Ate Base-Mediated Reactions : Origin of the Selectivity and Application for Creating Functional Aromatic Compounds
| Project/Area Number |
19790003
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Single-year Grants |
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| Research Field |
Chemical pharmacy
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| Research Institution | Nagoya University (2008-2009)
Tohoku University (2007) |
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Principal Investigator |
NAKA Hiroshi Nagoya University, 物質科学国際研究センター, 助教 (70431517)
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| Project Period (FY) |
2007 – 2009
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| Project Status |
Completed (Fiscal Year 2009)
|
| Budget Amount *help |
¥3,640,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥540,000)
Fiscal Year 2009: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2008: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2007: ¥1,300,000 (Direct Cost: ¥1,300,000)
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| Keywords | 有機反応学 / 金属錯体化学 |
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| Research Abstract |
The origin of the selectivity of alkylamido ate bases in directed ortho metalation has been investigated by means of spectroscopic and theoretical methods. Furthermore, efficient methods for the construction of functionalized aromatic compounds have been developed using ate complexes as chemoselective bases.
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Report
(4 results)
Research Products
(79 results)
