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Control of Acid-Site Location of Nano-Crystalline ZSM-5 Zeolite and its Application to Propylene Synthesis

Research Project

Project/Area Number 19760531
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeSingle-year Grants
Research Field Reaction engineering/Process system
Research InstitutionHokkaido University

Principal Investigator

TAGO Teruoki  Hokkaido University, 大学院・工学研究科, 准教授 (20304743)

Project Period (FY) 2007 – 2008
Project Status Completed (Fiscal Year 2008)
Budget Amount *help
¥3,660,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥360,000)
Fiscal Year 2008: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2007: ¥2,100,000 (Direct Cost: ¥2,100,000)
Keywordsナノサイズゼオライト / ZSM-5 ゼオライト / 界面活性剤 / 酸点不活性化フェニルシラン系化合物 / 低級オレフィン / プロピレン / イソブテン / ZSM-5ゼオライト / 酸点不活性化 / フェニルシラン系化合物 / ゼオライト / ZSM-5 / ナノクリスタル / オレフィン / 外表面酸点
Research Abstract

アセトンからプロピレンを含む低級オレフィンを選択的に合成する触媒の開発を実施した.申請者が開発した,水/界面活性剤/有機溶媒溶液を反応場としたゼオライトナノクリスタル合成法により,結晶サイズが約50nm〜70nm のZSM-5 ゼオライトナノクリスタルを合成した.同ゼオライトの結晶外表面上の酸点,あるいは結晶内クロスセクションの酸点を選択的に不活性化することで,低級オレフィン収率の向上に成功した.

Report

(3 results)
  • 2008 Annual Research Report   Final Research Report ( PDF )
  • 2007 Annual Research Report
  • Research Products

    (32 results)

All 2009 2008 2007 Other

All Journal Article (16 results) (of which Peer Reviewed: 14 results) Presentation (15 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] Preparation for Size-ControlledMOR Zeolite Nanocrystal using Water/Surfactant/Organic Solvent2009

    • Author(s)
      Tago T., Aoki D., Iwakai K., and Masuda T
    • Journal Title

      Topics in Catalysis 52

      Pages: 865-871

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of Mono-Dispersed Silicalite-1 Nanocrystals in Water-Surfactant-Organic Solvent2009

    • Author(s)
      Tago T., Iwakai K., Nishi M., and Masuda T
    • Journal Title

      J. Nanosc. Nanotechnol 9(1)

      Pages: 612-617

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of MonoDispersed Silicalite-1 Nanocrystals in WaterSurfactant-Organic Solvent2009

    • Author(s)
      Tago T., Iwakai K., Nishi M., and Masuda T.
    • Journal Title

      Journal of Nanoscience and Nanotechnology 9(1)

      Pages: 612-617

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Preparation for SizeControlled MOR Zeolite Nanocrystal using Water/Surfactant/Organic Solvent2009

    • Author(s)
      Tago T., Aoki D., Iwakai K., an d Masuda T.
    • Journal Title

      Topics in Catalysis (印刷中)

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Measurement of Intracrystalline Diffusivity of Benzene within MFI-type Zeolite from Bulk Benzene/Cyclohexane Liquid Phase2008

    • Author(s)
      Nakasaka Y., Tago T., Odate K., Masuda T
    • Journal Title

      Micropor. Mesopor. Mater 112

      Pages: 162-169

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] ゼオライトナノクリスタル新規合成法の開発2008

    • Author(s)
      多湖輝興, 岩貝和幸, 増田隆夫
    • Journal Title

      ケミカルエンジニヤリング 53(6)

      Pages: 432-439

    • Related Report
      2008 Final Research Report
  • [Journal Article] Preparation of hydrophilic silicalite-1 nanocrystal-layered membranes and their application to separating water from water-acetone solution2008

    • Author(s)
      Tago T., Nakasaka Y., Kayoda A., and Masuda T
    • Journal Title

      Micropor. Mesopor. Mater 115

      Pages: 176-183

    • NAID

      120000947381

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Measurement of Intracrystalline Diffusivity of Benzene within MFI-type Zeolite from Bulk Benzene/Cyclohexane Liquid Phase2008

    • Author(s)
      Nakasaka Y., Tago T., Odate K., Masuda T.
    • Journal Title

      Microporous and Mesoporous Materials 112

      Pages: 162-169

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Preparation of hydrophilic silicalite-1 nanocrystallayered membranes and their application to separating water from wateracetone solution2008

    • Author(s)
      Tago T., Nakasaka Y., Kayoda A., and Masuda T.
    • Journal Title

