • Journal Title: Mater. Res. Bull. 43 Pages: 111-119
  • Peer Reviewed
• [Journal Article] Anodic Electrodeposition of Redoxable Film from Manganese Oxide Nanosheet (2008)
  • Author(s): Takahiro Takei
  • Journal Title: J. Ceram. Soc. Jpn 116 Pages: 1222-1227
  • NAID: 110006987520
  • Peer Reviewed
• [Journal Article] Preparation of Oriented Titanium Phosphate and Tin Phosphate/Polyaniline Hybrid Films by Electrochemical Deposition (2008)
  • Author(s): Takahiro Takei
  • Journal Title: Langmuir 24 Pages: 8554-8560
  • Peer Reviewed
• [Journal Article] Preparation of Silylated a-Zirconium Phosphateand Its Thermal Behavior (2008)
  • Author(s): T.Takei, N.Kumada, N.Kinomura, H.Nakayama, M.Tsuhako
  • Journal Title: Mater.Res.Bull. 43 Pages: 111-119
  • Peer Reviewed
• [Journal Article] Formation Kinetics of Chemically Vapor-Deposited Carbon, on Mesoporous Silica (2007)
  • Author(s): Takahiro Takei, Teruyuki Dobashi, Yoshinori Yonesaki, Nobuhiro Kumada and Nobukazu Kinomura
  • Journal Title: J. Ceram. Soc. Jpn. 115 Pages: 541-545
  • NAID: 130000305391
  • Peer Reviewed
• [Journal Article] Silylation of Layered Zirconium Hydroxy Phosphate, and Its Porous Properties (2007)
  • Author(s): Takahiro Takei, Yoshinori Yonesaki, Nobuhiro Kumada and Nobukazu Kinomura
  • Journal Title: J. Mater. Sci. 42 Pages: 2837-2843
  • Peer Reviewed
• [Journal Article] Formation Kinetics of Chemically Vapor-Deposited Carbon on Mesoporous Silica (2007)
  • Author(s): T.Takei, T.Dobashi, Y.Yonesaki, N.Kumada and N.Kinomura
  • Journal Title: J.Ceram.Soc.Jpn. 115 Pages: 541-545
  • NAID: 130000305391
  • Peer Reviewed
• [Journal Article] Silylation of Layered Zirconium Hydroxy Phosphate and Its Porous Properties (2007)
  • Author(s): T.Takei, Y.Yonesaki, N.Kumad a and N.Kinomura
  • Journal Title: J.Mater.Sci. 42 Pages: 2837-2843
  • Peer Reviewed
• [Presentation] 遷移金属添加バーネサイトナノシート電着膜の電気化学特性 (2009)
  • Author(s): 武井貴弘、米崎功記、熊田伸弘、木野村暢一
  • Organizer: 電気化学会第76回大会
  • Place of Presentation: 京都
  • Year and Date: 2009-03-29
• [Presentation] 有機シラン修飾リン酸ジルコニウム-ポリアニリン複合膜の作製と電気化学特性 (2008)
  • Author(s): 武井貴弘、米崎功記、熊田伸弘、木野村暢一
  • Organizer: 日本セラミックス協会第21回秋季シンポジウム
  • Place of Presentation: 北九州
  • Year and Date: 2008-09-17
• [Presentation] 有機シラン修飾リン酸ジルコニウムーポリアニリン複合膜の作製と電気化学特性 (2008)
  • Author(s): 武井貴弘
  • Organizer: 日本セラミックス協会第21回秋季シンポジウム
  • Place of Presentation: 北九州
  • Year and Date: 2008-09-17
• [Presentation] Effect of Organosilane-Grafting to Layered Zirconium Phosphate on Redox Behavior for Electrodeposited Zirconium Phosphate/Polyaniline Hybrid Film (2008)
  • Author(s): Takahiro Takei, Yoshinori Yonesaki, Nobuhiro Kumada and Nobukazu Kinomura
  • Organizer: STAC2-STSI1
  • Place of Presentation: Makuhari
  • Year and Date: 2008-05-31
• [Presentation] 電気化学的手法による有機分子導入リン酸ジルコニウム-ポリアニリン複合配向膜の作製 (2008)
  • Author(s): 武井貴弘、米崎功記、熊田伸弘、木野村暢一
  • Organizer: 日本セラミックス協会2008年年会
  • Place of Presentation: 長岡
  • Year and Date: 2008-03-22
• [Presentation] 電気化学的手法による有機分子導入リン酸ジルコニウムーポリアニリン複合配向膜の作製 (2008)
  • Author(s): 武井貴弘, 米崎功記, 熊田伸弘, 木野村暢一
  • Organizer: 日本セラミックス協会2008年年会
  • Place of Presentation: 長岡技術科学大学
  • Year and Date: 2008-03-22
• [Remarks] ホームページ等
  • URL: http://www.inorg.yamanashi.ac.jp/ccst/laboratories/kinomura-lab/index-j.html