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Control of kinetic microstructure change in the gas separation membrane of metal complex oxide and extension of lifetime

Research Project

Project/Area Number 19760518
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeSingle-year Grants
Research Field Metal making engineering
Research InstitutionTokyo Institute of Technology

Principal Investigator

UEDA Mitsutoshi  Tokyo Institute of Technology, 大学院・理工学研究科, 助教 (90376939)

Project Period (FY) 2007 – 2009
Project Status Completed (Fiscal Year 2009)
Budget Amount *help
¥3,670,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥570,000)
Fiscal Year 2009: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2008: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2007: ¥1,200,000 (Direct Cost: ¥1,200,000)
Keywords金属複酸化物 / 酸素分離膜 / 酸素ポテンシャル勾配 / 酸素透過 / 動力学的組織変化 / イオンの流れの発散 / 化学ポテンシャル勾配 / 欠陥構造 / 拡散係数の酸素分圧依存性 / イオンの流束 / イオンの流束の発散
Research Abstract

Kinetic microstructure change in the membrane of SrCo_<0.8>Fe_<0.2>O_<3-δ> under the oxygen chemical potential gradient at 1173 K was experimentally observed in this study. From the experimental results, it was found that microstructure of the membrane drastically changed by the oxygen permeation through the membrane. Although this study also tried to estimate the microstructure change by calculating the divergence of the ionic flux through the membrane, it was difficult to obtain the calculated results.

Report

(4 results)
  • 2009 Annual Research Report   Final Research Report ( PDF )
  • 2008 Annual Research Report
  • 2007 Annual Research Report
  • Research Products

    (4 results)

All 2010

All Presentation (4 results)

  • [Presentation] 金属酸化物中の動力学的組織変化の定量的予測と金属の高温酸化への応用2010

    • Author(s)
      上田光敏
    • Organizer
      電気化学会第77回大会(特1K09)
    • Place of Presentation
      富山大学五福キャンパス, 富山
    • Year and Date
      2010-03-29
    • Related Report
      2009 Final Research Report
  • [Presentation] 金属酸化物中の動力学的組織変化の定量的予測と金属の高温酸化への応用2010

    • Author(s)
      上田光敏
    • Organizer
      電気化学会第77回大会(特1K09)
    • Place of Presentation
      富山大学五福キャンパス
    • Year and Date
      2010-03-29
    • Related Report
      2009 Annual Research Report
  • [Presentation] 1173 K, 酸素ポテンシャル勾配下におけるSrCo0. 8Fe0. 2O3-δ酸素分離膜中の組織変化の観察2010

    • Author(s)
      上田光敏, 河村憲一, 丸山俊夫
    • Organizer
      第5回固体イオニクスセミナー
    • Place of Presentation
      モンタナリゾート岩沼, 宮城(ポスター発表)
    • Related Report
      2009 Final Research Report
  • [Presentation] 1173K, 酸素ポテンシャル勾配下におけるSrCo_<0.8>Fe_<0.2>O_<3-δ>酸素分離膜中の組織変化の観察2010

    • Author(s)
      上田光敏, 河村憲一, 丸山俊夫
    • Organizer
      第5回固体イオニクスセミナー(ポスター発表:P-26)
    • Place of Presentation
      モンタナリゾート岩沼, 宮城
    • Related Report
      2009 Annual Research Report

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Published: 2007-04-01   Modified: 2016-04-21  

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