      Microporous and Mesoporous Materials 115

      Pages: 176-183

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of Mono-Dispersed Silicalite-1 Nanocrystals in Water-Surfactant-Organic Solvent2008

    • Author(s)
      Teruoki Tago, Kazuyuki Iwakai, Mieko Nishi, and Takao Masuda
    • Journal Title

      Journal of Nanoscience and Nanotechnology (印刷中)

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Preparation of hydrophilic silicalite-1 nanocrystal-layered membrane for separation of water from water-acetone solution by pervaporation2007

    • Author(s)
      Tago T., Nakasaka Y., Kayouda A. and Masuda T
    • Journal Title

      Separation & Purification Technology 58

      Pages: 7-11

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] ゼオライトナノクリスタル新規合成法の開発とアセトンからのオレフィン選択合成2007

    • Author(s)
      多湖輝興, 岩貝和幸, 坂元真梨子, 増田隆夫
    • Journal Title

      触媒 49(6)

      Pages: 495-497

    • NAID

      10019844700

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] ミクロ、メソ多孔体内の気・液相内の拡散機構2007

    • Author(s)
      中坂佑太, 多湖輝興, 矢野一久, 増田隆夫
    • Journal Title

      膜 32(6)

      Pages: 332-339

    • NAID

      10019981114

    • Related Report
      2008 Final Research Report
  • [Journal Article] Preparation of hydrophilic silicalite-1 nanocrystal-layered membrane for separation of water from water-acetone solution by pervaporation2007

    • Author(s)
      Tago T., Nakasaka Y., Kayouda A and Masuda T
    • Journal Title

      Separation & Purification Tecnology 58

      Pages: 7-11

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] ゼオライトナノクリスタル新規合成法の開発とアセトンからのオレフィン選択合成2007

    • Author(s)
      多湖輝興・岩貝和幸・坂元真梨子・増田隆夫
    • Journal Title

      触媒 49

      Pages: 495-497

    • NAID

      10019844700

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Control of Acid-Site Location of MFI Zeolite by Catalytic Cracking of Silane and its Application to Olefin Synthesis from Acetone

    • Author(s)
      Tago T., Sakamoto M., Iwakai K., Nishihara H., Mukai S.R., Tanaka T. and Masuda T
    • Journal Title

      J. Chem. Eng. Jpn (印刷中)

    • NAID

      130000142675

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Presentation] Measurement of liquid phase benzene diffusivity within porous materials using Raman spectroscopy2008

    • Author(s)
      Y. Nakasaka, T. Tago, K. Yano and T. Masuda
    • Organizer
      21th International Symposium on Chemical Engineering
    • Place of Presentation
      Saga, Saga University, Japan
    • Related Report
      2008 Final Research Report
  • [Presentation] Preparation of ZSM-5 nanocrystal-layered membrane and its application to MTO reaction2008

    • Author(s)
      K. Iwakai, T. Tago and T. Masuda
    • Organizer
      21th International Symposium on Chemical Engineering
    • Place of Presentation
      Saga, Saga University, Japan
    • Related Report
      2008 Final Research Report
  • [Presentation] Preparation of nano-crystalline BEA type zeolite by hydrothermal synthesis in water/surfactant/organic solvent2008

    • Author(s)
      A. Hyojo, D. Aoki, K. Iwakai, T. Tago and T. Masuda
    • Organizer
      21th International Symposium on Chemical Engineering
    • Place of Presentation
      Saga, Saga University, Japan
    • Related Report
      2008 Final Research Report
  • [Presentation] Olefin synthesis from acetone over BEA zeolite2008

    • Author(s)
      S. Ikeda, M. Sakamoto, H. Konno, T. Tago and T. Masuda
    • Organizer
      21th International Symposium on Chemical Engineering
    • Place of Presentation
      Saga, Saga University, Japan
    • Related Report
      2008 Final Research Report
  • [Presentation] Control of Acid-Site Location of MFI zeolite by Catalytic Cracking of Silane and its Application of olefin Synthesis from Acetone2008

    • Author(s)
      T. Tago, M. Sakamoto, K. Iwakai1, H. Nishihara, S. R. Mukai, T. Tanaka and T.Masuda
    • Organizer
      20th International Symposium on Chemical Reaction Engineering
    • Place of Presentation
      Kyoto, Kyoto International Conference Center, Japan
    • Related Report
      2008 Final Research Report
  • [Presentation] Liquid phase Diffusivity of Benzene within Mesoporous Materials Measured by Laser Raman Technique2008

    • Author(s)
      Y. Nakasaka, T. Tago, K. Yano and T. Masuda
    • Organizer
      20th International Symposium on Chemical Reaction Engineering
    • Place of Presentation
      Kyoto, Kyoto International Conference Center, Japan
    • Related Report
      2008 Final Research Report
  • [Presentation] Synthesis of hydrophilic silicalite-1 nanocrystal-layered membranes for separation of water from aqueous alcohol solutions by pervaporation2008

    • Author(s)
      Y. Nakasaka, T. Tago, T. Ichikawa, and T. Masuda
    • Organizer
      10th International Conferences on Inorganic Membranes
    • Place of Presentation
      Tokyo, Waseda University, Japan
    • Related Report
      2008 Final Research Report
  • [Presentation] Synthesis of Nano-Sized MOR Zeolite in Water/Surfactant/Organic Solvent2008

    • Author(s)
      T. Tago, D. Aoki, M. Ohori, K. Iwakai, T. Masuda
    • Organizer
      ICC14 Pre-Symposium
    • Place of Presentation
      Kyoto, Kyoto University, Japan
    • Related Report
      2008 Final Research Report
  • [Presentation] Control of Acid-Site Location on MFI Zeolite by Catalytic Cracking of Silane and its Application to Olefin Synthesis from Acetone2008

    • Author(s)
      Tago T., Sakamoto M., Iwakail K., Nishihara H., Mukai S.R., T anaka T., and Masuda T.
    • Organizer
      20 th International Symposium on Chemical Reaction Engineering
    • Place of Presentation
      Kyoto International Conference Center, Kyoto, Japan
    • Related Report
      2008 Annual Research Report
  • [Presentation] Preparation of Mono-Dispersed MFI-type Zeolite Nanocrystals via Hydrothermal Synthesis in Water/Surfactant/Oil Solution2007

    • Author(s)
      K. Iwakai, D. Aoki, T. Tago and T. Masuda
    • Organizer
      20th International Symposium on Chemical Engineering
    • Place of Presentation
      Daejeon, Hanbat National University, Korea
    • Related Report
      2008 Final Research Report
  • [Presentation] In-situ measurement of intracrystalline diffusivity of benzene within silicalite-1 in liquid phase2007

    • Author(s)
      Y. Nakasaka, T. Tago, K. Odate and T. Masuda
    • Organizer
      20th International Symposium on Chemical Engineering
    • Place of Presentation
      Daejeon, Hanbat National University, Korea
    • Related Report
      2008 Final Research Report
  • [Presentation] Preparation of hydrophilic silicalite-1 nanocrystal-layered membranes and their application to separating water from water-acetone solution2007

    • Author(s)
      T. Tago, A. Kayoda, K. Iwakai, Y. Nakasaka and T. Masuda
    • Organizer
      4th International Zeolite Membrane Meeting
    • Place of Presentation
      Zaragoza, University of ZaragozaSpain
    • Related Report
      2008 Final Research Report
  • [Presentation] Preparation of Size-controlled ZSM-5 Zeolite Nanocrystals via Hydrothermal Synthesis using Water/Surfactant/OilSolution2007

    • Author(s)
      T. Tago, K. Iwakai, M. Nishi and T. Masuda
    • Organizer
      11th Korean-Japan Symposium on Catalyst
    • Place of Presentation
      Seoul, Yonsei Univerisity, Korea
    • Related Report
      2008 Final Research Report
  • [Presentation] バイオマス由来アセトンからのオレフィン合成2007

    • Author(s)
      坂元真梨子・多湖輝興・増田隆夫
    • Organizer
      第100回触媒討論会
    • Place of Presentation
      北海道大学(札幌市)
    • Related Report
      2007 Annual Research Report
  • [Presentation] Preparation of Size-controlled ZSM-5 Zeolite Nanocrystals via Hydrothermal Synthesis using Water/Surfactant/Oil Solution2007

    • Author(s)
      Teruoki Tago, Kazuyuki Iwakai, Mieko Nishi and Takao Masuda
    • Organizer
      11th Korean-Japna Symbosium on Catalyst
    • Place of Presentation
      Yonsei Univ, Seoul, Korea
    • Related Report
      2007 Annual Research Report
  • [Patent(Industrial Property Rights)] バイオエタノールからのアセトン製造法2008

    • Inventor(s)
      増田隆夫・多湖輝興
    • Industrial Property Rights Holder
      北海道大学・日本碍子
    • Industrial Property Number
      2008-051498
    • Filing Date
      2008-03-03
    • Related Report
      2007 Annual Research Report

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Published: 2007-04-01   Modified: 2016-04-21  

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